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JPS6131798B2 - - Google Patents
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JPS6131798B2 - - Google Patents

Info

Publication number
JPS6131798B2
JPS6131798B2 JP57033089A JP3308982A JPS6131798B2 JP S6131798 B2 JPS6131798 B2 JP S6131798B2 JP 57033089 A JP57033089 A JP 57033089A JP 3308982 A JP3308982 A JP 3308982A JP S6131798 B2 JPS6131798 B2 JP S6131798B2
Authority
JP
Japan
Prior art keywords
thermoelectric
heat exchanger
heat transfer
submodule
piece
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP57033089A
Other languages
Japanese (ja)
Other versions
JPS58153092A (en
Inventor
Kenichi Hirabayashi
Shigeru Muraki
Hideaki Sugiura
Tatsu Suga
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Agency of Industrial Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology
Priority to JP57033089A priority Critical patent/JPS58153092A/en
Publication of JPS58153092A publication Critical patent/JPS58153092A/en
Publication of JPS6131798B2 publication Critical patent/JPS6131798B2/ja
Granted legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/30Energy from the sea, e.g. using wave energy or salinity gradient

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Hybrid Cells (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Description

【発明の詳細な説明】 この発明は、熱電素子を利用して熱を直接電気
に変換するための熱電発電機用熱交換器に関す
る。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a heat exchanger for a thermoelectric generator for directly converting heat into electricity using thermoelectric elements.

新エネルギー開発および省エネルギー技術開発
の一環として、海底と海面の温度差の如く量は膨
大であつても温度差が小さく従来利用されなかつ
た熱の利用に関する研究開発が最近内外で活発に
行なわれている。このような低熱落差の熱を直接
電気に変換する技術に「熱電素子による発電」が
ある。
As part of the development of new energy and energy-saving technology, research and development has recently been actively conducted at home and abroad on the use of heat, which has a small temperature difference and has not been used before, even though the amount is enormous, such as the difference in temperature between the seabed and the sea surface. There is. ``Thermoelectric power generation'' is a technology that directly converts heat with such a low thermal drop into electricity.

熱電素子とは、熱電性能(熱を電気に変換する
性能)のすぐれたN型とP型の半導体であつて、
その一方の面を加熱し、他方の面を冷却するとそ
の温度差に従つて両面間に起電力が発生する。N
型とP型とで加熱、冷却面と起電力の方向との関
係は逆になる。したがつて、第1図に示す如く、
熱電素子1のP型の熱電素子P1,P2,………とN
型の熱電素子N1,N2,………とを交互に並べ、
隣り合つた熱電素子の2つずつを上側ではP1
N1,P2とN2,………、下側ではN1とP2,………
と言う具合に金属電極片2で千鳥に接続し、いず
れか一方の面の電極片を加熱し、他の面の電極片
を冷却する、換言すれば、P型、N型の熱電素子
を電気的に直列に、熱的には並列に接合してサブ
モジユールにまとめ、その一方の面を加熱し、他
方の面を冷却して両面間に温度差を与えると、両
端の熱電素子に接続された端子間に起電力が発生
する。この熱による直接的な電力の発生現象は、
ゼーベツク、ペルチエ、トムソンの3効果および
ジユール発熱、熱伝導という5つの基礎的な物理
現象が互いに密接にかかわり合つた結果現われる
ものである。
Thermoelectric elements are N-type and P-type semiconductors with excellent thermoelectric performance (ability to convert heat into electricity).
When one surface is heated and the other surface is cooled, an electromotive force is generated between the two surfaces according to the temperature difference. N
The relationship between the heating and cooling surfaces and the direction of the electromotive force is opposite between the type and the P type. Therefore, as shown in Figure 1,
P-type thermoelectric elements P 1 , P 2 , ...... and N of thermoelectric element 1
type thermoelectric elements N 1 , N 2 , ...... are arranged alternately,
Each two adjacent thermoelectric elements are designated as P 1 on the upper side.
N 1 , P 2 and N 2 , ......, N 1 and P 2 , ...... on the lower side
The metal electrode pieces 2 are connected in a staggered manner, and the electrode pieces on one side are heated and the electrode pieces on the other side are cooled. In other words, the P-type and N-type thermoelectric elements are heated. When they are assembled into submodules by connecting them physically in series and thermally in parallel, and heating one side and cooling the other side to create a temperature difference between the two sides, the thermoelectric elements connected to the thermoelectric elements at both ends An electromotive force is generated between the terminals. This direct power generation phenomenon due to heat is
It appears as a result of the close interaction of five fundamental physical phenomena: the Seebeck, Peltier, and Thomson effects, Joule heat generation, and heat conduction.

一例として、海洋温度領域において最も高性能
を発揮するとされているビスマス・テルル系熱電
素子により構成された熱電サブモジユールの例を
第2図a,b,c,dに示す。aは該サブモジユ
ールの上面、bは正面、cは下面、dは側面を示
す。熱電素子1は直径13mm、厚さ1.5mmの円板状
をなし、P型及びN型素子を10個、都合20個の素
子を図に示す如く2列に、各列ではP型とN型と
が交互に並び横断方向の2個はP型とN型とが並
ぶように配設し、銅板よりなる電極片2で上面で
は第2図aに示す如く横断方向に並んだP型N型
の2個ずつを接続し、下面では第2図cに示す如
く、モジユールの長手方向に隣合つたP型N型の
2個を練瓦積みの如く互い違いに接続し、両端の
下面に電極片2の付かない熱電素子の下面には電
極板2と同様の端子板3を接続して構成されてい
る。電極板2及び端子板3は電気的導体であると
同時に伝熱面とも成る。熱電サブモジユール4の
一方の面を加熱し、他の面を冷却するために、例
えば第3図に示す如く外面が平面より成り内面が
円筒状の四角管5,6が従来実験室規模の熱電発
電機用熱交換器に用いられた。第3図において四
角管5は低温パイプであり内部に冷水を流し、四
角管6は高温パイプであり、内部に温水を流して
いる。冷水と温水の流動方向は互いに逆方向とな
つており、こうすることにより熱電サブモジユー
ル4を介して低温パイプ5と高温パイプ6との間
で熱交換が行なわれる場合、温度差はどこも同じ
にすることができる。上述の低温パイプ5、サブ
モジユール4、高温パイプ6を順次多段に積重ね
ることにより任意の発電量を得ることが出来る。
As an example, examples of thermoelectric submodules constructed from bismuth-tellurium thermoelectric elements, which are said to exhibit the highest performance in the ocean temperature range, are shown in FIGS. 2a, b, c, and d. a indicates the top surface, b the front surface, c the bottom surface, and d the side surface of the submodule. The thermoelectric element 1 has a disk shape with a diameter of 13 mm and a thickness of 1.5 mm, and has 10 P-type and N-type elements, a total of 20 elements arranged in two rows as shown in the figure, and each row has P-type and N-type elements. The electrode pieces 2 are arranged in such a way that they are arranged alternately in the transverse direction, and the P type and N type are arranged in parallel in the transverse direction, and the electrode piece 2 made of a copper plate has the P type and the N type arranged in the transverse direction as shown in Fig. 2a on the upper surface. As shown in Figure 2c, on the bottom side, two P type and N type pieces that are adjacent to each other in the longitudinal direction of the module are connected alternately like brickwork, and electrode pieces are connected on the bottom side of both ends. A terminal plate 3 similar to the electrode plate 2 is connected to the lower surface of the thermoelectric element not marked with 2. The electrode plate 2 and the terminal plate 3 serve as both electrical conductors and heat transfer surfaces. In order to heat one surface of the thermoelectric submodule 4 and cool the other surface, for example, as shown in FIG. 3, square tubes 5 and 6, each having a flat outer surface and a cylindrical inner surface, are used as conventional laboratory-scale thermoelectric generators. Used in machine heat exchangers. In FIG. 3, a square pipe 5 is a low-temperature pipe through which cold water flows, and a square pipe 6 is a high-temperature pipe through which hot water flows. The flow directions of cold water and hot water are opposite to each other, so that when heat is exchanged between the low temperature pipe 5 and the high temperature pipe 6 via the thermoelectric submodule 4, the temperature difference is the same everywhere. be able to. By sequentially stacking the above-described low temperature pipe 5, submodule 4, and high temperature pipe 6 in multiple stages, it is possible to obtain an arbitrary amount of power generation.

さて、上述の四角管の伝熱管はアルミニウム合
金の押出形材であり、実用規模の大型熱電発電機
用熱交換器の場合は、加工上の寸法公差や、部分
的な温度差に基く管の歪みにより管が熱電モジユ
ールの接着面から剥離したり、熱電サブモジユー
ル内の接着部、素子自体、ハンダ付け部に力が掛
り破損する恐れがある。又、実用規模の熱交換器
に必要な海水に対する耐食性が不充分である。
Now, the square heat transfer tube mentioned above is an extruded aluminum alloy section, and in the case of a heat exchanger for a large-scale thermoelectric generator on a practical scale, the size of the tube due to dimensional tolerances during processing or local temperature differences is required. The distortion may cause the tube to separate from the adhesive surface of the thermoelectric module, or the adhesive parts within the thermoelectric submodule, the element itself, and the soldered parts may be damaged due to stress. Furthermore, the corrosion resistance against seawater required for a practical-scale heat exchanger is insufficient.

これらの欠点を改善するために、実用規模の大
型熱交換器に対する伝熱構造として、第4図に示
す如く、高温及び低温用伝熱管として銅合金の円
管を用いた場合、一方の面にこれらの円管の外周
面に密着するほぼ半円形断面の凹面を有し、他面
に上記熱電サブモジユール4の電極片2に密着す
る平面を有するアルミニウム押出形材に電気絶縁
性アルマイト処理を施した伝熱片7を熱電サブモ
ジユール4の各2枚を1組として長手方向に並べ
(第4図には熱電サブモジユール4は一枚のみを
示す。)その上下面に熱伝導性接着剤で接着して
一体化した伝熱片付サブモジユールユニツト8を
構成し、第5図に示す如く、該ユニツト8の両側
の凹面の一方に低温伝熱管9が、他方の凹面には
高温伝熱管10が接触する如く、伝熱管9,10
とユニツト8とを交互に枠構造11内に多段に積
重ねて保持して構成された熱交換器が提案されて
いる。
In order to improve these drawbacks, as shown in Figure 4, as a heat transfer structure for a large-scale heat exchanger on a practical scale, when copper alloy circular tubes are used as heat transfer tubes for high and low temperatures, one side is An extruded aluminum profile having a concave surface with a substantially semicircular cross section that closely contacts the outer peripheral surface of these circular tubes and a flat surface that closely contacts the electrode piece 2 of the thermoelectric submodule 4 on the other surface was subjected to an electrically insulating alumite treatment. The heat transfer pieces 7 are arranged in the longitudinal direction in a set of two thermoelectric sub-modules 4 (only one thermoelectric sub-module 4 is shown in FIG. 4), and are bonded to the upper and lower surfaces of the thermoelectric sub-modules 4 with a thermally conductive adhesive. It constitutes an integrated submodule unit 8 with a heat transfer unit, and as shown in FIG. 5, a low temperature heat transfer tube 9 is in contact with one of the concave surfaces on both sides of the unit 8, and a high temperature heat transfer tube 10 is in contact with the other concave surface. As shown, heat exchanger tubes 9 and 10
A heat exchanger has been proposed in which heat exchangers and units 8 are alternately stacked and held in multiple stages within a frame structure 11.

この構成によれば、薄肉の伝熱管9,10と厚
肉の伝熱片7とは一体でなくなるため膨張は夫々
自由となり、上記の欠点は改善される。しかし伝
熱管9,10と伝熱片7との間の接触はメタル・
タツチにはなつているが、相互間に寸法公差があ
るため、全面的に完全に隙間なく接触することは
あり得ず、エアギヤツプが生ずることは避けられ
ない。エアギヤツプが生ずると大きな伝熱抵抗が
生ずる。
According to this configuration, since the thin heat transfer tubes 9 and 10 and the thick heat transfer piece 7 are no longer integrated, they can expand freely, and the above-mentioned drawbacks are improved. However, the contact between the heat exchanger tubes 9, 10 and the heat exchanger piece 7 is made of metal.
However, since there are dimensional tolerances between them, it is impossible for them to contact each other completely without any gaps, and it is inevitable that an air gap will occur. When an air gap occurs, a large heat transfer resistance occurs.

本発明は、第5図に示す構成の熱電発電機用熱
交換器における上述の伝熱片と伝熱管の接触面に
発生するエアギヤツプに起因する伝熱抵抗を減少
させるようにした熱交換器を提供することを目的
とする。
The present invention provides a heat exchanger for a thermoelectric generator having the configuration shown in FIG. 5, which reduces the heat transfer resistance caused by the air gap generated at the contact surface between the heat transfer piece and the heat transfer tube. The purpose is to provide.

以下、本発明を実施例にもとずいて詳細に説明
する。
Hereinafter, the present invention will be explained in detail based on examples.

本発明においては、この伝熱抵抗を減少させる
ため伝熱管9,10と伝熱片7との接合面に熱伝
導性の良いグリースを塗布し、これによつてエア
ギヤツプを埋め、しかも伝熱管9,10と伝熱片
とは潤滑されて相互間の変位を自由にしたことを
特徴とする。これにより伝熱抵抗が減少するとと
もに、両者間に熱膨脹差が生じた場合にも応力が
発生することが防止されひいては熱電サブモジユ
ールの接触部、素子自体、ハンダ付け等の破壊を
避けることが可能である。
In the present invention, in order to reduce this heat transfer resistance, grease with good thermal conductivity is applied to the joint surfaces of the heat transfer tubes 9 and 10 and the heat transfer piece 7, thereby filling the air gap. , 10 and the heat transfer piece are lubricated to allow free displacement between them. This reduces heat transfer resistance and prevents stress from occurring even if there is a difference in thermal expansion between the two, which in turn makes it possible to avoid damage to the contact parts of the thermoelectric submodule, the element itself, soldering, etc. be.

この目的に使用する熱伝導性グリースは粘度が
高く、分離率がなく、蒸発率が小さく、体積固有
抵抗が大きいなどの特性が要求される。
Thermal conductive grease used for this purpose is required to have characteristics such as high viscosity, no separation rate, low evaporation rate, and high volume resistivity.

実施例 種々の熱伝導性グリースを用いて実験を行つた
結果、米国アミコン社(Amicon Corp.)製アミ
コン910−50(シリコン系)及び同社製アミコン
928−86(オレフイン系)がこの目的に適うこと
が確認された。この他にも使用可能なものがあ
る。
Example As a result of experiments using various thermally conductive greases, Amicon 910-50 (silicon-based) manufactured by Amicon Corp. in the United States and Amicon manufactured by Amicon Corp.
It was confirmed that 928-86 (olefin type) is suitable for this purpose. There are others available as well.

以上の如く、本発明により、熱伝動性グリース
を伝熱管と伝熱片との接触面に塗布するだけの簡
単な手段で伝熱抵抗を大幅に減少させることがで
き、温度差の小さい海洋温度差発電等の発電効率
の向上に顕著な効果を得ることができる。
As described above, according to the present invention, the heat transfer resistance can be significantly reduced by simply applying thermally conductive grease to the contact surface between the heat transfer tube and the heat transfer piece, and the temperature difference in the ocean temperature is small. A remarkable effect can be obtained in improving power generation efficiency such as differential power generation.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は熱電素子を用いた発電原理を説明する
図式図、第2図a,b,c,dは夫々熱電素子サ
ブモジユールの1例の上面図、正面図、下面図及
び側面図、第3図は実験室規模の熱電発電機用熱
交換器の要部を示す斜視図、第4図は実用規模の
熱交換器に使用される伝熱片付サブモジユールユ
ニツトの1例を示す斜視図、第5図は第4図のサ
ブモジユールユニツトと円管伝熱管とを使用した
熱交換器の要部構造を示す断面図である。 1……熱電素子、2……電極片、4……サブモ
ジユール、7……伝熱片、8……伝熱片付サブモ
ジユールユニツト、9……低温伝熱管、10……
高温伝熱管、11……枠構造。
Figure 1 is a schematic diagram explaining the principle of power generation using a thermoelectric element; Figures 2a, b, c, and d are top, front, bottom, and side views of an example of a thermoelectric element submodule; The figure is a perspective view showing the main parts of a heat exchanger for a laboratory scale thermoelectric generator, and Figure 4 is a perspective view showing an example of a submodule unit with a heat transfer unit used in a practical scale heat exchanger. , FIG. 5 is a sectional view showing the main structure of a heat exchanger using the submodule unit shown in FIG. 4 and circular heat exchanger tubes. DESCRIPTION OF SYMBOLS 1... Thermoelectric element, 2... Electrode piece, 4... Submodule, 7... Heat transfer piece, 8... Submodule unit with heat transfer piece, 9... Low temperature heat exchanger tube, 10...
High temperature heat exchanger tube, 11...frame structure.

Claims (1)

【特許請求の範囲】[Claims] 1 N型とP型の熱電素子を交互に平板電極片に
より電気的に直列に熱的に並列に接続し、片側の
電極片外側を加熱面、他の側の電極片の外側を冷
却面として構成した熱電サブモジユールを、一面
に高温又は低温伝熱管の外周面に密着する形状を
有する凹面、他面に上記熱電サブモジユールの冷
却面又は加熱面に密着する平面を有する伝熱片の
2枚によりサンドウイツチ状に挾みその接触面を
熱伝導性接着剤で接着して一体の伝熱片付熱電サ
ブモジユールユニツトを構成し、該ユニツトの両
側の凹面の一方には高温伝熱管が、他方には低温
伝熱管が接触する如く、伝熱管と上記ユニツトと
を交互に枠構造内に多段に積重ね保持して成る熱
電発電機用熱交換器において、上記の伝熱片の凹
面と上記の伝熱管との接触面に熱伝導性グリース
を塗布したことを特徴とする熱電発電機用熱交換
器。
1 N-type and P-type thermoelectric elements are alternately connected electrically in series and thermally in parallel using flat plate electrode pieces, with the outside of the electrode piece on one side serving as a heating surface and the outside of the electrode piece on the other side serving as a cooling surface. The configured thermoelectric submodule is sandwiched between two heat transfer pieces, each having a concave surface on one side that has a shape that comes into close contact with the outer circumferential surface of the high temperature or low temperature heat transfer tube, and a flat surface that has a shape that comes into close contact with the cooling surface or heating surface of the thermoelectric submodule on the other surface. A thermoelectric submodule unit with a heat transfer piece is constructed by sandwiching the tubes in the form of a shape and bonding their contact surfaces with a thermally conductive adhesive to form an integrated thermoelectric submodule unit with a heat transfer piece. In a heat exchanger for a thermoelectric generator, the heat exchanger tubes and the unit are alternately stacked in a frame structure in multiple stages so that the low-temperature heat exchanger tubes are in contact with each other, and the concave surface of the heat exchanger piece and the heat exchanger tube are connected to each other. A heat exchanger for a thermoelectric generator, characterized in that the contact surface of the heat exchanger is coated with thermally conductive grease.
JP57033089A 1982-03-04 1982-03-04 Heat exchanger used in thermoelectric generator Granted JPS58153092A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57033089A JPS58153092A (en) 1982-03-04 1982-03-04 Heat exchanger used in thermoelectric generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57033089A JPS58153092A (en) 1982-03-04 1982-03-04 Heat exchanger used in thermoelectric generator

Publications (2)

Publication Number Publication Date
JPS58153092A JPS58153092A (en) 1983-09-10
JPS6131798B2 true JPS6131798B2 (en) 1986-07-22

Family

ID=12376947

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57033089A Granted JPS58153092A (en) 1982-03-04 1982-03-04 Heat exchanger used in thermoelectric generator

Country Status (1)

Country Link
JP (1) JPS58153092A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63188190U (en) * 1987-05-27 1988-12-02
JPS6432191U (en) * 1987-08-19 1989-02-28

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61276275A (en) * 1985-05-27 1986-12-06 チヤ−ルズ ジエイ コ−キ− Thermoelectric type electricity generator
JP2516305Y2 (en) * 1985-12-05 1996-11-06 株式会社小松製作所 Thermoelectric generator cooling device
CN102510244B (en) * 2011-12-02 2014-04-16 浙江大学 Annular array thermoelectric generator with functional gradient thermoelectric arms

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63188190U (en) * 1987-05-27 1988-12-02
JPS6432191U (en) * 1987-08-19 1989-02-28

Also Published As

Publication number Publication date
JPS58153092A (en) 1983-09-10

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