JPS6111903B2 - - Google Patents
Info
- Publication number
- JPS6111903B2 JPS6111903B2 JP13300176A JP13300176A JPS6111903B2 JP S6111903 B2 JPS6111903 B2 JP S6111903B2 JP 13300176 A JP13300176 A JP 13300176A JP 13300176 A JP13300176 A JP 13300176A JP S6111903 B2 JPS6111903 B2 JP S6111903B2
- Authority
- JP
- Japan
- Prior art keywords
- glaze
- parts
- emulsion
- added
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 claims description 33
- 229920000642 polymer Polymers 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 229920000126 latex Polymers 0.000 description 10
- 239000000919 ceramic Substances 0.000 description 9
- 239000004816 latex Substances 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- -1 Polyethylene Polymers 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920006173 natural rubber latex Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Description
【発明の詳細な説明】
本発明は釉薬の乾燥後の強度（生強度）の向上
とともに該釉薬の分散安定性を向上せしめるこを
目的とするものである。しかして本発明において
は該釉薬の乾燥後の強度（生強度）の向上のため
に高分子エマルジヨンを該釉薬に添加するもので
あるが、該釉薬は電解質を多種含むものでそれに
よつて高分子エマルジヨンが不安定になり更には
凝集するおそれがある。陶磁器素地に施釉するに
は浸し掛け、流し掛け、吹掛け等の方法がある
が、添加した高分子エマルジヨンが不安定になる
と釉薬の分散性が低下し施釉にむらを生じたり、
更に高分子エマルジヨンが凝集すれば施釉が出来
なくなると言つた不具合を生ずる。そのために該
釉薬をアルカリ性の状態にして高分子エマルジヨ
ンの安定化を図りかつ該釉薬の分散性を向上せし
めるのである。DETAILED DESCRIPTION OF THE INVENTION The object of the present invention is to improve the strength after drying (green strength) of a glaze as well as the dispersion stability of the glaze. However, in the present invention, a polymer emulsion is added to the glaze in order to improve the strength after drying (green strength), but the glaze contains various types of electrolytes, thereby increasing the polymer emulsion. The emulsion may become unstable and may even aggregate. There are methods such as dipping, pouring, and spraying to apply a glaze to a ceramic base, but if the added polymer emulsion becomes unstable, the dispersibility of the glaze decreases, resulting in uneven glazing.
Furthermore, if the polymer emulsion aggregates, there will be a problem that glazing will not be possible. For this purpose, the glaze is made alkaline to stabilize the polymer emulsion and improve the dispersibility of the glaze.
本発明を以下に詳細に説明する。 The present invention will be explained in detail below.
本発明に用いる釉薬とは鉛釉、フリツト釉、ブ
リストル釉、磁器釉等のすべての釉薬を含むもの
であり通常の水含有量は30〜55％である。 The glaze used in the present invention includes all glazes such as lead glaze, frit glaze, Bristol glaze, and porcelain glaze, and usually has a water content of 30 to 55%.
上記釉薬に添加する高分子エマルジヨンは例え
ばアクリル樹脂エマルジヨン、酢酸ビニル樹脂エ
マルジヨン、塩化ビニル樹脂エマルジヨン、塩化
ビニリデン樹脂エマルジヨン、弗化ビニル樹脂エ
マルジヨン、弗化ビニリデン樹脂エマルジヨン、
ポリエチレンエマルジヨン、ポリプロピレンエマ
ルジヨン、酢酸ビニル−エチレン共重合体エマル
ジヨン、天然ゴムラテツクス、スチレン−ブタジ
エンゴムラテツクス、アクリロニトリル−ブタジ
エンラテツクス、イソプレン−イソブテレンゴム
ラテツクス、イソブチレンゴムラテツクス、ポリ
ブタジエンラテツクス、ポリイソプレンラテツク
ス、ポリクロロプレンラテツクス、エチレン−プ
ロピレンラテツクス、エチレン−プロピレンター
ポリマーラテツクス等の合成樹脂、天然ゴム、合
成ゴム等の高分子の水性乳濁液をすべて含むもの
である。 Examples of the polymer emulsion to be added to the glaze include acrylic resin emulsion, vinyl acetate resin emulsion, vinyl chloride resin emulsion, vinylidene chloride resin emulsion, vinyl fluoride resin emulsion, vinylidene fluoride resin emulsion,
Polyethylene emulsion, polypropylene emulsion, vinyl acetate-ethylene copolymer emulsion, natural rubber latex, styrene-butadiene rubber latex, acrylonitrile-butadiene latex, isoprene-isobuterene rubber latex, isobutylene rubber latex, polybutadiene latex , synthetic resins such as polyisoprene latex, polychloroprene latex, ethylene-propylene latex, and ethylene-propylene terpolymer latex, and aqueous emulsions of polymers such as natural rubber and synthetic rubber.
上記高分子エマルジヨンは釉薬に対して固形分
対固形分として１〜10重量％（以下単に％とす
る）程度添加する。 The above-mentioned polymer emulsion is added to the glaze in an amount of about 1 to 10% by weight (hereinafter simply referred to as %) in terms of solid content.
高分子エマルジヨンはアルカリ性の状態におい
て該釉薬に添加混合せられる。このようにして得
られた釉薬組成物のPH値は望ましくは９以上、更
に望ましくは10以上である。アルカリ性の状態に
するには釉薬にアワモニア、カセイソーダ、カセ
イカリ、アミン等のアルカリを添加するか、また
は高分子エマルジヨンの製造前もしくは製造後に
あらかじめこれらアルカリを添加することによつ
て行われる。更に釉薬それ自体が充分アルカリ性
である時には、アルカリの添加は不用であること
は勿論のことである。 The polymer emulsion is added and mixed into the glaze under alkaline conditions. The pH value of the glaze composition thus obtained is preferably 9 or more, more preferably 10 or more. The alkaline state can be achieved by adding an alkali such as awamonia, caustic soda, caustic potash, or amine to the glaze, or by adding these alkalis before or after the production of the polymer emulsion. Furthermore, when the glaze itself is sufficiently alkaline, it goes without saying that addition of alkali is unnecessary.
本発明は上記構成を有するから釉薬組成物中の
高分子エマルジヨンはアルカリ性の状態において
凝集が防止されて安定化しており、かくして釉薬
の分散性も向上し良好な施釉作業性を示す。そし
て高分子エマルジヨンを釉薬に添加した場合には
該釉薬を陶磁器基地に施釉し乾燥した後の釉薬層
の強度、即ち焼成前の生釉強度および耐水性が向
上して生釉と生地、あるいは生地である上釉と下
釉もしくは中釉との密着性が向上し、もつて釉め
くれや欠け等が防止され、表面の仕上り状態が著
るしく改善されて不良品の発生を防止することが
出来る。そこで本発明の重要な効果として該生釉
素地に直接絵付けを行い焼成するいわゆる「オン
グレーズ」による絵付けが可能になるのである。
そして釉薬に高分子エマルジヨンを添加した場合
の大きな問題点である凝集を釉薬をアルカリ性に
することによつて防止し、該釉薬中の高分子エマ
ルジヨンを安定化させるとともに該釉薬自体の分
散性をも向上せしめ良好な施釉作業性を付与する
のである。 Since the present invention has the above configuration, the polymer emulsion in the glaze composition is prevented from agglomeration and stabilized in an alkaline state, thus improving the dispersibility of the glaze and exhibiting good glazing workability. When a polymer emulsion is added to a glaze, the strength of the glaze layer after applying the glaze to a ceramic base and drying, that is, the strength and water resistance of the raw glaze before firing, is improved, and the raw glaze and fabric or fabric are improved. This improves the adhesion between the top glaze and the bottom glaze or middle glaze, which prevents the glaze from peeling or chipping, significantly improves the surface finish, and prevents the occurrence of defective products. . Therefore, an important effect of the present invention is that it becomes possible to perform painting by so-called "on-glaze" in which the raw glaze is directly painted and fired.
By making the glaze alkaline, agglomeration, which is a major problem when adding polymer emulsion to glaze, is prevented, the polymer emulsion in the glaze is stabilized, and the dispersibility of the glaze itself is improved. This improves the workability of glazing.
本発明の釉薬組成物には高分子エマルジヨンの
他ポリビニルアルコール、ポリアクリル酸塩類、
ポリアクリルアミド、メチルセルロース、カルボ
キシメチルセルロース等の水溶性高分子、撥水
剤、顔料等が添加されてもよい。 In addition to the polymer emulsion, the glaze composition of the present invention includes polyvinyl alcohol, polyacrylates,
Water-soluble polymers such as polyacrylamide, methylcellulose, carboxymethylcellulose, water repellents, pigments, etc. may be added.
実施例 １
メチルメタクリルレート40重量部（以下単に部
とする）、エチルアクリレート60部の共重合体の
50％エマルジヨン２部を水35％を含む鉛釉100部
に添加し、カセイソーダによりPHを9.0とした。
しかして本釉薬組成物は極めて良好な分散性を示
し、施釉作業性も良好で陶磁器の素焼面に通常の
方法で均一に施釉され、かつ乾燥後の生強度は大
であつた。Example 1 A copolymer of 40 parts by weight of methyl methacrylate (hereinafter simply referred to as parts) and 60 parts of ethyl acrylate
Two parts of 50% emulsion were added to 100 parts of lead glaze containing 35% water, and the pH was brought to 9.0 with caustic soda.
The present glaze composition showed extremely good dispersibility, good workability in glazing, could be uniformly applied to the unglazed surface of ceramics by a conventional method, and had high green strength after drying.
実施例 ２
スチロール50部、ｎ−ブチルビニルエーテル50
部の共重合体の40％エマルジヨン５部を水40％を
含む鉛釉100部に添加し、アンモニア水によつて
PHを10.5とした。かかる鉛釉組成物は分散性良好
でしたがつて施釉作業性も良好であり陶磁器の素
焼面に施釉した場合の釉の生強度も大である。Example 2 Styrene 50 parts, n-butyl vinyl ether 50 parts
5 parts of 40% copolymer emulsion were added to 100 parts of lead glaze containing 40% water, and mixed with aqueous ammonia.
The pH was set to 10.5. Such a lead glaze composition had good dispersibility and therefore good workability in glazing, and the green strength of the glaze when applied to the unglazed surface of ceramics was also high.
実施例 ３
酢酸ビニル80部、ｎ−ブチルアクリレート20部
の共重合体の50％エマルジヨンを炭酸ソーダにて
PH9.8に調節して水50％を含む鉛釉100部に５部添
加するにPH9.4の釉薬組成物を得る。Example 3 A 50% emulsion of a copolymer of 80 parts of vinyl acetate and 20 parts of n-butyl acrylate was added to soda carbonate.
Adjust the pH to 9.8 and add 5 parts to 100 parts of lead glaze containing 50% water to obtain a glaze composition with a pH of 9.4.
実施例 ４
スチレン−ブタジエンゴムラテツクス（47％ゴ
ム分）３部を水50％を含むブリストル釉に添加
し、カセイカリにてPH10.0に調節する。かかるブ
リストル釉組成物は分散性良好でしたがつて施釉
作業性も良好であり、かつ施釉した際、釉の生強
度が大である。Example 4 Three parts of styrene-butadiene rubber latex (47% rubber content) are added to a Bristol glaze containing 50% water, and the pH is adjusted to 10.0 with caustic potash. Such a Bristol glaze composition had good dispersibility and therefore good workability in glazing, and when glazed, the green strength of the glaze was high.
実施例 ５
メチルメタクリルレート50部、ブチルメタクリ
ルレート45部、Ｎ−メチロールアクリルアミド５
部の共重合体の50％エマルジヨン10部を水40％を
含む鉛釉100部に添加しアンモニア水にてPH9.0と
した。しかして本釉薬組成物は分散性良好でした
がつて施釉作業性も良好であり、かつ施釉した際
釉の生強度が大であつた。この生釉上にハケおよ
びスクリーンにて絵付けを行い1200〜1300℃で焼
成し、鮮明な色調の陶磁器を得た。Example 5 50 parts of methyl methacrylate, 45 parts of butyl methacrylate, 5 parts of N-methylolacrylamide
10 parts of a 50% copolymer emulsion was added to 100 parts of lead glaze containing 40% water, and the pH was adjusted to 9.0 with aqueous ammonia. However, the present glaze composition had good dispersibility and therefore good workability in glazing, and the green strength of the glaze was high when glazed. Paintings were applied on this raw glaze using a brush and a screen and fired at 1,200 to 1,300°C to obtain ceramics with vivid colors.
実施例 ６
メチルメタクリルレート35部、エチルアクリレ
ート60部、グリシジル−メタクリルレート５部の
共重合体の50％エマルジヨンを水45％を含むPH
9.3磁器釉100部に10部加えPH9.1の釉薬組成物を
得た。この釉薬組成物を用い、陶磁器素焼き素地
に施釉し、ついで40℃にて３時間乾燥させたの
ち、生釉面に銅版転写により加飾し、1200〜1300
℃にて焼成したところ鮮明な発色の陶磁器を得
た。Example 6 A 50% emulsion of a copolymer of 35 parts of methyl methacrylate, 60 parts of ethyl acrylate, and 5 parts of glycidyl-methacrylate was added to a PH containing 45% of water.
9.3 Added 10 parts to 100 parts of porcelain glaze to obtain a glaze composition with a pH of 9.1. Using this glaze composition, glaze the unglazed ceramic base, dry it at 40℃ for 3 hours, and decorate the raw glaze surface by copper plate transfer.
When fired at ℃, ceramics with vivid colors were obtained.
実施例 ７
実施例６に用いた50％アクリルエマルジヨンを
水50％を含むPH9.5のフリツト釉10部に２部加
え、PH9.3の釉薬組成物を得た。Example 7 Two parts of the 50% acrylic emulsion used in Example 6 were added to 10 parts of a frit glaze with a pH of 9.5 containing 50% water to obtain a glaze composition with a pH of 9.3.
この釉薬組成物を用い陶磁器素焼き素地に施釉
しさらに施釉面に、水で４倍に希釈したアクリル
エマルジヨンを塗布し、これに水貼り用ビニール
転写紙絵柄を転写し1300℃にて焼成したところ鮮
明な発色の陶磁器を得た。 This glaze composition was used to glaze an unglazed ceramic base, and then an acrylic emulsion diluted 4 times with water was applied to the glazed surface. A vinyl transfer paper pattern for water application was transferred to this and fired at 1300℃. Ceramics with vivid colors were obtained.
Claims (1)
ルジヨンを添加混合したことを特徴とする釉薬組
成物。1. A glaze composition characterized by adding and mixing a polymer emulsion to a glaze in an alkaline state.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13300176A JPS5357213A (en) | 1976-11-04 | 1976-11-04 | Ceramic based mud |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13300176A JPS5357213A (en) | 1976-11-04 | 1976-11-04 | Ceramic based mud |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5357213A JPS5357213A (en) | 1978-05-24 |
| JPS6111903B2 true JPS6111903B2 (en) | 1986-04-05 |
Family
ID=15094457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13300176A Granted JPS5357213A (en) | 1976-11-04 | 1976-11-04 | Ceramic based mud |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5357213A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6252162A (en) * | 1985-08-29 | 1987-03-06 | 三井東圧化学株式会社 | Ceramic forming composition and ceramic formation therefrom |
| JPS61251557A (en) * | 1985-04-26 | 1986-11-08 | 名古屋油化株式会社 | Composition for china |
| CN108975879B (en) * | 2018-08-24 | 2021-06-04 | 王清霞 | Kiln-transmutation building cup firing process |
-
1976
- 1976-11-04 JP JP13300176A patent/JPS5357213A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5357213A (en) | 1978-05-24 |
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