JPS6238155B2 - - Google Patents
Info
- Publication number
- JPS6238155B2 JPS6238155B2 JP54058790A JP5879079A JPS6238155B2 JP S6238155 B2 JPS6238155 B2 JP S6238155B2 JP 54058790 A JP54058790 A JP 54058790A JP 5879079 A JP5879079 A JP 5879079A JP S6238155 B2 JPS6238155 B2 JP S6238155B2
- Authority
- JP
- Japan
- Prior art keywords
- inkjet recording
- water
- paper
- dye
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004078 waterproofing Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
- 239000000976 ink Substances 0.000 description 22
- 239000000975 dye Substances 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000001454 recorded image Methods 0.000 description 9
- 239000013053 water resistant agent Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- MZUSCVCCMHDHDF-UHFFFAOYSA-N P(=O)(=O)[W] Chemical compound P(=O)(=O)[W] MZUSCVCCMHDHDF-UHFFFAOYSA-N 0.000 description 4
- 239000000981 basic dye Substances 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 229920006317 cationic polymer Polymers 0.000 description 3
- 239000000982 direct dye Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 229920006318 anionic polymer Polymers 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- XRPLBRIHZGVJIC-UHFFFAOYSA-L chembl3182776 Chemical compound [Na+].[Na+].NC1=CC(N)=CC=C1N=NC1=CC=C(C=2C=CC(=CC=2)N=NC=2C(=CC3=CC(=C(N=NC=4C=CC=CC=4)C(O)=C3C=2N)S([O-])(=O)=O)S([O-])(=O)=O)C=C1 XRPLBRIHZGVJIC-UHFFFAOYSA-L 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 238000007602 hot air drying Methods 0.000 description 2
- -1 oleic acid diethylaminoethylamide acetate Chemical compound 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- JDASKPRUFDKACZ-UHFFFAOYSA-M 1-octadecylpyridin-1-ium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 JDASKPRUFDKACZ-UHFFFAOYSA-M 0.000 description 1
- MHOFGBJTSNWTDT-UHFFFAOYSA-M 2-[n-ethyl-4-[(6-methoxy-3-methyl-1,3-benzothiazol-3-ium-2-yl)diazenyl]anilino]ethanol;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(CCO)CC)=CC=C1N=NC1=[N+](C)C2=CC=C(OC)C=C2S1 MHOFGBJTSNWTDT-UHFFFAOYSA-M 0.000 description 1
- SSONCJTVDRSLNK-UHFFFAOYSA-N 2-methylprop-2-enoic acid;hydrochloride Chemical compound Cl.CC(=C)C(O)=O SSONCJTVDRSLNK-UHFFFAOYSA-N 0.000 description 1
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 1
- DUFCMRCMPHIFTR-UHFFFAOYSA-N 5-(dimethylsulfamoyl)-2-methylfuran-3-carboxylic acid Chemical compound CN(C)S(=O)(=O)C1=CC(C(O)=O)=C(C)O1 DUFCMRCMPHIFTR-UHFFFAOYSA-N 0.000 description 1
- WRAGBEWQGHCDDU-UHFFFAOYSA-M C([O-])([O-])=O.[NH4+].[Zr+] Chemical compound C([O-])([O-])=O.[NH4+].[Zr+] WRAGBEWQGHCDDU-UHFFFAOYSA-M 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- CDMXXXZRZWQJQE-UHFFFAOYSA-N acetic acid;2-methylprop-2-enoic acid Chemical compound CC(O)=O.CC(=C)C(O)=O CDMXXXZRZWQJQE-UHFFFAOYSA-N 0.000 description 1
- LIWAFFWGZQIWAG-UHFFFAOYSA-N acetic acid;n,n-dimethylaniline Chemical compound CC(O)=O.CN(C)C1=CC=CC=C1 LIWAFFWGZQIWAG-UHFFFAOYSA-N 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- KSCQDDRPFHTIRL-UHFFFAOYSA-N auramine O Chemical compound [H+].[Cl-].C1=CC(N(C)C)=CC=C1C(=N)C1=CC=C(N(C)C)C=C1 KSCQDDRPFHTIRL-UHFFFAOYSA-N 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 description 1
- 229960000228 cetalkonium chloride Drugs 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- UUPXKAJPMYOPLF-UHFFFAOYSA-N dimethyl(octadecyl)azanium;acetate Chemical compound CC(O)=O.CCCCCCCCCCCCCCCCCCN(C)C UUPXKAJPMYOPLF-UHFFFAOYSA-N 0.000 description 1
- FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- LRBQNJMCXXYXIU-QWKBTXIPSA-N gallotannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@H]2[C@@H]([C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-QWKBTXIPSA-N 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- SVYUQLNHVASWHX-UHFFFAOYSA-N n-(hydroxymethyl)prop-2-enamide;prop-2-enoic acid Chemical class OC(=O)C=C.OCNC(=O)C=C SVYUQLNHVASWHX-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- NMHTWXYFOWTMJH-UHFFFAOYSA-N oxiran-2-ylmethyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical class OC(=O)C=C.CC(=C)C(=O)OCC1CO1 NMHTWXYFOWTMJH-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 1
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- PEAGNRWWSMMRPZ-UHFFFAOYSA-L woodstain scarlet Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 PEAGNRWWSMMRPZ-UHFFFAOYSA-L 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0018—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using ink-fixing material, e.g. mordant, precipitating agent, after printing, e.g. by ink-jet printing, coating or spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Duplication Or Marking (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet (AREA)
Description
【発明の詳細な説明】
本発明はインクジエツト記録の耐水化法、特に
水性インクにより記録シート上に形成されたイン
クジエツト記録の耐水化法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for making inkjet recording water resistant, and particularly to a method for making inkjet recording water resistant formed on a recording sheet using water-based ink.
インクジエツト記録は騒音がなく、高速記録が
可能であり、記録紙も普通紙が使用できるため
に、端末プリンターなどに採用され近年急速に普
及している。また多数個のインクノズルを使用す
ることにより、多色記録を行うことも容易であ
り、各種のインクジエツト記録方式による多色イ
ンクジエツト記録が検討されている。 Inkjet recording is noiseless, can perform high-speed recording, and can use plain paper for recording, so it has been adopted in terminal printers and has become rapidly popular in recent years. Furthermore, by using a large number of ink nozzles, it is easy to perform multicolor recording, and multicolor inkjet recording using various inkjet recording methods is being studied.
インクジエツト記録に使用されるインクジエツ
ト記録シートは、上質紙、連続伝票用紙、アート
紙、コート紙、サイズ紙を添加せずに低密度に抄
いた紙、特開昭52―53012号、特開昭52―74340
号、特開昭53―49113号に記載されているような
インク吸収性が比較的良くて、且つインクの広が
りの少ないインクジエツト記録用紙、布、表面を
インク吸収性にしたプラスチツクスフイルム、木
板、金属板などである。 The inkjet recording sheets used for inkjet recording are high-quality paper, continuous slip paper, art paper, coated paper, paper made at low density without adding size paper, JP-A-52-53012, JP-A-52 ―74340
Inkjet recording paper with relatively good ink absorption and less ink spreading as described in Japanese Patent Application Laid-Open No. 53-49113, cloth, plastic film with an ink-absorbing surface, wooden board, Such as a metal plate.
これらのインクジエツト記録シートに対して
は、一般に水性インクによりインクジエツト記録
が行われる。インクジエツト記録用の水性インク
は、特開昭49―89534号、特開昭49―97620号、特
開昭50―143602号、特開昭50―102407号、特開昭
51―129310号、特開昭51―137506号、特開昭51―
137505号、特開昭51―115106号、特開昭51―
139408号、特開昭52―12008号、特開昭52―12009
号、特開昭52―12010号、特開昭52―74406号、特
公昭52―14643号、特公昭52―14644号、特開昭53
―77706号、特開昭53―119107号、特開昭53―
119108号、特公昭53―20882号などに記載されて
いるように、水溶性染料、湿潤剤、染料可溶化
剤、防黴剤、水、水混和性有機溶剤などよりなる
ものである。ここで水溶性染料としては、直接染
料、酸性染料、塩基性染料が使用されている。 Inkjet recording is generally performed on these inkjet recording sheets using water-based ink. Water-based inks for inkjet recording are disclosed in JP-A-49-89534, JP-A-49-97620, JP-A-50-143602, JP-A-50-102407, and JP-A-Sho.
No. 51-129310, JP-A-51-137506, JP-A-51-
No. 137505, Japanese Patent Application Publication No. 115106, Japanese Patent Application Publication No. 1973-
No. 139408, JP-A-52-12008, JP-A-52-12009
No., JP-A-52-12010, JP-A-52-74406, JP-A-52-14643, JP-A-52-14644, JP-A-53
-No. 77706, Japanese Patent Application Publication No. 119107, Japanese Patent Application Publication No. 1977-
As described in Japanese Patent Publication No. 119108, Japanese Patent Publication No. 53-20882, etc., it consists of a water-soluble dye, a wetting agent, a dye solubilizer, a fungicide, water, a water-miscible organic solvent, etc. Here, as water-soluble dyes, direct dyes, acid dyes, and basic dyes are used.
以上、述べたような従来公知のインクジエツト
記録シートに従来公知の水性インクにより記録さ
れたインクジエツト記録は、水がかかると染料に
よる記録がにじんだり、消失してしまい、耐水性
が殆んどない。また、高湿状態で長期間保存され
ると、インクジエツト記録がにじんでしまうこと
もある。 Inkjet recordings made using conventionally known aqueous inks on conventionally known inkjet recording sheets as described above have almost no water resistance, as the dye recordings smear or disappear when exposed to water. Furthermore, if stored for a long period of time in a high humidity condition, inkjet recordings may smear.
インクジエツト記録紙に染料染着成分が含まれ
ていて、単色インクジエツト記録のように噴射イ
ンク量が少ない場合には、耐水性の良い染料を選
べば実用的に問題のない耐水性が得られる場合も
ある。しかし、多色インクジエツト記録の場合
は、噴射されるインクが多量であり、インクジエ
ツト記録紙に染料染着性成分が含まれていても充
分な耐水性を得ることはできない。インクジエツ
ト記録紙が屋外掲示されるような場合は特に堅牢
な耐水性が必要であり、従来のインクジエツト記
録紙とインクの組合せによる多色インクジエツト
記録は全く実用に耐えないものであつた。 If the inkjet recording paper contains dye dyeing components and the amount of ink ejected is small, such as in monochrome inkjet recording, it may be possible to obtain practically acceptable water resistance by choosing a dye with good water resistance. be. However, in the case of multicolor inkjet recording, a large amount of ink is ejected, and even if the inkjet recording paper contains a dye-dyeable component, sufficient water resistance cannot be obtained. Particularly when inkjet recording paper is to be displayed outdoors, strong water resistance is required, and conventional multicolor inkjet recording using a combination of inkjet recording paper and ink has been completely impractical.
本発明の目的は、高度の耐水性を有するインク
ジエツト記録画像を得ることである。 An object of the present invention is to obtain inkjet recorded images having a high degree of water resistance.
本発明者等は、インクジエツト記録シートに水
性インクによりインクジエツト記録後、このイン
クジエツト記録シートに、水性インク中の染料と
イオン結合または配位結合によりレーキを形成し
て水不溶性とする耐水化剤を付与することによつ
て高度の耐水性が極めて容易に得られることを見
い出した。 After inkjet recording with water-based ink on an inkjet recording sheet, the present inventors applied a water-resistant agent to the inkjet recording sheet to form a lake through ionic or coordinate bonds with the dye in the water-based ink to make it water-insoluble. It has been found that a high degree of water resistance can be obtained extremely easily by doing so.
直接染料、酸性染料を含んだ水性インクにより
インクジエツト記録シートにインクジエツト記録
を行つた場合は、水溶性金属塩及びカオチン性ポ
リマーなどのカチオン性物質を耐水化剤として付
与することにより、染料中のスルホン酸基、カル
ボキシル基などのアニオン性基と水不溶性の染料
レーキが形成され、インクジエツト記録画像が耐
水化される。水性インクが塩基性染料を含む場合
は、リンタングステンモリブデン酸及びタンニン
などのアニオン性物質を耐水化剤として付与する
ことにより、染料中のアミノ基などのカチオン性
基と水不溶性の染料レーキが形成され、インクジ
エツト記録画像が耐水化される。 When inkjet recording is performed on an inkjet recording sheet using aqueous ink containing direct dyes or acidic dyes, sulfones in the dyes can be removed by adding cationic substances such as water-soluble metal salts and cationic polymers as water-resistant agents. A water-insoluble dye lake is formed with anionic groups such as acid groups and carboxyl groups, making the inkjet recorded image waterproof. If the aqueous ink contains a basic dye, an anionic substance such as phosphotungsten molybdic acid and tannin is added as a water-resistant agent to form a water-insoluble dye lake with cationic groups such as amino groups in the dye. The inkjet recorded image is made water resistant.
直接染料、酸性染料を含んだ水性インクの耐水
化剤としては、硫酸アルミニウム、塩化アルミニ
ウム、ポリ塩化アルミニウム、酢酸アルミニウ
ム、塩化バリウム、塩化亜鉛、塩化カルシウム、
酢酸カルシウム、炭酸ジルコニウムアンモン、酢
酸ジルコニウムなどの２価以上の金属の水溶性金
属塩、アルミナゾルなどのカチオン性ゾル、ジメ
チルアニリン酢酸塩、ステアリルジメチルアミン
酢酸塩、オレイン酸ジエチルアミノエチルアミド
酢酸塩、オクタデシルピリジニウムブロマイド、
ステアリルトリメチルアンモニウムクロライド、
セチルジメチルベンジルアンモニウムクロライド
などの低分子カチオン性物質、カチオン性ポリマ
ー特にポリエチレンイミン、ポリエチレンイミン
―エピクロルヒドリン反応物、ポリエチレンイミ
ン―アクリルアミド付加物、ポリエチレンイミン
―アクリロニトリル付加物、アシル化ポリエチレ
ンイミン、ポリアミド―ポリアミン樹脂、ポリア
ミド―ポリアミン―エピクロルヒドリン樹脂、ポ
リジメチルアミノエチルメタクリレート酢酸塩、
ポリジメチルアミノエチルメタクリレート塩酸塩
のエピクロルヒドリンによる第４級化物などの架
橋または酸の揮発により水不溶性となるカチオン
性ポリマーが使用される。 Water-resistant agents for water-based inks containing direct dyes and acid dyes include aluminum sulfate, aluminum chloride, polyaluminum chloride, aluminum acetate, barium chloride, zinc chloride, calcium chloride,
Water-soluble metal salts of divalent or higher valent metals such as calcium acetate, ammonium zirconium carbonate, zirconium acetate, cationic sols such as alumina sol, dimethylaniline acetate, stearyldimethylamine acetate, oleic acid diethylaminoethylamide acetate, octadecylpyridinium bromide,
stearyltrimethylammonium chloride,
Low-molecular cationic substances such as cetyldimethylbenzylammonium chloride, cationic polymers, especially polyethyleneimine, polyethyleneimine-epichlorohydrin reaction products, polyethyleneimine-acrylamide adducts, polyethyleneimine-acrylonitrile adducts, acylated polyethyleneimine, polyamide-polyamine resins , polyamide-polyamine-epichlorohydrin resin, polydimethylaminoethyl methacrylate acetate,
A cationic polymer that becomes water-insoluble by crosslinking or acid volatilization, such as a quaternized product of polydimethylaminoethyl methacrylate hydrochloride with epichlorohydrin, is used.
塩基性染料を含んだ水性インクの耐水化剤とし
ては、リンタングステン酸、リンモリブデン酸、
リンタングステンモリブデン酸などの水溶性金属
塩、タンニン酸、吐酒石、脂肪酸、アルキルベン
ゼンスルホン酸、フエノール化合物のスルホン化
物、ナフタリンスルホン酸縮合物などの低分子ア
ニオン性物質、アニオン性ポリマー特にスチレン
―無水マレイン酸共重合物のアンモニウム塩、α
―オレフイン―無水マレイン酸共重合物のアンモ
ニウム塩、Ｎ―メチロールアクリルアミド―アク
リル酸共重合物のアンモニウム塩、グリシジルメ
タクリレート―アクリル酸共重合物のアンモニウ
ム塩などの架橋またはアルカリの揮発により水不
溶性となるアニオン性ポリマーが使用される。 Water-resistant agents for water-based inks containing basic dyes include phosphotungstic acid, phosphomolybdic acid,
Water-soluble metal salts such as phosphotungsten molybdic acid, tannic acid, tartarite, fatty acids, alkylbenzenesulfonic acids, sulfonated products of phenolic compounds, low-molecular anionic substances such as naphthalenesulfonic acid condensates, anionic polymers, especially styrene-anhydride Ammonium salt of maleic acid copolymer, α
- Ammonium salts of olefin-maleic anhydride copolymers, ammonium salts of N-methylol acrylamide-acrylic acid copolymers, ammonium salts of glycidyl methacrylate-acrylic acid copolymers, etc. become water-insoluble due to crosslinking or volatilization of alkali. Anionic polymers are used.
以上のような耐水化剤は、水、水混和性有機溶
剤により溶液としてインクジエツト記録シートに
付与される。耐水化剤の溶液濃度は0.5〜10％、
更に好ましくは１〜５％が適当である。水混和性
有機溶剤としては、メタノール、エタノール、ア
セトン、ジメチルホルムアミドなどが適してい
る。耐水化剤溶液に紫外線吸収剤、螢光染料、溌
水剤などを添加しても良い。 The above-mentioned waterproofing agent is applied to an inkjet recording sheet as a solution using water or a water-miscible organic solvent. The solution concentration of water resistant agent is 0.5-10%,
More preferably, 1 to 5% is appropriate. Suitable water-miscible organic solvents include methanol, ethanol, acetone, dimethylformamide, and the like. An ultraviolet absorber, a fluorescent dye, a water repellent, etc. may be added to the water resistant agent solution.
耐水化剤のインクジエツト記録シートへの付与
方法としては、スプレー、ロールコート、グラビ
アコートなどによる塗布が適している。インクジ
エツト記録に使用されるインクジエツトノズルか
ら耐水化剤をスプレーすることも可能である。こ
の場合は、インクジエツト記録部のみに耐水化剤
を選択的に付与することができる。耐水化剤を付
与後、必要に応じて、熱風、赤外線などにより乾
燥しても良い。 Suitable methods for applying the waterproof agent to the inkjet recording sheet include spraying, roll coating, gravure coating, and the like. It is also possible to spray the waterproofing agent from an inkjet nozzle used for inkjet recording. In this case, the waterproofing agent can be selectively applied only to the inkjet recording area. After applying the waterproofing agent, it may be dried using hot air, infrared rays, etc., if necessary.
耐水化剤の付与量は溶液として５ｇ／m2〜50
ｇ／m2で使用されるが、付与量が多いとインクジ
エツト記録画像がにじむことがあるので、付与量
はなるべく少ない方が良い。にじみを防止するに
は、水混和性有機溶剤の量を多くすることが望ま
しい。 The amount of water resistant agent applied is 5 g/m 2 ~ 50 as a solution.
g/m 2 , but if the applied amount is too large, the inkjet recorded image may smear, so it is better to apply as little as possible. To prevent bleeding, it is desirable to increase the amount of water-miscible organic solvent.
リンタングステンモリブデン酸と塩基性染料の
組合せのように適当な耐水化剤を使用すれば、耐
水性だけでなくインクジエツト記録に耐光性を付
与することもできる。 By using a suitable waterfastening agent such as a combination of phosphotungsten molybdic acid and a basic dye, it is possible to impart not only waterfastness but also lightfastness to the inkjet recording.
本発明に使用されるインクジエツト記録シート
は、サイズ剤を添加しない低密度紙、上質紙、ア
ート紙、コート紙、特開昭52―53012号、特開昭
52―74340号、特開昭53―49113号に記載されてい
るインク吸収性とインクの広がりを調節したイン
クジエツト記録用紙、水溶性高分子塗布紙、染料
吸着性を有する顔料を塗布した紙、布、インク吸
収層を有するプラスチツクスフイルム、木板、金
属板などである。 The inkjet recording sheet used in the present invention includes low-density paper without adding a sizing agent, high-quality paper, art paper, coated paper, JP-A-52-53012, JP-A-Sho.
52-74340 and JP-A-53-49113, inkjet recording paper with controlled ink absorption and ink spread, paper coated with water-soluble polymer, paper coated with pigments having dye adsorption properties, and cloth. , a plastic film with an ink absorbing layer, a wooden board, a metal board, etc.
本発明の利点は、第１に高度の耐水性を有する
インクジエツト記録が容易に得られること、第２
にインクジエツト記録の耐光性が向上すること等
である。 The advantages of the present invention are, firstly, that inkjet recording with a high degree of water resistance can be easily obtained;
Another advantage is that the light resistance of inkjet recording is improved.
以下、実施例について述べる。 Examples will be described below.
実施例 １
木材パルプ100部に、ポリアミド―ポリアミン
―エピクロルヒドリン樹脂0.5部のみを添加して
抄紙した密度0.7ｇ／cm3、坪量100ｇ／m2の紙をイ
ンクジエツト記録紙に使用し、ダイレクトブルー
86、アシツドレツド73、アシツドイエロー26、ダ
イレクトブラツク38をそれぞれ含む４色の水性イ
ンクで多色インクジエツト記録を行つた。インク
ジエツト記録後直ちにインクジエツト記録紙に耐
水化剤として、AlCl3・6H2Oの２％溶液（溶媒
水／エタノール＝50／50）を10ml／m2スプレー塗
布を行つた。塗布後、熱風乾燥を行つた。Example 1 A paper with a density of 0.7 g/cm 3 and a basis weight of 100 g/m 2 made by adding only 0.5 parts of polyamide-polyamine-epichlorohydrin resin to 100 parts of wood pulp was used as an inkjet recording paper, and Direct Blue was used.
Multicolor inkjet recording was performed using four color aqueous inks including 86, Acid Red 73, Acid Yellow 26, and Direct Black 38, respectively. Immediately after inkjet recording, a 2% solution of AlCl 3 6H 2 O (solvent
Water/ethanol = 50/50) was applied by spraying at 10 ml/m 2 . After application, hot air drying was performed.
このようにして耐水化したインクジエツト記録
紙は、10分間水浸して（20℃）も染料の溶出は全
くなく記録画像耐水化処理を施さないインクジエ
ツト記録紙は、染料が殆んど溶出し、記録画像が
消失してしまつた。 Inkjet recording paper that has been made water resistant in this way shows no dye elution even after being immersed in water for 10 minutes (at 20°C).Inkjet recording paper that has not been subjected to water resistance treatment shows that most of the dye is eluted and the recorded image has disappeared.
実施例 ２
坪量100ｇ／m2のサイズ原紙に、炭酸カルシウ
ム100部及びゼラチン30部よりなる塗布液を固型
分で片面10ｇ／m2塗布してインクジエツト記録紙
をつくつた。このインクジエツト記録紙にダイレ
クトブラツク38を含む水性インクを噴射して単色
インクジエツト記録を行つた。インクジエツト記
録時に、画像記録ノズルと別のノズルからアルミ
ナゾール１％溶液（溶媒 水／エタノール＝50／
50）を耐水化剤として全面スプレーした。耐水化
剤のスプレー量は10ml／m2であつた。実施例１と
同じようにインクジエツト記録紙を水浸したとこ
ろ、耐水化処理したインクジエツト記録紙は記録
画像が消失しなかつたが、耐水化処理を施さない
インクジエツト記録紙は、記録画像が消失した。Example 2 An inkjet recording paper was prepared by applying a coating solution consisting of 100 parts of calcium carbonate and 30 parts of gelatin in a solid amount of 10 g/m 2 to one side of a base paper having a basis weight of 100 g/m 2 . Aqueous ink containing Direct Black 38 was jetted onto this inkjet recording paper to perform monochrome inkjet recording. During inkjet recording, a 1% aluminazole solution (solvent water/ethanol = 50/
50) was sprayed on the entire surface as a waterproofing agent. The amount of water resistant agent sprayed was 10 ml/m 2 . When the inkjet recording paper was immersed in water in the same manner as in Example 1, the recorded image did not disappear on the inkjet recording paper that had been treated to make it waterproof, but the recorded image disappeared on the inkjet recording paper that had not been treated to make it waterproof.
実施例 ３
坪量100ｇ／m2のサイズ原紙に、ゼラチンを固
型分で片面５ｇ／m2塗布してインクジエツト記録
紙とした。このインクジエツト記録紙に、実施例
１と同様にインクジエツト記録及び耐水化処理を
行つた。実施例と同じようにインクジエツト記録
紙を水浸しても記録画像は消失しなかつた。Example 3 Inkjet recording paper was prepared by applying gelatin in a solid amount of 5 g/m 2 on one side to a base paper having a basis weight of 100 g/m 2 . This inkjet recording paper was subjected to inkjet recording and water resistance treatment in the same manner as in Example 1. Even when the inkjet recording paper was immersed in water in the same manner as in the example, the recorded image did not disappear.
実施例 ４
実施例３のインクジエツト記録用紙に、ベーシ
ツクブルー５、ベーシツクバイオレツト14、ベー
シツクイエロー２をそれぞれ含む３色の水性イン
クで多色インクジエツト記録を行つた。インクジ
エツト記録後、インクジエツト記録紙に耐水化剤
としてリンタングステンモリブデン酸２％水溶液
を10ml／m2スプレー塗布した。塗布後、熱風乾燥
を行つた。この耐水化処理したインクジエツト記
録紙を実施例１と同じ様に水浸しても、記録画像
は消失せず、染料の耐光性も耐水化処理をしない
ものにくらべて向上した。Example 4 Multicolor inkjet recording was performed on the inkjet recording paper of Example 3 using three color aqueous inks containing Basic Blue 5, Basic Violet 14, and Basic Yellow 2, respectively. After inkjet recording, a 2% aqueous solution of phosphotungsten molybdic acid was sprayed onto the inkjet recording paper at 10 ml/m 2 as a waterproofing agent. After application, hot air drying was performed. When this water-resistant inkjet recording paper was immersed in water in the same manner as in Example 1, the recorded image did not disappear, and the light resistance of the dye was improved compared to the paper that was not water-resistant.
Claims (1)
着色した水性インクによりインクジエツト記録
後、該水性インク中の染料とレーキを形成する耐
水化剤を付与することを特徴とするインクジエツ
ト記録の耐水化法。1. A method for making inkjet recording waterproof, which comprises applying a waterproofing agent that forms a lake with the dye in the aqueous ink after inkjet recording on an inkjet recording sheet using a colored aqueous ink containing a dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5879079A JPS55150396A (en) | 1979-05-14 | 1979-05-14 | Method for attaining waterproof property to ink jet recorded sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5879079A JPS55150396A (en) | 1979-05-14 | 1979-05-14 | Method for attaining waterproof property to ink jet recorded sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55150396A JPS55150396A (en) | 1980-11-22 |
| JPS6238155B2 true JPS6238155B2 (en) | 1987-08-17 |
Family
ID=13094360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5879079A Granted JPS55150396A (en) | 1979-05-14 | 1979-05-14 | Method for attaining waterproof property to ink jet recorded sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55150396A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0215123U (en) * | 1988-07-15 | 1990-01-30 |
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| US6719420B2 (en) | 2001-05-10 | 2004-04-13 | Canon Kabushiki Kaisha | Liquid composition, ink set, method for forming colored portion on recording medium, and ink-jet recording apparatus |
| US6863391B2 (en) | 2001-05-10 | 2005-03-08 | Canon Kabushiki Kaisha | Liquid composition, ink set, method of forming a colored section on recording medium and ink-jet recording apparatus |
| US6821328B2 (en) | 2001-05-10 | 2004-11-23 | Canon Kabushiki Kaisha | Liquid composition, ink set, method of forming colored portion in recording medium and ink-jet recording apparatus |
| US6746114B2 (en) | 2001-05-10 | 2004-06-08 | Canon Kabushiki Kaisha | Ink set, process for forming colored portion and ink-jet recording apparatus |
| JP4458776B2 (en) | 2002-07-03 | 2010-04-28 | キヤノン株式会社 | Inkjet recording apparatus, image processing method, and control program |
| FR2842540B1 (en) * | 2002-07-18 | 2004-10-01 | Eastman Kodak Co | MATERIAL FOR INKJET PRINTING IMAGE FORMATION |
| JP4377136B2 (en) | 2003-02-05 | 2009-12-02 | 富士フイルム株式会社 | Ink for inkjet recording |
| EP2227509B1 (en) | 2007-12-28 | 2016-09-28 | Canon Kabushiki Kaisha | Surface-modified inorganic pigment, colored surface-modified inorganic pigment, recording medium and production processes thereof, and image forming method and recorded image |
| WO2016117330A1 (en) * | 2015-01-23 | 2016-07-28 | Canon Kabushiki Kaisha | Image forming method and ink set |
-
1979
- 1979-05-14 JP JP5879079A patent/JPS55150396A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0215123U (en) * | 1988-07-15 | 1990-01-30 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55150396A (en) | 1980-11-22 |
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