JPS6227497B2 - - Google Patents
Info
- Publication number
- JPS6227497B2 JPS6227497B2 JP6272579A JP6272579A JPS6227497B2 JP S6227497 B2 JPS6227497 B2 JP S6227497B2 JP 6272579 A JP6272579 A JP 6272579A JP 6272579 A JP6272579 A JP 6272579A JP S6227497 B2 JPS6227497 B2 JP S6227497B2
- Authority
- JP
- Japan
- Prior art keywords
- phosphor
- conductive film
- filament
- bulb
- alumina
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 23
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 19
- 239000012535 impurity Substances 0.000 claims description 10
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 10
- 229910052753 mercury Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000000941 radioactive substance Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 230000005611 electricity Effects 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000012857 radioactive material Substances 0.000 description 7
- 230000006378 damage Effects 0.000 description 5
- 230000002159 abnormal effect Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/38—Exhausting, degassing, filling, or cleaning vessels
- H01J9/385—Exhausting vessels
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Electron Tubes, Discharge Lamp Vessels, Lead-In Wires, And The Like (AREA)
- Discharge Lamps And Accessories Thereof (AREA)
Description
本発明はけい光ランプの製造方法に関し、特に
ラピツトスタート形けい光ランプの製造に適す
る。
従来一般に予熱始動形けい光ランプにおいて、
バルブ内を排気しながらフイラメントに通電して
電子放射性物質を分解し、そののち水銀封入前に
両フイラメント間に高電圧を印加して微光放電を
生じさせて管内各部たとえばけい光体やバルブの
吸着ガス、未分解電子放射性物質の分解ガスなど
の不純ガスを排除することが知られている。
しかしこの技術をバルブ内面に透明導電膜を形
成し、この導電膜上にけい光体被膜を設けたラピ
ツトスタート形けい光ランプに適用すると、微光
放電時の電流が導電膜に流れてこの導電膜を破壊
するため、著く始動困難となるばかりか、管内に
封入された水銀が導電膜の破壊された部分に付着
して外観にも悪影響を及ぼし、不適当であつた。
特に、ラピツトスタート形けい光ランプは一般に
メインワイヤにサブワイヤを巻回してなる二次コ
イルをさらに巻回してなる三重コイルフイラメン
トが用いられているが、メインワイヤに比較して
サブワイヤの抵抗が大きいため、通電時サブワイ
ヤの温度が低く、このためサブワイヤ週辺の電子
放射性物質の分解が不充分となり、不純ガスの排
出が完全に行われにくく、二重コイルフイラメン
トを使用した他の予熱始動形けい光ランプに比較
して点灯初期にスネーキングという異状放電現象
が起りやすく、また数千時間点灯後に不純ガスと
水銀とが結合して生じる黒化現象が生じやすい。
このためにも前述の水銀封入前の微光放電による
不純ガスの排除が必要となる。
本発明はこのような事情に基づいてなされたも
ので、バルブ内面に形成した導電膜上にγアルミ
ナとけい光体とを被着しかつ上記バルブの両端に
電子放射性物質を被着したフイラメントを封装し
てけい光ランプを排気しながらフイラメントに通
電して電子放射性物質を分解しつつフイラメント
間に高電圧を印加して微光放電を生じさせ、この
放電によつて電子放射性物質を完全に分解し、管
内各部の吸着不純ガスを放出させ、しかも導電膜
の損傷を防止したことである。
以下、本発明の詳細を実施例によつて説明す
る。まず、本発明を適用すべきけい光ランプの1
例を第1図に示す。図中1は直管形バルブ、2は
このバルブ1内面に形成された透明導電膜、3は
この導電膜上に形成されたけい光体被膜、4は上
記バルブ1の端面を閉塞するフレヤステム、5,
5はこのステム4を貫通して上記バルブ1内に延
在する1対のリード線、6はこのリード線5,5
の先端部間に装架された三重コイルフイラメン
ト、7はこのフイラメント6に塗布された電子放
射性物質、8は上記ステム4に設けられた排気管
である。
上記けい光体被膜3はけい光体にこのけい光体
重量の0.1〜1wt%のγアルミナを混合して被着形
成したものである。
つぎに、このけい光ランプの排気封止工程を第
2図示の排気スケジユールによつて概説すれば、
ターンテーブル10の縁に多数のヘツドが環状配
設されており、このヘツドの第1ポジシヨン11
でランプを装着し、第2ポジシヨン12で排気管
8が排気系に導通し、範囲13に属するポジシヨ
ンが加熱炉14内にあつて排気しながら加熱して
吸着不純ガスを排除する。ついで、範囲15に属
するポジシヨン16において、リード線5,5が
ライテイングレール17,17に接触してフイラ
メント6に通電しその熱によつて電子放射性物質
7が分解活性化され、このとき放出された分解ガ
スは充分に排出される。そして、ポジシヨン18
において、各フイラメント6,6にそれぞれ約
0.55Aの加熱電流を通流しながら図示しない他の
レールによつて両端のフイラメント6,6間に約
700Vの無負荷電圧を印加して微光放電を生じさ
せ、この放電のイオン衝撃によつて電子放射性物
質7を完全に分解し、また分解済の電子放射性物
質やけい光体被膜3などの管内部材に吸着されて
いた不純ガスも同時に放出されて排出される。そ
して、ポジシヨン19において、水銀を封入し、
ついでポジシヨン20において始動ガスを封入
し、ポジシヨン21において排気管8を封止し、
ポジシヨン22において封止ランプを取り出す。
しかして、けい光体にアルミナを混合してなる
けい光体被膜3はアルミナを含有しない場合に比
較して、100〜200V低い約500〜600Vの無負荷電
圧でも容易に微光放電が行なわれる。そしてアル
ミナの混合比が高くなるほど効果が大きいが、γ
アルミナの混入量がけい光体重量の2%程度にな
ると別の問題であるところの寿命中における光束
低下が大きくなり、好ましくない。実験によれば
γアルミナの混入量の好ましい範囲はけい光体重
量の0.1〜1.0%である。このように、けい光体被
膜3にγアルミナを混入したことにより、無負荷
電圧を下げることが可能になり、この結果導電膜
2の破壊が実用上問題にならない程度まで軽減で
きるようになつた。換言すれば、導電膜2の破壊
を防止できる程度まで、この導電膜2に流入する
放電電流の分岐電流を抑制することができた。
しかしてγアルミナの作用は、ゲツタ作用によ
り、ランプ中の真空度を上げて放電電流がランプ
空間を流れ易くすることにあると考えられる。つ
まり、このゲツタ作用はけい光体にゲツタ剤を混
合して塗布した場合、通常の排気工程すなわちラ
ンプを加熱し排気し自然冷却を行なう工程中冷却
の過程において、ランプの放電空間中の不純ガス
を吸収して放電を容易にすることである。しかし
て、ゲツタ剤として種々のものが考えられるが、
粒径が細いほどよく、水銀とアマルガムと結合し
にくいこと、および寿命未期までその性能が変ら
ないことなどが要求され、γアルミナはこれらの
条件をほぼ満している。また、γアルミナの粒度
を変更した試験では平均粒径で5〜50mμのもの
が放電電流を下げるのに最も効果があつた。
つぎに、ラピツトスタート形40Wけい光ランプ
を例にとり、上述した本例ランプと比較例とにつ
いた異状放電発生率と管壁黒化発生率とを比較し
た。この結果を次表に示す。
The present invention relates to a method for manufacturing a fluorescent lamp, and is particularly suitable for manufacturing a rapid-start type fluorescent lamp. Conventionally, in preheating start type fluorescent lamps,
While evacuating the inside of the bulb, electricity is applied to the filament to decompose the electron radioactive material, and then, before filling in mercury, a high voltage is applied between both filaments to create a faint discharge that disturbs various parts of the tube, such as the phosphor and the bulb. It is known to eliminate impurity gases such as adsorbed gases and decomposed gases of undecomposed electron radioactive substances. However, when this technology is applied to a rapid-start fluorescent lamp that has a transparent conductive film formed on the inner surface of the bulb and a phosphor film on top of this conductive film, the current during a faint discharge flows through the conductive film and this Since the conductive film is destroyed, it is not only difficult to start, but also the mercury sealed in the tube adheres to the destroyed part of the conductive film, adversely affecting the appearance, which is inappropriate.
In particular, rapid start type fluorescent lamps generally use a triple coil filament, which is made by winding a subwire around a main wire and further winding a secondary coil, but the resistance of the subwire is higher than that of the main wire. Therefore, the temperature of the sub-wire is low when energized, and as a result, the decomposition of the electron radioactive material on the side of the sub-wire is insufficient, and impurity gas is difficult to be completely discharged. Compared to optical lamps, it is more likely to cause an abnormal discharge phenomenon called snaking in the early stages of lighting, and it is also more likely to cause blackening caused by the combination of impure gas and mercury after being lit for several thousand hours.
For this purpose as well, it is necessary to eliminate impurity gas by the faint discharge described above before filling the mercury. The present invention was made based on the above circumstances, and includes a method in which gamma alumina and a phosphor are coated on a conductive film formed on the inner surface of a bulb, and a filament coated with an electron radioactive substance is sealed at both ends of the bulb. Then, while evacuating the fluorescent lamp, electricity is applied to the filament to decompose the electron radioactive substance, and a high voltage is applied between the filaments to generate a faint discharge, and this discharge completely decomposes the electron radioactive substance. , the adsorbed impurity gas in various parts of the tube is released, and furthermore, damage to the conductive film is prevented. Hereinafter, the details of the present invention will be explained with reference to Examples. First, one of the fluorescent lamps to which the present invention is applied
An example is shown in FIG. In the figure, 1 is a straight tube type bulb, 2 is a transparent conductive film formed on the inner surface of the bulb 1, 3 is a phosphor coating formed on the conductive film, 4 is a flare stem that closes the end face of the bulb 1, 5,
5 is a pair of lead wires extending through the stem 4 and into the valve 1; 6 is a pair of lead wires 5, 5;
A triple coil filament is mounted between the tips of the filament 6, 7 is an electron radioactive material coated on the filament 6, and 8 is an exhaust pipe provided on the stem 4. The phosphor coating 3 is formed by adhering to the phosphor a mixture of gamma alumina in an amount of 0.1 to 1 wt% of the weight of the phosphor. Next, the exhaust sealing process for this fluorescent lamp will be summarized using the exhaust schedule shown in the second diagram.
A number of heads are arranged in a ring around the edge of the turntable 10, and a first position 11 of the heads
The lamp is attached at the second position 12, the exhaust pipe 8 is connected to the exhaust system, and the position belonging to the range 13 is located in the heating furnace 14, which is heated while being evacuated to eliminate the adsorbed impurity gas. Next, at position 16 belonging to range 15, the lead wires 5, 5 contact the writing rails 17, 17 to energize the filament 6, and the electron radioactive substance 7 is decomposed and activated by the heat, and is emitted at this time. The cracked gas is sufficiently exhausted. And position 18
In each filament 6, 6, approximately
While passing a heating current of 0.55A, another rail (not shown) is used to connect the filaments 6 and 6 at both ends.
A no-load voltage of 700V is applied to generate a faint discharge, and the ion bombardment of this discharge completely decomposes the electron radioactive material 7, and also removes the decomposed electron radioactive material and phosphor coating 3 inside the tube. Impure gas adsorbed on the member is also released and exhausted at the same time. Then, in position 19, mercury is sealed,
Next, starting gas is charged at position 20, and exhaust pipe 8 is sealed at position 21.
At position 22, the sealed lamp is taken out. Therefore, the phosphor coating 3 made of a phosphor mixed with alumina easily causes a weak discharge even at a no-load voltage of approximately 500 to 600 V, which is 100 to 200 V lower than that in a case that does not contain alumina. . The higher the alumina mixing ratio, the greater the effect, but γ
When the amount of alumina mixed is about 2% of the weight of the phosphor, another problem arises, which is that the luminous flux decreases significantly during the life, which is not preferable. According to experiments, the preferred range of the amount of gamma alumina mixed is 0.1 to 1.0% of the phosphor weight. In this way, by mixing γ alumina into the phosphor film 3, it has become possible to lower the no-load voltage, and as a result, the destruction of the conductive film 2 can be reduced to the extent that it does not pose a problem in practice. . In other words, the branch current of the discharge current flowing into the conductive film 2 could be suppressed to the extent that destruction of the conductive film 2 could be prevented. Therefore, it is thought that the function of γ alumina is to increase the degree of vacuum in the lamp through getter action, thereby making it easier for the discharge current to flow through the lamp space. In other words, when a getter agent is mixed and applied to the phosphor, this getter effect is caused by the impurity gas in the discharge space of the lamp during the normal exhaust process, that is, the process of heating the lamp, exhausting the lamp, and performing natural cooling. The purpose is to absorb and facilitate discharge. However, there are many different types of sticklers, but
The finer the particle size, the better, the less likely it is to combine with mercury and amalgam, and the performance of which remains unchanged until the end of its life, and γ alumina nearly satisfies these conditions. In addition, in tests in which the particle size of γ alumina was varied, particles with an average particle size of 5 to 50 mμ were most effective in lowering the discharge current. Next, using a rapid start type 40W fluorescent lamp as an example, the abnormal discharge occurrence rate and tube wall blackening occurrence rate were compared between the above-mentioned lamp of this example and the comparative example. The results are shown in the table below.
【表】
このように、本例方法によれば微光放電によつ
て未分解の電子放射性物質を分解し、かつ吸着不
純ガスを排除でき、ランプ完成後の残留不純ガス
による異状放電が管壁黒化が少なく、しかもγア
ルミナの作用により導電膜の損傷が少なく、した
がつて始動電圧上昇や水銀付着による点灯外観の
劣化が少ない。
なお、前述の実施例はγアルミナをけい光体に
混入してけい光体被膜に形成したが本発明はこれ
に限らず、たとえば導電膜上にγアルミナ被膜を
形成し、そのうえにγアルミナを含まないけい光
体被膜を形成してもよく、あるいは導電膜上にγ
アルミナを含まないけい光体被膜を形成し、その
うえにγアルミナを被着してもよい。
このように、本発明のけい光ランプの製造方法
は、バルブ内面に形成した導電膜にγアルミナと
けい光体とを被着し、上記バルブの両端に電子放
射性物質を被着したフイラメントを封装してなる
けい光ランプを排気しながら上記フイラメントに
通電して上記電子放射性物質を分解しつつ水銀封
入前に上記両端のフイラメント間に高電圧を印加
して微光放電を生じさせ管内不純ガスを排除する
ので、異状放電や管壁黒化が少なく、しかも導電
被膜の損傷が少ないので始動電圧の上昇や水銀付
着による点灯外観劣化が少ない利点がある。[Table] In this way, according to the method of this example, it is possible to decompose undecomposed electron radioactive materials by low-light discharge and eliminate adsorbed impurity gases, and prevent abnormal discharges caused by residual impurity gases from occurring on the tube wall after the lamp is completed. There is little blackening, and there is little damage to the conductive film due to the action of γ alumina, so there is little deterioration in lighting appearance due to increased starting voltage or mercury adhesion. Note that in the above embodiment, γ alumina is mixed into a phosphor to form a phosphor film, but the present invention is not limited to this. For example, a γ alumina film is formed on a conductive film, and γ alumina is added thereto. A phosphor film may be formed on the conductive film, or a γ film may be formed on the conductive film.
An alumina-free phosphor coating may be formed and gamma alumina deposited thereon. As described above, the method for manufacturing a fluorescent lamp of the present invention includes coating gamma alumina and a phosphor on a conductive film formed on the inner surface of a bulb, and sealing a filament coated with an electron radioactive substance on both ends of the bulb. While evacuating the fluorescent lamp, electricity is applied to the filament to decompose the electron radioactive substance, and before filling in mercury, a high voltage is applied between the filaments at both ends to generate a faint discharge and eliminate impurity gas inside the tube. Therefore, there is less abnormal discharge and blackening of the tube wall, and there is less damage to the conductive coating, so there is an advantage that there is less increase in starting voltage and less deterioration in lighting appearance due to mercury adhesion.
第1図は本発明のけい光ランプの製造方法を適
用すべきランプの一例の断面図、第2図はその製
造方法を示す説明図である。
1……バルブ、2……導電膜、3……けい光体
被膜、6……フイラメント、7……電子放射性物
質。
FIG. 1 is a sectional view of an example of a lamp to which the fluorescent lamp manufacturing method of the present invention is applied, and FIG. 2 is an explanatory diagram showing the manufacturing method. DESCRIPTION OF SYMBOLS 1... Bulb, 2... Conductive film, 3... Phosphor coating, 6... Filament, 7... Electron radioactive material.
Claims (1)
とけい光体とを被着し、上記バルブの両端に電子
放射性物質を被着したフイラメントを封装してな
るけい光ランプを排気しながら上記フイラメント
に通電して上記電子放射性物質を分解しつつ水銀
封入前に上記両端のフイラメント間に高電圧を印
加して微光放電を生じさせ管内不純ガスを排除す
ることを特徴とするけい光ランプの製造方法。 2 けい光体にこのけい光体重量の0.1%ないし
1%のγアルミナを混合して被着したことを特徴
とする前記特許請求の範囲第1項記載のけい光ラ
ンプの製造方法。[Claims] 1. A fluorescent lamp comprising gamma alumina and a phosphor coated on a conductive film formed on the inner surface of the bulb, and a filament coated with an electron radioactive substance at both ends of the bulb is evacuated. The method is characterized in that, while electricity is applied to the filament to decompose the electron radioactive substance, a high voltage is applied between the filaments at both ends to generate a faint discharge and eliminate impurity gas in the tube before filling with mercury. Method of manufacturing light lamps. 2. A method for manufacturing a fluorescent lamp according to claim 1, characterized in that gamma alumina is mixed and deposited on the phosphor in an amount of 0.1% to 1% of the weight of the phosphor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6272579A JPS55155441A (en) | 1979-05-23 | 1979-05-23 | Manufacture of fluorescent lamp |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6272579A JPS55155441A (en) | 1979-05-23 | 1979-05-23 | Manufacture of fluorescent lamp |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55155441A JPS55155441A (en) | 1980-12-03 |
| JPS6227497B2 true JPS6227497B2 (en) | 1987-06-15 |
Family
ID=13208618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6272579A Granted JPS55155441A (en) | 1979-05-23 | 1979-05-23 | Manufacture of fluorescent lamp |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55155441A (en) |
-
1979
- 1979-05-23 JP JP6272579A patent/JPS55155441A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55155441A (en) | 1980-12-03 |
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