JPS6134617B2 - - Google Patents
Info
- Publication number
- JPS6134617B2 JPS6134617B2 JP54153875A JP15387579A JPS6134617B2 JP S6134617 B2 JPS6134617 B2 JP S6134617B2 JP 54153875 A JP54153875 A JP 54153875A JP 15387579 A JP15387579 A JP 15387579A JP S6134617 B2 JPS6134617 B2 JP S6134617B2
- Authority
- JP
- Japan
- Prior art keywords
- source
- region
- drain
- electrode
- diffusion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 10
- 239000000758 substrate Substances 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 5
- 239000004065 semiconductor Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 230000005669 field effect Effects 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229920005591 polysilicon Polymers 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000008280 blood Substances 0.000 description 6
- 210000004369 blood Anatomy 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 229910052814 silicon oxide Inorganic materials 0.000 description 5
- 229910052581 Si3N4 Inorganic materials 0.000 description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000004204 blood vessel Anatomy 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
Landscapes
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Measurement Of The Respiration, Hearing Ability, Form, And Blood Characteristics Of Living Organisms (AREA)
Description
【発明の詳細な説明】
本発明はイオンセンサ用電界効果トランジスタ
(以下ISFEと称す。)の構造に関するものであ
る。ISFETはゲート絶縁膜上にゲート電極(金
属)を設けることなく、これを電解液例えば血液
中に浸漬することにより血液と絶縁膜との界面に
生ずる電位の変化によつて半導体表面(ソース,
ドレイン間)の導電率が変わることを利用して血
液中のイオン活量を検出するように構成されてい
る。一般にISFETは生体センサとして利用する
場合には注射器(針)内等に挿着されて血管内で
血液中に浸漬されるので、構造上繊細であるこ
と、特に血液中に浸漬されるセンサ部(ゲート
部等)は該血液と完全に絶縁がなされているこ
と、及びセンサ出力を容易に外部に取出しでき
る電極構造(リード線を含む)を備えていること
等が望ましい。第1図a,bはこの種のISFET
の従来構造を示す平面図及同a図A―A′断面図
で、図において1は一導電型(例えばP型)半導
体基体、2は該基体1の一表面に紐状に形成され
たn+型ソース拡散領域、3は該ソース領域2の
回りに形成されたP+型チヤンネルストツプ領
域、4はゲート部、5はn+型ドレイン拡散領
域、6は該基体1の全面を覆う如く形成された酸
化シリコン膜(si02)或は窒化シリコン膜
(siN)等の絶縁皮膜、S及びDはソース電極及
びドレイン電極で夫々図示しない他の外部導出用
リード線に接続される。係る構造のISFETはソ
ース領域2及びドレイン領域5の表面幾可学形状
を細長く形成することにより先端をセンサ(ゲー
ト)部とし、又後端をソース電極部及びドレイン
電極部とすることにより該後端を血液に浸漬する
ことなくリード線の取出しを容易にしている。然
し乍ら該ソース及びドレイン領域の夫々先端及び
後端間の中間部はその表面を絶縁皮膜6で保護さ
れて内部配線用としての機能を兼用するためにそ
の抵抗値を低く形成することが要求される。この
ために拡散時に不純物を長時間拡散して高不純物
濃度にしなければならず、これに伴い該ソース及
びドレイン領域の拡散深さが深くなり、又サイド
(横方向)拡散が著しく幾可学形状寸法等に余裕
がなく小型化し難い。又、高濃度、長時間の拡散
により基体(シリコン)1の結晶に欠陥を生じ製
品歩留が低下したり或は工程が長時間になる等の
難点がある。第2図はこの種の他の従来構造を示
す概略断面図で、センサ部4とリード線取出部を
分離し、この間の内部配線をアルミニウム(A
)等の金属細線7により行い、又センサ部のゲ
ート部分を除きそれ以外のセンサ部及び金属細線
7の表面をエポキシ、或はRTV等の絶縁樹脂8
で被うようにしたものである。係る構造において
は絶縁樹脂8の接着が十分でなく、又、該絶縁樹
脂8は耐薬品性に劣るために電解液との絶縁が十
分に保てないばかりかゲート部分のみを残して該
樹脂を塗布することが困難であり、更に形状が大
型化する等の欠点がある。本発明は係る点を鑑み
センサ部等と電解液の絶縁を酸化或は窒化シリコ
ン膜等の半導体絶縁皮膜を用いて行うと共に中間
配線部を不純物をドープしたポリシリコン(多結
晶シリコン)により行うようにして述上の欠点を
一挙に排除した新規なISFETを提供するもの
で、以下図面を用いて本発明を詳細に説明する。
第3図a,bは本発明の一実施例構造を示す平面
図及び同a図A―A′断面図で従来例と同一符号
は同等部分を示す。本発明はシリコン基体1の先
端部に最少必要面積のソース領域2及びドレイン
領域5を拡散により形成し、その後該基体1の全
面に酸化シリコン膜(Si02)を形成する。次いで
該ソース領域2及びドレイン領域5の所要表面上
のシリコン膜を除去した後、該表面と他のシリコ
ン膜Si02を覆い該基体1の後端方向に紐状もしく
は帯状のポリシリコン層9を形成する。このポリ
シリコン層9はCVD法(Chemical Vapor
Deposition)等により容易に形成でき、しかも形
成時に不純物を高濃度にドーブせしめることによ
りその抵抗値を任意に調整できる。次いで該ポリ
シリコン層9上に酸化シリコン膜Si02を形成し、
更に全シリコン膜上に窒化シリコン膜SiNを形成
する。そして該基体表面の後端において所要部の
窒化シリコン膜及び酸化シリコン膜を除去してポ
リシリコン層を露出せしめ、該露出表面にソース
電極S及びドレイン電極Dを形成するようにした
ものである。このような構成を持つ本発明の
ISFETはセンサ部を基体の先端部に集約できる
ので拡散工程が省略でき特に拡散時のサイド拡散
がなく、基体の形状が小型化され、しかもシリコ
ン結晶の欠陥が生じないので製品歩留が向上す
る。又、電極配線は任意の形状に容易に形成で
き、しかも該配線部の絶縁処理が容易であり、安
定する等ISFETとして要求される繊細形状絶縁
処理及び電極取出し等が十分満足するものであ
る。第4図a,bは本発明の他の実施例構造を示
す平面図及び同a図A―A′断面図で、1つのシ
リコン基体1に共通のドレイン拡散領域5と2つ
の紐状ソース領域2,2′を形成し、該ソース領
域2,2′の所要表面より該基体1の後端方向に
ポリシリコン層9を形成することにより複合セン
サを構成するようにしたものである。この構造に
よれば複合センサの構造に予め拡散領域を形成し
た後、該センサの組合せに応じてポリシリコン層
の配線形状を変えることが可能なために該センサ
の集積化が容易である。以上の説明から明らかな
ように本発明によれば構成簡単にして微細化され
たISFETが提供できるので実用上の効果は大き
い。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to the structure of a field effect transistor (hereinafter referred to as ISFE) for an ion sensor. ISFET does not have a gate electrode (metal) on the gate insulating film, and when it is immersed in an electrolyte, such as blood, the semiconductor surface (source,
It is configured to detect the ionic activity in blood by utilizing the change in conductivity between the drains and drains. Generally, when ISFET is used as a biosensor, it is inserted into a syringe (needle) and immersed in blood within a blood vessel, so it is structurally delicate, especially the sensor part that is immersed in blood. It is desirable that the gate portion, etc.) be completely insulated from the blood, and that it be provided with an electrode structure (including lead wires) that allows the sensor output to be easily taken out to the outside. Figure 1 a and b show this type of ISFET.
1 is a plan view and a sectional view taken along the line A-A' of FIG. 3 is a P+ type channel stop region formed around the source region 2; 4 is a gate portion; 5 is an N+ type drain diffusion region; 6 is formed to cover the entire surface of the substrate 1. The insulating films S and D, such as a silicon oxide film (si02) or a silicon nitride film (siN), are connected to other external lead wires (not shown) at source and drain electrodes, respectively. In the ISFET having such a structure, the surface geometry of the source region 2 and drain region 5 is formed to be elongated so that the tips serve as the sensor (gate) section, and the rear ends serve as the source electrode section and the drain electrode section. The lead wire can be easily taken out without immersing the end in blood. However, since the surface of the intermediate portion between the tip and rear end of the source and drain regions is protected by an insulating film 6 and also serves as an internal wiring, it is required that the resistance value thereof be made low. . For this reason, it is necessary to diffuse impurities for a long time to achieve a high impurity concentration during diffusion, and as a result, the diffusion depth of the source and drain regions becomes deep, and the side (lateral direction) diffusion significantly shapes the geometry. It is difficult to downsize due to lack of space in dimensions, etc. Further, due to the high concentration and long-time diffusion, defects may occur in the crystals of the substrate (silicon) 1, resulting in lower product yields or longer process times. FIG. 2 is a schematic cross-sectional view showing another conventional structure of this type, in which the sensor part 4 and the lead wire extraction part are separated, and the internal wiring between them is connected to aluminum (A
), etc., and the surface of the other sensor parts and the metal wire 7 except for the gate part of the sensor part is coated with epoxy or insulating resin 8 such as RTV.
It was designed to be covered with In such a structure, the adhesion of the insulating resin 8 is insufficient, and since the insulating resin 8 has poor chemical resistance, it is not possible to maintain sufficient insulation from the electrolyte, and the resin is removed leaving only the gate portion. It has drawbacks such as difficulty in coating and increased size. In view of these points, the present invention uses a semiconductor insulating film such as a silicon oxide or nitride film to insulate the sensor part, etc. and the electrolyte, and the intermediate wiring part is made of polysilicon (polycrystalline silicon) doped with impurities. The present invention is to provide a new ISFET that eliminates the above-mentioned drawbacks at once.The present invention will be explained in detail below with reference to the drawings.
FIGS. 3a and 3b are a plan view showing the structure of an embodiment of the present invention, and a cross-sectional view taken along line A-A' in FIG. In the present invention, a source region 2 and a drain region 5 having the minimum required area are formed at the tip of a silicon substrate 1 by diffusion, and then a silicon oxide film (Si02) is formed on the entire surface of the substrate 1. Next, after removing the silicon film on the required surfaces of the source region 2 and drain region 5, a string-like or band-like polysilicon layer 9 is formed in the direction of the rear end of the base 1, covering the surface and the other silicon film Si02. do. This polysilicon layer 9 is formed using the CVD method (Chemical Vapor
The resistance value can be adjusted as desired by doping with impurities at a high concentration during formation. Next, a silicon oxide film Si02 is formed on the polysilicon layer 9,
Further, a silicon nitride film SiN is formed over the entire silicon film. Then, a required portion of the silicon nitride film and silicon oxide film is removed at the rear end of the base surface to expose the polysilicon layer, and a source electrode S and a drain electrode D are formed on the exposed surface. The present invention having such a configuration
With ISFET, the sensor part can be concentrated at the tip of the substrate, so the diffusion process can be omitted, there is no side diffusion during diffusion, the shape of the substrate can be made smaller, and there are no silicon crystal defects, which improves product yield. . In addition, the electrode wiring can be easily formed into any shape, and the insulation treatment of the wiring portion is easy, and the insulation treatment for delicate shapes and electrode extraction required for ISFETs, such as stability, are fully satisfied. FIGS. 4a and 4b are a plan view and a sectional view taken along line A-A' in FIG. 2 and 2' are formed, and a polysilicon layer 9 is formed from the required surfaces of the source regions 2 and 2' toward the rear end of the base 1, thereby constructing a composite sensor. According to this structure, after forming the diffusion region in advance in the structure of the composite sensor, it is possible to change the wiring shape of the polysilicon layer depending on the combination of the sensors, so that the sensor can be easily integrated. As is clear from the above description, according to the present invention, it is possible to provide a miniaturized ISFET with a simple structure, and therefore the practical effects are great.
第1図、第2図は従来構造図、第3図、第4図
は本発明の実施例構造図である。図において1は
半導体基体、2,2′はソース拡散領域、3はチ
ヤンネルストツプ領域、4はゲート部、5はドレ
イン拡散領域、6は絶縁皮膜、7は金属細線、8
は絶縁樹脂、9はポリシリコン層、Sはソース電
極、Dはドレイン電極である。
1 and 2 are conventional structural diagrams, and FIGS. 3 and 4 are structural diagrams of an embodiment of the present invention. In the figure, 1 is a semiconductor substrate, 2 and 2' are source diffusion regions, 3 is a channel stop region, 4 is a gate portion, 5 is a drain diffusion region, 6 is an insulating film, 7 is a thin metal wire, and 8
9 is an insulating resin, 9 is a polysilicon layer, S is a source electrode, and D is a drain electrode.
Claims (1)
領域を形成すると共に、前記ソース領域及びドレ
イン領域間の前記半導体表面にゲート用絶縁膜を
形成し、該絶縁膜上にゲート電極(金属)を形成
しないように構成されたイオンセンサ用電界効果
トランジスタにおいて、前記ソース領域又はドレ
イン領域の少くとも一表面とソース電極又はドレ
イン電極間を不純物を含む多結晶シリコンにより
配線するようにしたことを特徴とするイオンセン
サ用電界効果トランジスタ。1. A source region and a drain region are formed on one surface of a semiconductor substrate, and a gate insulating film is formed on the semiconductor surface between the source region and the drain region, and a gate electrode (metal) is not formed on the insulating film. In the field effect transistor for an ion sensor, the ion sensor is characterized in that wiring is formed between at least one surface of the source region or the drain region and the source electrode or the drain electrode using polycrystalline silicon containing impurities. field effect transistor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15387579A JPS5676042A (en) | 1979-11-28 | 1979-11-28 | Field effect transistor for ion sensor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15387579A JPS5676042A (en) | 1979-11-28 | 1979-11-28 | Field effect transistor for ion sensor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5676042A JPS5676042A (en) | 1981-06-23 |
| JPS6134617B2 true JPS6134617B2 (en) | 1986-08-08 |
Family
ID=15572014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15387579A Granted JPS5676042A (en) | 1979-11-28 | 1979-11-28 | Field effect transistor for ion sensor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5676042A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0725688Y2 (en) * | 1985-12-18 | 1995-06-07 | 新電元工業株式会社 | Semiconductor ion sensor |
| CN102290349A (en) * | 2010-06-21 | 2011-12-21 | 无锡华润上华半导体有限公司 | Semiconductor structure and forming method thereof |
| GB201608758D0 (en) * | 2016-05-18 | 2016-06-29 | Dnae Group Holdings Ltd | Improvements in or relating to packaging for integrated circuits |
-
1979
- 1979-11-28 JP JP15387579A patent/JPS5676042A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5676042A (en) | 1981-06-23 |
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