JPS6135525B2 - - Google Patents
Info
- Publication number
- JPS6135525B2 JPS6135525B2 JP57099051A JP9905182A JPS6135525B2 JP S6135525 B2 JPS6135525 B2 JP S6135525B2 JP 57099051 A JP57099051 A JP 57099051A JP 9905182 A JP9905182 A JP 9905182A JP S6135525 B2 JPS6135525 B2 JP S6135525B2
- Authority
- JP
- Japan
- Prior art keywords
- cladding
- core
- sio
- glass
- polarization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005253 cladding Methods 0.000 claims description 30
- 239000011521 glass Substances 0.000 claims description 21
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 18
- 239000013307 optical fiber Substances 0.000 claims description 12
- 230000005855 radiation Effects 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000010287 polarization Effects 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 229910005793 GeO 2 Inorganic materials 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
- C03C13/04—Fibre optics, e.g. core and clad fibre compositions
- C03C13/045—Silica-containing oxide glass compositions
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/10—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
- G02B6/105—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type having optical polarisation effects
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Optics & Photonics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Manufacture, Treatment Of Glass Fibers (AREA)
- Glass Compositions (AREA)
Description
【発明の詳細な説明】
本発明は低損失な耐放射線性偏波面保存光フア
イバに関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a low-loss, radiation-resistant, polarization-maintaining optical fiber.
単一モード伝送用の光フアイバで、クラツドを
断面楕円形にし、コアに異方性歪を起こし、光弾
性効果によつて長軸、短軸方向の屈折率、従つて
伝搬定数の差を大きくし、偏波面を保存する偏波
面保存光フアイバは、例えば特開昭56−99306号
によつてすでによく知られている。 An optical fiber for single-mode transmission.The cladding has an elliptical cross-section and anisotropic strain is created in the core, which increases the difference in refractive index in the major and minor axis directions, and therefore in the propagation constant, due to the photoelastic effect. However, a polarization-maintaining optical fiber that preserves the polarization plane is already well known, for example, from Japanese Patent Laid-Open No. 56-99306.
この構造は、その断面が第1図に示すような3
層構造からなり、断面楕円形のクラツド12とし
ては、SiO2−B2O3ガラスもしくはSiO2+G2O2+
B2O3ガラスが採用できることが指摘されてい
る。 This structure has a cross section as shown in Figure 1.
The cladding 12, which has a layered structure and has an elliptical cross section, is made of SiO 2 −B 2 O 3 glass or SiO 2 +G 2 O 2 +
It has been pointed out that B 2 O 3 glass can be used.
楕円形クラツド12にはB2O3含有ガラスを採
用するのは、異方性歪を起こす材料としてB2O3
が有力であるためである。11はコア、13は外
側ジヤケツトである。 The reason why B 2 O 3 -containing glass is used for the elliptical cladding 12 is because B 2 O 3 is a material that causes anisotropic strain.
This is because it is powerful. 11 is a core, and 13 is an outer jacket.
ところが、B2O3は1.2μm帯以上の長波長帯で
大きな吸収損失を受けるため、従来偏波面保存光
フアイバの使用を短波長帯に限つていた。 However, since B 2 O 3 suffers from large absorption loss in the long wavelength band of 1.2 μm or more, the use of polarization-maintaining optical fibers has conventionally been limited to short wavelength bands.
そこで、コア及びコアに直接接する層には
B2O3を含有させない構造が発明された。 Therefore, for the core and the layer directly in contact with the core,
A structure that does not contain B 2 O 3 was invented.
それが第2図に示すような4層構造であり、極
めて優れた特性を呈することから、今日の偏波面
保存光フアイバの主流となつている。 It has a four-layer structure as shown in FIG. 2, and because it exhibits extremely excellent characteristics, it has become the mainstream of today's polarization-maintaining optical fibers.
この4層構造では、コア21がSiO2+GeO2ガ
ラスであり、コア21に接する第1クラツド22
がSiO2ガラスであり、断面楕円形の第2クラツ
ド23がSiO2+B2O3+P2O5ガラスであり、外側
の第3クラツド24がSiO2ガラスである。 In this four-layer structure, the core 21 is made of SiO 2 +GeO 2 glass, and the first cladding 22 in contact with the core 21
is SiO 2 glass, the second cladding 23 having an elliptical cross section is SiO 2 +B 2 O 3 +P 2 O 5 glass, and the outer third cladding 24 is SiO 2 glass.
一般の使用では、このような構造の偏波面保存
光フアイバでも何ら問題は生じないのであるが、
放射線の存在する雰囲気で使用すると、伝送損失
が放射線の影響によつて著しく増大する。そのた
め、耐放射線性に優れ、しかも偏波面保存特性等
は損うことのない新たな構造が要求されている。 In general use, polarization-maintaining optical fibers with this structure do not cause any problems, but
When used in an atmosphere where radiation is present, transmission loss increases significantly due to the effects of radiation. Therefore, a new structure is required that has excellent radiation resistance and does not impair polarization preservation characteristics.
本発明は斯かる状況に鑑み、長波長帯での吸収
〓〓〓〓
損失を低減し、耐放射線性に優れ、しかも製造が
容易な偏波面保存光フアイバを提供することを目
的とする。 In view of this situation, the present invention has been developed to absorb absorption in a long wavelength band.
It is an object of the present invention to provide a polarization-maintaining optical fiber that has reduced loss, excellent radiation resistance, and is easy to manufacture.
本発明の構成を一実施例を示す第3図を参照し
て具体的に説明する。 The structure of the present invention will be specifically explained with reference to FIG. 3 showing one embodiment.
第3図において、31はコアであり、高純度
SiO2からなる。 In Figure 3, 31 is the core, which has high purity.
Consists of SiO2 .
32はB2O3を含まず、SiO2+F系ガラスから
なる断面楕円形の第1クラツドであり、33は
SiO2+B2O3系ガラスからなる断面楕円形の第2
クラツドであり、34は第3クラツドであり、例
えば若干不純物を含んだSiO2ガラスからなる。 32 is a first clad with an elliptical cross section made of SiO 2 +F glass and does not contain B 2 O 3 ;
A second glass with an elliptical cross section made of SiO 2 + B 2 O 3 glass
A third cladding 34 is made of, for example, SiO 2 glass containing some impurities.
ここで第2クラツド33におけるB2O3の量は
5〜15モル%である。 Here, the amount of B 2 O 3 in the second cladding 33 is 5 to 15 mol %.
このような構成の偏波面保存光フアイバを製造
する場合の例を以下に説明する。 An example of manufacturing a polarization-maintaining optical fiber having such a configuration will be described below.
まず、第3クラツドとなる外径18mm、厚さ1.5
mmの透明石英ガラス管の内壁面にSiO2+B2O3系
ガラス膜を添着する。 First, the third cladding has an outer diameter of 18 mm and a thickness of 1.5 mm.
A SiO 2 +B 2 O 3 based glass film is attached to the inner wall surface of a mm transparent quartz glass tube.
このときのB2O3の量は5〜15モル%であるこ
とが製造上重要である。 It is important in production that the amount of B 2 O 3 at this time is 5 to 15 mol %.
この内壁面に第1クラツドとなるSiO2+F系
ガラス膜を添着し、さらにその内面に高純度
SiO2の膜を添着する。 A SiO 2 +F-based glass film is attached to this inner wall surface as the first cladding, and a high-purity glass film is attached to the inner surface.
A film of SiO 2 is applied.
その後ガラス管の一端を封じ、他端より減圧器
により管内の圧力を−5mmH2Oにし、酸水素バー
ナーで約1900℃に加熱し、バーナーの移動速度を
5mm/minとしてガラス管を中実にする。このよ
うにして得られた中実母材を加熱線引きして偏波
面保存光フアイバを得る。 After that, one end of the glass tube is sealed, the pressure inside the tube is reduced to -5 mmH 2 O from the other end using a pressure reducer, and the glass tube is heated to approximately 1900℃ with an oxyhydrogen burner, and the burner is moved at a speed of 5 mm/min to solidify the glass tube. . The thus obtained solid base material is heated and drawn to obtain a polarization preserving optical fiber.
ここで重要なことは、第2クラツドのB2O3量
を5〜15モル%とすることである。 What is important here is that the amount of B 2 O 3 in the second cladding is 5 to 15 mol %.
すなわち、内側のコアを円形に保ちつつ、この
第2クラツドを楕円形に形成するためには、5〜
6モル%が限界的粘性であり、これよりドープ量
が少ないと楕円形に形成することが困難である。 That is, in order to form this second clad into an oval shape while keeping the inner core circular, it is necessary to
6 mol% is the critical viscosity, and if the doping amount is less than this, it is difficult to form an elliptical shape.
また、15〜16モル%はこの層の内側に高融点ガ
ラス層が安定的に形成できる限界粘性であり、こ
れよりB2O3の量が多いとコアの安定化が難しく
なり伝送損失が増大するという欠点がある。 In addition, 15 to 16 mol% is the critical viscosity at which a high melting point glass layer can be stably formed inside this layer, and if the amount of B 2 O 3 is larger than this, it will be difficult to stabilize the core and transmission loss will increase. There is a drawback that it does.
コアは高純度SiO2としたので粘性が大きく、
第2クラツドを楕円形に潰す際コアが同時に潰れ
ることがない。 The core is made of high-purity SiO 2 , so it has high viscosity.
When crushing the second clad into an oval shape, the core is not crushed at the same time.
以上、内付CVD法のみによる製造方法につい
て述べたが、第1クラツドまで上記方法で製造し
た後別の方法で製造したコアロツドをRT法によ
り一体化してもよく、あるいはまた、コアと第1
クラツドの複合ロツドを別の製造方法により製造
し、第2クラツドまで上記方法で製造したガラス
管とを一体化して母材を製造することもできる。 Although the manufacturing method using only the internal CVD method has been described above, the core rod may be manufactured by the above method up to the first cladding and then integrated by the RT method, or alternatively, the core and the first cladding may be integrated by the RT method.
It is also possible to manufacture a base material by manufacturing a composite rod of the cladding by another manufacturing method and integrating it with the glass tube manufactured by the above method up to the second cladding.
第1クラツドのドーパンド量により、第1クラ
ツドは円形にも楕円形にもなり得るが、円形の場
合には第1クラツドは異方性付与については特に
効果を奏さないのに対し、第1クラツドが楕円形
の場合には第2クラツドともども異方性付与に役
立つものである。 Depending on the amount of dopant in the first clad, the first clad can have either a circular or an elliptical shape, but in the case of a circular shape, the first clad has no particular effect on imparting anisotropy; If it is elliptical, both the second cladding and the second cladding are useful for imparting anisotropy.
特に本発明の場合、コアが高純度SiO2で硬い
のに対して、第1クラツドはコアより軟かく、ク
ツシヨンのように作用するため、コアに対して圧
力を付与する方向である楕円第2クラツドの短軸
方向においては、第1クラツドの厚さが薄い方が
異方性付与にはより効果的である。 Particularly in the case of the present invention, while the core is made of high-purity SiO 2 and is hard, the first cladding is softer than the core and acts like a cushion. In the short axis direction of the cladding, the thinner the first cladding is, the more effective it is for imparting anisotropy.
また第1クラツドの厚さはコア径の1/2倍ない
しコア径の2倍程度が望ましい。 The thickness of the first cladding is preferably about 1/2 to twice the core diameter.
以上説明した本発明の耐放射線性偏波面保存光
フアイバであれば次のような顕著な効果を奏す
る。 The radiation-resistant polarization-maintaining optical fiber of the present invention described above provides the following remarkable effects.
(1) コアに高純度SiO2であり、GeO2やP2O5等の
ドーパントが含まれていないので、放射線の影
響による伝送損失増大がほとんどなく、耐放射
線性に優れている。(1) Since the core is made of high-purity SiO 2 and does not contain dopants such as GeO 2 or P 2 O 5 , there is almost no increase in transmission loss due to the effects of radiation, and it has excellent radiation resistance.
(2) コアが高純度SiO2であり粘度が高いので楕
円層形成のために減圧を行つた場合にも形状が
くずれることがない。(2) Since the core is made of high-purity SiO 2 and has a high viscosity, the shape will not collapse even when reduced pressure is applied to form an elliptical layer.
(3) コアに接する第1クラツド層はB2O3を含ま
ないので長波長帯における吸収損失はほとんど
ない。(3) Since the first cladding layer in contact with the core does not contain B 2 O 3 , there is almost no absorption loss in the long wavelength band.
(4) 第2クラツドは楕円形であり、B2O3を含
み、これが有力な異方性歪付与材として働くの
で偏波面保存性に優れている。(4) The second cladding has an elliptical shape and contains B 2 O 3 , which acts as a powerful anisotropic strain imparting material and has excellent polarization preservation properties.
(5) 第2クラツドにおけるB2O3の層が厳選され
ているため、内付CVD法等一般的な製造方法
もしくはその組合せにより容易に製造でき、満
足できる特性の再現性も高い。(5) Since the B 2 O 3 layer in the second cladding is carefully selected, it can be easily manufactured by a general manufacturing method such as internal CVD method or a combination thereof, and the reproducibility of satisfactory characteristics is high.
第1図及び第2図は従来の偏波面保存光フアイ
バを示す断面説明図であり、第3図は本発明の一
実施例を示す断面説明図である。
〓〓〓〓
31:コア、32:第1クラツド、33:第2
クラツド、34:第3クラツド。
〓〓〓〓
1 and 2 are cross-sectional explanatory diagrams showing a conventional polarization-maintaining optical fiber, and FIG. 3 is a cross-sectional explanatory diagram showing an embodiment of the present invention. 〓〓〓〓
31: Core, 32: 1st Clad, 33: 2nd
Clad, 34: Third Clad. 〓〓〓〓
Claims (1)
の第1クラツドを有し、その外側に断面が楕円形
の第2クラツドを有し、さらにその外側に断面が
円形の第3クラツドを有し、前記コアは高純度
SiO2からなり、前記第1クラツドはSiO2+F系
ガラスからなり、前記第2クラツドはSiO2+
B2O3系ガラスからなり、前記第2クラツドにお
けるB2O3の量が5〜15モル%であることを特徴
とする耐放射線性偏波面保存光フアイバ。1. A core having a circular cross section, a first cladding having an elliptical cross section outside the core, a second cladding having an elliptical cross section outside the core, and a third cladding having a circular cross section outside the core. And the core is of high purity
The first cladding is made of SiO 2 +F glass, and the second cladding is made of SiO 2 +
A radiation-resistant polarization-maintaining optical fiber made of B 2 O 3 glass, characterized in that the amount of B 2 O 3 in the second cladding is 5 to 15 mol %.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57099051A JPS58215607A (en) | 1982-06-09 | 1982-06-09 | Radiation resistant polarization maintaining optical fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57099051A JPS58215607A (en) | 1982-06-09 | 1982-06-09 | Radiation resistant polarization maintaining optical fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58215607A JPS58215607A (en) | 1983-12-15 |
| JPS6135525B2 true JPS6135525B2 (en) | 1986-08-13 |
Family
ID=14236775
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57099051A Granted JPS58215607A (en) | 1982-06-09 | 1982-06-09 | Radiation resistant polarization maintaining optical fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58215607A (en) |
-
1982
- 1982-06-09 JP JP57099051A patent/JPS58215607A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58215607A (en) | 1983-12-15 |
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