JPS608280B2 - dry cleaning agent - Google Patents
dry cleaning agentInfo
- Publication number
- JPS608280B2 JPS608280B2 JP21415582A JP21415582A JPS608280B2 JP S608280 B2 JPS608280 B2 JP S608280B2 JP 21415582 A JP21415582 A JP 21415582A JP 21415582 A JP21415582 A JP 21415582A JP S608280 B2 JPS608280 B2 JP S608280B2
- Authority
- JP
- Japan
- Prior art keywords
- cleaning agent
- dry cleaning
- silica particles
- cleaning
- carpet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012459 cleaning agent Substances 0.000 title claims description 20
- 238000005108 dry cleaning Methods 0.000 title claims description 13
- 239000000835 fiber Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- 239000007844 bleaching agent Substances 0.000 claims description 3
- 239000007850 fluorescent dye Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000645 desinfectant Substances 0.000 claims description 2
- 230000005484 gravity Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 description 15
- 239000000758 substrate Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 241000252233 Cyprinus carpio Species 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 241000931705 Cicada Species 0.000 description 2
- 241000270666 Testudines Species 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 244000144992 flock Species 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 241001556567 Acanthamoeba polyphaga mimivirus Species 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000269820 Euthynnus affinis Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical compound ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 241000269851 Sarda sarda Species 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- -1 nonionic Chemical group 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 210000000689 upper leg Anatomy 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】
本発明の乾式掃除剤は洗剤と適度の水分等を含む粉体等
を汚染物上に撒き、これをブラシで汚染物に擦り込み2
0〜3び分乾燥後、バキューム・クリーナで吸取って掃
除する所語乾式クリーニングに類する掃除用の材料に関
するものである。DETAILED DESCRIPTION OF THE INVENTION The dry cleaning agent of the present invention is prepared by sprinkling a powder containing detergent and an appropriate amount of moisture on a contaminated object, and then rubbing it into the contaminated object with a brush.
This relates to a cleaning material similar to dry cleaning, which is performed by drying for 0 to 3 minutes and then sucking it up with a vacuum cleaner.
本発明の掃除剤は主にカーペット類に使用されるが、た
たみ、レザー、タイル、化粧モルタル、毛皮等にも広く
使用することができる特徴を有する。The cleaning agent of the present invention is mainly used for carpets, but has the characteristic that it can be widely used for tatami mats, leather, tiles, decorative mortar, fur, etc.
本発明の乾式掃除剤を構成する担体はモース硬度4.5
〜5、粒子強度3.5%以下、粒径10〜200ムのシ
リカ粒子と長さ10〜200一の有機質の短繊維よりな
る。The carrier constituting the dry cleaning agent of the present invention has a Mohs hardness of 4.5.
~5. Consisting of silica particles with a particle strength of 3.5% or less and a particle size of 10 to 200 mm and organic short fibers with a length of 10 to 200 mm.
茂式掃除剤を用いる場合、洗浄する基材たとえばカーペ
ットの中にも毛と化繊においては機械的摩耗度が異なり
、それに応じて使いわけなければならない。When using a Shigeru type cleaning agent, the degree of mechanical abrasion differs between hair and synthetic fibers of the substrate to be cleaned, such as carpet, and it must be used accordingly.
すなわち硬質な硬度を有する担体で造られた乾式掃除剤
は洗浄力に対し優れた効果を発揮するが、カーペットを
損傷する危険性がある。一方、欧質の硬度を有する担体
で造られた乾式掃除剤はカーペットを損傷する危険はな
いが、洗浄力において問題を生ずる。このような観点か
ら、本発明者等はあらゆる基材に対して損傷を与えず、
しかも優れた洗浄力を有する乾式掃除剤を得るため、鋭
意研究した結果モース硬度4〜4.5、粒子強度3.5
%以下、粒径10〜200山のシリカ粒子と長さ10〜
200〃の有機質の短繊維とを洗浄すべき基材に応じて
最適の割合に混合してなる平均見掛比重0.2〜0.8
平均最大含水率50〜300%の多孔性の担体を用いる
ことにより、従来にない優れた洗浄力を有し、しかも基
村を損傷しない洗浄剤を造ることに成功した。That is, a dry cleaning agent made of a carrier having hardness exhibits an excellent effect on cleaning power, but there is a risk of damaging the carpet. On the other hand, dry cleaning agents made with carriers having European hardness pose no risk of damaging carpets, but do pose problems in cleaning power. From this point of view, the present inventors have developed a method that does not cause damage to any base material,
Moreover, in order to obtain a dry cleaning agent with excellent cleaning power, we conducted extensive research and found that the Mohs hardness is 4-4.5 and the particle strength is 3.5.
% or less, silica particles with a particle size of 10 to 200 peaks and a length of 10 to 200
An average apparent specific gravity of 0.2 to 0.8 made by mixing 200% organic short fibers in an optimal ratio depending on the substrate to be cleaned.
By using a porous carrier with an average maximum moisture content of 50 to 300%, we succeeded in creating a cleaning agent that has unprecedented cleaning power and does not damage the base.
すなわち本発明の乾式掃除剤はこれを基材(たとえばカ
ーペット)に撒きブラシ等で擦り込む時、担体中の硬質
系成分のシリカ粒子(モース硬度4〜4.5)と軟質系
成分の有機質の短繊維とが浸り合い、硬質成分の強力な
洗浄力を保持しつつ、軟質成分の働きにより基材を保護
する理想の洗浄剤である。尚本発明担体の成分であるシ
リカ粒子と有機質の短繊維との配合割合はカーペット繊
維及びカーペットの織り方等により異なるが、粒子強度
3.5%以下のシリカ成分に対し有機質の短繊維成分は
5〜95の重量%、好ましくは20〜70の重量%であ
る。That is, when the dry cleaning agent of the present invention is sprinkled onto a substrate (for example, a carpet) and rubbed with a brush, the hard component silica particles (Mohs hardness 4 to 4.5) in the carrier and the soft component organic matter are mixed. It is an ideal cleaning agent that mixes with short fibers and maintains the strong cleaning power of the hard components while protecting the base material through the action of the soft components. The blending ratio of silica particles and organic short fibers, which are components of the carrier of the present invention, differs depending on the carpet fibers and the weaving method of the carpet, but the organic short fiber component is 5 to 95% by weight, preferably 20 to 70% by weight.
一般に洗浄作業における洗浄効果は洗浄剤による化学的
な洗浄力と洗濯機、洗浄機、手、ブラシ等による物理的
な洗浄力との相乗効果によるものであり、その効果は夫
々が半々位であると言われている。In general, the cleaning effect in cleaning work is due to the synergistic effect of the chemical cleaning power of the cleaning agent and the physical cleaning power of the washing machine, washing machine, hands, brushes, etc., and the effectiveness of each is about 50-50. It is said that
本発明における乾式掃除剤担体においても上記の物理的
洗浄力を効果的に発揮するためには、洗浄する基材を傷
めない程度の硬質成分を配合し、基材に付着した汚れを
剥取ることで洗浄力を高め得ることができる。In order to effectively exhibit the above-mentioned physical cleaning power in the dry cleaning agent carrier of the present invention, it is necessary to mix a hard component to an extent that does not damage the substrate to be cleaned, and to peel off dirt attached to the substrate. can improve cleaning power.
また有機質の短繊維成分は硬質担体成分による物理的な
洗浄力により基材から剥離した汚れの拭き取り作用とカ
ーペット基材の保護的役割を行なうものである。本発明
の乾式掃除剤の坦体成分の配合割合はカーペットの繊維
及び綴り方等により異なり、例えば、純毛カーペットの
場合有機質の短繊維成分を主体に、又合成繊維、特にナ
イロン繊維の場合は硬質粒子成分を主体に配合すること
により優れた洗浄力効果とカーペット基材の保護効果が
得られる。Further, the organic short fiber component plays a role of wiping off dirt peeled off from the base material due to the physical detergency of the hard carrier component and protects the carpet base material. The blending ratio of the carrier component of the dry cleaning agent of the present invention varies depending on the fiber of the carpet and the method of binding. For example, in the case of pure wool carpet, organic short fiber components are the main component, and in the case of synthetic fibers, especially nylon fibers, hard fiber components are used. By blending mainly particle components, excellent detergency effects and carpet base protection effects can be obtained.
シリカ粒子のモース硬度4.5〜5(モース硬度計によ
り測定した)粒子強度3、5%以下(日本工業規格JI
SK1464工業用乾燥剤による)の規定は洗浄時にお
けるブラシ等による擦り洗いにより、シリカ粒子が粒径
10山以下の微粒子になるとカーペット等の洗浄すべき
基材の奥深く入り込み、容易の回収できなくなるためで
ある。Mohs hardness of silica particles is 4.5 to 5 (measured by Mohs hardness meter), particle strength is 3.5% or less (Japanese Industrial Standard JI
The regulations for SK1464 industrial desiccant) are because when scrubbing with a brush or the like during cleaning, if silica particles become fine particles with a particle size of 10 or less, they will penetrate deep into the substrate to be cleaned, such as carpets, and cannot be easily recovered. It is.
また有機質の短繊維成分としては例えば長さ10〜20
0仏、直径5〜50仏程度のパルプフロック(製紙用)
、人絹フロック、セルロシン等が用いられる。In addition, as an organic short fiber component, for example, the length is 10 to 20
Pulp flock (for paper making) with a diameter of 0 French and 5 to 50 French
, human silk flock, cellulosin, etc. are used.
次に坦体に含有せしめてなる洗浄としてはあらゆる種類
の界面活性剤(アニオン系、ノニオン系、カチオン系、
両性)、石鹸等が使用される。Next, all kinds of surfactants (anionic, nonionic, cationic,
amphoteric), soap, etc. are used.
さらにビルダー、溶剤、蛍光染料、酵素剤、漂白剤及び
殺菌剤等を適宜必要に応じて含有せしめることができる
。以下に洗浄力に優れ、基材を傷めない本発明の乾式掃
除剤の実施例として表1の処方例1〜8対称例として処
方例9〜12による掃除剤の性能試験の結果を表2に示
す。Furthermore, builders, solvents, fluorescent dyes, enzymes, bleaching agents, bactericidal agents, and the like can be contained as appropriate and necessary. Examples of dry cleaning agents of the present invention that have excellent cleaning power and do not damage substrates are listed below in Table 1 as Prescription Examples 1 to 8. Table 2 lists performance test results for cleaning agents based on Prescription Examples 9 to 12 as symmetrical examples. show.
これらの掃除剤はドライブレンダーを用いてシリカ粒子
と短繊維とを充分に混合した後、洗浄剤及び水を、更に
必要に応じてビルダー、溶剤、蛍光染料、酵素剤、漂白
剤及び殺菌剤等を加えて製造した。These cleaning agents are made by thoroughly mixing silica particles and short fibers using a dry blender, then adding detergent and water, and if necessary, builder, solvent, fluorescent dye, enzyme agent, bleach, disinfectant, etc. Manufactured by adding.
雌 き亀 −蓮 警官 ^ン ごう 彰( 【【 C、 山 三菜e − の日ミ(一 ゆ塚,A< 寸も 峰川トNf ^蓬日(ふ川 町 山 )の ′′′ ト m如く。female Turtle −Lotus police officer ^n Gou Akira ( [[C, mountain Sansai e- Sunmi (one) Yuzuka, A< Dimensions too Minekawa To Nf ^Fukawa Machiyama)'s ``To'' Like m.
人下。Underpeople.
い・l〇/、ご コ ミ n ^ 。I・l〇/、Thank you for your comment.
00」ー〉扇○ 胸鮒増? )四鎧)川S山 縄^ミミ0認〇 三d小l卜い態入 モ。00”ー〉Fan ○ More carp breast? ) Four Armors) Kawa S Mountain Rope ^ Mimi 0 approval 3d small size entry Mo.
lーィ縦もR。The vertical length is also R.
日日心地もめNミミ’‘鰹ミ 母ざココ叫峰ぐ 〇心い入○^ 山川ートト【地 ミゆン^三世櫨 。N Mimi'' Katsuomi My mother screams at me 〇My heart ○^ Toto Yamakawa [earth] Miyun ^ Sansei Haki .
略)こト繋町^トふへ/S 畑山HHコィ感 堤寸トトム川だ NOザザ三七ン 世(下下コキ○ 。(Omitted) Koto Tsunagi Town ^ Tofuhe/S Hatayama HH Koi feeling It's the Totom River. NO ZA ZA 37 World (down and down job○ .
コごい感日ミ熊鞄腿 。Kogoi Sensitive Mikuman's thighs .
)蓬蓬態HI…豊麗溝溝齢 紐ふ川川川対日 翼や洋様母船。) Penpenguo state HI…Fengliogougou age Himofu Kawakawa vs. Japan Tsubasa and Western-style motherships.
【寸にいめd【
出世母出世母母
性能試験
‘11 洗浄力試験法
東レ株式会社製ナイロンコントラクトカーベットCS−
200−2(ゴールド)と川島織物■社製純毛グッドマ
ン10カーペットGRに、日本油化学協会指定(注12
)の人工汚垢を東京電色■製しフレクト光沢計TC−脚
(グリーンフィルター使用)にて、未汚染カーペット1
00%反射率に対し、50%反射率となるよう、スポン
ジにて、カーペット表面に均一に塗り拡げるご汚染され
たカーペットを50×420柳(21000地)に切断
し、実施例1〜10の処方品及び対照例11〜12の処
方品を5夕の割合で均一に散布,し、ガードナー・スト
レート・ライン・ウオツシャビリテイー・アンド・アプ
レーション(注13)(ブタ宅ブラシの上に500夕の
鉛性の錘りを載せ、5抗団振動させて、同一条件にて洗
浄した後、力−べ・ット繊維の損傷性、回収性能、汚染
後と洗浄後の反射率をレフレクト反射光沢計にて測定し
た。[Suninime d] Performance Test '11 Cleaning Power Test Method Nylon Contract Carvet CS- manufactured by Toray Industries, Inc.
200-2 (gold) and Kawashima Orimono Pure Wool Goodman 10 Carpet GR, designated by Japan Oil Chemists Association (Note 12)
) on uncontaminated carpet 1 using Tokyo Denshoku's Flect Gloss Meter TC-leg (using a green filter).
Spread it evenly over the carpet surface with a sponge so that the reflectance is 50% compared to the 00% reflectance. The prescription products and the prescription products of Control Examples 11 to 12 were uniformly spread at a rate of 5 days, and Gardner Straight Line Washability and Appplication (Note 13) (on top of the pig house brush) was applied. After washing under the same conditions with a 500-meter lead weight and vibration, the damage properties, recovery performance, and reflectance after contamination and after washing of the fibers were measured. Measured using a reflection gloss meter.
(注一12)
汚垢組成
,カーーボン:ブラック(日本油化学協会指定)1
729極度硬化牛脂(IV5以下、mp57o0
程度)216タ流動パラフィン(試薬一級)
7.5夕四塩化エチレン(試薬一級) 15〆
(洋一13)米国ガードナーラボラトリーインコーポレ
ーション社製船岬
蓮ふ
庵ト
」蚕 上
灘gI
)奴
g布
霊や
蟹岬
筆置 き ‐
・りへ −
趣岬。(Note 12) Dirt composition, carbon: Black (designated by Japan Oil Chemists Association) 1
729 extremely hardened beef tallow (IV5 or less, mp57o0
degree) 216 ta liquid paraffin (reagent grade 1)
7.5 Ethylene Tetrachloride (Reagent Grade 1) 15〆 (Yoichi 13) Manufactured by Gardner Laboratory Inc., U.S.A. Funamaki Renfuanto' Silkworm Kaminada gI) Yag Furei and Crab Misaki Brush Holder Ki - Rihe - Cape Shu.
×篤蓮。×Atsuren.
ふ欄りS×ヤ窓鮒 べ積へ ,庭底総 」蚤芯(榊S峰山 時蝉磯中一時S 総#べ磯鰍球特 g洋」セ晒史球 り′WSVI史 」)鰹盤ど鮒l ヶg偽お蝉繁鮒 Y。Funeruri S×Yamado Carp To Bezumi, Niwaso Sou ” Flea Core (Sakaki S Mineyama Tokisemi Iso Junior High School S Total #beiso oyster ball special G-Yo” se exposed history ball ri'WSVI history ”) Bonito board do Carp Gag fake cicada carp Y.
広広燈凶総ー山叢る偽S偽
Rの遜り樋時Q
ト単鰍巽球時
)l回庇岬史郎
SC)〉篭Q史
繁昌岬噛る総代
蛤途単侍母蛾
鴎事ぽA ぷ亀
ミ感鎌」鎌 蓮○
主湊義孝竜霊と
主蝉置く鍵雫丈窓
・畑)総 g
皿L 舵 燈
米亀 鶏 鰹
寸町 ぬい ※
1丁 f f
幻出 出母
表2に示す如く本発明の乾式掃除剤は外観、散布性、回
収性、損傷性、洗浄効果の、全てにわたり優れた性能を
発揮した。Hirokotou Kousou - A mountain of false S False R's inferiority time Q Tomono Tatsumi ball time) 1 Eomisaki Shiro SC) 〉 Kagome Q history Shigemasaki biting general representative clam Tounan Samurai Moth Ojipo A Pukami Kankama" Sickle Lotus ○ Lord Minato Yoshitaka Ryūrei and the main cicada placed in a key drop-length window/field) Total g Plate L Rudder Tomai Turtle Chicken Bonito Suncho Nui * 1 knife f f Illusion Birth table 2 As shown in Figure 2, the dry cleaning agent of the present invention exhibited excellent performance in all aspects including appearance, dispersibility, recovery performance, damage resistance, and cleaning effect.
Claims (1)
径10〜200μのシリカ粒子と、該シリカ粒子に対し
て5〜950重量%の長さ10〜200μの有機質の短
繊維よりなり、平均見掛比重0.2〜0.8、平均最大
含水率50〜300%の担体に、該担体に対して0.0
1〜30重量%の洗浄剤及び20〜250重量%の水を
、更に必要に応じビルダー、溶剤、蛍光染料、酵素剤、
漂白剤及び殺菌剤の一種又は二種以上を含有せしめてな
る乾式掃除剤。1 From silica particles with a Mohs hardness of 4.5 to 5, a particle strength of 3.5% or less, and a particle size of 10 to 200μ, and organic short fibers with a length of 10 to 200μ, 5 to 950% by weight relative to the silica particles. 0.0 to a carrier with an average apparent specific gravity of 0.2 to 0.8 and an average maximum moisture content of 50 to 300%.
1 to 30% by weight of a cleaning agent and 20 to 250% by weight of water, and if necessary, a builder, a solvent, a fluorescent dye, an enzyme agent,
A dry cleaning agent containing one or more of bleach and disinfectant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21415582A JPS608280B2 (en) | 1982-12-07 | 1982-12-07 | dry cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21415582A JPS608280B2 (en) | 1982-12-07 | 1982-12-07 | dry cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59105100A JPS59105100A (en) | 1984-06-18 |
| JPS608280B2 true JPS608280B2 (en) | 1985-03-01 |
Family
ID=16651131
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21415582A Expired JPS608280B2 (en) | 1982-12-07 | 1982-12-07 | dry cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS608280B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61130400A (en) * | 1984-11-28 | 1986-06-18 | ユ−ホ−ケミカル株式会社 | Dry cleaning agent |
| JPS6225198A (en) * | 1985-07-25 | 1987-02-03 | ユ−ホ−ケミカル株式会社 | Bleaching detergent composition |
-
1982
- 1982-12-07 JP JP21415582A patent/JPS608280B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59105100A (en) | 1984-06-18 |
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