JPS6214264B2 - - Google Patents
Info
- Publication number
- JPS6214264B2 JPS6214264B2 JP59099286A JP9928684A JPS6214264B2 JP S6214264 B2 JPS6214264 B2 JP S6214264B2 JP 59099286 A JP59099286 A JP 59099286A JP 9928684 A JP9928684 A JP 9928684A JP S6214264 B2 JPS6214264 B2 JP S6214264B2
- Authority
- JP
- Japan
- Prior art keywords
- solution
- salt
- freezing
- osmotic pressure
- food
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000013305 food Nutrition 0.000 claims description 17
- 238000007710 freezing Methods 0.000 claims description 16
- 230000008014 freezing Effects 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 7
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 239000001103 potassium chloride Substances 0.000 claims description 6
- 235000011164 potassium chloride Nutrition 0.000 claims description 6
- 239000000600 sorbitol Substances 0.000 claims description 6
- 238000004321 preservation Methods 0.000 claims description 5
- 235000013311 vegetables Nutrition 0.000 claims description 5
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
- 235000014102 seafood Nutrition 0.000 claims description 4
- 235000013399 edible fruits Nutrition 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 238000005057 refrigeration Methods 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 22
- 230000003204 osmotic effect Effects 0.000 description 16
- 150000003839 salts Chemical class 0.000 description 15
- 239000003761 preservation solution Substances 0.000 description 7
- 238000005554 pickling Methods 0.000 description 5
- 241000238557 Decapoda Species 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 235000010356 sorbitol Nutrition 0.000 description 3
- 238000010257 thawing Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QBUKAFSEUHGMMX-MTJSOVHGSA-N (5z)-5-[[3-(1-hydroxyethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical compound C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C(C)O QBUKAFSEUHGMMX-MTJSOVHGSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Freezing, Cooling And Drying Of Foods (AREA)
Description
本発明は、生の魚介類・野菜・果物などの生鮮
食品またはそれの加工品を、流通過程または保存
において、低温に保持し、品質の保持と日持ちを
良好にするための、生鮮食品またはそれの加工品
の低温保存方法についての改良に関する。
食品を低温で保存する手段には、食品を凍結さ
せないで0℃付近から10℃付近までの温度で保存
する冷蔵と、凍結させて0℃以下の温度で保存す
る凍蔵とがあり、冷蔵のなかには、0℃前後の氷
温で貯ぞうする氷温貯蔵がある。
食品の保存は、出来るだけ低温で行なうことが
有効であるが、食品によつては、0℃以下の低温
にして凍結させると、解凍したときに水が分離し
て流れ出すドリツプ現象や、多孔質状になるスポ
ンジ現象を起こして、品質を著しく低下させるも
のがあるので、氷点を降下させて凍結させずに0
℃以下の低温で保存させることが望まれ、また、
凍結して保存する場合においても、解凍後に生ず
るドリツプ現象やスポンジ現象を出来だけ少なく
することが望まれている。
しかし、従前においては、氷点降下させ、ま
た、解凍の際に生ずるドリツプ現象やスポンジ現
象を抑えるのに、全て塩を用いるようにしてい
た。これは、毒性がないことと、味を害なわない
ことの、前堤となる条件を満たす適当なものが他
に見つからなかつたことによる。
ところで、この塩を用いる従来手段は、塩の味
が著しく強く、添加する量を多くすると塩からく
なつて食味に堪えないようになることから、添加
量が2〜3%程度に制約され、それ以上いれるこ
とが出来ないこと、塩分の摂取がナトリウムのと
りすぎとなつて健康を害なうことから、その使用
量をさらに少なくすることが要求されることで、
充分な氷点降下、ならびにドリツプ現象の抑制の
効果を上げ得ない問題がある。
本発明法は、この問題を解消せしめるためにな
されたものであつて、塩を使用しないで、また、
使用してもその量を少なく抑えて、食品の味を害
なわず、かつ、毒性を与えずに、氷点を降下さ
せ、ドリツプ現象を抑制し得る新たな手段を提起
することを目的とするものである。
しかして、本発明法は、上述の問題を解消すべ
く種々の研究を行なつたところ、従来用いられて
いた塩によるドリツプ現象の抑制作用が、添加し
た塩の濃度によるものではなく、その塩の添加に
よる浸透圧によるもので、他の物質で同等の浸透
圧となるようにすれば、同等の効果が得られ、ま
た、その浸透圧は、溶液内に複数の溶質を存在さ
せたときにはそれら溶質の各浸透圧の総和でよい
ことが判り、また、このように複数の溶質をもつ
て高浸透圧の溶液(漬液)を作る際、塩化カリウ
ムと、エタノールと、ソルビツトと、グリセリン
とを配合して調整すると、その溶液及びそれに漬
込んだ食品の氷点を、殆んど味に影響を与えない
で浸透圧に略比例して降下させるだけでなく、食
品に粘性を与えて、ドリツプ現象の抑制が一層効
果的になることが判つたことによるものである。
そして、このことから、本発明においては、生
の魚介類・野菜・果実などの生鮮食品またはそれ
の加工品を、塩化カリウムと、エタノールと、ソ
ルビツトと、グリセリンとを配合してなる溶液に
漬込むか、その溶液を添加する前処理を行なつて
冷蔵または凍蔵して保存する手段を提起するもの
である。
次に実施例を説明する。
実施例 1
野沢菜漬の低温保存、
塩化カリウム120g、アルコール120ml、ソルビ
ツト20g、グリセリン10gの割合で配合して高浸
透圧の溶液を作り、これを漬液(保存液)の原液
とする。この原液は、発明者小川敏男の計算式
(参考・東京農試報告第8号4頁)によれば、各
溶質の浸透圧の分圧が、アルコール12%で約70気
圧、塩化カリウム12%で69気圧、ソルビツト20%
で30気圧、グリセリン10%で28気圧となり、これ
らの総和の浸透圧が197気圧となる。この浸透圧
値は、食塩の飽和に近い25%溶液の浸透圧152気
圧に比して遥かに高い。
しかも、それぞれの溶質の高濃度の単用による
食味を損なう欠点を相補つた高浸透圧の保存液と
なる。次に、全量に対し2%の割合で食塩を添加
して小袋に詰めた野沢菜の小袋詰めに対して、こ
の原液を、4%〜8%の割合に薄めて野沢菜と同
量添加する処理を施し、この状態のまま密封し
て、零度前後の低温で冷蔵保存する。
このように処理した野沢菜の小袋詰めの漬液の
浸透圧値は次表の如くなり、氷点はそれぞれ降下
する。
The present invention is a method for maintaining fresh foods such as raw seafood, vegetables, and fruits or processed products thereof at low temperatures during the distribution process or storage to maintain quality and improve shelf life. This invention relates to improvements in low-temperature preservation methods for processed products. There are two ways to preserve food at low temperatures: refrigeration, which stores food at temperatures between 0°C and 10°C without freezing it, and freezing, which stores food at temperatures below 0°C after freezing. Some types of storage include freezing temperature storage, which stores food at freezing temperatures around 0°C. It is effective to preserve food at as low a temperature as possible, but depending on the food, if you freeze it at a low temperature below 0°C, it may cause the drip phenomenon in which water separates and flows out when thawed, or it may become porous. There are some substances that cause a spongy phenomenon that causes the quality to deteriorate significantly.
It is desirable to store it at a low temperature below ℃, and
Even when frozen and stored, it is desirable to minimize the dripping and sponging phenomena that occur after thawing. However, in the past, salt was used to lower the freezing point and to suppress the dripping and sponging phenomena that occur during thawing. This is because no other suitable material could be found that satisfies the requirements of being non-toxic and not causing any harm to the taste. By the way, in the conventional means using this salt, the taste of salt is extremely strong, and if the amount added is too large, the salt becomes dull and the taste becomes unbearable, so the amount added is limited to about 2 to 3%. Since it is not possible to add more than that amount, and because consuming salt can lead to too much sodium and harm your health, there is a need to further reduce the amount of salt used.
There is a problem in that it is not possible to sufficiently lower the freezing point and suppress the drip phenomenon. The method of the present invention was made to solve this problem, and does not use salt, and
The purpose is to propose a new means that can reduce the freezing point and suppress the dripping phenomenon without harming the taste or toxicity of food by reducing the amount used. It is. However, in order to solve the above-mentioned problems, the method of the present invention has revealed that the suppressing effect of the dripping phenomenon caused by the salt used in the past is not due to the concentration of the added salt, but rather due to the salt concentration. This is due to the osmotic pressure caused by the addition of solutes, and the same effect can be obtained by creating the same osmotic pressure with another substance, and when multiple solutes are present in the solution, the osmotic pressure It was found that the sum of the osmotic pressures of the solutes was sufficient, and when making a high osmotic solution (soaking solution) with multiple solutes, potassium chloride, ethanol, sorbitol, and glycerin were combined. When adjusted, it not only lowers the freezing point of the solution and the food soaked in it in approximately proportion to the osmotic pressure without affecting the taste, but also adds viscosity to the food and suppresses the dripping phenomenon. This is because it has been found to be even more effective. Therefore, in the present invention, fresh foods such as raw seafood, vegetables, and fruits, or processed products thereof, are soaked in a solution containing potassium chloride, ethanol, sorbitol, and glycerin. The present invention proposes a means of pre-treating the liquid by adding a solution thereof and storing it by refrigerating or freezing. Next, an example will be described. Example 1 Low-temperature preservation of Nozawa pickled vegetables. A solution with high osmotic pressure is prepared by blending 120 g of potassium chloride, 120 ml of alcohol, 20 g of sorbitol, and 10 g of glycerin, and this is used as the stock solution of the pickling solution (preservation solution). According to inventor Toshio Ogawa's calculation formula (reference: Tokyo Agricultural Test Report No. 8, p. 4), the partial pressure of the osmotic pressure of each solute is approximately 70 atm with 12% alcohol and 12% potassium chloride. 69 atm, sorbitol 20%
The osmotic pressure is 30 atm, 28 atm with 10% glycerin, and the total osmotic pressure is 197 atm. This osmotic pressure value is much higher than the osmotic pressure of 152 atm for a 25% solution of salt, which is close to saturation. Moreover, the preservation solution has a high osmotic pressure, which compensates for the disadvantage of deteriorating taste due to the single use of high concentrations of each solute. Next, this undiluted solution is diluted to a ratio of 4% to 8% and added in the same amount as Nozawana to the sachets of Nozawana, which are packed with salt added at a ratio of 2% to the total amount. After processing, seal it in this state and store it in the refrigerator at a low temperature around zero degrees. The osmotic pressure values of the pickled solutions of Nozawana sachets packed in sachets treated in this way are as shown in the following table, and the freezing point decreases in each case.
【表】 また、保存後の状況は次の通りであつた。【table】 The conditions after storage were as follows.
【表】
実施例 2
エビの低温保存
前記実施例1で示した保存液(原液)を、水で
3倍に薄めて漬液を作り、この漬液に、生エビを
約10分間漬浸する処理を行ない、しかるのち、そ
の漬液から引き上げて、5℃程度の低温で冷蔵す
るか、または、マイナス35℃位で急速に凍結して
マイナス10℃位で凍蔵する。
このようにして行なつた生のエビの保存状態は
次の通りであつた。[Table] Example 2 Low-temperature preservation of shrimp The preservation solution (undiluted solution) shown in Example 1 above was diluted three times with water to make a pickling solution, and raw shrimp were soaked in this pickling solution for about 10 minutes. After that, remove it from the soaking liquid and refrigerate it at a low temperature of about 5℃, or quickly freeze it at about -35℃ and freeze it at about -10℃. The preservation conditions of the raw shrimp in this manner were as follows.
【表】【table】
【表】【table】
【表】
実施例 3
野菜類を漬液と共に袋に封入した浅漬類を、そ
れの漬液に対し前記実施例1で用いた保存液(原
液)を5%〜10%の割合で添加した後、凍結する
か、または凍結しないで、低温で保存する。結果
は良好であつた。
実施例 4
生の魚介類を、前記実施例1で用いた保存液
(原液)中に通すか、その保存液を3〜5倍に薄
めた液に10分間程漬浸した後、凍結させるかまた
は凍結させないで、低温にて保存する。結果は良
好であつた。
以上説明したように、本発明法は、生鮮食品ま
たはその加工品を、冷蔵または凍蔵する際に、食
品を、塩化カリウムと、エタノールと、ソルビツ
トと、グリセリンとを配合して調整した高浸透圧
の溶液に漬込むか、この溶液を添加する処理を行
なつた後に、冷蔵または凍蔵することで、この溶
液中の複数の溶質の各浸透圧の分圧の総和による
高い浸透圧により、氷点降下と解凍時のドリツプ
現象の抑止とをはかるようにしているのだから、
食塩を全く使用しないで、または使用してもその
量を少なく抑えて、食塩を用いた場合よりも、食
品の品質を良好に保持しながら低温保存が行なえ
るようになる。
しかも、保存液中の各溶質は、個々の量が少な
いことから食味を損なうことがなく、さらに、保
存する食品に粘性を与えることからドリツプ現象
の抑止が効果的になる。[Table] Example 3 Lightly pickled vegetables were sealed in a bag together with a pickling solution, and the preservation solution (undiluted solution) used in Example 1 was added to the pickling solution at a ratio of 5% to 10%, and then frozen. or store at low temperatures without freezing. The results were good. Example 4 Either pass raw seafood through the preservation solution (undiluted solution) used in Example 1, or immerse it in a solution diluted 3 to 5 times the preservation solution for about 10 minutes, and then freeze it. Or store at low temperature without freezing. The results were good. As explained above, in the method of the present invention, when fresh foods or processed products thereof are refrigerated or frozen, the food is treated with a highly permeable compound containing potassium chloride, ethanol, sorbitol, and glycerin. By immersing it in a high-pressure solution or adding this solution, and then refrigerating or freezing it, the high osmotic pressure resulting from the sum of the partial pressures of each osmotic pressure of multiple solutes in this solution, This is because we are trying to reduce the freezing point and suppress the drip phenomenon during thawing.
By not using salt at all, or by using only a small amount of salt, it is possible to preserve the quality of food at a lower temperature than when using salt. Moreover, since each solute in the preservation solution is present in a small amount, it does not impair the taste, and furthermore, since it imparts viscosity to the food to be preserved, the dripping phenomenon is effectively suppressed.
Claims (1)
その加工品を、塩化カリウムと、エタノールと、
ソルビツトと、グリセリンとを配合してなる溶液
に漬込むか、その溶液を添加する前処理を行なつ
て、冷蔵または凍蔵して保存することを特徴とす
る生鮮食品またはその加工品の低温保存方法。1. Fresh foods such as raw seafood, vegetables, fruits, etc. or their processed products are treated with potassium chloride, ethanol,
Low-temperature preservation of fresh foods or processed products thereof, characterized in that they are pretreated by soaking in or adding a solution containing sorbitol and glycerin, and then stored under refrigeration or freezing. Method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59099286A JPS60241876A (en) | 1984-05-17 | 1984-05-17 | Method for preserving perishable food or processed food thereof at low temperature |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59099286A JPS60241876A (en) | 1984-05-17 | 1984-05-17 | Method for preserving perishable food or processed food thereof at low temperature |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60241876A JPS60241876A (en) | 1985-11-30 |
| JPS6214264B2 true JPS6214264B2 (en) | 1987-04-01 |
Family
ID=14243402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59099286A Granted JPS60241876A (en) | 1984-05-17 | 1984-05-17 | Method for preserving perishable food or processed food thereof at low temperature |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60241876A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61249376A (en) * | 1985-04-30 | 1986-11-06 | Jipukomu Kk | Food capsule |
| JP7010707B2 (en) * | 2018-01-13 | 2022-01-26 | 克彦 岡山 | Food preservatives and food preservation methods |
-
1984
- 1984-05-17 JP JP59099286A patent/JPS60241876A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60241876A (en) | 1985-11-30 |
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