JPS6154761B2 - - Google Patents
Info
- Publication number
- JPS6154761B2 JPS6154761B2 JP18423482A JP18423482A JPS6154761B2 JP S6154761 B2 JPS6154761 B2 JP S6154761B2 JP 18423482 A JP18423482 A JP 18423482A JP 18423482 A JP18423482 A JP 18423482A JP S6154761 B2 JPS6154761 B2 JP S6154761B2
- Authority
- JP
- Japan
- Prior art keywords
- layer
- urethane oligomer
- polyester
- organism
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 15
- 229920000728 polyester Polymers 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 11
- 241000238631 Hexapoda Species 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920003002 synthetic resin Polymers 0.000 claims description 5
- 239000000057 synthetic resin Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 229920000832 Cutin Polymers 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920002101 Chitin Polymers 0.000 claims description 2
- -1 drying it Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 21
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000238421 Arthropoda Species 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 241000254137 Cicadidae Species 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 235000011511 Diospyros Nutrition 0.000 description 1
- 244000236655 Diospyros kaki Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000013008 moisture curing Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
Landscapes
- Adornments (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
【発明の詳細な説明】
この発明は、木の葉、花弁、昆虫などを用いた
ブローチ、イヤリング、ペンダント、タイ止めな
どのアクセサリー類、造花、生物標本と、その製
造方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to accessories such as brooches, earrings, pendants, and ties, artificial flowers, and biological specimens made of leaves, petals, insects, etc., and methods for manufacturing the same.
木の葉、昆虫類など、クチクラ層を有する生物
体に、樹脂をコーテイングすることは極めて困難
である。これは、クチクラ層が、植物ではクチン
を、又、昆虫など節足動物ではキチンを主成分と
するため、樹脂の「のり」が悪いためと考えられ
る。したがつて、クチクラ層を有する生物体に樹
脂をコーテイングしても、樹脂が容易に剥離して
しまう。 It is extremely difficult to coat living organisms that have a cuticle layer, such as tree leaves and insects, with resin. This is thought to be because the cuticle layer mainly consists of cutin in plants and chitin in arthropods such as insects, which causes the resin to "glue" poorly. Therefore, even if a biological body having a cuticle layer is coated with a resin, the resin easily peels off.
又、コーテイングする樹脂も、強度と適度の可
撓性を有しなければならない。とくに、木の葉、
花弁など薄い生物体を用いてアクセサリーを製作
する場合には、衝撃による樹脂のひび割れを防ぐ
ため、可撓性を有することが必要である。 Furthermore, the coating resin must also have strength and appropriate flexibility. Especially the leaves,
When making accessories using thin biological bodies such as flower petals, it is necessary to have flexibility to prevent the resin from cracking due to impact.
しかしながら、上述のように強度と適度な可撓
性を有する樹脂は、そのままでは、クチクラ層を
有する生物体にコーテイングしても、すぐ剥離し
てしまう。 However, as described above, a resin having strength and appropriate flexibility will easily peel off even if it is coated on a biological body having a cuticle layer.
そこで、この発明は、乾燥したクチクラ層を有
する生物体を、クチクラ層の全部又は表層部を溶
解除去するための溶剤と、クチクラ層の全部又は
表層部を除去した生物体外面に、ウレタンオリゴ
マー層を形成させるためのウレタンオリゴマー液
との混合液中に、生物体を浸漬し、ウレタンオリ
ゴマー層上に、ポリエステル系塗装剤を塗布する
ことによつて、生物体に強度と適度の可撓性を有
する樹脂層を形成することを目的とする。 Therefore, the present invention removes an organism having a dry cuticle layer by dissolving and removing all or the surface layer of the cuticle layer, and applying a urethane oligomer layer to the outer surface of the organism from which all or the surface layer of the cuticle layer has been removed. The biological body is immersed in a mixture with a urethane oligomer liquid to form a urethane oligomer layer, and a polyester coating agent is applied onto the urethane oligomer layer to impart strength and appropriate flexibility to the biological body. The purpose is to form a resin layer with
以下、この発明を、木の葉を素材としたブロー
チ製造の実施例に基づいて詳説する。 Hereinafter, this invention will be explained in detail based on an example of manufacturing a brooch using tree leaves as a material.
素材とする木の葉は、サクラ、イチヨウ、カキ
など、丈夫なものを選定する。 The leaves of trees used as materials are selected from durable ones such as cherry, fig, and persimmon.
まず、木の葉を、シリカゲルなどの乾燥剤を入
れた容器中に密閉して、2〜3日間乾燥させる。
このように乾燥させた木の葉は、乾燥前とほとん
ど色が変らない。 First, the leaves are sealed in a container containing a desiccant such as silica gel and dried for two to three days.
Leaves dried in this way have almost no change in color from before drying.
乾燥した木の葉は、溶剤であるメチレンクロラ
イドと、コンクリートシーラー用のウレタンオリ
ゴマー液(湿気硬化型)との混合液(重量比で、
メチレンクロライド1、ウレタンオリゴマー液
2)中に、1〜2日間浸漬する。 Dried tree leaves are a mixture of methylene chloride, a solvent, and a urethane oligomer liquid (moisture curing type) for concrete sealer (in terms of weight ratio).
Immerse in methylene chloride 1 and urethane oligomer liquid 2 for 1 to 2 days.
この浸漬過程で、木の葉のクチクラ層の主成分
であるクチンが、エチレンクロライドにより溶出
するため、ウレタンオリゴマーが、木の葉にウレ
タンオリゴマー層を形成する。 During this soaking process, cutin, which is the main component of the cuticle layer of leaves, is eluted by ethylene chloride, so that the urethane oligomers form a urethane oligomer layer on the leaves.
なお、溶剤としては、クチクラ層を溶解可能な
アセトン、トルエンなどを用いることも可能であ
る。 In addition, as a solvent, it is also possible to use acetone, toluene, etc. that can dissolve the cuticle layer.
次に、メチレンクロライドとウレタンオリゴマ
ー液との混合液に浸漬した木の葉を、1時間程乾
燥させる。 Next, the leaves soaked in the mixture of methylene chloride and urethane oligomer liquid are dried for about 1 hour.
さいごに、ポリエステル系塗装剤をコーテイン
グするが、このポリエステル系塗装剤は、粘性の
小さい水状のゲルコート用のポリエステル塗装剤
と、粘性の大きい水あめ状のコンクリート塗装用
ポリエステル塗装剤とを、重量比で5:3の割合
で混合したものである。前者は、強度、及び硬度
を与えるもので、又、後者は、適度の可撓性を与
えるものである。ゲルコート用ポリエステル塗装
剤は、ポリエステルに促進剤としてオクテンサン
コバルト又はナステンサンコバルトを、触媒とし
て過酸化物を加えたものである。又、コンクリー
ト塗装用ポリエステルは、ポリエステルに触媒と
して過酸化物を加えたものである。いずれも室温
硬化型である。なお、所望により、さらに粘性を
高めるため、歯科用即時重合レジン(粉末状メタ
アクリルサン樹脂のアクリル接着剤)を、重量比
2の割合で混入してもよい。 Finally, a polyester paint is applied.This polyester paint is made by combining a water-like gel coat polyester paint with a low viscosity and a syrup-like polyester paint with a high viscosity for concrete painting. They were mixed at a ratio of 5:3. The former provides strength and hardness, and the latter provides appropriate flexibility. The polyester coating agent for gel coat is made by adding octenthane cobalt or nastenethane cobalt as an accelerator and peroxide as a catalyst to polyester. Polyester for concrete coating is made by adding peroxide as a catalyst to polyester. Both are room temperature curing types. If desired, in order to further increase the viscosity, dental instant polymerization resin (acrylic adhesive of powdered methacrylic acid resin) may be mixed at a weight ratio of 2.
上記ポリエステル系塗装剤の混合液を、補強用
のピアノ線、ピンなどを、裏側にのせた木の葉
に、筆を用いて、数回重ね塗りをして、厚みを持
たせる。表面は1回塗りとする。コーテイング後
は、室温で乾燥させればよい。乾燥後の変形、変
色、ひび割れなどは皆無である。 Using a brush, apply the above-mentioned polyester paint mixture several times to a tree leaf on which reinforcing piano wire, pins, etc. are placed on the back side to give it thickness. Apply one coat to the surface. After coating, it may be dried at room temperature. There is no deformation, discoloration, or cracking after drying.
以上詳述したように、この発明の特色は、素材
とする生物体外面のクチクラ層の全部又は一部を
溶出させて、ウレタンオリゴマー層を形成し、ウ
レタンオリゴマー層上に、ポリエステル系塗装剤
をコーテイングすることにある。 As detailed above, the feature of the present invention is that a urethane oligomer layer is formed by eluting all or a part of the cuticle layer on the outer surface of a living organism, and a polyester coating agent is applied on the urethane oligomer layer. It's about coating.
実験によると、素材に直接、合成樹脂をコーテ
イングすれば、クチクラ層が存在するためすぐ剥
離し、又、溶剤により、クチクラ層の全部又は一
部を除去しても、合成樹脂をコーテイングするこ
とはできない。ウレタンオリゴマー層を素材上に
形成して、はじめて、合成樹脂をコーテイングす
ることが可能である。さらに、ウレタンオリゴマ
ー層となじむ塗装剤としては、ポリエステル系だ
けである。 Experiments have shown that if a synthetic resin is directly coated on a material, it will peel off immediately due to the presence of the cuticle layer, and even if all or part of the cuticle layer is removed with a solvent, the synthetic resin coating will not be applied. Can not. It is only possible to coat a material with a synthetic resin after forming a urethane oligomer layer on the material. Furthermore, only polyester-based coating agents are compatible with the urethane oligomer layer.
なお、上述の方法で、花弁、蝉などの昆虫類、
えびなどの節足動物を、アクセサリーにすること
ができ、又、生物標本とすることも可能である。 In addition, using the method described above, flower petals, insects such as cicadas,
Arthropods such as shrimp can be used as accessories or biological specimens.
Claims (1)
面に形成したウレタンオリゴマー層上に、ポリエ
ステル層をコーテイングしたことを特徴とする合
成樹脂をコーテイングした生物体。 2 クチクラ層を有する植物、昆虫等の生物体を
乾燥し、クチン又はキチンを溶解可能な溶剤と、
ウレタンオリゴマー液との混合液中に浸漬したの
ち、乾燥させ、ポリエステル系塗装剤でコーテイ
ングすることを特徴とする合成樹脂をコーテイン
グした生物体の製造方法。[Scope of Claims] 1. An organism coated with a synthetic resin, characterized in that a polyester layer is coated on a urethane oligomer layer formed on the outer surface of an organism such as a plant or insect having a cuticle layer. 2 A solvent capable of dissolving cutin or chitin by drying organisms such as plants and insects that have a cuticular layer;
A method for producing a living organism coated with a synthetic resin, which comprises immersing the organism in a mixture with a urethane oligomer liquid, drying it, and coating it with a polyester coating agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18423482A JPS5973501A (en) | 1982-10-18 | 1982-10-18 | Organism coated with synthetic resin and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18423482A JPS5973501A (en) | 1982-10-18 | 1982-10-18 | Organism coated with synthetic resin and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5973501A JPS5973501A (en) | 1984-04-25 |
| JPS6154761B2 true JPS6154761B2 (en) | 1986-11-25 |
Family
ID=16149717
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18423482A Granted JPS5973501A (en) | 1982-10-18 | 1982-10-18 | Organism coated with synthetic resin and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5973501A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4808447A (en) * | 1986-10-23 | 1989-02-28 | Baker Marion A | Preserved flowers and other substrates |
| JPH07184709A (en) * | 1993-12-27 | 1995-07-25 | Shigeo Tanaka | Accessory or tortoiseshell-like product and its manufacture |
| CN102388860B (en) * | 2011-10-18 | 2014-04-23 | 沈阳大学 | Preparation method of small-sized forensic insect specimen |
| TWI517991B (en) * | 2012-11-23 | 2016-01-21 | 衣姵絲股份有限公司 | A plant decoration and the method for forming the same |
| CN110178837A (en) * | 2019-06-11 | 2019-08-30 | 滁州学院 | A kind of manufacture craft of chu chrysanthemum sample |
-
1982
- 1982-10-18 JP JP18423482A patent/JPS5973501A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5973501A (en) | 1984-04-25 |
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