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JPS6132266B2 - - Google Patents
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JPS6132266B2 - - Google Patents

Info

Publication number
JPS6132266B2
JPS6132266B2 JP53046873A JP4687378A JPS6132266B2 JP S6132266 B2 JPS6132266 B2 JP S6132266B2 JP 53046873 A JP53046873 A JP 53046873A JP 4687378 A JP4687378 A JP 4687378A JP S6132266 B2 JPS6132266 B2 JP S6132266B2
Authority
JP
Japan
Prior art keywords
doping
fiber
quartz pipe
optical fiber
core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP53046873A
Other languages
Japanese (ja)
Other versions
JPS54138631A (en
Inventor
Masaaki Yoshida
Hiroshi Yokota
Shuzo Suzuki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Electric Industries Ltd
Original Assignee
Sumitomo Electric Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Electric Industries Ltd filed Critical Sumitomo Electric Industries Ltd
Priority to JP4687378A priority Critical patent/JPS54138631A/en
Publication of JPS54138631A publication Critical patent/JPS54138631A/en
Publication of JPS6132266B2 publication Critical patent/JPS6132266B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00Fibre or filament compositions
    • C03C13/04Fibre optics, e.g. core and clad fibre compositions
    • C03C13/045Silica-containing oxide glass compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
  • Manufacture, Treatment Of Glass Fibers (AREA)

Description

【発明の詳細な説明】 本発明は光伝送用フアイバ(以下単に光フアイ
バと言う)の製造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of manufacturing an optical transmission fiber (hereinafter simply referred to as optical fiber).

光フアイバの低損失化が急速に進み、フアイバ
を伝送路とした通信方式が実用化されようとして
いる。光フアイバに要求される重要な伝送特性と
しては、 低損失 広帯域 が挙げられる。フアイバの伝送帯域は普通ベース
バンドの周波数特性によつて評価され、この帯域
が大であるということは、伝送容量が大となると
いうことである。フアイバの伝送帯域を大にする
方法としては種々提案されているが、最も有望な
方法は、第1図のコア部1(光集中領域)の屈折
率にある分布形f(r)を持たせ、各伝搬可能な
モードの群速度を一致させ、帯域を広げるという
方法である。
The loss of optical fibers has been rapidly reduced, and communication systems using fibers as transmission paths are about to be put into practical use. Important transmission characteristics required of optical fiber include low loss and wide bandwidth. The transmission band of a fiber is usually evaluated by the frequency characteristics of the baseband, and a large band means a large transmission capacity. Various methods have been proposed to increase the transmission band of the fiber, but the most promising method is to have the refractive index distribution shape f(r) in the core part 1 (light concentration region) shown in Figure 1. , the band velocity is expanded by matching the group velocities of each propagable mode.

これを実現する屈折率分布形としては下式に於
いて f(r)≒(r/a)のものが良く知られている。
The refractive index distribution shape that realizes this is given by the following formula: The one where f(r)≈(r/a) 2 is well known.

このような分布形を有するフアイバを気相成長法
(CVD法)にて製造する場合困難な問題がある。
又、所要の伝送帯域を得ようとする場合には、f
(r)の関数形を変化させる必要がある。
There are difficult problems when manufacturing fibers having such a distribution shape by a vapor phase deposition method (CVD method).
Also, when trying to obtain the required transmission band, f
It is necessary to change the functional form of (r).

一般に上記式(1)に従うようにGe、Al、P、
Ti、Ga等の屈折率を高めるような原料を変化さ
せ、光フアイバのコア部にドーピングする方法が
取られているが、所要の伝送帯域が安定に得られ
ないなど、製造上困難な問題がある。
In general, Ge, Al, P,
Methods of doping the core portion of optical fibers by changing raw materials that increase the refractive index, such as Ti and Ga, have been used, but there are problems in manufacturing, such as the inability to stably obtain the required transmission band. be.

本発明は、これらの問題点を解決し、所要の伝
送帯域を容易に得ることを目的としたものであ
る。その特徴とする点は光フアイバのコア部の断
面内屈折率分布がコアの中心近傍のある領域では
変化がなくほぼ一定であり、その周囲のコア領域
ではある円対称関数になるように形成された光伝
送用フアイバ、および光フアイバのコア部にドー
ピングし、ある円対称関数を有するフアイバを気
相成長法にて製造する方法において、Ge,Al,
P,Ti,Gaのドーピング原料を少なくとも1種
類含み、ある円対称関数に従つて段階的に変化さ
せ増量し形成した後、ある領域からドーピング原
料を変化なく形成せしめる光伝送フアイバの製造
方法である。式(1)に示したような分布形を有する
フアイバをGe,Al,P,Ti,Ga等の屈折率を高
めるような元素をコア部にドーピング
(doping)し、気相成長法にて製造する場合、第
2図に示すようにコア中心部にて、ドーピング元
素含有量が最も多くなるように段階的変化させ増
量し形成される方法が一般的であり、そのようす
を第2図に示す。ところで、第3図に示すような
CVD内スス付という製造法において、原料であ
るSi化合物、ドーピング化合物、およびキヤリア
ガスであるO2などの混合気体を石英パイプ内部
に送り込みガラス管をバーナで加熱し、気相酸化
分解反応で石英パイプ内にガラスの層を積層させ
る。しかる後に第4図に示すごとく外部加熱によ
つてガラスパイプをつぶし中実化する。一般には
コラツプスと呼ぶ、このコラツプスによつて中実
化されたガラスロツドを高温温加熱し所定のフア
イバ径に紡糸し、分布形を有する光フアイバを得
る。この一般的方法によると、光フアイバの伝送
帯域は200MHZ.Kmから、1000MHZ.Kmとバラツキ
が大きく、一定の伝送帯域を有する光フアイバを
安定に得るためには、困難であつた。一方、フア
イバの伝送帯域をある所定の値に制御しようとす
る場合、従来の方法であれば式(1)中の関数f
(r)をある関数に制御しなければならないが、
この為には、細部の屈折率分布を精密に制御しな
ければならず、製造上困難であつた。
The present invention aims to solve these problems and easily obtain the required transmission band. The characteristic point is that the refractive index distribution in the cross section of the core of the optical fiber is almost constant with no change in a certain region near the center of the core, and is formed so that it has a circularly symmetrical function in the surrounding core region. In the method of manufacturing optical transmission fibers by doping the core portion of the optical fiber and having a certain circularly symmetric function by vapor phase growth, Ge, Al,
This is a method for manufacturing an optical transmission fiber that includes at least one type of doping material such as P, Ti, or Ga, and after forming the fiber by increasing the amount by changing it stepwise according to a certain circularly symmetrical function, the doping material is formed from a certain region without changing. . A fiber with a distribution shape as shown in formula (1) is manufactured by doping the core with elements that increase the refractive index, such as Ge, Al, P, Ti, Ga, etc., using a vapor phase growth method. In this case, the common method is to increase the doping element content in stages at the center of the core, as shown in Figure 2. . By the way, as shown in Figure 3
In the manufacturing method called CVD internal sooting, a mixture of raw materials such as Si compounds, doping compounds, and carrier gas O 2 is fed into the quartz pipe, the glass tube is heated with a burner, and the quartz pipe is heated by a gas phase oxidation decomposition reaction. A layer of glass is laminated inside. Thereafter, as shown in FIG. 4, the glass pipe is crushed and solidified by external heating. The glass rod solidified by this collapse, which is generally called a collapse, is heated at a high temperature and spun to a predetermined fiber diameter to obtain an optical fiber having a distribution shape. According to this general method, the transmission band of the optical fiber varies widely from 200 MHZ.Km to 1000 MHZ.Km, and it is difficult to stably obtain an optical fiber having a constant transmission band. On the other hand, when trying to control the fiber transmission band to a certain predetermined value, the conventional method uses the function f in equation (1).
(r) must be controlled to a certain function, but
For this purpose, it is necessary to precisely control the refractive index distribution in detail, which is difficult to manufacture.

本発明は、これらの問題を解決し、所要の伝送
帯域を容易にしかも、安定に得る、光フアイバの
製造方法に関するものである。その実施例を第5
図、第6図に示す。本発明の特徴は、第5図に示
すようにドーピング元素含有量をコア中心部r=
oのある領域から変化なく設定し、形成し、しか
る後にドーピング元素含有量をある円対称関数に
従つて段階的に変化させた点にある。第6図は、
光フアイバのコア一部にP、Bの2種類のドーピ
ング元素を一定含有量含ませ、Geの含有量をあ
る円対称関数に従つて段階的に変化させコア中心
部r=oにおいてコア中心部から、ある領域だけ
変化なく設定して形成させた実施例である。
The present invention solves these problems and relates to a method of manufacturing an optical fiber that can easily and stably obtain the required transmission band. The example is the fifth example.
As shown in FIG. The feature of the present invention is that, as shown in FIG.
o is set and formed without any change from a certain region, and then the doping element content is changed stepwise according to a certain circularly symmetric function. Figure 6 shows
Two types of doping elements, P and B, are contained in a certain amount in a part of the core of the optical fiber, and the Ge content is changed stepwise according to a certain circularly symmetric function, so that This is an example in which only a certain area is set and formed without change.

実施例、第5図、第6図、第7図に従つて作成
した光フアイバと従来の第2図に示す方法で作成
した光フアイバの各種特性を表1に示す。表中、
フアイバ特性の周波数特性(MHZ.Km)は、任意
の周波数で強度変調された光を入射させ、その周
波数成分の減衰量を測定する方法で評価した。具
体的には6dB減衰した時の周波数を測定し、長さ
換算で算出した。周波数特性の値が大きいものほ
ど広帯域のフアイバであると言える。また表中パ
ルス特性は単一パルスをフアイバに入射した時、
出射パルスの形状を測定し、パルス割れが生じて
いるかどうかを観察した。光フアイバを用いた通
信方式は、多くの場合パルス符号変調方式
(PCM)で行なわれる。この場合例えば上記した
パルス割れの現象が生じた時には、符号の誤りと
なり、信号の品質を劣化させることになる。した
がつてパルス割れのないフアイバを安定に製造す
ることは極めて重要な問題であつた。
Table 1 shows various characteristics of the optical fibers produced according to the examples, FIGS. 5, 6, and 7, and the optical fibers produced by the conventional method shown in FIG. In the table,
The frequency characteristics (MHZ.Km) of the fiber characteristics were evaluated by injecting light whose intensity was modulated at a given frequency and measuring the amount of attenuation of the frequency component. Specifically, we measured the frequency when it was attenuated by 6 dB and calculated it by converting it into length. It can be said that a fiber with a larger frequency characteristic value has a wider band. In addition, the pulse characteristics in the table are when a single pulse is input into the fiber.
The shape of the emitted pulse was measured and it was observed whether pulse cracking occurred. Communication systems using optical fibers are often based on pulse code modulation (PCM). In this case, for example, when the above-mentioned pulse cracking phenomenon occurs, a code error occurs and the quality of the signal deteriorates. Therefore, it has been an extremely important problem to stably produce fibers that are free from pulse cracks.

表1の実施例1、2、3、4、5、6、7に示
すごとく本発明による方法、ドーピング元素をあ
る円対称関数に従つて段階的に変化させ、その後
ある領域からドーピング原料を変化なく設定し、
形成して得られたフアイバは、周波数特性が600
〜1000MHZ.Kmと広帯域が得られ、パルス特性で
パルス割れのないフアイバが得られることが分つ
た。比較例1、2、3、4で示すごとく従来の設
定方法で作成したフアイバは、200〜300MHZ.Km
と帯域がせまくパルス割れのあるフアイバで、光
通信方式には適要できないものである。
As shown in Examples 1, 2, 3, 4, 5, 6, and 7 in Table 1, the method according to the present invention involves changing the doping element stepwise according to a certain circular symmetry function, and then changing the doping material from a certain region. Set without
The resulting fiber has a frequency characteristic of 600
It was found that a wide band of ~1000MHZ.Km was obtained, and a fiber with no pulse cracking was obtained in terms of pulse characteristics. As shown in Comparative Examples 1, 2, 3, and 4, the fibers made using the conventional setting method were 200 to 300 MHZ.Km.
This fiber has a narrow band and pulse cracking, making it unsuitable for optical communication systems.

上述したように本発明によれば実施例に示す如
く低損失で広帯域を有する光フアイバの得られる
利点がある。
As described above, according to the present invention, there is an advantage that an optical fiber having a low loss and a wide band can be obtained as shown in the embodiments.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は光フアイバの断面図と屈折率の分布状
態を示し、1光フアイバのコア、2光フアイバの
クラツドを示す。 第2図は、従来方法に従つたドーピング元素の
含有量変化と光フアイバコア径の関係を示す特性
図、第3図、第4図は一般のCVD、内スス付法
の例でガラス管3をバーナ4で加熱する状態の説
明図、第5図、第6図、第7図は、本発明の例
で、ドーピング元素の含有量変化と光フアイバコ
ア径の関係を示す特性図。
FIG. 1 shows a cross-sectional view of an optical fiber and the distribution of refractive index, and shows the core of one optical fiber and the cladding of two optical fibers. Figure 2 is a characteristic diagram showing the relationship between doping element content change and optical fiber core diameter according to the conventional method, and Figures 3 and 4 show the glass tube 3 as an example of the general CVD and internal soot deposition method. 5, 6, and 7 are characteristic diagrams showing the relationship between changes in doping element content and optical fiber core diameter in examples of the present invention.

【表】【table】

【表】【table】

Claims (1)

【特許請求の範囲】[Claims] 1 原料およびドーピングの混合気体をO2と共
に回転する石英パイプ内へ導入し、石英パイプに
添つて移動する熱源により前記混合気体を反応さ
せてガラスの層を順次石英パイプの内壁面に堆積
し、これを中実化した後紡糸するCVD内スス付
法において屈折率を高めるコア部のドーピング材
料を段階的に増量し、ある領域からドーピング材
料を一定に供給して形成することを特徴とする光
伝送用フアイバの製造方法。
1. Introducing a gas mixture of raw materials and doping into a rotating quartz pipe together with O2 , causing the gas mixture to react with a heat source moving along the quartz pipe, and sequentially depositing a glass layer on the inner wall surface of the quartz pipe; The light is formed by increasing the amount of the doping material in the core part that increases the refractive index stepwise in a CVD internal sooting method in which the material is solidified and then spun, and the doping material is constantly supplied from a certain region. Method of manufacturing transmission fiber.
JP4687378A 1978-04-19 1978-04-19 Fiber for optical communication and its production Granted JPS54138631A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4687378A JPS54138631A (en) 1978-04-19 1978-04-19 Fiber for optical communication and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4687378A JPS54138631A (en) 1978-04-19 1978-04-19 Fiber for optical communication and its production

Publications (2)

Publication Number Publication Date
JPS54138631A JPS54138631A (en) 1979-10-27
JPS6132266B2 true JPS6132266B2 (en) 1986-07-25

Family

ID=12759456

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4687378A Granted JPS54138631A (en) 1978-04-19 1978-04-19 Fiber for optical communication and its production

Country Status (1)

Country Link
JP (1) JPS54138631A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3031147A1 (en) * 1980-08-18 1982-03-18 Siemens AG, 1000 Berlin und 8000 München METHOD FOR PRODUCING GLASS WITH A PRE-DETERMINED REFRIGERATION PROFILE AND ALKALINE-FREE GLASS FROM AN OXIS OF A BASE MATERIAL DOPED WITH ONE OR SEVERAL SUBSTANCES

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5028846A (en) * 1973-07-16 1975-03-24

Also Published As

Publication number Publication date
JPS54138631A (en) 1979-10-27

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