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JPS607350B2 - Fuel supply method for liquid fuel cells - Google Patents
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JPS607350B2 - Fuel supply method for liquid fuel cells - Google Patents

Fuel supply method for liquid fuel cells

Info

Publication number
JPS607350B2
JPS607350B2 JP54143529A JP14352979A JPS607350B2 JP S607350 B2 JPS607350 B2 JP S607350B2 JP 54143529 A JP54143529 A JP 54143529A JP 14352979 A JP14352979 A JP 14352979A JP S607350 B2 JPS607350 B2 JP S607350B2
Authority
JP
Japan
Prior art keywords
fuel
chamber
air
supply method
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP54143529A
Other languages
Japanese (ja)
Other versions
JPS5667172A (en
Inventor
達志 杉本
富夫 原
勲 荒巻
清 井沢
弘毅 田村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Resonac Corp
Original Assignee
Hitachi Ltd
Shin Kobe Electric Machinery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd, Shin Kobe Electric Machinery Co Ltd filed Critical Hitachi Ltd
Priority to JP54143529A priority Critical patent/JPS607350B2/en
Publication of JPS5667172A publication Critical patent/JPS5667172A/en
Publication of JPS607350B2 publication Critical patent/JPS607350B2/en
Expired legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04186Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
  • Degasification And Air Bubble Elimination (AREA)

Description

【発明の詳細な説明】 本発明はヒドラジン空気又は酸素燃料電池、メタノール
空気又は酸素燃料電池などの燃料溶解形燃料電池に関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to fuel soluble fuel cells such as hydrazine air or oxygen fuel cells and methanol air or oxygen fuel cells.

本発明者等は先に燃料熔解形燃料電池における燃料供給
方法としてト多孔質の絶縁体又は金属からなる燃料フィ
ル夕を用いることを提案した。
The present inventors previously proposed the use of a fuel filter made of a porous insulator or metal as a fuel supply method for a fuel melting type fuel cell.

この方法は、電解液と燃料の混合溶液(以下「ァノラィ
ト」と呼ぶ。)を燃料室で静止させる液静止形で従来か
ら用いられている燃料供給チューブによって燃料を燃料
室へ供給する方法と比較して、電池本体の各単電池への
均一供給の点で顕著な効果が認められた。また、アノラ
ィトをポンプで循環する液循環形においても同様の効果
が認められ、燃料供給の負荷追随性も改善された。しか
し、燃料フィル夕の形状が「先に提案した四角形の形状
の場合、燃料の分解ガスが燃料フィル夕の下部に提補し
、電池を長時間運転する場合、各単電池への燃料の供給
が不均一になることがいましば生じた。本発明はトこれ
らの欠点を解決する燃料フィル夕を用いた液体燃料電池
の燃料供給方法を提供するものである。
This method is compared to the method of supplying fuel to the fuel chamber using a fuel supply tube, which is a liquid stationary type that keeps a mixed solution of electrolyte and fuel (hereinafter referred to as "anolite") stationary in the fuel chamber. A remarkable effect was observed in terms of uniform supply of the battery body to each unit cell. Similar effects were also observed in the liquid circulation type, in which the anolyte was circulated by a pump, and the load followability of the fuel supply was also improved. However, if the shape of the fuel filter is the rectangular shape proposed earlier, the decomposed gas of the fuel will be supplied to the bottom of the fuel filter, and if the battery is operated for a long time, the fuel will not be supplied to each unit cell. The present invention provides a method for supplying fuel to a liquid fuel cell using a fuel filter, which solves these drawbacks.

次に本発明の詳細について説明する。第竃図は従来の四
角形の形をした燃料フィル夕を有する液静止形のヒドラ
ジン空気燃料電池を示したものである。
Next, details of the present invention will be explained. Figure 1 shows a conventional liquid stationary hydrazine air fuel cell having a square shaped fuel filter.

1‘まヒドラジン極「 4は空気極、5は電解液室であ
る。
1' is the hydrazine electrode, 4 is the air electrode, and 5 is the electrolyte chamber.

燃料室3に燃料であるヒドラジンを空気室8に空気を供
給することにより、ヒドラジンと空気中の酸素の電気化
学的反応から電気ェネルギを取り出すことができる。空
気は空気供給口9から空気室8に供給され、空気排出口
首蟹より排出される。ヒドラジンは燃料流路をよりト燃
料フィル6を通して燃料室3に供給される。また「 ヒ
ドラジンと酸素の電気化学的反応において生成するガス
はガス排出口電軍より排気される。第2図は燃料室枠2
の平面図である。燃料室枠2の内部を切抜いた部分は燃
料室8であり、上部にガス排出ロー百を、上部右側に空
気排気出口18「下部左側に空気供給口を設けてある。
燃料流路孔ま下部に設け「多孔質の燃料フィル夕げま燃
料室3と燃料流路?を流体接続するように枠中に接着保
持されている。このような四角形の形状をした燃料フィ
ル夕では第3図に示したように「燃料分解ガス亀2が燃
料フィル夕の表面に停滞し〜燃料の供給に支障をきたす
ようになる。第4図は下方へ突部を有し「その突部を燃
料中へ浸債するようにした本発明になる燃料フィル夕の
一実施例である。
By supplying hydrazine, which is a fuel, to the fuel chamber 3 and air to the air chamber 8, electrical energy can be extracted from the electrochemical reaction between hydrazine and oxygen in the air. Air is supplied to the air chamber 8 from the air supply port 9 and is discharged from the air discharge port. Hydrazine is supplied to the fuel chamber 3 through a fuel filter 6 through a fuel flow path. In addition, ``The gas generated in the electrochemical reaction of hydrazine and oxygen is exhausted from the gas outlet electric arm.Figure 2 shows the fuel chamber frame 2.
FIG. A cutout inside the fuel chamber frame 2 is the fuel chamber 8, which has a gas exhaust row at the top, an air exhaust outlet 18 at the top right, and an air supply port at the bottom left.
A porous fuel filter is provided at the bottom of the fuel channel hole and is adhesively held in the frame to fluidically connect the fuel chamber 3 and the fuel channel. In the evening, as shown in Figure 3, the fuel decomposition gas 2 stagnates on the surface of the fuel filter and becomes a hindrance to the fuel supply. This is an embodiment of a fuel filter according to the present invention in which a protrusion is immersed into fuel.

第5図ト第8図。第7図、第8図、第9図、第畳0図は
本発明になる燃料フィル夕の代表的な形状を示したもの
であるが「 この限りではない。このような形状をした
燃料フィル夕を用いることによりも燃料分解ガスが表面
の一部に停滞しても、突起部の停滞しない部分を通り燃
料を矢印のように均一に供給することが可能となる。
Figures 5 and 8. Although Figures 7, 8, 9, and 0 show typical shapes of the fuel filter according to the present invention, the present invention is not limited to this. Even if the fuel decomposition gas stagnates on a part of the surface, the fuel can be uniformly supplied as shown by the arrow through the portion of the protrusion where it does not stagnate.

【図面の簡単な説明】[Brief explanation of the drawing]

第言図は従来の形状をもった多孔質の燃料フィル夕を有
する液静止形のヒドラジン空気燃料電池〜第2図は燃料
室枠の平面図、第3図は第2図の燃料フィルタ下部に分
解ガスが停滞した図、第4図は本発明になる燃料フィル
夕の一実施例の図L第5図「第6図t第7図「第8図「
第9図「第亀鰭図は本発明になる燃料フィル夕の代表的
な形状を示す図である。 2は燃料室枠「 3は燃料室〜 6は燃料フィルタト7
は燃料流路。 第亀図 第2図 第3図 第4図 第馬図 第鱈図 第?図 第舞図 第9図 第的図
Figure 2 shows a static type hydrazine-air fuel cell with a porous fuel filter having a conventional shape - Figure 2 is a plan view of the fuel chamber frame, and Figure 3 shows the lower part of the fuel filter in Figure 2. Figure 4 shows an embodiment of the fuel filter according to the present invention.
FIG. 9 is a diagram showing a typical shape of a fuel filter according to the present invention. 2 is a fuel chamber frame, 3 is a fuel chamber, and 6 is a fuel filter 7.
is the fuel flow path. Figure 2 Turtle Figure 3 Figure 4 Horse Figure Cod Figure ? Figure No. 9 Figure 9

Claims (1)

【特許請求の範囲】[Claims] 1 電解液と燃料の混合溶液を燃料室で静止させ、燃料
室に燃料のみを供給するか、該混合溶液をポンプで燃料
室に供給するようにした液体燃料電池において、該燃料
室を形成する燃料室枠に燃料流路を備え、燃料の流れと
平行で燃料流路内に突起した多孔質燃料フイルタを介し
て該燃料室と該燃料流路を流体接続させることにより、
燃料の分解ガスのフイルタ面の停滞による燃料供給の妨
害を除去するようにしたことを特徴とする液体燃料電池
の燃料供給方法。
1. In a liquid fuel cell in which a mixed solution of electrolyte and fuel is kept stationary in a fuel chamber and only fuel is supplied to the fuel chamber, or the mixed solution is supplied to the fuel chamber with a pump, the fuel chamber is formed. By providing a fuel flow path in the fuel chamber frame and fluidly connecting the fuel chamber and the fuel flow path via a porous fuel filter that is parallel to the flow of fuel and protrudes into the fuel flow path,
A fuel supply method for a liquid fuel cell, characterized in that interference with fuel supply due to stagnation of fuel decomposition gas on a filter surface is eliminated.
JP54143529A 1979-11-06 1979-11-06 Fuel supply method for liquid fuel cells Expired JPS607350B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP54143529A JPS607350B2 (en) 1979-11-06 1979-11-06 Fuel supply method for liquid fuel cells

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54143529A JPS607350B2 (en) 1979-11-06 1979-11-06 Fuel supply method for liquid fuel cells

Publications (2)

Publication Number Publication Date
JPS5667172A JPS5667172A (en) 1981-06-06
JPS607350B2 true JPS607350B2 (en) 1985-02-23

Family

ID=15340854

Family Applications (1)

Application Number Title Priority Date Filing Date
JP54143529A Expired JPS607350B2 (en) 1979-11-06 1979-11-06 Fuel supply method for liquid fuel cells

Country Status (1)

Country Link
JP (1) JPS607350B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61201961A (en) * 1985-03-05 1986-09-06 Koito Mfg Co Ltd Drive mechanism
JPH01141594U (en) * 1988-03-15 1989-09-28

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61201961A (en) * 1985-03-05 1986-09-06 Koito Mfg Co Ltd Drive mechanism
JPH01141594U (en) * 1988-03-15 1989-09-28

Also Published As

Publication number Publication date
JPS5667172A (en) 1981-06-06

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