JPS6228117B2 - - Google Patents
Info
- Publication number
- JPS6228117B2 JPS6228117B2 JP1101483A JP1101483A JPS6228117B2 JP S6228117 B2 JPS6228117 B2 JP S6228117B2 JP 1101483 A JP1101483 A JP 1101483A JP 1101483 A JP1101483 A JP 1101483A JP S6228117 B2 JPS6228117 B2 JP S6228117B2
- Authority
- JP
- Japan
- Prior art keywords
- calcium
- leaves
- plants
- solution
- absorbed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 14
- 239000004281 calcium formate Substances 0.000 claims description 14
- 229940044172 calcium formate Drugs 0.000 claims description 14
- 235000019255 calcium formate Nutrition 0.000 claims description 14
- 238000005507 spraying Methods 0.000 claims description 10
- 239000003337 fertilizer Substances 0.000 claims description 9
- 239000004480 active ingredient Substances 0.000 claims description 4
- 241000196324 Embryophyta Species 0.000 description 18
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 13
- 229960005069 calcium Drugs 0.000 description 13
- 239000011575 calcium Substances 0.000 description 13
- 229910052791 calcium Inorganic materials 0.000 description 13
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 230000008635 plant growth Effects 0.000 description 8
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 7
- 239000001527 calcium lactate Substances 0.000 description 7
- 229960002401 calcium lactate Drugs 0.000 description 7
- 235000011086 calcium lactate Nutrition 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000001110 calcium chloride Substances 0.000 description 6
- 229910001628 calcium chloride Inorganic materials 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 description 2
- -1 nitrate ions Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000150 monocalcium phosphate Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
Landscapes
- Fertilizers (AREA)
Description
本発明は植物体内にカルシウム分を吸収させる
ために植物の葉面に散布して用いる肥料に関する
ものである。
一般に、植物体内において、カルシウム分は、
細胞の同化力を高め、養分転流を強化して、植物
の生長を促進させる働きがある等植物の生育上有
効であることが知られている。このため従来で
は、例えば土壌中に石灰を施肥し、この石灰中の
カルシウム分を植物の根から吸収させることが行
なわれているが、これではカルシウム分が根から
排出される二酸化炭素や雨水と反応して重炭酸カ
ルシウムの形で地下に流亡し、或いは、他の化学
肥料により土壌中に与えられる硝酸イオン、硫酸
イオン、塩素イオン等と反応して硝酸カルシウ
ム、硫酸カルシウム、塩化カルシウム等の形で地
下に流亡し、このためにカルシウム分が植物体内
へ十分に吸収されなかつた。また、植物体内に吸
収されたカルシウム分は一般にその体内中の古い
組織から新しい組織へ移動し難い性質をもつてい
ることから、カルシウム分が根から茎を伝つて葉
に至るまで植物全内に亘つて十分に供給されず、
そのために植物の生長効果が十分に発揮されてい
なかつた。
このようなことから、カルシウム分を植物に葉
面散布して葉を通じて植物体内に吸収させること
も行なわれており、そのための散布剤として、例
えば、塩化カルシウム液が知られているが、塩化
カルシウム中の塩素イオンは植物にとつてあまり
必要でなく時には葉を枯らして葉の光合成の機能
を阻害するといつた問題もあつて、葉面散布用の
肥料としては必ずしも適切なものではなかつた。
本発明者はこのような実情に鑑み、種々実験し
た結果、葉から植物体内への吸収性が良く、か
つ、成分的にも植物に害を与えない葉面散布用の
肥料を発明するに至つたものであり、その要旨と
するところは、ギ酸カルシウムを有効成分とする
植物の葉面散布用肥料に存するものである。
次に実験例を挙げて本発明を説明する。
表1は各種カルシウム分を含む化合物の水(水
温20℃)に対する溶解量と、そのときのPH値
The present invention relates to a fertilizer that is applied to the leaves of plants in order to absorb calcium into the plants. Generally, in plants, calcium content is
It is known to be effective for plant growth, such as increasing the assimilation power of cells, strengthening nutrient translocation, and promoting plant growth. Conventionally, for example, lime is fertilized into the soil and the calcium in the lime is absorbed by the plant roots, but this method does not allow the calcium to be absorbed by the carbon dioxide and rainwater released from the roots. It reacts and flows underground in the form of calcium bicarbonate, or it reacts with nitrate ions, sulfate ions, chloride ions, etc. given to the soil by other chemical fertilizers and forms calcium nitrate, calcium sulfate, calcium chloride, etc. Therefore, the calcium content was not absorbed into the plant body sufficiently. In addition, calcium absorbed into the plant body generally has a property that it is difficult to move from old tissues to new tissues within the body, so calcium is distributed throughout the plant from the roots to the stems to the leaves. have not been adequately supplied for a long time,
Therefore, the plant growth effect was not fully exhibited. For this reason, calcium is sometimes sprayed on the leaves of plants to be absorbed into the plant body through the leaves.For example, calcium chloride solution is known as a spraying agent for this purpose, but calcium chloride The chlorine ions contained therein were not very necessary for plants, and sometimes caused the leaves to wither and inhibit the photosynthetic function of the leaves, so it was not necessarily suitable as a fertilizer for foliar spraying. In view of these circumstances, the present inventor has conducted various experiments, and as a result has come up with a fertilizer for foliar spraying that is highly absorbable from the leaves into the plant body and does not cause any harm to plants in terms of its ingredients. Its gist lies in a fertilizer for foliar spraying on plants containing calcium formate as an active ingredient. Next, the present invention will be explained by giving experimental examples. Table 1 shows the amounts of various calcium-containing compounds dissolved in water (water temperature 20°C) and their PH values.
【表】
を示したものである。
表1より明らかなように、水に対する溶解量は
塩化カルシウム>ギ酸カルシウム>乳酸カルシウ
ム>第一リン酸カルシウム>水酸化カルシウムの
順で、塩化カルシウムと本発明に係るギ酸カルシ
ウムが水に対する溶解量が多く、これを有効成分
とする散布剤の製造が最も容易である。また、PH
値の比較より、ギ酸カルシウム液と塩化カルシウ
ム液が略々中性であつて、植物に対する酸又は塩
基による害が最も少なく、次に弱酸性の乳酸カル
シウム液、最も不適当なものは強酸性の第一リン
酸カルシウム液と強アルカリ性の水酸化カルシウ
ム液である。しかし、前述したように塩素イオン
を含む塩化カルシウム液は葉を故らす欠点がある
のに対して、ギ酸カルシウム液は分解すると植物
の生育上有効、かつ害のない二酸化炭素および水
を発生させるものであり、この点、ギ酸カルシウ
ムは塩化カルシウムよりも成分的に好ましい。
次に上記表1に示した化合物のうち、ギ酸カル
シウムと乳酸カルシウムについて、所定の散布剤
に組成した後、実際に植物の葉面に散布して実験
を行なつた。実験方法としては、ギ酸カルシウム
50倍区、100倍区、および乳酸カルシウム50倍区
の稀釈水溶液を作成し、これに展着剤(アグラー
5000倍区)を加えて散布剤を作り、この各散布剤
をマルバカイドウ台に接木したM26苗木の葉面に
スプレーした。そして、約30日間放置した後、葉
を摘取つて熱風乾燥し、湿式分解してからこの乾
物中に含有されるカルシウム量およびマグネシウ
ム量をEDTA法により定量分析した。その結果を
表2に示す。[Table] As is clear from Table 1, the amount dissolved in water is in the order of calcium chloride>calcium formate>calcium lactate>monocalcium phosphate>calcium hydroxide, and calcium chloride and calcium formate according to the present invention have a larger amount dissolved in water. It is easiest to produce a dusting agent containing this as an active ingredient. Also, PH
Comparison of values shows that calcium formate solution and calcium chloride solution are almost neutral and cause the least harm to plants from acids or bases, followed by weakly acidic calcium lactate solution, and the most unsuitable one is strongly acidic calcium lactate solution. These are monobasic calcium phosphate solution and strongly alkaline calcium hydroxide solution. However, as mentioned above, calcium chloride solution containing chloride ions has the disadvantage of damaging leaves, whereas calcium formate solution, when decomposed, generates carbon dioxide and water that are useful and harmless for plant growth. In this respect, calcium formate is preferable to calcium chloride in terms of its composition. Next, among the compounds shown in Table 1 above, calcium formate and calcium lactate were formulated into a predetermined spraying agent, and then an experiment was conducted by actually spraying them on the leaves of plants. As an experimental method, calcium formate
Create diluted aqueous solutions of 50x, 100x, and 50x calcium lactate, and add a spreading agent (Aglar) to this.
5,000 times) to make a spraying agent, and each of these spraying agents was sprayed on the leaves of M26 seedlings grafted on a Marubakaido stand. After being left for about 30 days, the leaves were picked, dried with hot air, and subjected to wet decomposition, and the amounts of calcium and magnesium contained in the dried matter were quantitatively analyzed using the EDTA method. The results are shown in Table 2.
【表】
表2より明らかなように、葉に含有されるカル
シウム量はギ酸カルシウム液散布のものでは50倍
区および100倍区のいずれの場合も、葉面散布無
し、および乳酸カルシウム液散布のものよりも多
く、また、マグネシウム量もギ酸カルシウム液散
布のものが最も多かつた。
このことは、ギ酸カルシウム液中のカルシウム
イオンが乳酸カルシウム液中のカルシウムイオン
よりも植物への吸収性が良いことを意味し、ま
た、このために、植物の細胞同化力が高められて
土壌中のマグネシウム分が根から盛んに吸収され
たものと考えられる。マグネシウムは葉の光合成
を活発に行なわせるので、植物の生長が益々促進
されることが期待できるものである。
以上実施例について説明したように、本発明に
係る葉面散布用肥料は、ギ酸カルシウムを有効成
分としたものであるから、肥料中のカルシウム分
が葉を通じて植物体内へ効率良く吸収されて植物
の生育を助長させる。また、ギ酸カルシウムがそ
のカルシウム分を吸収された後には二酸化炭素と
水とに分解し、これらは植物の生育に害がないば
かりでなく、却つて植物の生育に有効に寄与する
ものであつて、従来の塩化カルシウムを成分とす
る散布剤のように葉を枯らすといつた問題もな
い。従つて、植物の生長が従来よりも顕著に高め
られ、産業上有益である。[Table] As is clear from Table 2, the amount of calcium contained in leaves is the same for both 50x and 100x when sprayed with calcium formate solution, without foliar spraying, and when calcium lactate solution is sprayed. In addition, the amount of magnesium was the highest in the calcium formate liquid spray. This means that the calcium ions in the calcium formate solution are better absorbed by plants than the calcium ions in the calcium lactate solution. It is thought that the magnesium content in the leaves was absorbed actively through the roots. Since magnesium activates photosynthesis in leaves, it can be expected to further promote plant growth. As explained above in the examples, since the foliar spray fertilizer according to the present invention contains calcium formate as an active ingredient, the calcium content in the fertilizer is efficiently absorbed into the plant body through the leaves, and the fertilizer is absorbed into the plant body through the leaves. Encourage growth. In addition, after calcium formate absorbs its calcium content, it decomposes into carbon dioxide and water, which not only do not cause any harm to plant growth, but also contribute effectively to plant growth. There is no problem with drying leaves, which is the case with conventional sprays containing calcium chloride. Therefore, the growth of plants is significantly increased compared to the conventional method, which is industrially beneficial.
Claims (1)
散布用肥料。1. Fertilizer for foliar spraying of plants containing calcium formate as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1101483A JPS59137384A (en) | 1983-01-25 | 1983-01-25 | Fertilizer for plant foliar spray |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1101483A JPS59137384A (en) | 1983-01-25 | 1983-01-25 | Fertilizer for plant foliar spray |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59137384A JPS59137384A (en) | 1984-08-07 |
| JPS6228117B2 true JPS6228117B2 (en) | 1987-06-18 |
Family
ID=11766257
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1101483A Granted JPS59137384A (en) | 1983-01-25 | 1983-01-25 | Fertilizer for plant foliar spray |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59137384A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3135503B2 (en) | 1996-08-09 | 2001-02-19 | 花王株式会社 | Fertilizer absorption promoter composition and fertilizer composition |
| JP3902818B2 (en) * | 1996-10-21 | 2007-04-11 | 村樫石灰工業株式会社 | Method for producing composition for spraying leaves or fruits of plants |
| US6387147B2 (en) | 1998-02-06 | 2002-05-14 | Kao Corporation | Fertilizer composition |
| DE10143084A1 (en) * | 2001-09-03 | 2003-03-20 | Bayer Cropscience Ag | Fruit thinning process |
| DE102006053539A1 (en) | 2006-11-14 | 2008-05-15 | Lanxess Deutschland Gmbh | Calcium fertilizers |
| CL2009000300A1 (en) * | 2008-02-15 | 2010-09-10 | Lanxess Distrib Gmbh | Formulation comprising calcium salts and formate salts plus an organic acid with a pka between 2 and 6; uses and methods that use this formulation to combat blight caused in plants by the bacterium erwinia amylovora. |
| JP5453380B2 (en) * | 2010-12-13 | 2014-03-26 | 晃栄化学工業株式会社 | fertilizer |
-
1983
- 1983-01-25 JP JP1101483A patent/JPS59137384A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59137384A (en) | 1984-08-07 |
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