JPS6158546B2 - - Google Patents
Info
- Publication number
- JPS6158546B2 JPS6158546B2 JP54037124A JP3712479A JPS6158546B2 JP S6158546 B2 JPS6158546 B2 JP S6158546B2 JP 54037124 A JP54037124 A JP 54037124A JP 3712479 A JP3712479 A JP 3712479A JP S6158546 B2 JPS6158546 B2 JP S6158546B2
- Authority
- JP
- Japan
- Prior art keywords
- alloy
- hardenability
- extrusion
- less
- extrudability
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
Description
本発明は、建築材、輸送用機器、日用品など外
観的美しさと強度とを要求される材料として好適
な押出材を得るに適したAl−Mg−Si系合金およ
びその押出材の製造法に関する。
押出成形用アルミニウム合金としては、すでに
日本工業規格に工業用純アルミニウムのほかAl
−Cu系合金、Al−Mn系合金、Al−Mg−Si系合
金、Al−Zn−Mg系合金などが規定されている。
この中、Al−Mg−Si系合金では、Mg2Siの量
が多くなるほど、焼入性が悪くなる傾向がある。
例えば6061合金では、ほとんどT6処理しなけれ
ば十分な強度が得られない。また焼入れ時の水冷
のために押出材に顕著なひずみが発生し、形状不
良を起す欠点があつた。その上、押出成型時に押
出速度を上げると、押出表面が焼付いて粗くなり
表面程度が悪くなつたり光沢が失なわれて押出材
が白つぽくなる傾向がある。
本発明は、Al−Mg−Si系合金における上記の
欠点を改善することを目的としてなされたもの
で、Mg0.35〜1.5%、Si0.2〜1.0%、Cu0.11〜
0.45%、Cr0.04〜0.3%、B0.005〜0.02%未満を、
Fe0.05〜0.35%を含むことを特徴とする押出性、
焼入性の良好なAl−Mg−Si系合金であり、ま
た、かかる組成のアルミニウム合金ビレツトを
450〜600℃で加熱して均質化熱処理を行い、400
〜550℃で押出加工することを特徴とする押出材
の製造法である。
本発明の最も特徴とするところは、Bを添加す
ることによつて、押出材の表面程度を損わずに十
分な押出速度が保証でき、かつ焼入性も良くなる
ために、更めてT6処理をすることなく、即ちT5
処理のみで必要にして十分な強度を得ることがで
きるものである。かかる改善はBがAlとともに
AlB2という金属間化合物を形成し、この化合物
がダイスベアリング面に付着しているアルミニウ
ムなどの付着物を取除く、一種の洗浄効果(研磨
効果)があるためである。また、Bは添加成分で
あるCrと結合して、Crの焼入性劣化作用を緩和
改善する。
Bが0.02%以上になるとAl−Bの粗大な金属間
化合物を形成して溶湯中で沈降し、Bの添加効果
が失なわれる。Bが0.005未満ではCrとの結合結
果が得られにくい。
Mg、Siはともに製品の強度を上げるのに効果
がある。Mg0.35%、Si0.2%より少ないと、強度
が不足し、Mg1.5%、Si1.0%を越えると焼入性を
低下させて、水冷しないと十分な強度が得られな
い。
CuはMgと結びついて強度を上昇させるのに効
果があるが、0.45%を越えると押出圧力を上げ、
押出性が低下する。また耐食性も悪くなる。0.11
%未満では十分な添加効果が得られない。
Crは再結晶を微細化させ押出材の結晶粒界割
れの防止に効果があり、またBと結合して前述の
効果を生ぜしめるが、0.3%を越えると、押出
性、焼入性ともに低下する。0.04%未満では十分
な添加効果が得られない。
Feは押出材の再結晶粒を微細化する効果があ
る。0.35%を越えると押出性が低下したり(ピツ
クアツプや表面欠陥の増大)、焼入性が低下す
る。0.05%未満では充分な添加効果が得られな
い。
不純物は各成分で0.05%以下なら支障がない。
本発明組成合金のビレツトを押出成形するに
は、まず450〜600℃で加熱して均質化処理を行な
う。加熱時間は4〜24時間が適当である。この加
熱によりAl−Fe−Si系の共晶化合物が凝集球状
化と固溶化するのに対し、Al−Cr−B系の化合
物がマトリツクス中に均一に析出し、この両者の
相互作用により押出性、焼入性が改善される。加
熱後400〜550℃で押出加工を行なうと、押出材の
表面から約0.1mm程度の深さまで均一で微細な再
結晶組織を形成し、この均一な再結晶組織の形成
が、押出加工の際のダイスとの焼付を防ぎ、押出
材の表面程度を良好にする。
上記の均質化処理温度が450℃未満であると原
子の拡散速度が遅く、効果が不十分であり、600
℃を越えると鋳塊が部分的に融ける恐れがあつて
不適当である。
また、押出加工温度は、400℃未満であると押
出圧力が高くなるとともに、押出時合金元素の固
溶化で加工性が十分でなくなり、T5強度が著し
く低下する。550℃を越えると押出材の表面程度
が悪くなり、加工熱が加算されて粒界が融ける恐
れがあつて好ましくない。
つぎに実施例並びに比較例について述べる。
まず合金として下記3つの合金を用意した。I
は本発明合金であり、、は比較用合金であ
る。
() Al−0.85%Mg−0.65%Si−0.20%Fe−0.35
%Cu−0.1%Cr−0.015%B
() Al−1.0%Mg−0.6%Si−0.20%Fe−0.2%
Cu−0.1%Cr
() Al−0.85%Mg−0.65%Si−0.20%Fe−0.35
%Cu−0.1%Cr
上記合金、、よりなるビレツトを520℃
で8時間の均質化処理後、460℃で押出した。押
出時ダイクエンチングによる水冷材と押出速度20
〜50m/分による空冷材を押出後1日経過したの
ち、焼戻しした時の耐力により焼入性を比較し
た。第1表にその結果を示すが合金の焼入性が
一番優れていた。
The present invention relates to an Al-Mg-Si alloy suitable for obtaining an extruded material suitable for use in construction materials, transportation equipment, daily necessities, and other materials that require good appearance and strength, and a method for producing the extruded material. . As aluminum alloys for extrusion molding, Japanese Industrial Standards already include industrial pure aluminum as well as aluminum alloys.
-Cu-based alloys, Al-Mn-based alloys, Al-Mg-Si-based alloys, Al-Zn-Mg-based alloys, etc. are specified. Among these, in Al-Mg-Si alloys, the hardenability tends to deteriorate as the amount of Mg 2 Si increases.
For example, 6061 alloy requires almost no T6 treatment to obtain sufficient strength. Furthermore, due to water cooling during quenching, significant distortion occurs in the extruded material, resulting in poor shape. Moreover, if the extrusion speed is increased during extrusion molding, the extruded surface tends to be baked and become rough, resulting in poor surface quality and loss of gloss, resulting in the extruded material becoming whitish. The present invention was made with the aim of improving the above-mentioned drawbacks of Al-Mg-Si alloys.
Less than 0.45%, Cr0.04~0.3%, B0.005~0.02%,
extrudability, characterized by containing 0.05-0.35% Fe;
It is an Al-Mg-Si alloy with good hardenability, and an aluminum alloy billet with such a composition is
Homogenization heat treatment is performed by heating at 450-600℃, and 400℃
This is a method for producing extruded materials characterized by extrusion processing at ~550°C. The most characteristic feature of the present invention is that by adding B, a sufficient extrusion speed can be guaranteed without damaging the surface quality of the extruded material, and the hardenability is also improved. without T 6 treatment, i.e. T 5
It is possible to obtain the necessary and sufficient strength through treatment alone. Such improvement is achieved by B along with Al.
This is because it forms an intermetallic compound called AlB 2 , and this compound has a kind of cleaning effect (polishing effect) that removes deposits such as aluminum adhering to the die bearing surface. Further, B combines with Cr, which is an additive component, to alleviate and improve the hardenability deterioration effect of Cr. When B exceeds 0.02%, coarse intermetallic compounds of Al-B are formed and precipitate in the molten metal, and the effect of B addition is lost. When B is less than 0.005, it is difficult to obtain a bonding result with Cr. Both Mg and Si are effective in increasing the strength of products. If it is less than 0.35% Mg and 0.2% Si, the strength will be insufficient, and if it exceeds 1.5% Mg and 1.0% Si, the hardenability will decrease and sufficient strength will not be obtained unless water-cooled. Cu combines with Mg and is effective in increasing strength, but when it exceeds 0.45%, the extrusion pressure increases and
Extrudability decreases. Corrosion resistance also deteriorates. 0.11
If the amount is less than %, a sufficient addition effect cannot be obtained. Cr is effective in refining recrystallization and preventing grain boundary cracking in extruded materials, and also combines with B to produce the above-mentioned effects, but if it exceeds 0.3%, both extrudability and hardenability decrease. do. If it is less than 0.04%, sufficient addition effect cannot be obtained. Fe has the effect of refining the recrystallized grains of the extruded material. If it exceeds 0.35%, extrudability decreases (increase in pick-ups and surface defects) and hardenability decreases. If it is less than 0.05%, sufficient addition effect cannot be obtained. There is no problem if impurities are 0.05% or less for each component. In order to extrude a billet of the alloy composition of the present invention, it is first heated at 450 to 600°C to perform a homogenization treatment. A suitable heating time is 4 to 24 hours. As a result of this heating, the Al-Fe-Si eutectic compound aggregates into spherules and becomes a solid solution, while the Al-Cr-B compound precipitates uniformly in the matrix, and the interaction between the two causes extrudability. , hardenability is improved. When extrusion processing is performed at 400 to 550℃ after heating, a uniform and fine recrystallized structure is formed from the surface of the extruded material to a depth of about 0.1 mm, and the formation of this uniform recrystallized structure is prevents seizure with the die and improves the surface quality of the extruded material. If the above homogenization temperature is lower than 450℃, the diffusion rate of atoms will be slow and the effect will be insufficient.
If the temperature exceeds ℃, the ingot may partially melt, which is inappropriate. Furthermore, if the extrusion processing temperature is less than 400°C, the extrusion pressure will be high, and the processability will be insufficient due to solid solution of alloying elements during extrusion, resulting in a significant decrease in T5 strength. If the temperature exceeds 550°C, the surface quality of the extruded material will deteriorate and processing heat will be added, which may cause grain boundaries to melt, which is not preferable. Next, examples and comparative examples will be described. First, the following three alloys were prepared as alloys. I
is an alloy of the present invention, and is a comparative alloy. () Al−0.85%Mg−0.65%Si−0.20%Fe−0.35
%Cu−0.1%Cr−0.015%B () Al−1.0%Mg−0.6%Si−0.20%Fe−0.2%
Cu−0.1%Cr () Al−0.85%Mg−0.65%Si−0.20%Fe−0.35
%Cu−0.1%Cr A billet consisting of the above alloy was heated to 520°C.
After homogenization for 8 hours, extrusion was carried out at 460°C. Water cooling material and extrusion speed 20 by die quenching during extrusion
One day after extruding the air-cooled material at ~50 m/min, the hardenability was compared based on the yield strength when tempered. The results are shown in Table 1, and the hardenability of the alloy was the best.
【表】
また、各合金を水冷せずに押出速度を変えて、
押出後の表面程度を比較した。表面程度は表面あ
らさ(平均あらさ)で比較した。結果を第2表に
示すが合金が表面程度において一番優れてい
る。なお、第2表中上段の数値は平均あらさ(μ
m)である。[Table] In addition, by changing the extrusion speed of each alloy without water cooling,
The surface quality after extrusion was compared. The surface quality was compared based on surface roughness (average roughness). The results are shown in Table 2, and the alloy was the best in terms of surface quality. The values in the upper middle row of Table 2 are the average roughness (μ
m).
【表】
以上、本発明によれば押出性、焼入性の良好な
アルミニウム合金材が得られ、それを押出成形す
ることによつて、表面程度の良好な製品が得られ
るもので、建築材、車両構造材などの製造に有用
である。[Table] As described above, according to the present invention, an aluminum alloy material with good extrudability and hardenability can be obtained, and by extrusion molding it, a product with a good surface quality can be obtained. , useful for manufacturing vehicle structural materials, etc.
Claims (1)
0.45%、Cr0.04〜0.3%、B0.005%〜0.02%未満、
Fe0.05〜0.35%を含むことを特徴とする押出性、
焼入性の良好なAl−Mg−Si系合金。 2 Mg0.35〜1.5%、Si0.2〜1.0%、Cu0.11〜
0.45%、Cr0.04〜0.3%、B0.005%〜0.02%未満、
Fe0.05〜0.35%を含むアルミニウム合金ビレツト
を450〜600℃で加熱して均質化熱処理を行ない、
400〜550℃で押出加工することを特徴とする押出
性、焼入性の良好なAl−Mg−Si系合金による押
出材の製造法。[Claims] 1 Mg0.35~1.5%, Si0.2~1.0%, Cu0.11~
0.45%, Cr0.04~0.3%, B0.005%~less than 0.02%,
extrudability, characterized by containing 0.05-0.35% Fe;
Al-Mg-Si alloy with good hardenability. 2 Mg0.35~1.5%, Si0.2~1.0%, Cu0.11~
0.45%, Cr0.04~0.3%, B0.005%~less than 0.02%,
An aluminum alloy billet containing 0.05 to 0.35% Fe is heated at 450 to 600°C to perform homogenization heat treatment,
A method for producing an extruded material from an Al-Mg-Si alloy with good extrudability and hardenability, characterized by extrusion processing at 400 to 550°C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3712479A JPS55131152A (en) | 1979-03-30 | 1979-03-30 | Manufacture of a -mg-si type alloy with high extrudability and hardenability, and extruded material thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3712479A JPS55131152A (en) | 1979-03-30 | 1979-03-30 | Manufacture of a -mg-si type alloy with high extrudability and hardenability, and extruded material thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55131152A JPS55131152A (en) | 1980-10-11 |
| JPS6158546B2 true JPS6158546B2 (en) | 1986-12-12 |
Family
ID=12488847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3712479A Granted JPS55131152A (en) | 1979-03-30 | 1979-03-30 | Manufacture of a -mg-si type alloy with high extrudability and hardenability, and extruded material thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55131152A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012255191A (en) * | 2011-06-08 | 2012-12-27 | Sankyo Tateyama Inc | Aluminum alloy |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59143039A (en) * | 1983-02-04 | 1984-08-16 | Nippon Light Metal Co Ltd | Manufacturing method of Al-Mg-Si aluminum alloy ingot for extrusion |
| JPS61256699A (en) * | 1985-05-09 | 1986-11-14 | 住友軽金属工業株式会社 | Wiring support for magnetic disc unit |
| JPS63247334A (en) * | 1987-04-03 | 1988-10-14 | Showa Alum Corp | Aluminum alloy for extrusion having excellent surface smoothness |
| US5460895A (en) * | 1993-06-14 | 1995-10-24 | General Motors Corporation | Corrosion-resistant aluminum alloy |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3717512A (en) * | 1971-10-28 | 1973-02-20 | Olin Corp | Aluminum base alloys |
-
1979
- 1979-03-30 JP JP3712479A patent/JPS55131152A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012255191A (en) * | 2011-06-08 | 2012-12-27 | Sankyo Tateyama Inc | Aluminum alloy |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55131152A (en) | 1980-10-11 |
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