JPS6139022B2 - - Google Patents
Info
- Publication number
- JPS6139022B2 JPS6139022B2 JP58083753A JP8375383A JPS6139022B2 JP S6139022 B2 JPS6139022 B2 JP S6139022B2 JP 58083753 A JP58083753 A JP 58083753A JP 8375383 A JP8375383 A JP 8375383A JP S6139022 B2 JPS6139022 B2 JP S6139022B2
- Authority
- JP
- Japan
- Prior art keywords
- potassium chloride
- glycine
- added
- aqueous solution
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 66
- 235000011164 potassium chloride Nutrition 0.000 claims description 33
- 239000001103 potassium chloride Substances 0.000 claims description 33
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 150000001413 amino acids Chemical class 0.000 claims description 8
- 239000000796 flavoring agent Substances 0.000 claims description 8
- 235000019634 flavors Nutrition 0.000 claims description 8
- 150000007524 organic acids Chemical class 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 230000003804 effect on potassium Effects 0.000 claims 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 28
- 239000004471 Glycine Substances 0.000 description 14
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 10
- 235000019606 astringent taste Nutrition 0.000 description 10
- 235000019658 bitter taste Nutrition 0.000 description 10
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 9
- 235000002949 phytic acid Nutrition 0.000 description 9
- 229940068041 phytic acid Drugs 0.000 description 9
- 239000000467 phytic acid Substances 0.000 description 9
- 235000001014 amino acid Nutrition 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 235000005985 organic acids Nutrition 0.000 description 4
- 235000019643 salty taste Nutrition 0.000 description 4
- 230000001953 sensory effect Effects 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 235000013373 food additive Nutrition 0.000 description 3
- 239000002778 food additive Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000004278 EU approved seasoning Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 235000019640 taste Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000015872 dietary supplement Nutrition 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- -1 etc. Chemical compound 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Landscapes
- Seasonings (AREA)
Description
本発明は、塩化カリウムの塩味を損なうことな
く味覚的欠点である渋味および苦味を消去させる
と共にアミノ酸および有機酸の添加に基き風味が
著しく改善化されるように成したことを特徴とす
る塩化カリウムの風味改善法に関するものであ
る。
塩化カリウムは塩味を有し、近来、調味料の減
塩用として、またカリウムの栄養補給のためのド
リンク剤添加用として盛んに利用されている。然
し乍ら、塩化カリウムは塩味の外に食感を著しく
損ねる渋味および苦味が強いと云う欠点を有し、
従つて、該塩化カリウムを飲食料用添加物として
多量に用いることは食感上困難とされた。
本発明は上述した如き在来に於ける問題点の解
消化を図つたものである。
すなわち本発明は、塩化カリウムに対しキレー
ト作用を有するアミノ酸またはアミノ酸混合含有
物を重量比1/3以上添加してこれを水溶液とな
し、然る後、キレート作用を有する有機酸を所要
量添加することに依りPH度4.5以下の弱酸性に調
節して塩化カリウム含有の水溶液を得、また必要
に応じてこれを乾燥物化するように成したことを
特徴とする塩化カリウムの風味改善法に係るもの
である。
本発明は、添加物として金属をキレートする能
力の高いアミノ酸、またはこれに代えてアミノ酸
混合含有物である蛋白質分解物及び動植物エキス
等を用いるが、アミノ酸としてはキレート作用が
強くかつ甘味を有するグリシン、アラニン等を用
い、特にグリシンがその特性上最も適している。
また、本発明に用いるもう一つの添加物である有
機酸であるが、これはほとんどの有機酸類が使用
可能とされるが、そのうちでもキレート作用及び
緩衝作用が特に強いと云う性質を具えているフイ
チン酸が最も適している。
以下に、アミノ酸としてグリシンを、また有機
酸としてフイチン酸を用いて塩化カリウムの風味
変化について官能試験を行なつた結果を説明す
る。
(1) 塩化カリウムにグリシンだけを加えた試験塩
化カリウム(食添用)とグリシン(食添用)の
混合量は以下の通りである。
The present invention is characterized in that the astringency and bitterness, which are the taste defects of potassium chloride, are eliminated without impairing the salty taste, and the flavor is significantly improved based on the addition of amino acids and organic acids. This invention relates to a method for improving the flavor of potassium. Potassium chloride has a salty taste, and has recently been widely used for reducing salt in seasonings and as an addition to drinks for nutritional supplementation of potassium. However, potassium chloride has the disadvantage that in addition to its salty taste, it has a strong astringent and bitter taste that significantly impairs the texture.
Therefore, it has been difficult to use large amounts of potassium chloride as an additive for food and beverages in terms of texture. The present invention aims to solve the above-mentioned conventional problems. That is, in the present invention, an amino acid or a mixture of amino acids having a chelating effect is added to potassium chloride at a weight ratio of 1/3 or more to form an aqueous solution, and then a required amount of an organic acid having a chelating effect is added. A method for improving the flavor of potassium chloride, which is characterized in that the aqueous solution containing potassium chloride is obtained by adjusting the pH to a weak acidity of 4.5 or less, and if necessary, converting this into a dried product. It is. In the present invention, amino acids with a high ability to chelate metals are used as additives, or instead, protein decomposition products containing mixed amino acids, animal and plant extracts, etc. are used as additives. , alanine, etc., and glycine is particularly suitable due to its characteristics.
Furthermore, organic acids are another additive used in the present invention. Most organic acids can be used, but among them, organic acids have particularly strong chelating and buffering effects. Phytic acid is the most suitable. Below, the results of a sensory test regarding flavor change of potassium chloride using glycine as an amino acid and phytic acid as an organic acid will be explained. (1) Test in which only glycine is added to potassium chloride The mixing amounts of potassium chloride (for food additive use) and glycine (for food additive use) are as follows.
【表】
官能試験は、塩化カリウムの濃度が1/20にな
るように蒸留水を加えて行なつた。その結果は
下記表1に示す通りであつた。[Table] The sensory test was conducted by adding distilled water so that the concentration of potassium chloride was 1/20. The results were as shown in Table 1 below.
【表】
表1により明らかなように、グリシンの添加
量が増加するにつれて、塩化カリウムの苦渋味
は感じなくなり、塩化カリウムに対するグリシ
ンの添加量が1/2以上になると、苦渋味は殆ん
ど感じなくなる。しかしグリシンの添加量が増
加するにつれて甘味が増してくる。
(2) 塩化カリウムにフイチン酸だけを加えた試験
塩化カリウムの3%水溶液(PH5.9)をつく
り、この水溶液のPH度を50%フイチン酸溶液を
うすめたもので5.0〜3.0の範囲に調節して、各
区分について官能試験を行なつた。その結果は
下記表2に示す通りであつた。[Table] As is clear from Table 1, as the amount of glycine added increases, the bitter and astringent taste of potassium chloride becomes less perceivable, and when the amount of glycine added to potassium chloride becomes 1/2 or more, the bitter and astringent taste is almost gone. I stop feeling it. However, as the amount of glycine added increases, the sweetness increases. (2) Test in which only phytic acid was added to potassium chloride A 3% aqueous solution (PH5.9) of potassium chloride was prepared, and the pH of this aqueous solution was adjusted to a range of 5.0 to 3.0 with a diluted 50% phytic acid solution. A sensory test was conducted for each category. The results were as shown in Table 2 below.
【表】
+、±、−:表1に同じ
表2により明らかなように、PH度が4.0以下
では苦渋味は感じなくなるが、当然酸味が強く
なつてくる。
(3) 塩化カリウムにグリシンとフイチン酸を加え
た場合
前記(1)の試験で塩化カリウムにグリシンを
0.33g添加したときは、殆んど苦渋味は感じな
くなるので、塩化カリウム1gとりこれとグリ
シン0.3gを加えて100mlとし(PH5.8)、これに
フイチン酸を加えてPH度を5.0、4.5、4.0および
3.5に調節して官能試験を行なつた。その結果
は下記表3に示す通りであつた。[Table] +, ±, -: Same as Table 1 As is clear from Table 2, when the PH degree is 4.0 or less, bitterness and astringency are no longer felt, but the sourness naturally becomes stronger. (3) When glycine and phytic acid are added to potassium chloride In the test (1) above, glycine and phytic acid are added to potassium chloride.
When 0.33g is added, there is almost no bitter or astringent taste, so take 1g of potassium chloride and add this and 0.3g of glycine to make 100ml (PH5.8), then add phytic acid to bring the pH to 5.0, 4.5. , 4.0 and
A sensory test was conducted by adjusting the temperature to 3.5. The results were as shown in Table 3 below.
【表】
+、±、−:表1に同じ
表3により明らかなように、PH度4.5以下で
は苦渋味は殆んど感じなくなり、かつ、甘味お
よび酸味が加わつてきて全体として調和された
味になり、相乗的の効果が期待できることが確
認された。
以上の結果をまとめると、塩化カリウムに対す
るグリシンの添加量は1/3程度で、その水溶液の
PH度を4.5以下にフイチン酸で調節すると、塩化
カリウム自体の渋味苦味はなくなり、塩味に甘味
と酸味が加わつて塩化カリウムの風味は改善向上
化されることが確認された。
次に、本発明の具体的実施例について説明す
る。
実施例
塩化カリウム、グリシンおよびフイチン酸(50
%水溶液)はすべて食添用のものを用いた。塩化
カリウム10gをとり、これにグリシン3.5gを添
加し、水を加えて両者を完全に溶解させた後に希
釈したフイチン酸を所要量(数滴)加えてPH度を
4.0に調節して塩化カリウム含有の水溶液を得
た。得られた水溶液の一部を乾燥させて塩化カリ
ウム含有の乾燥物を得た。
上記の如くして得られた塩化カリウム含有の水
溶液および同乾燥物は、何れも塩化カリウム特有
の渋味および苦味が全くなくなり、かつ適度の甘
味および酸味を具えた極めて調和された風味のあ
る食感を示した。
以上詳述した如く、本発明によつて得られた塩
化ナトリウム含有水溶液および同乾燥物は、何れ
も塩化カリウムが個有する渋味や苦味と云う食感
上の欠点を全く感じさせないばかりでなく、適度
の甘味および酸味が付与されて極めて卓越した風
味をかもし出すものであるから、本発明に依れば
塩化ナトリウムの調味料の減塩用またはカリウム
の栄養補給のためのドリンク剤添加用としての大
量利用が何等問題なく達成化されることとなる。[Table] +, ±, -: Same as Table 1 As is clear from Table 3, when the pH level is below 4.5, bitterness and astringency are hardly felt, and sweetness and sourness are added and the overall balance is harmonized. It was confirmed that it has a good taste and that a synergistic effect can be expected. To summarize the above results, the amount of glycine added to potassium chloride is about 1/3, and the amount of glycine added is about 1/3 of that of potassium chloride.
It was confirmed that when the pH level is adjusted to 4.5 or less with phytic acid, the astringent and bitter taste of potassium chloride itself disappears, sweetness and sourness are added to the salty taste, and the flavor of potassium chloride is improved. Next, specific examples of the present invention will be described. Examples Potassium chloride, glycine and phytic acid (50
% aqueous solution) were all food additives. Take 10g of potassium chloride, add 3.5g of glycine to it, add water to completely dissolve both, then add the required amount (several drops) of diluted phytic acid to adjust the pH level.
4.0 to obtain an aqueous solution containing potassium chloride. A part of the obtained aqueous solution was dried to obtain a dried product containing potassium chloride. Both the potassium chloride-containing aqueous solution and the dried product obtained as above are completely free from the astringency and bitterness characteristic of potassium chloride, and have an extremely harmonious flavor with moderate sweetness and sourness. showed feelings. As detailed above, both the sodium chloride-containing aqueous solution and the dried product obtained by the present invention not only do not have the texture defects of potassium chloride, such as astringency and bitterness, but also Since it is imparted with appropriate sweetness and sourness and produces an extremely outstanding flavor, according to the present invention, large quantities of sodium chloride can be added to seasonings to reduce salt or to add potassium to nutritional supplements. It will be possible to use it without any problems.
Claims (1)
ミノ酸またはアミノ酸混合含有物を重量比1/3
以上添加してこれを水溶液となし、然る後、キレ
ート作用を有する有機酸を所要量添加することに
依りPH度4.5以下の弱酸性に調節して塩化カリウ
ム含有の水溶液を得、また必要に応じてこれを乾
燥物化するように成したことを特徴とする塩化カ
リウムの風味改善法。1. Amino acids or amino acid mixtures that have a chelating effect on potassium chloride at a weight ratio of 1/3
Add the above to make an aqueous solution, and then add the required amount of an organic acid with chelating action to adjust the pH to a weak acidity of 4.5 or less to obtain an aqueous solution containing potassium chloride. A method for improving the flavor of potassium chloride, which is characterized in that the potassium chloride is dried.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58083753A JPS59210866A (en) | 1983-05-13 | 1983-05-13 | Method for improving flavor of potassium chloride |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58083753A JPS59210866A (en) | 1983-05-13 | 1983-05-13 | Method for improving flavor of potassium chloride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59210866A JPS59210866A (en) | 1984-11-29 |
| JPS6139022B2 true JPS6139022B2 (en) | 1986-09-02 |
Family
ID=13811294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58083753A Granted JPS59210866A (en) | 1983-05-13 | 1983-05-13 | Method for improving flavor of potassium chloride |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59210866A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5173323A (en) * | 1991-07-22 | 1992-12-22 | Omari Yunis J | Process for removing the bitterness from potassium chloride |
| JPH0576309A (en) * | 1991-09-19 | 1993-03-30 | Takara Shuzo Co Ltd | Saline taste agent powder |
| PT1139793E (en) | 1998-12-23 | 2010-01-19 | Sinai School Medicine | Inhibitors of the bitter taste response |
| US7455872B2 (en) | 2005-06-20 | 2008-11-25 | Redpoint Bio Corporation | Compositions and methods for producing a salty taste in foods or beverages |
| US7452563B2 (en) | 2005-06-20 | 2008-11-18 | Redpoint Bio Corporation | Compositions and methods for producing flavored seasonings that contain reduced quantities of common salt |
| JP2017225386A (en) * | 2016-06-22 | 2017-12-28 | 日清フーズ株式会社 | Fish egg sauce |
| JP6883329B2 (en) * | 2017-12-25 | 2021-06-09 | 大洋香料株式会社 | Salt enhancer |
-
1983
- 1983-05-13 JP JP58083753A patent/JPS59210866A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59210866A (en) | 1984-11-29 |
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