JPS6221244B2 - - Google Patents
Info
- Publication number
- JPS6221244B2 JPS6221244B2 JP4456279A JP4456279A JPS6221244B2 JP S6221244 B2 JPS6221244 B2 JP S6221244B2 JP 4456279 A JP4456279 A JP 4456279A JP 4456279 A JP4456279 A JP 4456279A JP S6221244 B2 JPS6221244 B2 JP S6221244B2
- Authority
- JP
- Japan
- Prior art keywords
- wire
- winding
- superconducting
- compound
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 claims description 20
- 238000004804 winding Methods 0.000 claims description 19
- 239000002887 superconductor Substances 0.000 claims description 9
- 238000009792 diffusion process Methods 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 claims description 5
- 239000002905 metal composite material Substances 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 4
- 230000003014 reinforcing effect Effects 0.000 description 12
- 239000002131 composite material Substances 0.000 description 10
- 239000010949 copper Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 230000008602 contraction Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229910016347 CuSn Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910018182 Al—Cu Inorganic materials 0.000 description 1
- 229910018575 Al—Ti Inorganic materials 0.000 description 1
- 229910003336 CuNi Inorganic materials 0.000 description 1
- 229910002535 CuZn Inorganic materials 0.000 description 1
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- KHYBPSFKEHXSLX-UHFFFAOYSA-N iminotitanium Chemical compound [Ti]=N KHYBPSFKEHXSLX-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910001000 nickel titanium Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F6/00—Superconducting magnets; Superconducting coils
- H01F6/06—Coils, e.g. winding, insulating, terminating or casing arrangements therefor
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Description
本発明は巻線後拡散熱処理を行うことによつて
化合物超電導体を形成させる超電導マグネツトの
改良に関するものであり、特にコイルを補強せん
とするものである。
従来この種超電導マグネツトは第1図aに示す
如く巻枠1例えばステンレスボビンに拡散反応に
よつて化合物超電導体を形成する複合線2をソレ
ノイド巻にした後、その最外層としてステンレス
鋼線或はキユプロニツケル線等の補強線3を数層
巻線し、これを高温度にて熱処理して化合物超電
導体を形成せしめていたものである。なお、補強
線3の配列については第1図bに示す如く丸線或
は角線が整列巻線されているものである。
而して上記の補強線は室温或は低温においては
高拡散張力を有するが、一旦高温にさらされると
軟化し、その拡張力は1/3程度に減少する。従つ
て補強線としての作用を十分に発揮することが出
来ないものであつた。更に上記補強線は金属線か
らなるため、拡散熱処理により形成される化合物
超電導体よりも線膨張係数が大きいため、必然的
に収縮量も大きくなり巻線にゆるみや収縮歪によ
る局部的圧縮応力が加わり、化合物超電導線によ
る巻線にガタを生ずるとか或は化合物超電導線に
損傷をあたえるものであつた。
本発明はかゝる欠点を改善せんとして鋭意研究
を行つた結果、高強度を有し且つ熱伝導に優れた
巻線よりなる超電導マグネツトを見出したもので
ある。即ち本発明は巻線後拡散熱処理によつて化
合物超電導体を形成せしめる超電導マグネツトに
おいて、巻線の少くとも最外層を非磁性金属マト
リツクス中に非超電導性化合物繊維を不連続に分
散せしめた非磁性金属複合体にて形成せしめたこ
とを特徴とするものである。
本発明の1例を図面にもとづき説明すると、第
2図aに示す如く巻枠1例えばステンレス鋼ボビ
ンに拡散反応によつて化合物超電導体を形成する
複合線2をソレノイド巻きした後、少くともその
最外層を、非磁性金属マトリツクス中に非超電導
性化合物繊維(超電導特性を示さない化合物繊
維)を不連続に分散せしめた非磁性金属複合線4
にて形成せしめた後、高温にて熱処理し、化合物
超電導体及び非超電導性化合物を同時に形成せし
めたものである。
なお上記非磁性金属複合線は必ず巻線の最外層
に設けるものであるが、その中間層に設けてもよ
く、又その層は1層又は複数層に設けてもよい。
又本発明において複合線4は第2図bに示す如
く補強線5をコイルに巻いて形成するものであ
り、この補強線5の構成は非磁性マトリツクス6
の中に非超電導性化合物7を複数本内蔵せしめた
ものである。
なお非磁性金属マトリツクスとしてはCu、
Al、Ag、CuNi、CuSn、CuZn、ステンレス鋼な
どが使用される。又非超電導化合物としてはCu
―Ti、Al―Ti、Ni―Ti、Al―Cu、Cu―NbTi系
などの各種化合物が使用される。
この補強線5の配列は第2図bに示す以外に平
角線、テープ、成形撚線など整列巻線可能なもの
であれば何れの配列でも差支えない。
次に本発明の実施例について説明する。
実施例 1
CuSn合金中にニオブ505芯を埋込み、その外周
にTa管及びOFHC銅管を夫々被覆し、外径0.25
mmφの複合線を得た。なおこの複合線は10mmのピ
ツチにてツイストされている。
而して上記複合線12本×500mを0.25×0.75mm2
のステンレス鋼条の周囲に撚線成形して0.68×
1.21の複合撚線をえた。かゝる複合撚線に30μ
mt×5mmwのガラステープをZ方向およびS方向
の2層にテーピング加工を行い0.8×1.33mm2の導
体450mをえた。
この導体を用いて巻胴径60φ、外径100φ、長
さ150のソレノイド2個を作装し、その一方に
銅とTi―10%Nb合金とが1:1で複合された外
径0.3mmの複合線を4層配列巻線して本発明にお
けるソレノイドとした。
又他方0.3mmφキユプロニツケル線を4層配列
巻線して従来のソレノイドとした。
これら2個のソレノイドを650℃×45Hr拡散熱
処理を行いNb3Sn化合物超電導体を形成せしめ
た。
なお上記の導体の短尺試料を650℃×45Hr拡散
熱処理を行つて臨界電流を測定した結果、10Tで
195±5Aの範囲にあることを確認した。
而して前記本発明ソレノイド及び従来のソレノ
イドを夫々NbTi合金超電導マグネツト(内径130
mmφ)によつて7Tバイアス磁界をかけて通電し
た結果は第1表に示す通りである。
The present invention relates to an improvement in a superconducting magnet in which a compound superconductor is formed by performing a diffusion heat treatment after winding, and in particular, it is intended to strengthen the coil. Conventionally, this type of superconducting magnet has been manufactured by winding a composite wire 2, which forms a compound superconductor through a diffusion reaction, around a winding frame 1, for example, a stainless steel bobbin, as a solenoid winding, as shown in FIG. A reinforcing wire 3 such as a Cypronickel wire is wound in several layers and then heat treated at a high temperature to form a compound superconductor. The reinforcing wires 3 are arranged in such a manner that round wires or square wires are wound in alignment as shown in FIG. 1b. The above-mentioned reinforcing wire has high diffusion tension at room temperature or low temperature, but once exposed to high temperature, it softens and its expansion force decreases to about 1/3. Therefore, it was not possible to fully demonstrate its function as a reinforcing wire. Furthermore, since the reinforcing wire is made of metal wire, its coefficient of linear expansion is larger than that of a compound superconductor formed by diffusion heat treatment, so the amount of shrinkage will inevitably increase, causing local compressive stress due to loosening and shrinkage strain in the winding. In addition, the winding of the compound superconducting wire may become loose or may be damaged. The present invention has been made as a result of extensive research aimed at improving these drawbacks, and as a result has discovered a superconducting magnet made of a winding wire that has high strength and excellent thermal conductivity. That is, the present invention relates to a superconducting magnet in which a compound superconductor is formed by diffusion heat treatment after winding, in which at least the outermost layer of the winding is a non-magnetic metal matrix in which non-superconducting compound fibers are discontinuously dispersed. It is characterized by being made of a metal composite. One example of the present invention will be explained based on the drawings. As shown in FIG. A non-magnetic metal composite wire 4 whose outermost layer is a non-magnetic metal matrix in which non-superconducting compound fibers (compound fibers that do not exhibit superconducting properties) are discontinuously dispersed.
After forming the superconductor at a high temperature, it is heat-treated at a high temperature to simultaneously form a compound superconductor and a non-superconducting compound. Although the above-mentioned nonmagnetic metal composite wire is necessarily provided in the outermost layer of the winding, it may be provided in an intermediate layer thereof, or the layer may be provided in one layer or in multiple layers. Further, in the present invention, the composite wire 4 is formed by winding a reinforcing wire 5 into a coil as shown in FIG.
A plurality of non-superconducting compounds 7 are built into the core. Note that the non-magnetic metal matrix is Cu,
Al, Ag, CuNi, CuSn, CuZn, stainless steel, etc. are used. Also, as a non-superconducting compound, Cu
- Various compounds such as Ti, Al-Ti, Ni-Ti, Al-Cu, and Cu-NbTi are used. The reinforcing wires 5 may be arranged in any arrangement other than that shown in FIG. 2b, as long as they can be wound in alignment, such as rectangular wires, tapes, and stranded wires. Next, examples of the present invention will be described. Example 1 A niobium 505 core is embedded in a CuSn alloy, and its outer periphery is covered with a Ta tube and an OFHC copper tube, with an outer diameter of 0.25.
A composite line of mmφ was obtained. This composite wire is twisted at a pitch of 10mm. Then, the above 12 composite lines x 500m are 0.25 x 0.75mm 2
Stranded wire is formed around a stainless steel strip of 0.68×
A composite strand of 1.21 was obtained. 30μ for such composite stranded wire
A 450 m conductor measuring 0.8 x 1.33 mm 2 was obtained by taping two layers of mt x 5 mm w glass tape in the Z direction and S direction. Two solenoids with a drum diameter of 60φ, an outer diameter of 100φ, and a length of 150 mm were fabricated using this conductor, and one of the solenoids had an outer diameter of 0.3 mm with a 1:1 composite of copper and Ti-10%Nb alloy. The solenoid of the present invention was made by winding the composite wire in a four-layer arrangement. On the other hand, a conventional solenoid was made by winding 0.3 mmφ Cypronickel wire in a four-layer arrangement. These two solenoids were subjected to diffusion heat treatment at 650°C for 45 hours to form a Nb 3 Sn compound superconductor. In addition, as a result of performing diffusion heat treatment on a short sample of the above conductor at 650℃ x 45 hours and measuring the critical current, it was found that the critical current was measured at 10T.
It was confirmed that it was within the range of 195±5A. The solenoid of the present invention and the conventional solenoid were each made of a NbTi alloy superconducting magnet (inner diameter 130 mm).
Table 1 shows the results of applying current by applying a 7T bias magnetic field (mmφ).
【表】
また、超電導ソレノイドの外側に配列巻線した
銅とTi―10%含金線およびキユプロニツケル線
を650℃、45Hrの条件で処理した試料について強
度、熱収縮率および推定熱伝導率を測定し、
Nb3Sn線の特性と対比したところ下記第2表の結
果を得た。[Table] In addition, the strength, thermal contraction rate, and estimated thermal conductivity were measured for samples of copper, Ti-10% gold-containing wire, and Cypronickel wire arranged and wound on the outside of the superconducting solenoid and treated at 650℃ and 45 hours. death,
When compared with the characteristics of Nb 3 Sn wire, the results shown in Table 2 below were obtained.
【表】
すなわち、実測値では強度が約2倍、熱収縮率
が約1/2.5であることが判つた。
上表より明らかの如く本発明のソレノイドによ
つて10.1T、従来ソレノイドによつて8.7Tの磁界
を達成したことが確認された。更に本発明ソレノ
イドにおいてはトレーニングも殆んど観測されず
磁界も安定に発生することが出来たが、従来のソ
レノイドはトレーニングが激しく励磁毎に巻線の
移動音が検出され不安定であつた。このことは従
来のソレノイドにおいて補強線であるキユプロニ
ツケル線が650℃で軟化して強度が低下し補強材
としての作用が著しく阻害されたこと及びキユプ
ロニツケルが低温まで冷却される過程で熱収縮が
大きく化合物超電導巻線の配列を乱したことに起
因するものと考えられる。
以上詳述した如く本発明によればコイルの補強
のために使用する補強線が焼鈍された金属に比し
て約3倍の強度を示し且つ熱伝導も通常の金属線
と同等であることを示した。更に熱収縮が通常の
金属の約1/3と少いばかりでなく化合物超電導線
と殆んど同等であるため熱収縮による損傷は全く
認められなかつた。従つて巻線後の熱処理に際し
安定したコイルを形成する等顕著な効果を有す
る。[Table] In other words, the actual measured values showed that the strength was about twice as high and the heat shrinkage rate was about 1/2.5. As is clear from the table above, it was confirmed that the solenoid of the present invention achieved a magnetic field of 10.1T, and the conventional solenoid achieved a magnetic field of 8.7T. Furthermore, in the solenoid of the present invention, almost no training was observed and a magnetic field could be generated stably, whereas in the conventional solenoid, the training was intense and the sound of the winding movement was detected every time it was excited, making it unstable. This is due to the fact that the reinforcing wire in conventional solenoids, the Cypronickel wire, softens at 650°C, reducing its strength and significantly inhibiting its function as a reinforcing material.In addition, in the process of cooling the Cypronickel to a low temperature, the thermal contraction is large and the compound This is thought to be due to the disordered arrangement of the superconducting windings. As detailed above, according to the present invention, the reinforcing wire used for reinforcing the coil has approximately three times the strength of annealed metal, and has the same thermal conductivity as ordinary metal wire. Indicated. Furthermore, the thermal shrinkage was not only about 1/3 that of ordinary metals, but also almost the same as that of compound superconducting wires, so no damage due to thermal contraction was observed. Therefore, it has remarkable effects such as forming a stable coil during heat treatment after winding.
第1図は従来の超電導マグネツトを示すもので
あり、第1図aはその概略説明図、第1図bは従
来のマグネツトにおける補強線の配列図、第2図
は本発明超電導マグネツトを示すものであり、第
2図aはその概略説明図、第2図bは本発明マグ
ネツトにおける補強線の配列図である。
1…巻枠、2…複合線、3…補強線、4…非磁
性金属複合線、5…補強線、6…非磁性マトリツ
クス、7…非超電導性化合物。
Fig. 1 shows a conventional superconducting magnet, Fig. 1a is a schematic explanatory diagram thereof, Fig. 1b is an arrangement diagram of reinforcing wires in the conventional magnet, and Fig. 2 shows a superconducting magnet of the present invention. FIG. 2a is a schematic explanatory diagram thereof, and FIG. 2b is an arrangement diagram of reinforcing wires in the magnet of the present invention. DESCRIPTION OF SYMBOLS 1... Winding frame, 2... Composite wire, 3... Reinforced wire, 4... Non-magnetic metal composite wire, 5... Reinforced wire, 6... Non-magnetic matrix, 7... Non-superconducting compound.
Claims (1)
形成せしめる超電導マグネツトにおいて、巻線の
少くとも最外層を非磁性金属マトリツクス中に非
超電導性化合物繊維を不連続に分散せしめた非磁
性金属複合体にて形成することを特徴とする超電
導マグネツト。1. In a superconducting magnet in which a compound superconductor is formed by diffusion heat treatment after winding, at least the outermost layer of the winding is a non-magnetic metal composite in which non-superconducting compound fibers are discontinuously dispersed in a non-magnetic metal matrix. A superconducting magnet characterized by being formed in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4456279A JPS55138208A (en) | 1979-04-12 | 1979-04-12 | Super-conducting magnet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4456279A JPS55138208A (en) | 1979-04-12 | 1979-04-12 | Super-conducting magnet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55138208A JPS55138208A (en) | 1980-10-28 |
| JPS6221244B2 true JPS6221244B2 (en) | 1987-05-12 |
Family
ID=12694931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4456279A Granted JPS55138208A (en) | 1979-04-12 | 1979-04-12 | Super-conducting magnet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55138208A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0349366Y2 (en) * | 1984-12-17 | 1991-10-22 |
-
1979
- 1979-04-12 JP JP4456279A patent/JPS55138208A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55138208A (en) | 1980-10-28 |
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