JPS6136064B2 - - Google Patents
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- JPS6136064B2 JPS6136064B2 JP8759280A JP8759280A JPS6136064B2 JP S6136064 B2 JPS6136064 B2 JP S6136064B2 JP 8759280 A JP8759280 A JP 8759280A JP 8759280 A JP8759280 A JP 8759280A JP S6136064 B2 JPS6136064 B2 JP S6136064B2
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Description
本発明は耐食性にすぐれた航空機のストリンガ
ー用素材およびその製造法についてである。
本発明におけるストリンガーとは第1図に示す
ように航空機の胴体1の内部に使用される長手方
向および円周方向の補強材2(ストリンガー)お
よび3(ストリンガーフレーム)のことであつ
て、その断面形状は第2図に示すaハツ型、bZ
型およびcJ型等が代表的なものである。
航空機ストリンガー用材料にはAA7075合金が
主として用いられているが、AA7075合金は耐食
性の点で問題がある場合があるため、AA7075合
金を芯材としAA7072合金を皮材とした耐食性良
好な7075合金クラツド材も使用されている。
このAA7075合金クラツド材ストリンガーの従
来法による代表的な製造法はつぎのとおりである
AA7075合金を約460〜480℃で約16〜24時間の均
質化熱処理し、このAA7075合金を芯材とし、
AA7072合金を皮材として約400℃で厚さ4〜8
mm程度に熱間クラツド圧延し、約410℃×約1時
間の中間焼鈍をしたのち1時間当り約25℃の冷却
速度で炉冷し、厚さ2〜4mm程度の板に冷間圧延
したのち、8〜12時間の昇温時間で約420℃に昇
温し、その温度で約2時間加熱軟化したのち、1
時間当り約25℃の冷却速度で約235℃まで冷却
し、約235℃で6時間保持後空冷してストリンガ
ー素材とし、さらに加工度最大90%の段付き冷間
圧延加工(テーパーロール加工)をし、又は段付
き冷間圧延加工をすることなく溶体化処理してス
トリンガー用材料を製造していた。上記中、段付
き冷間圧延加工は例えば、第3図に示すような形
態にすなわち、長さ方向で圧延加工度を変え、加
工度0の部分A、比較的低加工度の部分B、中間
の加工度の部分C、高加工度の部分Dなどを有す
る形態に加工する。これは強度を要しない部分の
肉厚を薄くすることにより航空機全体の重量を軽
減するためのものである。このようにして製造さ
れたストリンガー用材料をセクシヨンロール成形
により、例えば第2図(a)に示すハツト型に成形
し、ついでT6テンパー処理を施すことによりス
トリンガーとするものである。
上記のような工程でストリンガーを製造する場
合にはつぎのような点が問題となる。
すなわち、従来法によりストリンガー素材とし
て製造されたAA7075合金O材のクラツド板は芯
材の結晶粒径が150〜250μm程度の粗大であり、
この素材を10〜30%程度の低加工度の冷間加工
(テーパー圧延)後に溶体化処理を行なう場合に
は素材の結晶粒よりさらに芯材の結晶粒が粗大化
し、約20%の加工度の部分が経験上最も粗大化し
ている。勿論このような素材を使用する場合でも
50%以上の冷間加工を行なつた後に溶体化処理を
行なう部分では芯材の結晶粒径50μm程度の微細
結晶粒が得られるが、1本のストリンガー内には
冷間加工度0から最大90%までの種々の加工度の
部分が存在するため、ストリンガーの全長約10m
全体にわたつて芯材の結晶粒径を100μm以下に
することは極めて難しい。
第4図には既存のストリンガー素材を種々の加
工度で冷間加工後に溶体化処理した場合の加工度
(上段)と芯材の結晶粒径(下段)との関係の1
例を示す。加工度の大きいD,F,G等の部分で
は結晶粒は微細であるが、加工度の小さいA,
B,C,E等の部分では結晶粒は非常に大きい。
A,B,C,E等の結晶粒径が100μm以上の
部分については機械的性質、伸び、破壊靭性値等
が低下すると共にセクシヨンロール成形時に肌荒
が生じたり、割れが発生するため、ストリンガー
の製造が極めて難しいばかりでなく、その機能も
低下する。また結晶粒が100μm以上の場合には
ケミカルミーリング後の面粗さが粗く疲労強度が
低下する。
本発明は上記のような問題点を解決せんとする
もので、芯材の結晶粒径が100μm以下でかつ10
〜30%程度の低加工度の冷間加工を行なつた後に
溶体化処理を行なつても芯材の結晶粒径が100μ
m以下である耐食性にすぐれたストリンガー素材
およびかかる素材の製造法を提供するものであ
る。
すなわち、本発明の第1発明は、Zn5.1〜8.1
%、Mg1.8〜3.4%、Cu1.2〜2.6%、Ti0.20%以
下、さらにCr0.18〜0.35%又はZr0.05〜0.25%の
1種又は2種を含み、残りAlと不純物より構成
される組成を有する合金を芯材としてZn0.8〜1.3
%を含むAl合金を皮材とする片面又か両面クラ
ツド材で、芯材の結晶粒径が100μm以下であ
り、かつ軽度の冷間加工後に溶体化処理を行なつ
ても芯材の結晶粒径が100μm以下である耐食性
にすぐれた航空機ストリンガー素材である。
本発明ストリンガー素材の芯材合金成分の限定
理由を以下に示す。
Zn……5.1%未満の場合にはT6処理後の素材の強
度が低く、8.1%を越えると靭性が低下した
り、応力腐食割れの危険がある。
Mg……1.8%未満の場合にはT6処理後の素材の
強度が低く、3.4%を越えると、軟質材の冷間
加工性が悪く、またT6処理後の素材の靭性が
低下する。
Cu……1.2%未満の場合にはT6処理後の素材の強
度が低く、2.6%を越えると素材の靭性が低下
する。
Ti……0.20%以下の添加は鋳造組織の微細化鋳造
時の鋳塊割れの防止に有効であるが、0.20%を
こえると巨大な金属間化合物が晶出する。
Cr……0.18%未満の場合には応力腐食割れの危険
があり、0.35%を越えると巨大な金属間化合物
が晶出するもので好ましくない。
Zr……0.05〜0.25%の添加は応力腐食割れの防止
とさらに結晶粒の微細化に有効であるが、0.05
未満の場合にはその効果が少なく、0.25%をこ
えると巨大な金属間化合物が晶出するので好ま
しくない。
なお、不純物元素としてのFe,Si,Mnは以下
のように規制する必要がある。
Fe……Feは結晶粒微細化に効果があるが、0.50
%をこえると合金中の不溶性化合物の量が増加
するため素材の靭性が低下する。
Si……Siは結晶粒の微細化に効果があるが、0.40
%をこえると合金中の不溶性化合物の量が増加
するため素材の靭性が低下する。
Mn……Mnは応力腐食割れの防止に効果がある
が、0.70%をこえると焼入性や靭性が低下す
る。
皮材の合金としては、耐食性に劣る芯材を保護
し耐食性を向上させる目的で、AA7075合金合せ
板(AA Alclad 7075 Sheet and Plate)や
AA7178合金合せ板(AA Alclad 7178 Sheet
and Plate)の場合と同様にAA7072合金を使用す
る。
本発明の素材を使用して航空機ストリンガーを
製造する場合には、テーパーロール加工の加工度
の大小にかかわらず、全長にわたつて溶体化処理
後の芯材の結晶粒が100μm以下のストリンガー
を得ることが可能であり、溶体化処理後の結晶粒
径が100μm以下の場合にはセクシヨンロール成
形時に肌荒や割れが全く生じないばかりでなく、
機械的性質、破壊靭性値、ケミカルミーリング
性、耐食性等にすぐれたストリンガーを得ること
が可能となる。
本発明の第2発明は上記第1発明における航空
機ストリンガー素材の製造法であつて、上記限定
のアルミニウム合金の芯材と皮材を均質化処理し
てから熱間クラツド圧延を行ない、その後冷間圧
延により所定の厚みにまで圧延した材料を320〜
500℃の温度に平均昇温速度が11℃/分より大き
い速度で急速に加熱することにより軟化すること
を特徴とする方法である。
本第2発明は上記限定のアルミニウム合金を均
質化処理するが、この均質化処理は芯材のアルミ
ニウム合金鋳塊を400〜490℃で2〜48時間十分に
加熱し、Zn,Mg,Cu等の元素を十分に固溶させ
ると共にCrやZrを微細な金属間化合物として析
出させるものである。温度が低いか時間が短いか
して均質化処理が不十分な場合には、アルミニウ
ム合金鋳塊の熱間加工性が悪く、耐応力腐食割れ
性が低下したり、結晶粒が粗大化したりする。ま
た、均質化処理温度が490℃よりも高いと共晶融
解を生じるので好ましくない。
皮材の合金鋳塊についても400〜560℃の温度で
2〜48時間の均質化処理を行ない、Zn等の添加
元素を十分に固溶させることが望ましい。均質化
処理後に皮材鋳塊は所定の厚みに圧延して皮材と
する。熱間圧延に先立つて芯材と皮材を脱脂洗滌
し、芯材と皮材を溶接により接合する。熱間クラ
ツド圧延は、350〜470℃の温度で開始することが
望ましい。350℃未満の場合には変形抵抗が大き
いので圧延加工性が悪く、470℃を越えると脆化
するので加工割れが生ずるようになり好ましくな
い。クラツド率については片面0.05〜10%とする
ことが望ましい。0.05%未満の場合には皮付圧延
が困難であるばかりでなく、皮材が損傷しやすく
耐食性にも問題がある。クラツド率が10%を越え
た場合には合せ板の熱処理後の強度が低下するの
で問題である。熱間圧延終了後、必要に応じて軟
化を行なう。軟化は300〜460℃の温度に保持後に
1時間当り30℃以下の冷却速度で260℃程度まで
冷却する必要がある。この軟化工程はつぎの冷間
圧延の加工度を高くとる場合に特に必要である。
冷間圧延における加工度は20%以上が望まし
く、加工度が低い場合にはストリンガー素材の芯
材の結晶粒径が100μm以上に粗大化する。
冷間圧延した材料は320〜500℃の温度に平均昇
温速度が11℃/分より大きい速度で急速加熱する
ことによる軟化が行なわれるが、この工程は高品
質のストリンガー素材を得る上で特に重要であ
る。
従来からAA7075合金の軟化の方法は413〜454
℃に加熱し、この温度で2時間保持し、空気中で
冷却し、232℃に再加熱し、この温度に6時間保
持し、それから室温まで冷却することによつて行
なわれている。この方法は、米国防省のMIL−
H6088E軍用規格中5,2,7,2項で推奨する
方法であり、航空機用7075合金の軟化方法はすべ
て上記方法に準拠しており、当業者の常識となつ
ている。本発明における上記軟化工程はかかる当
業者の常識を打破つたものである。
加熱温度が500℃をこえると材料が溶融した
り、芯材の異常結晶粒成長が起こり再結晶粒が著
しく粗大化するので好ましくない。
加熱温度が320℃より低い場合には材料が完全
に軟化、再結晶しないためストリンガーを製造す
る際の段付き冷間圧延加工(テーパーロール加
工)で割れが生ずる問題がある。
結局320〜500℃の温度で加熱軟化する場合にの
み100μm以下の微細な芯材の再結晶粒を有する
ストリンガー素材の製造が可能となる。
上記温度への昇温速度については、平均11℃/
分より大きい速度で急速加熱を行なうことが必須
で、この場合には加熱途上における芯材中のMg
−Nn系化合物の析出が少なく、冷間圧延により
導入された転位組識は急速加熱による軟化を行う
ことにより均一微細なセル組織に変化する。この
ような組織を有する素材を弱加工度のテーパーロ
ール加工(10〜30%)を行なつた後に溶体化処理
を行なう場合には均一微細なセル組織を核として
再結晶が進行するため均一微細な芯材の再結晶粒
が得られる。昇温速度が平均11℃/分以下の場合
には所定の軟化温度への加熱中に芯材中でMg−
Zn系の化合物が不均一析出すると共に転位組織
も完全に消滅するかあるいは粗大な不均一なサイ
ズのセル組織が残留する。このような素材を弱加
工のテーパーロール加工後に溶体化処理を行なう
場合には前記のような均一微細な再結晶粒は得ら
れず、芯材の結晶粒は著しく粗大化する。
急速加熱による軟化後の冷却速度については冷
却速度が1時間当りの30℃未満の場合には完全な
O材が得られるので、素材の冷間加工性は良好で
あり、1度に90%程度のテーパーロール圧延が可
能である。
これに対し急速加熱による軟化後の冷却速度が
速い場合には焼きが入り時効硬化するため、通常
の一般O材よりは強度の高い素材となるから比較
的加工度の低いストリンガー素材としては適用が
可能であるが、高加工度を必要とするストリンガ
ーへの適用には加工性の点で問題がある。
本発明の第3発明はその対策のためのもので、
第2発明において軟化の際の冷却速度が1時間当
り30℃以上のときには、200〜500℃に再加熱し
て、とりわけ再加熱温度が200〜350℃未満の場合
には空冷するか、1時間当り30℃以下の速度で冷
却し、再加熱温度が350〜500℃の場合には1時間
当り30℃以下の速度で冷却することを特徴とする
方法である。
すなわち、急速加熱後の冷却速度が1時間当り
30℃以上のときには焼きが入り時効硬化するた
め、所定の温度に再加熱してO材とする必要があ
る。再加熱温度が200℃より低い温度では軟化せ
ず、500℃を越えると結晶粒が粗大化するおそれ
がある。そして、再加熱後の冷却速度は再び焼き
が入らないようにするため再加熱温度が比較的低
温の200〜350℃未満の場合には空冷するか、冷却
速度が1時間当り30℃以下の冷却速度で冷却し、
再加熱温度が比較的高温の350〜500℃の場合に
は、冷却速度が1時間当り30℃以下の冷却速度で
冷却する。再加熱温度が200〜350℃未満の場合は
温度が低いので、冷却は空冷でも焼きが入らな
い。また再加熱温度が350〜500℃の場合は、冷却
速度は1時間当り30℃より大きいと焼きが入つて
好ましくない。このようにすることによつて、急
速軟化後の冷却速度が速い場合でも高加工度が可
能となる。
また、再加熱温度は得られた素材の引張強さお
よび素材を段付きテーパーロール加工した後、溶
体化処理した材料(以下W材と呼ぶことがあ
る。)の芯材の結晶粒径に影響することが実験に
より分つた。この関係の一例を第5図に示す。
第5図は急速加熱による軟化を行つた材料を各
温度で再加熱したO材の引張強さ及びこのO材を
20%冷間加工後470℃×40分溶体化処理したの
ち、水焼入したW材の結晶粒径再加熱温度との関
係を示す。
即ち、急速加熱による軟化後空冷し、室温に放
置した素材は焼きが入つているから、引張強さは
高く、再加熱することにより引張強さは再加熱温
度の上昇とともに低くなつている。また、再加熱
後20%の冷間加工を施したW材の芯材の結晶粒径
は、再加熱温度により異り、再加熱温度200〜350
℃のときの結晶粒径は約25〜35μmで比較的小さ
く、再加熱温度350〜440%のときの結晶粒径は35
〜50μmで可成り大きく、再加熱温度440〜500℃
のときの結晶粒径は30〜35μmと再び小さくな
る。
つぎに、実施例により本発明をさらに詳細に説
明する。
The present invention relates to an aircraft stringer material with excellent corrosion resistance and a method for manufacturing the same. The stringers in the present invention refer to the longitudinal and circumferential reinforcing members 2 (stringers) and 3 (stringer frames) used inside the fuselage 1 of an aircraft, as shown in FIG. The shape is a-shaped, bZ as shown in Figure 2.
Typical examples include type and cJ type. AA7075 alloy is mainly used as a material for aircraft stringers, but since AA7075 alloy sometimes has problems with corrosion resistance, we have developed a 7075 alloy cladding with good corrosion resistance that uses AA7075 alloy as the core material and AA7072 alloy as the skin material. materials are also used. The typical conventional manufacturing method for this AA7075 alloy clad stringer is as follows.
AA7075 alloy is homogenized at about 460-480℃ for about 16-24 hours, and this AA7075 alloy is used as a core material.
AA7072 alloy is used as the skin material and the thickness is 4 to 8 at about 400℃.
After hot cladding rolling to a thickness of approximately 2 mm, intermediate annealing at approximately 410°C for approximately 1 hour, cooling in a furnace at a cooling rate of approximately 25°C per hour, and cold rolling into a plate approximately 2 to 4 mm thick. , the temperature was raised to about 420℃ over a heating time of 8 to 12 hours, and after being heated and softened at that temperature for about 2 hours, 1
The material is cooled to approximately 235°C at a cooling rate of approximately 25°C per hour, held at approximately 235°C for 6 hours, and then air cooled to form a stringer material, which is then subjected to stepped cold rolling processing (taper roll processing) with a processing rate of up to 90%. Alternatively, stringer materials were produced by solution treatment without step cold rolling. Among the above, the stepped cold rolling process is performed, for example, in a form as shown in FIG. It is processed into a form having a part C with a processing degree of , a part D with a high processing degree, etc. This is to reduce the overall weight of the aircraft by reducing the thickness of parts that do not require strength. The stringer material thus produced is formed into a hat shape, for example, as shown in FIG. 2(a), by section roll forming, and then subjected to T6 tempering to form a stringer. When producing stringers using the process described above, the following problems arise. In other words, the clad plate of AA7075 alloy O material produced as a stringer material by the conventional method has a coarse core material crystal grain size of about 150 to 250 μm,
When this material is subjected to solution treatment after cold working (taper rolling) with a low workability of about 10 to 30%, the crystal grains of the core become even coarser than the crystal grains of the material, resulting in a workability of about 20%. According to my experience, this part is the most coarsened. Of course, even when using such materials
In areas where solution treatment is applied after 50% or more cold working, fine crystal grains with a core grain size of approximately 50 μm are obtained, but within a single stringer, the degree of cold working varies from 0 to max. There are parts with various processing degrees up to 90%, so the total length of the stringer is approximately 10 m.
It is extremely difficult to reduce the crystal grain size of the core material to 100 μm or less throughout. Figure 4 shows the relationship between the working degree (upper row) and the core material grain size (lower row) when existing stringer materials are subjected to solution treatment after cold working at various working degrees.
Give an example. The crystal grains are fine in parts D, F, G etc. where the degree of work is high, but in areas A, where the degree of work is small.
In areas such as B, C, and E, the crystal grains are very large. In areas where the crystal grain size is 100 μm or more, such as A, B, C, and E, the mechanical properties, elongation, fracture toughness, etc. decrease, and roughness and cracks occur during section roll forming. Not only is the stringer extremely difficult to manufacture, but its functionality is also reduced. Furthermore, if the crystal grains are 100 μm or more, the surface roughness after chemical milling will be rough and the fatigue strength will be reduced. The present invention aims to solve the above-mentioned problems.
Even if solution treatment is performed after cold working with a low working degree of ~30%, the crystal grain size of the core material remains 100μ.
The object of the present invention is to provide a stringer material with excellent corrosion resistance and a method for producing such a material. That is, the first invention of the present invention provides Zn5.1 to 8.1
%, Mg1.8~3.4%, Cu1.2~2.6%, Ti0.20% or less, and further contains one or two of Cr0.18~0.35% or Zr0.05~0.25%, and the remaining Al and impurities. Zn0.8~1.3 with an alloy having the composition as a core material
% aluminum alloy as the skin material, the crystal grain size of the core material is 100μm or less, and the crystal grain size of the core material is 100μm or less, and even if solution treatment is performed after mild cold working, the crystal grains of the core material are This is an aircraft stringer material with excellent corrosion resistance and a diameter of 100μm or less. The reasons for limiting the core alloy components of the stringer material of the present invention are shown below. Zn...If it is less than 5.1%, the strength of the material after T6 treatment will be low, and if it exceeds 8.1%, there is a risk of decreased toughness and stress corrosion cracking. Mg...If it is less than 1.8%, the strength of the material after T6 treatment will be low, and if it exceeds 3.4%, the cold workability of the soft material will be poor and the toughness of the material after T6 treatment will be reduced. Cu...If it is less than 1.2%, the strength of the material after T6 treatment will be low, and if it exceeds 2.6%, the toughness of the material will be reduced. Addition of Ti at 0.20% or less is effective in refining the casting structure and preventing cracking of the ingot during casting, but if it exceeds 0.20%, huge intermetallic compounds will crystallize. Cr...If it is less than 0.18%, there is a risk of stress corrosion cracking, and if it exceeds 0.35%, a huge intermetallic compound will crystallize, which is not preferable. Zr……Addition of 0.05 to 0.25% is effective in preventing stress corrosion cracking and further refining crystal grains, but
If it is less than 0.25%, the effect will be small, and if it exceeds 0.25%, a huge intermetallic compound will crystallize, which is not preferable. Note that Fe, Si, and Mn as impurity elements need to be regulated as follows. Fe...Fe is effective in refining grains, but 0.50
%, the amount of insoluble compounds in the alloy increases and the toughness of the material decreases. Si...Si is effective in refining crystal grains, but 0.40
%, the amount of insoluble compounds in the alloy increases and the toughness of the material decreases. Mn...Mn is effective in preventing stress corrosion cracking, but if it exceeds 0.70%, hardenability and toughness decrease. As the alloy for the skin material, AA Alclad 7075 Sheet and Plate and
AA Alclad 7178 Sheet
and Plate) using AA7072 alloy. When manufacturing aircraft stringers using the material of the present invention, regardless of the degree of tapered roll processing, stringers with crystal grains in the core material after solution treatment over the entire length are 100 μm or less. If the crystal grain size after solution treatment is 100 μm or less, not only will no roughness or cracks occur during section roll forming, but
It becomes possible to obtain stringers with excellent mechanical properties, fracture toughness values, chemical milling properties, corrosion resistance, etc. A second invention of the present invention is a method for manufacturing an aircraft stringer material according to the first invention, which comprises homogenizing the core material and skin material of the aluminum alloy limited above, then hot clad rolling, and then cold rolling. Material rolled to a specified thickness by 320~
This method is characterized by softening by rapid heating to a temperature of 500° C. at an average heating rate of more than 11° C./min. The second invention homogenizes the aluminum alloy limited above, and this homogenization treatment involves sufficiently heating the core aluminum alloy ingot at 400 to 490°C for 2 to 48 hours. The elements are sufficiently dissolved in solid solution, and Cr and Zr are precipitated as fine intermetallic compounds. If homogenization treatment is insufficient due to low temperature or short time, hot workability of the aluminum alloy ingot will be poor, stress corrosion cracking resistance will decrease, and crystal grains will become coarse. . Furthermore, if the homogenization treatment temperature is higher than 490°C, eutectic melting will occur, which is not preferable. It is desirable that the alloy ingot of the skin material is also subjected to a homogenization treatment at a temperature of 400 to 560°C for 2 to 48 hours to sufficiently dissolve additional elements such as Zn. After the homogenization treatment, the skin material ingot is rolled to a predetermined thickness to form the skin material. Prior to hot rolling, the core material and skin material are degreased and washed, and the core material and skin material are joined by welding. Hot clad rolling is preferably started at a temperature of 350-470°C. If the temperature is less than 350°C, the deformation resistance is high, resulting in poor rolling workability, and if it exceeds 470°C, it becomes brittle and may cause processing cracks, which is undesirable. The cladding rate is preferably 0.05 to 10% on one side. When it is less than 0.05%, it is not only difficult to roll with skin, but also the skin material is easily damaged and there are problems in corrosion resistance. If the cladding ratio exceeds 10%, it is a problem because the strength of the laminated plate after heat treatment decreases. After hot rolling, softening is performed as necessary. For softening, it is necessary to maintain the temperature at 300 to 460°C and then cool it to about 260°C at a cooling rate of 30°C or less per hour. This softening step is particularly necessary when the subsequent cold rolling is to be performed at a high degree of working. The working degree in cold rolling is desirably 20% or more, and if the working degree is low, the crystal grain size of the core material of the stringer material becomes coarser to 100 μm or more. The cold-rolled material is softened by rapid heating to temperatures between 320 and 500°C with an average heating rate greater than 11°C/min. This process is particularly important for obtaining high quality stringer material. is important. Conventionally, the method of softening AA7075 alloy is 413~454
C., held at this temperature for 2 hours, cooled in air, reheated to 232.degree. C., held at this temperature for 6 hours, and then cooled to room temperature. This method is based on the U.S. Department of Defense's MIL-
This is the method recommended in Sections 5, 2, 7, and 2 of the H6088E military standard, and all softening methods for aircraft 7075 alloy comply with the above method and are common knowledge to those skilled in the art. The above-mentioned softening step in the present invention breaks the common sense of those skilled in the art. If the heating temperature exceeds 500°C, the material may melt or abnormal crystal grain growth of the core material may occur, resulting in significantly coarse recrystallized grains, which is not preferable. If the heating temperature is lower than 320°C, the material will not completely soften and recrystallize, resulting in the problem of cracks occurring during stepped cold rolling (taper roll processing) when manufacturing stringers. After all, it is possible to produce a stringer material having fine core recrystallized grains of 100 μm or less only when it is heated and softened at a temperature of 320 to 500°C. Regarding the heating rate to the above temperature, the average is 11℃/
It is essential to perform rapid heating at a rate greater than 1 minute, and in this case, Mg in the core material during heating
- There is little precipitation of Nn-based compounds, and the dislocation structure introduced by cold rolling changes into a uniform fine cell structure by softening by rapid heating. When a material with such a structure is subjected to a weak taper roll process (10 to 30%) and then subjected to solution treatment, recrystallization proceeds with the uniform fine cell structure as the core, resulting in a uniform fine cell structure. Recrystallized grains of core material are obtained. If the heating rate is less than 11℃/min on average, Mg-
As the Zn-based compound precipitates non-uniformly, the dislocation structure either completely disappears or a coarse cell structure of non-uniform size remains. If such a material is subjected to solution treatment after weak tapering roll processing, the above-mentioned uniform and fine recrystallized grains cannot be obtained, and the crystal grains of the core material become extremely coarse. Regarding the cooling rate after softening due to rapid heating, if the cooling rate is less than 30℃ per hour, a complete O material can be obtained, so the cold workability of the material is good, and about 90% at a time. tapered roll rolling is possible. On the other hand, if the cooling rate after softening due to rapid heating is fast, quenching occurs and age hardening occurs, resulting in a material with higher strength than ordinary O material, so it cannot be used as a stringer material with a relatively low degree of processing. Although it is possible, there are problems in terms of processability when applied to stringers that require a high degree of processing. The third invention of the present invention is for the countermeasure,
In the second invention, when the cooling rate during softening is 30°C or more per hour, it is reheated to 200 to 500°C, and especially if the reheating temperature is less than 200 to 350°C, it is cooled in air or for 1 hour. This method is characterized by cooling at a rate of 30°C or less per hour, and when the reheating temperature is 350 to 500°C, cooling at a rate of 30°C or less per hour. In other words, the cooling rate after rapid heating is
When the temperature is 30°C or higher, it will harden and age harden, so it is necessary to reheat it to a predetermined temperature to make the O material. If the reheating temperature is lower than 200°C, it will not soften, and if it exceeds 500°C, the crystal grains may become coarse. In order to prevent reheating, the cooling rate after reheating should be air cooled if the reheating temperature is relatively low (less than 200 to 350℃), or the cooling rate should be 30℃ or less per hour. cooling at speed,
When the reheating temperature is relatively high, 350 to 500°C, cooling is performed at a cooling rate of 30°C or less per hour. If the reheating temperature is less than 200-350℃, the temperature is so low that baking will not occur even if air cooling is used. Further, when the reheating temperature is 350 to 500°C, it is not preferable that the cooling rate is higher than 30°C per hour because baking occurs. By doing so, even if the cooling rate after rapid softening is fast, a high degree of processing is possible. In addition, the reheating temperature affects the tensile strength of the obtained material and the crystal grain size of the core material of the material (hereinafter sometimes referred to as W material) that is solution-treated after processing the material into a stepped taper roll. It was found through experiments that An example of this relationship is shown in FIG. Figure 5 shows the tensile strength of O material obtained by reheating the material that has been softened by rapid heating at various temperatures, and the tensile strength of this O material.
The graph shows the relationship between the crystal grain size and reheating temperature of a W material that was water-quenched after 20% cold working and solution treatment at 470°C for 40 minutes. That is, a material that is air-cooled after being softened by rapid heating and left at room temperature has a high tensile strength because it is hardened, and when reheated, the tensile strength decreases as the reheating temperature increases. In addition, the crystal grain size of the core material of W material that has been subjected to 20% cold working after reheating varies depending on the reheating temperature.
℃, the crystal grain size is relatively small, about 25-35 μm, and when the reheating temperature is 350-440%, the crystal grain size is 35 μm.
~50μm, quite large, reheating temperature 440~500℃
The crystal grain size at this time becomes small again to 30 to 35 μm. Next, the present invention will be explained in more detail with reference to Examples.
【表】
実施例 1
上記表1に示した合金No.1およびNo.4を芯材と
しNo.10合金を皮材として本発明方法により製造さ
れた芯材の結晶粒径100μm以下のストリンガー
素材と、No.1およびNo.4合金を芯材とし、No.10合
金を皮材として従来法により製造された芯材の結
晶粒径100μmの3mm厚のストリンガー素材の諸
性能比較結果を表2に示す。芯材の結晶粒が微細
であり、しかも冷間加工して焼入後の芯材の結晶
粒が微細な本発明素材は従来法による素材で問題
となるセクシヨンロール成形時の肌荒・割れ等の
問題を解消することができた。
また本発明材は破壊靭性値、ケミカルミーリン
グ性にもすぐれており、AA7072合金をクラツド
しているため従来材に比べて耐食性も著しくすぐ
れている。[Table] Example 1 Stringer material with crystal grain size of core material of 100 μm or less produced by the method of the present invention using alloys No. 1 and No. 4 shown in Table 1 as core materials and alloy No. 10 as skin material. Table 2 shows the performance comparison results of a 3 mm thick stringer material with a core grain size of 100 μm manufactured by the conventional method using No. 1 and No. 4 alloys as the core material and No. 10 alloy as the skin material. Shown below. The material of the present invention, which has fine crystal grains in the core material and also has fine crystal grains in the core material after cold working and quenching, does not suffer from rough skin and cracking during section roll forming, which is a problem with materials made using conventional methods. We were able to resolve the issues such as: The material of the present invention also has excellent fracture toughness and chemical milling properties, and because it is clad with AA7072 alloy, it has significantly better corrosion resistance than conventional materials.
【表】
本発明による製造法:
芯材の均質化処理(460℃×16hr)→熱間クラ
ツド圧延(400℃で300mm→6mmに圧延)→冷間圧
延(6mm→3mm)→急速加熱(450℃に昇温速度
200℃/分で加熱し3分保持)→冷却(5℃/分
で冷却)→再加熱(300℃×1hr)→冷却(20℃/
hrの冷却速度で200℃まで冷却し、その後空冷)
従来法による製造法:
芯材の均質化処理(460℃×16hr)→熱間クラ
ツド圧延(400℃で6mmまで圧延)→軟化(420℃
×1hr加熱→炉冷)→冷間圧延(6→3mm)→軟
化(420℃×2hr加熱)→25℃/hrで235℃まで冷
却→235℃で6hr保持→空冷。
実施例2(急速加熱の昇温速度の影響)
表1に示す合金No.1を470℃で24時間の均質化
処理後No.10合金を皮材として410℃より熱間クラ
ツド圧延を開始し、350mmより6mm厚の板に圧延
した。熱間圧延の終了温度は340℃であつた。つ
いで6mm厚板を3mm厚まで冷間圧延し、これを表
3に示す種々の昇温速度で450℃に加熱し、2分
間保持した後に1時間当り25℃の冷却速度で冷却
し、3mmO材とした。この板を種々の加工度で冷
間加工後にソルトバスを使用して470℃×40分の
溶体化処理後に水焼入した材料(W材)の芯材の
結晶粒度と450℃への昇温速度の関係を表3に示
す。なおクラツド率は片面2.4%の両面クラツド
である。[Table] Manufacturing method according to the present invention: Homogenization treatment of core material (460°C x 16hr) → Hot clad rolling (rolling from 300mm to 6mm at 400°C) → Cold rolling (6mm → 3mm) → Rapid heating (450°C) Heating rate in °C
Heating at 200℃/min and holding for 3 minutes) → Cooling (cooling at 5℃/min) → Reheating (300℃ x 1hr) → Cooling (20℃/min)
hr cooling rate to 200℃, then air cooling) Conventional manufacturing method: Core material homogenization treatment (460℃ x 16hr) → Hot clad rolling (rolled to 6 mm at 400℃) → Softening (420℃)
x 1hr heating → furnace cooling) → cold rolling (6 → 3mm) → softening (420℃ x 2hr heating) → cooling to 235℃ at 25℃/hr → holding at 235℃ for 6 hours → air cooling. Example 2 (Influence of temperature increase rate during rapid heating) After homogenizing alloy No. 1 shown in Table 1 at 470°C for 24 hours, hot clad rolling was started at 410°C using No. 10 alloy as a skin material. , 350mm was rolled into a 6mm thick plate. The finishing temperature of hot rolling was 340°C. Next, the 6 mm thick plate was cold rolled to a thickness of 3 mm, heated to 450°C at various heating rates shown in Table 3, held for 2 minutes, and then cooled at a cooling rate of 25°C per hour to form a 3 mm O material. And so. The grain size of the core material of the material (W material) obtained by cold working this plate at various working degrees, solution treatment using a salt bath for 40 minutes at 470°C, and water quenching and the temperature increase to 450°C. Table 3 shows the speed relationship. The cladding rate is 2.4% on one side and cladding on both sides.
【表】【table】
【表】
表3に示されるように、450℃への昇温速度が
平均11℃/分より大きい場合には素材の芯材の結
晶粒および冷間加工後溶体化処理した材料の芯材
の結晶粒は100μm以下の均一微細粒であるが、
平均11℃/分以下の場合には芯材の結晶粒は著し
く粗大化する。
ついで上記3mmO材のうち代表的なものについ
てさらに詳細に性能を検討するため、ストリンガ
ーの加工に相当する0〜80%の冷間圧延を行な
い、これをソルトバスを使用して470℃で40分の
溶体化処理してから水焼入したW材および焼入後
に120℃で24時間時効したT6材の諸性能を表4に
示す。昇温速度が平均11℃/分より大きい材料は
ストリンガー素材として良好な性能を有してい
る。なお、耐食性についてもNo.10のAA7072合金
をクラツドしているため問題はない。[Table] As shown in Table 3, when the heating rate to 450°C is higher than an average of 11°C/min, the crystal grains of the core material of the material and the core material of the material subjected to solution treatment after cold working are The crystal grains are uniform fine grains of 100 μm or less,
When the average temperature is below 11°C/min, the crystal grains of the core material become significantly coarsened. Next, in order to examine the performance of typical 3mmO materials mentioned above in more detail, we performed 0 to 80% cold rolling, which corresponds to stringer processing, and rolled this at 470°C for 40 minutes using a salt bath. Table 4 shows the various performances of the W material, which was solution-treated and water-quenched, and the T6 material, which was aged at 120°C for 24 hours after quenching. Materials with a heating rate greater than 11° C./min on average have good performance as stringer materials. Furthermore, there is no problem with corrosion resistance as it is made of No. 10 AA7072 alloy.
【表】【table】
【表】
実施例3(加熱温度の影響)
表1に示した合金No.2を芯材とし、No.10合金を
皮材として実施例2と全く同じ方法で3mmの冷間
圧延上りクラツド板に圧延した。この板を320〜
520℃間の各温度に、種々の昇温速度で加熱し、
その後1分当り5℃の冷却速度で冷却し、ついで
300℃で1時間加熱し、1時間当り20℃の冷却速
度で冷却し3mmO材とした。なお、クラツド率は
2.5%であり、片面のみクラツドを行なつた。
上記3mmO材を冷間加工後に、ソルトバスを使
用して470℃で40分の溶体化処理後に水焼入した
W材の芯材の結晶粒度と昇温時間2分で昇温させ
た加熱温度の関係を表5に示す。弱加工後に溶体
化処理を行なつた場合でも芯材の結晶粒の微細な
材料の得られるのは、冷間圧延上りの板を320〜
500℃の温度に急速加熱して軟化したO材のみで
あり、加熱温度がこの範囲外の場合には弱加工後
に溶体化処理しても芯材の結晶粒の微細な材料は
得られない。[Table] Example 3 (Effect of heating temperature) A 3 mm cold-rolled clad plate was prepared in exactly the same manner as in Example 2 using Alloy No. 2 shown in Table 1 as the core material and No. 10 alloy as the skin material. Rolled to . This board is 320~
Heated to various temperatures between 520℃ at various heating rates,
After that, it was cooled at a cooling rate of 5°C per minute, and then
It was heated at 300°C for 1 hour and cooled at a cooling rate of 20°C per hour to form a 3 mmO material. In addition, the clud rate is
2.5%, and cladding was performed on only one side. After cold working the above 3mmO material, the crystal grain size of the core material of the W material was water-quenched after solution treatment at 470℃ for 40 minutes using a salt bath, and the heating temperature was increased with a heating time of 2 minutes. The relationship is shown in Table 5. Even if solution treatment is performed after mild working, a core material with fine grains can only be obtained when the cold-rolled plate is heated to 320~320
It is only O material that has been softened by rapid heating to a temperature of 500°C, and if the heating temperature is outside this range, a material with fine core grains cannot be obtained even if solution treatment is performed after weak working.
【表】
表5に示した条件で軟化した3mm厚O材のうち
の3例につき、最大80%の冷間圧延をし、470℃
で40分の溶体化処理をしてから水焼入れしたW材
および焼入後に122℃で25時間時効したT6材につ
いての試験をした。その結果を表6に示すが、各
例ともストリンガー素材として十分な性能を有し
ていた。[Table] Three examples of 3 mm thick O material softened under the conditions shown in Table 5 were cold rolled to a maximum of 80% and heated to 470°C.
Tests were conducted on W material that was solution-treated for 40 minutes and then water-quenched, and T6 material that was aged at 122°C for 25 hours after quenching. The results are shown in Table 6, and each example had sufficient performance as a stringer material.
【表】
実施例4(加熱保持時間の影響)
表1に示す合金No.3を芯材とし、No.10合金を皮
材として実施例2と全くじ方法で3mm厚の冷間圧
延上り板にクラツド圧延した。この板を表7に示
す昇温速で480〜385℃の温度に加熱し、各時間保
持したのち、1分当り5℃の冷却速度で冷却し、
ついで300℃×1時間の加熱後空冷し3mmO材と
した。なおクラツド率は2.5%であり、両面のク
ラツドを行なつた。
この3mmのO材を20%の冷間圧延後にソルトバ
スを使用して470℃で40分の溶体化処理後に水焼
入したW材の芯材の結晶粒径と加熱温度と保持時
間の関係を表7に示す。[Table] Example 4 (Effect of heating holding time) A 3 mm thick cold rolled plate was prepared in the same manner as in Example 2 using Alloy No. 3 shown in Table 1 as the core material and No. 10 alloy as the skin material. Clad rolled. This plate was heated to a temperature of 480 to 385°C at the heating rate shown in Table 7, held for each time, and then cooled at a cooling rate of 5°C per minute.
Then, after heating at 300°C for 1 hour, the material was cooled in air to obtain a 3 mmO material. The cladding rate was 2.5%, and cladding was performed on both sides. The relationship between the crystal grain size, heating temperature, and holding time of the W material core material, which was water-quenched after 20% cold rolling of this 3 mm O material and then solution treatment at 470℃ using a salt bath for 40 minutes. are shown in Table 7.
【表】
この表7から判るとおり、各保持時間にわたつ
て芯材の結晶粒の微細な材料が得られることは明
らかである。
上記の3mmの材板を0〜90%冷間圧延したのち
に、溶体化処理して水焼入したW材の芯材の結晶
粒は全て100μm以下であり、1.5t(t=板厚)
の曲げ半径で90゜曲げを行なつた場合にも肌荒れ
や割れは全く生ぜず、ストリンガー素材として好
適なものであつた。
実施例 5
表1に示したNo.1合金の350mm厚鋳塊を芯材と
し、No.10合金を皮材として表8に示す製造条件の
下でクラツド圧延し、最終2〜5mm厚のO材板と
した。なお、クラツド率は片面2.2%であり両面
クラツドを行なつた。
表8におけるNo.1〜17の製造条件で製造したO
材板を20%冷間圧延したのちにソルトバスを使用
して470℃で40分の溶体化処理後に水焼入し、120
℃で24時間時効したT6材の諸性能の試験結果を
表9に示す。
表9より明らかなように本発明の条件により製
造したストリンガー素材の芯材の結晶粒径は100
μm以下であり、冷間加工後に焼入した材料につ
いても芯材の結晶粒径は100μm以下と粗大化せ
ず、またW材、T6材共にストリンガー材料とし
て良好な性能を示している。なお、表9には加工
度20%の場合の結果のみ示したが、0〜80%の冷
間加工を行なう場合についても溶体化処理後の芯
材の結晶粒径は全て100μm以下であり、W材,
T6材共にストリンガー用材料として十分な性能
を有していた。[Table] As can be seen from Table 7, it is clear that a material with fine crystal grains of the core material can be obtained over each holding time. The crystal grains of the core material of the W material, which was cold rolled from 0 to 90% of the above 3 mm material plate, solution treated and water quenched, are all less than 100 μm, and are 1.5 t (t = plate thickness).
Even when bent at 90 degrees with a bending radius of , no roughening or cracking occurred at all, making it suitable as a stringer material. Example 5 A 350 mm thick ingot of the No. 1 alloy shown in Table 1 was used as the core material, and No. 10 alloy was used as the skin material to be clad rolled under the production conditions shown in Table 8, and a final 2-5 mm thick ingot was rolled. It was made into a timber board. The cladding rate was 2.2% on one side, and double-sided cladding was performed. O manufactured under the manufacturing conditions of Nos. 1 to 17 in Table 8
After cold-rolling the material plate by 20%, it was solution-treated at 470°C for 40 minutes using a salt bath, and then water-quenched to 120%.
Table 9 shows the test results of various performances of T6 material aged at ℃ for 24 hours. As is clear from Table 9, the crystal grain size of the core material of the stringer material manufactured under the conditions of the present invention is 100.
The crystal grain size of the core material is 100 μm or less even for materials quenched after cold working, and does not become coarse, and both the W material and the T6 material exhibit good performance as stringer materials. Although Table 9 shows only the results when the degree of working is 20%, even when cold working is performed from 0 to 80%, the crystal grain size of the core material after solution treatment is all 100 μm or less, W material,
Both T6 materials had sufficient performance as stringer materials.
【表】【table】
【表】【table】
【表】【table】
【表】
実施例6(合金組成の影響)
表1に示した合金No.3〜7の400mm厚鋳塊を470
℃で25時間均質化処理したのち、芯材とし、No.10
合金を皮材として400℃より熱間クラツド圧延を
開始し、6mm厚の板に圧延した。熱間圧延終了温
度は300℃であつた。ついで、6mm厚板を3mm厚
まで冷間圧延し、平均昇温速度300℃/分で460℃
に加熱し、5分間その温度に保持したのち、1分
当り10℃の冷却速度で冷却し、その後300℃で1
時間加熱後空冷し3mmO材とした。
比較のため表1に示した合金No.8並びにNo.9合
金を芯材とし、No.10合金を皮材として同じ方法で
最終3mmのO板材とした。なおクラツド率は2.6
%であり片面のみクラツドを行なつた。これらの
O材板のストリンガー素材としての性能をみるた
め、各O材板を20%冷間圧延したのち、470℃で
40分間溶体化処理し水焼入したW材および焼入後
に120℃で24時間時効したT6材についての試験を
した。その諸性能を表10に示す。
合金3〜7を芯材とする場合はストリンガー材
として良好な性能を有しているが、No.8合金を芯
材とする場合は強度が低く、No.9合金を芯材とす
る場合は芯材の応力腐食割れの危険があるためス
トリンガー材としての使用には問題がある。[Table] Example 6 (Influence of alloy composition) A 400 mm thick ingot of alloy No. 3 to 7 shown in Table 1 was
After homogenizing at ℃ for 25 hours, it was used as a core material and No.10
Hot clad rolling was started at 400°C using the alloy as a skin material, and a plate with a thickness of 6 mm was rolled. The hot rolling finish temperature was 300°C. Next, the 6 mm thick plate was cold rolled to 3 mm thickness and heated to 460°C at an average heating rate of 300°C/min.
After heating at that temperature for 5 minutes, cooling at a cooling rate of 10°C per minute, and then cooling at 300°C for 1 minute.
After heating for a period of time, it was air cooled to obtain a 3 mmO material. For comparison, alloys No. 8 and No. 9 shown in Table 1 were used as the core material, and alloy No. 10 was used as the skin material, and a final 3 mm O plate material was prepared in the same manner. The crud rate is 2.6.
%, and cladding was performed on only one side. In order to examine the performance of these O material plates as stringer materials, each O material plate was cold rolled by 20% and then rolled at 470℃.
Tests were conducted on W material that was solution treated for 40 minutes and water quenched, and T6 material that was aged at 120°C for 24 hours after quenching. Its various performances are shown in Table 10. When alloys 3 to 7 are used as the core material, they have good performance as stringer materials, but when No. 8 alloy is used as the core material, the strength is low, and when No. 9 alloy is used as the core material, the stringer material has good performance. Its use as a stringer material is problematic because of the risk of stress corrosion cracking of the core material.
第1図は航空機胴体内部の一部斜視図、第2図
a,b,cはストリンガーの断面形状の例、第3
図はストリンガー素材の加工状態を示す斜視図、
第4図は加工度と結晶粒径との関係の1例を示す
説明図、第5図は素材の引張強さとW材の結晶粒
径と再加熱温度との関係を示すグラフである。
1……胴体、2……補強材(ストリンガー)、
3……補強材(ストリンガーフレーム)。
Figure 1 is a partial perspective view of the inside of the aircraft fuselage, Figures 2 a, b, and c are examples of cross-sectional shapes of stringers, and Figure 3
The figure is a perspective view showing the processing state of the stringer material.
FIG. 4 is an explanatory diagram showing an example of the relationship between the working degree and the grain size, and FIG. 5 is a graph showing the relationship between the tensile strength of the material, the grain size of the W material, and the reheating temperature. 1... Body, 2... Reinforcement material (stringer),
3...Reinforcement material (stringer frame).
Claims (1)
%、Ti0.20%以下、さらにCr0.18〜0.35%又は
Zr0.05〜0.25%の1種又は2種を含み、残りAlと
不純物より構成される組成を有する合金を芯材と
し、Zn0.8〜1.3%を含むAl合金を皮材とする片面
又は両面クラツド材で、芯材の結晶粒径が100μ
m以下であり、かつ軽度の冷間加工後に溶体化処
理を行なつても芯材の結晶粒径が100μm以下で
ある耐食性にすぐれた航空機ストリンガー素材。 2 Zn5.1〜8.1%、Mg1.8〜3.4%、Cu1.2〜2.6
%、Ti0.20%以下、さらにCr0.18〜0.35%又は
Zr0.05〜0.25%の1種又は2種を含み、残りAlと
不純物よりなる合金を均質化処理してから芯材と
し、Zn0.8〜1.3%を含むAl合金を皮材として片面
又は両面クラツドの熱間クラツド圧延を行ない、
その後冷間圧延により所定の厚みにまで圧延した
材料を320〜500℃の温度に平均昇温速度11℃/分
より大きい速度で急速に加熱することにより軟化
し、芯材の結晶粒径が100μm以下であり、かつ
軽度の冷間加工後に溶体化処理を行なつても芯材
の結晶粒径が100μm以下であることを特徴とす
る耐食性にすぐれた航空機ストリンガー素材の製
造法。 3 Zn5.1〜8.1%、Mg1.8〜3.4%、Cu1.2〜2.6
%、Ti0.20%以下、さらにCr0.18〜0.35%又は
Zr0.05〜0.25%の1種又は2種を含み、残りAlと
不純物よりなる合金を均質化処理してから芯材と
し、Zn0.8〜1.3%を含むAl合金を皮材として片面
又は両面の熱間クラツド圧延を行ない、その後冷
間圧延により所定の厚みにまで圧延した材料を
320〜500℃の温度に平均昇温速度が11℃/分より
大きい速度で急速加熱することにより軟化し、こ
の軟化の際の冷却速度が1時間当り30℃以上のと
きに200〜500℃に再加熱して再加熱温度が200〜
350℃未満の場合には空冷又は1時間当り30℃以
下の速度で冷却し、又再加熱温度が350〜500℃の
場合には1時間当り30℃以下の速度で冷却し、芯
材の結晶粒径が100μm以下であり、かつ軽度の
冷間加工後に溶体化処理を行なつても芯材の結晶
粒径が100μm以下であることを特徴とする耐食
性にすぐれた航空機ストリンガー素材の製造法。[Claims] 1 Zn5.1-8.1%, Mg1.8-3.4%, Cu1.2-2.6
%, Ti0.20% or less, further Cr0.18~0.35% or
One side or both sides with an alloy containing one or two types of Zr0.05~0.25% and the remainder consisting of Al and impurities as the core material and an Al alloy containing 0.8~1.3% Zn as the skin material. Clad material with a core grain size of 100μ
An aircraft stringer material with excellent corrosion resistance, in which the crystal grain size of the core material is 100 μm or less even after mild cold working and solution treatment. 2 Zn5.1-8.1%, Mg1.8-3.4%, Cu1.2-2.6
%, Ti0.20% or less, further Cr0.18~0.35% or
An alloy containing one or two types of Zr0.05~0.25% and the remaining Al and impurities is homogenized and used as a core material, and an Al alloy containing Zn0.8~1.3% is used as a skin material on one or both sides. Perform hot crud rolling of the crud,
The material is then cold-rolled to a predetermined thickness and then rapidly heated to a temperature of 320 to 500°C at an average temperature increase rate of greater than 11°C/min to soften it, and the crystal grain size of the core material is reduced to 100 μm. A method for producing an aircraft stringer material with excellent corrosion resistance, characterized in that the crystal grain size of the core material is 100 μm or less even after mild cold working and solution treatment. 3 Zn5.1~8.1%, Mg1.8~3.4%, Cu1.2~2.6
%, Ti0.20% or less, further Cr0.18~0.35% or
An alloy containing one or two types of Zr0.05~0.25% and the remaining Al and impurities is homogenized and used as a core material, and an Al alloy containing Zn0.8~1.3% is used as a skin material on one or both sides. The material is hot clad rolled and then cold rolled to a specified thickness.
It is softened by rapid heating to a temperature of 320 to 500°C at an average heating rate of more than 11°C/min, and when the cooling rate during this softening is 30°C or more per hour, it is heated to 200 to 500°C. Reheat and reheat temperature is 200 ~
If the temperature is less than 350°C, cool by air or at a rate of 30°C or less per hour, and if the reheating temperature is 350 to 500°C, cool at a rate of 30°C or less per hour to remove the crystals of the core material. A method for producing an aircraft stringer material with excellent corrosion resistance, characterized in that the grain size is 100 μm or less, and the crystal grain size of the core material is 100 μm or less even after mild cold working and then solution treatment.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8759280A JPS5713140A (en) | 1980-06-27 | 1980-06-27 | Material for stringer of airplane with superior corrosion resistance and its manufacture |
| US06/173,529 US4410370A (en) | 1979-09-29 | 1980-07-30 | Aircraft stringer material and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8759280A JPS5713140A (en) | 1980-06-27 | 1980-06-27 | Material for stringer of airplane with superior corrosion resistance and its manufacture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5713140A JPS5713140A (en) | 1982-01-23 |
| JPS6136064B2 true JPS6136064B2 (en) | 1986-08-16 |
Family
ID=13919260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8759280A Granted JPS5713140A (en) | 1979-09-29 | 1980-06-27 | Material for stringer of airplane with superior corrosion resistance and its manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5713140A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102020128738A1 (en) | 2020-11-02 | 2022-05-05 | Bayerische Motoren Werke Aktiengesellschaft | Wheel cover assembly, vehicle having a wheel cover assembly and method of operating such a vehicle |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1211023B (en) * | 1981-04-15 | 1989-09-29 | Italia Alluminio | COMPOSITE PLATES IN ALUMINUM ALLOYS. |
| JP5128124B2 (en) * | 2003-04-10 | 2013-01-23 | アレリス、アルミナム、コブレンツ、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | Al-Zn-Mg-Cu alloy |
| JP2022532347A (en) * | 2019-06-03 | 2022-07-14 | ノベリス・インコーポレイテッド | Ultra-high-strength aluminum alloy products and their manufacturing methods |
-
1980
- 1980-06-27 JP JP8759280A patent/JPS5713140A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102020128738A1 (en) | 2020-11-02 | 2022-05-05 | Bayerische Motoren Werke Aktiengesellschaft | Wheel cover assembly, vehicle having a wheel cover assembly and method of operating such a vehicle |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5713140A (en) | 1982-01-23 |
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