JPS6124191B2 - - Google Patents
Info
- Publication number
- JPS6124191B2 JPS6124191B2 JP5728578A JP5728578A JPS6124191B2 JP S6124191 B2 JPS6124191 B2 JP S6124191B2 JP 5728578 A JP5728578 A JP 5728578A JP 5728578 A JP5728578 A JP 5728578A JP S6124191 B2 JPS6124191 B2 JP S6124191B2
- Authority
- JP
- Japan
- Prior art keywords
- head
- substrates
- nozzle
- metal
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/1623—Manufacturing processes bonding and adhesion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1607—Production of print heads with piezoelectric elements
- B41J2/161—Production of print heads with piezoelectric elements of film type, deformed by bending and disposed on a diaphragm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/164—Manufacturing processes thin film formation
- B41J2/1643—Manufacturing processes thin film formation thin film formation by plating
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Particle Formation And Scattering Control In Inkjet Printers (AREA)
Description
【発明の詳細な説明】
本発明はインクジエツト記録装置に関し、特に
そのヘツド部分の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an inkjet recording device, and particularly to a method for manufacturing a head portion thereof.
従来の衝撃式等の記録装置に変つて最近インク
ジエツト記録装置が注目され、数々の発表がなさ
れている。第1図はそれらの一例であり、インク
滴噴射ヘツド1は内部にインク室2が形成され、
このインク室2は管3によりインク供給源に結合
される。噴射ヘツド1の前面中央部分にはノズル
4が形成され、インク室2に結合されている。ま
た噴射ヘツド1の後部は振動板5で構成され、イ
ンク室2の後部壁を形成すると共に圧電振動子6
がこの振動板5に固着されている。今、圧電振動
子6にパルス状の電界を加えると、振動板5が変
形し、インク室は体積変化を起すためにインクが
圧力上昇し、ノズルよりインク粒となつて飛び出
す。このような構造のヘツドはサイズが比較的大
きく、特に多数のノズルを密集させてて配列し、
マルチノズルインク噴射ヘツドとする場合には、
小型化、コスト及び信頼度等の面で問題が生じ
る。 Recently, inkjet recording devices have been attracting attention in place of conventional impact type recording devices, and a number of publications have been made. FIG. 1 shows an example of such an ink droplet ejecting head 1, in which an ink chamber 2 is formed inside.
This ink chamber 2 is connected by a tube 3 to an ink supply source. A nozzle 4 is formed at the center of the front surface of the ejection head 1 and is connected to an ink chamber 2. The rear part of the injection head 1 is composed of a diaphragm 5, which forms the rear wall of the ink chamber 2 and a piezoelectric vibrator 6.
is fixed to this diaphragm 5. Now, when a pulsed electric field is applied to the piezoelectric vibrator 6, the diaphragm 5 is deformed and the volume of the ink chamber changes, causing the pressure of the ink to rise and eject as ink droplets from the nozzle. Heads with this type of structure are relatively large in size, and have a large number of nozzles arranged closely together.
When using a multi-nozzle ink ejection head,
Problems arise in terms of miniaturization, cost, reliability, etc.
本発明の目的は小型で信頼性にすぐれた安価な
ヘツドの製造方法を提供することにある。 SUMMARY OF THE INVENTION An object of the present invention is to provide a method for manufacturing a small, reliable, and inexpensive head.
本発明の他の目的は、前記の如くノズル密集度
の高いマルチノズルヘツドにも特に適したヘツド
の新構造を提供する点にある。 Another object of the present invention is to provide a new head structure particularly suitable for multi-nozzle heads with high nozzle density as described above.
本発明のインクジエツト記録装置のヘツドの製
造方法は、一対の基板の接合部にそれぞれ金属層
を形成し前記金属層の加熱溶着により前記基板を
接合し、前記基板間にインクが充填される圧力室
及び該圧力室に連通したノズルを形成し前記圧力
室に対応してて電気―機械変換素子を備えたイン
クジエツト記録装置のヘツドの製造方法として、
前記一方の基板には前記圧力室及びノズル対応形
状部の輪郭の外側部分に前記基板接合用の金属ハ
ンダ層を、前記輪郭部には前記輪郭線に沿つて金
属の突出部を形成し、前記他方の基板には前記輪
郭の外側部分に前記基板接合用の金属ハンダ層を
形成し、その後前記一対の基板を前記接合用の金
属ハンダ層同士の加熱溶着により接合し、前記基
板間に前記圧力室及びノズルを形成すると共に、
前記金属層の接合面の延長面を前記突出部に交差
させることを特徴とする。 A method for manufacturing a head of an inkjet recording device according to the present invention includes forming a metal layer on each joint portion of a pair of substrates, joining the substrates by heat welding the metal layers, and forming a pressure chamber between the substrates filled with ink. and a method for manufacturing a head of an inkjet recording device, which has a nozzle communicating with the pressure chamber and is equipped with an electro-mechanical conversion element corresponding to the pressure chamber.
On the one substrate, a metal solder layer for bonding the substrate is formed on an outer portion of the contour of the pressure chamber and nozzle corresponding shaped portion, a metal protrusion is formed on the contour portion along the contour line, and a metal protrusion is formed on the contour portion along the contour line. A metal solder layer for bonding the substrates is formed on the outer portion of the contour on the other substrate, and then the pair of substrates are bonded by heat welding the metal solder layers for bonding, and the pressure is applied between the substrates. While forming a chamber and a nozzle,
It is characterized in that an extension surface of the bonding surface of the metal layer intersects the protrusion.
以下、図面に従つて説明する。 This will be explained below with reference to the drawings.
第2図a,bは本発明のヘツド構成を説明する
ための基本図であり、11はガラス等の基板で、
12,13及び14は内部インク室(特に13は
圧電振動子により体積変化を起こさせるための圧
縮室、14はインクだめである)。15はノズル
となる部分でありこの形状を作るために斜線で示
した部分は厚さ数10μm〜数100μm程度にAu及
びSnメツキ16が施こされている。この形状は
例えば一旦基板片面に全面にメツキを施した後、
レジスト塗布、、露光等をするフオトエツチング
等の公知技術を用いて簡単に作成できる。 FIGS. 2a and 2b are basic diagrams for explaining the head configuration of the present invention, and 11 is a substrate made of glass or the like;
12, 13, and 14 are internal ink chambers (in particular, 13 is a compression chamber for causing a volume change by a piezoelectric vibrator, and 14 is an ink reservoir). Reference numeral 15 denotes a part that will become a nozzle, and to create this shape, the shaded part is plated with Au and Sn 16 to a thickness of about 10 μm to several 100 μm. For example, after plating the entire surface of one side of the board,
It can be easily created using known techniques such as resist coating, photoetching, etc.
第3図に本発明を用いたヘツドの組立方法を示
す。Au及びSnメツキされた第2図a,bに示す
如き下基板11と、全面もしくは下基板と対称形
状にAu及びSnメツキされた上基板21を重ね全
体を400゜〜500℃に加熱する。するとAu及びSn
メツキ部分は溶融し、強固なAu―Sn共晶を作
る。これにより上下の板は完全に接合され、Au
及びSnメツキでかこまれた部分は、内部インク
室、ノズル等の空間を形成する。なお、22は内
部インク室にインクを供給する孔であり、パイプ
23等によりインク供給源に結合する。また24
は圧電振動子で第2図のインク室13の直上に固
着され、電界により基板21を変形させインク室
13を圧縮する。従来マルチノズル噴射へツドと
して、セラミツク基板、ガラス基板等をエツチン
グにより加工して内部インク室、ノズル等を形成
する提案もなされているが、本発明はこれらの方
式に比し、信頼性の面で非常に有利である。 FIG. 3 shows a method of assembling a head using the present invention. A lower substrate 11 plated with Au and Sn as shown in FIGS. 2a and 2b and an upper substrate 21 plated with Au and Sn on the entire surface or in a shape symmetrical to the lower substrate are stacked and the whole is heated to 400° to 500°C. Then Au and Sn
The metal part melts and forms a strong Au-Sn eutectic. As a result, the upper and lower plates are completely joined, and the Au
The area surrounded by Sn plating forms a space for an internal ink chamber, a nozzle, etc. Note that 22 is a hole for supplying ink to the internal ink chamber, and is connected to an ink supply source through a pipe 23 or the like. 24 again
is a piezoelectric vibrator fixed directly above the ink chamber 13 in FIG. 2, and deforms the substrate 21 by an electric field to compress the ink chamber 13. Conventionally, there have been proposals to form internal ink chambers, nozzles, etc. by etching a ceramic substrate, a glass substrate, etc. as a multi-nozzle ejection head, but the present invention has improved reliability compared to these methods. is very advantageous.
以上は本発明の基本的な構成であるが、Au―
Sn共晶接合の詳細な説明とさらに改良されたヘ
ツド構成法について述べる。第4図a,bは、
Au―Sn共晶接合の方法を示し、第2図及び第3
図に示すヘツドの断面の一部を示す。下ガラス基
板11及び上ガラス基板21にAu及びSnメツキ
を施すための下地となるCr及びAuの蒸着膜31
を形成する。この蒸着膜は一旦基板全面に蒸着膜
を施し、レジスト塗布、露光等するフオトエツチ
ング法等によりノズル等に必要なパターンを形成
する。 The above is the basic configuration of the present invention.
A detailed explanation of Sn eutectic bonding and a further improved head construction method are presented. Figure 4 a and b are
The Au-Sn eutectic bonding method is shown in Figures 2 and 3.
2 shows a part of the cross section of the head shown in the figure. Cr and Au vapor deposited film 31 that serves as a base for applying Au and Sn plating to the lower glass substrate 11 and the upper glass substrate 21
form. This vapor-deposited film is once applied to the entire surface of the substrate, and a pattern required for the nozzle and the like is formed by a photo-etching method such as resist coating and exposure.
次に下ガラス基板の蒸着膜31の上にAuメツ
キ32、Snメツキ33を約8:2の重量比の割
合で施こし全体の厚みtを数10μm〜数100μm
とする(これは第2図のノズル15先端のサイズ
及び圧縮室13のサイズ等設計値によつて適当な
値をとる)。 Next, Au plating 32 and Sn plating 33 are applied on the vapor deposited film 31 of the lower glass substrate at a weight ratio of approximately 8:2, and the total thickness t is several tens of micrometers to several hundred micrometers.
(This is an appropriate value depending on design values such as the size of the tip of the nozzle 15 and the size of the compression chamber 13 in FIG. 2).
さらに上ガラス基板の前記下ガラス基板と対称
のパターンよりわずかに内側に入りこんだ蒸着膜
31上に、金メツキ34を前記下ガラス基板上の
Auメツキ32、Snメツキ33部分の内側の位置
となるように厚みt′(=t+数μm〜数10μm)
に施す。この上下ガラスをbのように重ね上下よ
り圧力を加え金メツキ34部分をt′−tの厚みの
差の分だ押しつぶすようにして、この部分を圧接
した後全体を400℃〜500℃に加熱するAuメツキ
31及びAuメツキ32部分及びAuメツキ34部
分とSnメツキ33部分の一部が溶融し強固なAu
―Sn共晶を形成し、上下ガラスが接合される。
Auメツキ部分34はこのときストツパーの役目
を果し、Au―Sn共晶がAuメツキ部分より内側に
流出するのを防ぎ空間35の形状は完全に保たれ
る。(空間35は特にノズル先端に於ては幅数10
μmの形状となり精密を要するので第3図を用い
て説明した方法に比し精度が保たれる。)
第5図はさらに改良されたヘツド構成法として
第3図に示した圧電振動子24を一体に形成した
例を示す。第2図〜第4図の方法で作成したヘツ
ド41上に共通電極42を蒸着等で作り、その上
に例えばZnOの膜43をスパツタ等の手段で均一
に付着する。ZnOは良い圧電材料として知られ、
しかも蒸着、スパツタ等の手段により薄膜化、厚
膜化できるので本実施例の如きヘツドをマルチノ
ズル化する場合は、駆動圧電振動子を一度に作り
込むことができ非常に有利な方法である。さてこ
のZnOの膜上に第2図の圧縮インク室13の位置
に対応する個所に蒸着等で対向電極44を作る。 Furthermore, gold plating 34 is applied on the vapor deposited film 31 on the upper glass substrate, which is slightly inward from the pattern symmetrical to the lower glass substrate.
Thickness t' (= t + several μm to several tens of μm) so that it is located inside the Au plating 32 and Sn plating 33 parts.
give to These upper and lower glasses are stacked as shown in b, and pressure is applied from above and below to crush the gold-plated 34 part by the difference in thickness between t' and t.After this part is pressed together, the whole is heated to 400℃ to 500℃. The parts of the Au plating 31, the Au plating 32, the Au plating 34, and the Sn plating 33 are melted and become solid Au.
- Forms Sn eutectic and joins the upper and lower glass.
At this time, the Au plating portion 34 serves as a stopper, preventing the Au-Sn eutectic from flowing inward from the Au plating portion, and the shape of the space 35 is maintained perfectly. (The space 35 has a width of several tens, especially at the tip of the nozzle.)
Since the shape is micrometer and requires precision, accuracy is maintained compared to the method explained using FIG. 3. ) FIG. 5 shows an example in which the piezoelectric vibrator 24 shown in FIG. 3 is integrally formed as a further improved head construction method. A common electrode 42 is formed by vapor deposition or the like on the head 41 prepared by the method shown in FIGS. 2 to 4, and a film 43 of, for example, ZnO is uniformly deposited thereon by means such as sputtering. ZnO is known as a good piezoelectric material,
Moreover, since the film can be made thinner or thicker by means such as vapor deposition or sputtering, when the head is made into a multi-nozzle structure as in this embodiment, it is a very advantageous method since the drive piezoelectric vibrator can be fabricated all at once. Now, on this ZnO film, a counter electrode 44 is formed by vapor deposition or the like at a location corresponding to the position of the compressed ink chamber 13 in FIG. 2.
インクを噴出させるための基板21の変形量は
微少でよいため、電極42,44間に電界を印加
しても電界が印加されない部分に影響を及ぼすこ
とはない。 Since the amount of deformation of the substrate 21 for ejecting ink may be minute, even if an electric field is applied between the electrodes 42 and 44, it will not affect the portions to which no electric field is applied.
なお本発明のAu―Sn共晶による接合方法はエ
ツチング等でインク室やノズルを形成した板の接
合にも応用することができる。 Note that the Au--Sn eutectic bonding method of the present invention can also be applied to bonding plates on which ink chambers and nozzles have been formed by etching or the like.
上記本発明によれば、一対の金属の接合部を両
基板に金属ハンダ層を形成し該金属ハンダ層の加
熱溶着により接合するが、基板の接合部に金属の
突出部を形成し、基板の接合後に金属ハンダ層の
溶着面の延長面が金属の突出部と交差するように
する。かかる金属の突出部は圧力室やノズルのイ
ンクの流路等のインクに接する側に形成され、そ
の外側に金属接合部が形成される。従つて、圧力
室やノズルにインクが充填される等しても、接合
面に直接インクが接触せず、必ず金属突出部でさ
えぎられることになるから、インクにより接合部
が侵され、接合の信頼性が非常に高く、反応性の
高いインクを使用したり、又は電気―機械振動素
子の振動が高周波である等しても、剥離等するこ
とがない。 According to the present invention, a pair of metals are joined by forming a metal solder layer on both substrates and heat welding the metal solder layer. After bonding, the extended surface of the welding surface of the metal solder layer intersects with the protrusion of the metal. Such a metal protrusion is formed on the side of the pressure chamber or the ink flow path of the nozzle that comes into contact with ink, and a metal joint is formed on the outside thereof. Therefore, even if the pressure chamber or nozzle is filled with ink, the ink will not come into direct contact with the joint surface and will always be blocked by a metal protrusion, so the joint will be attacked by the ink and the joint will be damaged. It has very high reliability and will not peel off even if highly reactive ink is used or the vibration of the electro-mechanical vibration element is high frequency.
第1図は従来のインクジエツト記録装置のヘツ
ドの構成例。第2図a,bは本発明のインクジエ
ツト記録装置のヘツドの基本説明図で、bはaの
A―A′断面。第3図a,bは本発明のインクジ
エツト記録装置のヘツドの組立図。第4図a,b
は本発明のインクジエツト記録装置のヘツドの組
立方法の断面図。第5図a,bはさらに改良され
た本発明のインクジエツト記録装置のヘツド構成
例。
1…ヘツド、2…インク室、3…管、4…ノズ
ル、5…振動板、6…圧電振動子、11…基板、
12,13,14…インク室、15…ノズル、1
6…Au及びSnメツキ、21…基板、22…孔、
23…パイプ、31…Cr及びAu蒸着膜、32…
Auメツキ、33…Snメツキ、34…Auメツキ、
35…空間、41…ヘツド、42…電極、43…
ZnOスパツタ膜、44…電極。
FIG. 1 shows an example of the configuration of a head of a conventional inkjet recording device. Figures 2a and 2b are basic explanatory views of the head of the inkjet recording apparatus of the present invention, and b is a cross section taken along line AA' of a. 3a and 3b are assembly diagrams of the head of the inkjet recording apparatus of the present invention. Figure 4 a, b
1 is a sectional view showing a method of assembling a head of an inkjet recording apparatus according to the present invention. FIGS. 5a and 5b show an example of the head configuration of a further improved inkjet recording apparatus of the present invention. DESCRIPTION OF SYMBOLS 1...Head, 2...Ink chamber, 3...Pipe, 4...Nozzle, 5...Vibration plate, 6...Piezoelectric vibrator, 11...Substrate,
12, 13, 14... Ink chamber, 15... Nozzle, 1
6...Au and Sn plating, 21...substrate, 22...hole,
23... Pipe, 31... Cr and Au vapor deposited film, 32...
Au plating, 33...Sn plating, 34...Au plating,
35... Space, 41... Head, 42... Electrode, 43...
ZnO sputtered film, 44...electrode.
Claims (1)
し前記金属層の加熱溶着により前記基板を接合
し、前記基板間にインクが充填される圧力室及び
該圧力室に連通したノズルを形成し前記圧力室に
対応して電気―機械変換素子を備えたインクジエ
ツト記録装置のヘツドの製造方法として、 前記一方の基板には前記圧力室及びノズル対応
形状部の輪郭の外側部分に前記基板接合用の金属
ハンダ層を、前記輪郭部には前記輪郭線に沿つて
金属の突出部を形成し、前記他方の基板には前記
輪郭の外側部分に前記基板接合用の金属ハンダ層
を形成し、その後前記一対の基板を前記接合用の
金属ハンダ層同士の加熱溶着により接合し、前記
基板間に前記圧力室及びノズルを形成すると共
に、前記金属層の接合面の延長面を前記突出部に
交差させることを特徴とするインクジエツト記録
装置のヘツドの製造方法。[Scope of Claims] 1. A metal layer is formed at each joining portion of a pair of substrates, and the substrates are joined by heat welding of the metal layers, and the space between the substrates is communicated with a pressure chamber filled with ink and the pressure chamber. A method for manufacturing a head of an inkjet recording device in which a nozzle is formed and an electro-mechanical transducer is provided corresponding to the pressure chamber, the one substrate is provided with an outer portion of the outline of the shaped portion corresponding to the pressure chamber and the nozzle. A metal solder layer for bonding the substrates is formed on the contour portion, a metal protrusion is formed along the contour line, and a metal solder layer for bonding the substrates is formed on the other substrate outside the contour. After that, the pair of substrates are bonded by heat welding the metal solder layers for bonding, and the pressure chamber and nozzle are formed between the substrates, and the extension surface of the bonding surface of the metal layer is exposed to the protrusion. 1. A method of manufacturing a head for an inkjet recording device, characterized in that the head is made to intersect with the head of the inkjet recording device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5728578A JPS54148533A (en) | 1978-05-15 | 1978-05-15 | Head of ink jet recorder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5728578A JPS54148533A (en) | 1978-05-15 | 1978-05-15 | Head of ink jet recorder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54148533A JPS54148533A (en) | 1979-11-20 |
| JPS6124191B2 true JPS6124191B2 (en) | 1986-06-10 |
Family
ID=13051261
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5728578A Granted JPS54148533A (en) | 1978-05-15 | 1978-05-15 | Head of ink jet recorder |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS54148533A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210181155A1 (en) * | 2018-09-03 | 2021-06-17 | Nskensa Co., Ltd. | Method for evaluating corroded part |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55118875A (en) * | 1979-03-07 | 1980-09-12 | Canon Inc | Method of fabricating multinozzle recording head |
| JPS579534U (en) * | 1980-06-19 | 1982-01-19 | ||
| JPS5793444U (en) * | 1980-12-01 | 1982-06-09 | ||
| DE3104077A1 (en) * | 1981-02-06 | 1982-09-09 | Philips Patentverwaltung Gmbh, 2000 Hamburg | "WRITING HEAD FOR INK JET PRINTER" |
| JPH0121800Y2 (en) * | 1981-04-06 | 1989-06-28 | ||
| JPS57163334U (en) * | 1981-04-07 | 1982-10-14 | ||
| JPS5817146U (en) * | 1981-07-27 | 1983-02-02 | 日本電気株式会社 | injection head |
| US8297742B2 (en) * | 2010-03-19 | 2012-10-30 | Fujifilm Corporation | Bonded circuits and seals in a printing device |
-
1978
- 1978-05-15 JP JP5728578A patent/JPS54148533A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210181155A1 (en) * | 2018-09-03 | 2021-06-17 | Nskensa Co., Ltd. | Method for evaluating corroded part |
| US11644445B2 (en) * | 2018-09-03 | 2023-05-09 | Kunihiko Niimi | Method for evaluating corroded part |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54148533A (en) | 1979-11-20 |
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