JPS6240425B2 - - Google Patents
Info
- Publication number
- JPS6240425B2 JPS6240425B2 JP54039971A JP3997179A JPS6240425B2 JP S6240425 B2 JPS6240425 B2 JP S6240425B2 JP 54039971 A JP54039971 A JP 54039971A JP 3997179 A JP3997179 A JP 3997179A JP S6240425 B2 JPS6240425 B2 JP S6240425B2
- Authority
- JP
- Japan
- Prior art keywords
- cylindrical body
- ring
- sprayed
- rings
- piston
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
Description
【発明の詳細な説明】
本発明は内燃機関用ピストンリングの製法に係
り、更に詳しくは耐摩耗性、耐焼付性が要求され
るシリンダあるいはシリンダライナとのピストン
リングの摺動面に溶射処理を施こす方法に関する
ものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing a piston ring for an internal combustion engine, and more specifically, the present invention relates to a method for manufacturing a piston ring for an internal combustion engine. It relates to the method of application.
近年、内燃機関において、性能を向上させる目
的で行なわれる高速回転化、高圧縮化や排気ガス
対策による熱負荷の増大等は、ピストン、ピスト
ンリング、シリンダライナの各摺動部にかかる負
担を増加し、これらに対する要求を益々苛酷なも
のにしている。特にデイーゼル内燃機関において
は、カーボンスーツの発生もあつて、ピストンリ
ングはデイーゼル内燃機関の高速回転化にともな
い耐焼付性、耐摩耗性、耐スカツフイング性が
益々要求されてきている。 In recent years, internal combustion engines have been driven to higher speeds and higher compression rates to improve performance, as well as increased heat loads due to exhaust gas countermeasures, which have increased the burden on the sliding parts of the piston, piston rings, and cylinder liners. However, the demands on these things are becoming increasingly strict. Particularly in diesel internal combustion engines, piston rings are increasingly required to have seizure resistance, abrasion resistance, and scuffing resistance as diesel internal combustion engines increase in speed due to the occurrence of carbon suits.
従来、これらの機械的特性が改良されたピスト
ンリングとして、シリンダライナに接続する外周
面にクロム(Cr)メツキ又はモリブデン溶射を
施こしたものが知られている。このうち、クロム
メツキを施こしたピストンリングは、耐摩耗性は
良好であるが、相手側のシリンダライナ鋳鉄材と
の耐焼付性がよくないため、焼付、スカツフイン
グを発生し易いという欠点を有している。これら
の理由から、モリブデン溶射やカーバイト、セラ
ミツクの溶射が採用されたり、検討されたりして
いるが、製造にあたり溶射工程で種々の制約があ
ることから、多くの工程を必要とし、コスト高の
一因ともなつている。すなわち、ピストンリング
は、1個づつ溶射するには小さすぎるため、第1
図に示すように多数のピストンリング1,1,
1,…を重ね合せて筒状体11とし、この筒状体
の外周に溶射したのち、個々のリングに分けると
いう方法が経済的でもあることから従来より行な
われているが、単に筒状体11の外周に溶射した
のでは、溶射層によつて一体化され個々のリング
に分割できないという問題があつた。そのため従
来は、第2図に示すようにリングの外周中央部に
リング溝2を形成し、このリング溝2内に溶射層
3を形成しているのが実情である。 Conventionally, as piston rings with improved mechanical properties, there have been known piston rings whose outer circumferential surface connected to the cylinder liner is plated with chromium (Cr) or sprayed with molybdenum. Among these, chrome-plated piston rings have good wear resistance, but they do not have good seizure resistance with the mating cylinder liner cast iron material, so they have the disadvantage of being prone to seizure and scuffing. ing. For these reasons, molybdenum thermal spraying, carbide, and ceramic thermal spraying have been adopted or are being considered, but because there are various restrictions in the thermal spraying process during manufacturing, they require many steps and are expensive. It is also a contributing factor. In other words, the piston rings are too small to be thermally sprayed one by one, so the first
As shown in the figure, a large number of piston rings 1, 1,
1,... to form a cylindrical body 11, thermal spraying is applied to the outer periphery of this cylindrical body, and then separation into individual rings is conventionally carried out because it is economical. 11, there was a problem that the rings were integrated by the sprayed layer and could not be divided into individual rings. Therefore, conventionally, as shown in FIG. 2, a ring groove 2 is formed at the center of the outer periphery of the ring, and a thermal spray layer 3 is formed within this ring groove 2.
この従来法は、第1図に示すようにピストンリ
ング1,1…を重ね合せて筒状体11とした後、
両端の保持具4.4を軸として筒状体11を回転
させて、第3図Aに示すようにリング1の1本、
1本に所定のリング溝2を切削加工し、シヨツト
ブラストしたのち、予熱し溶射する(第3図
B)。このように溶射した面をリング表面の一部
が削り取られるまで(第3図BのX−X線まで)
研削加工して筒状体を個々に切離し、溶射リング
を得ている。 In this conventional method, as shown in FIG. 1, piston rings 1, 1... are stacked to form a cylindrical body 11,
By rotating the cylindrical body 11 about the holders 4.4 at both ends, one of the rings 1, as shown in FIG. 3A,
A predetermined ring groove 2 is cut into one ring, shot blasted, and then preheated and thermally sprayed (Fig. 3B). Continue spraying the sprayed surface until part of the ring surface is scraped off (up to line X-X in Figure 3 B).
The cylindrical bodies are individually separated by grinding to obtain thermal spray rings.
しかして、上記従来法によるときは、クロムメ
ツキ法に比べて、工程上では溝加工や溶射層の研
削加工などの加工数が増大し、また製品としては
摺動面の減少というマイナス面があり、又コスト
面でもクロムメツキ法に比べ割高になるため、我
が国では特殊な車を除いては、性能、耐久性の点
で有利であるにもかかわらず溶射リングが使用さ
れていないのが実状である。 However, when using the above conventional method, compared to the chrome plating method, there is a disadvantage that the number of processes such as groove processing and thermal spray layer grinding increases, and the sliding surface of the product decreases. In addition, since it is more expensive than the chrome plating method, thermal sprayed rings are not used in Japan except for special vehicles, despite their advantages in terms of performance and durability.
本発明は、溶射リングの製造工程においてリン
グの溝加工をすることなく、量産的にしかも低コ
ストで溶射ピストンリングが製造できる新らしい
製法を提供することを目的としている。 An object of the present invention is to provide a new manufacturing method that allows thermal spray piston rings to be manufactured in mass production at low cost without grooving rings in the process of manufacturing thermal spray rings.
本発明方法は、鋳鉄、鋼母材よりなるリングの
外周面に、必要ならばその両端に0.1〜0.3cの面
取りを行ない、さらに面取り部を含めて外周面に
弗素樹脂(テフロン)、四三酸化鉄などの溶射粒
子が付着しにくい表面処理を施した後、溶射すべ
き部分の表面処理層を除去し、溶射することを特
徴とする。 The method of the present invention involves chamfering the outer circumferential surface of a ring made of cast iron or steel base material, if necessary, by 0.1 to 0.3 cm at both ends, and then applying fluororesin (Teflon) to the outer circumferential surface, including the chamfered portions. The method is characterized in that after applying a surface treatment such as iron oxide to make it difficult for thermal spray particles to adhere, the surface treatment layer of the area to be thermally sprayed is removed and thermal spraying is carried out.
本発明において、面取り加工したときは、筒状
体の全外周に表面処理を施し、次に軽度の研削加
工を施すことによつて、面取り部にのみテフロ
ン、四三酸化鉄などの表面処理層が残るため、溶
射時の溶射粒子はこの面取り部には付着せず、ラ
イナとの摺動面にのみ付着するので溶射後の研削
加工による取代は基本的には、溶射による表面粗
さのみを加工するだけでよく、クロムメツキ並の
コストでしかも耐スカツフイング性、耐焼付性の
優れた溶射リングを得ることができる。 In the present invention, when chamfering is performed, the entire outer periphery of the cylindrical body is subjected to surface treatment, and then a light grinding process is applied to form a surface treatment layer of Teflon, triiron tetroxide, etc. only on the chamfered part. remains, so the spray particles during thermal spraying do not adhere to this chamfer, but only to the sliding surface with the liner, so the removal by grinding after thermal spraying basically only removes the surface roughness caused by thermal spraying. All that is required is processing, and a thermal sprayed ring with excellent scuffing and seizure resistance can be obtained at a cost comparable to that of chrome plating.
なお、四三酸化鉄皮膜を形成するような場合に
は、面取り加工をせず従来の溝に相当する部分の
四三酸化鉄皮膜を除去するだけでよい。 In addition, in the case where a triiron tetroxide film is to be formed, it is sufficient to simply remove the triiron tetroxide film in the portion corresponding to the conventional groove without chamfering.
次に本発明の一例を第4図A〜Eにしたがつて
説明する。 Next, an example of the present invention will be explained with reference to FIGS. 4A to 4E.
まず、第4図Aに示すように外周面両端に面取
り5を行なつたピストンリング1を重ね合せて筒
状体(マンドレル)11にした後、テフロン又は
四三酸化鉄などの溶射粒子の付着し難い表面処理
層6を形成し(第4図B)、次に外周面のみを研
削加工して溶射すべきリング表面を露出させると
ともに所定の寸法に仕上げた後(第4図C)、予
熱し、溶射を行なう(第4図D)。その後溶射面
を仕上げ研削して目的とするリングを得る。 First, as shown in FIG. 4A, piston rings 1 with chamfers 5 on both ends of their outer peripheral surfaces are stacked to form a cylindrical body (mandrel) 11, and then thermal spray particles such as Teflon or triiron tetroxide are attached. After forming a surface treatment layer 6 that is difficult to spray (Fig. 4B), and then grinding only the outer peripheral surface to expose the ring surface to be thermally sprayed and finishing it to the predetermined dimensions (Fig. 4C), preheating is performed. Then, thermal spraying is performed (Fig. 4D). After that, the sprayed surface is finish ground to obtain the desired ring.
溶射は、外周面の溶射皮膜が母材の材料と密着
性が劣る場合は、下地溶射として密着性、耐熱性
の優れた金属材料の溶射を施し、しかる後耐摩耗
性、耐焼付性、耐スカツフイング性の優れた溶射
皮膜を外周面に形成させるとよい。 In thermal spraying, if the thermal spray coating on the outer peripheral surface has poor adhesion to the base material, a metal material with excellent adhesion and heat resistance is applied as a base thermal spray, and then the coating is coated with abrasion resistance, seizure resistance, and resistance. It is preferable to form a thermal spray coating with excellent scuffing properties on the outer peripheral surface.
又、テフロン等のコーデイング処理は、工程に
よつては筒状体とする前でも後でもよい。 Furthermore, the coating treatment with Teflon or the like may be performed before or after forming the cylindrical body, depending on the process.
溶射皮膜の厚さを0.2mm以上とした製品リング
を得る場合には、従来法ではリング溝は加工取代
を見込んで0.25〜0.3mmにする必要があり、その
溶射厚さは0.25以上必要となる。このとき溶射皮
膜は第3図Bに示した様にリング溝以外にも付着
するため、溶射後の研削加工取代は溶射層の厚さ
0.25〜0.3mmとリングの加工取代0.05〜0.1mmを合
せた0.3〜0.4mmとなり、研削加工に手間がかか
る。一方、本発明によれば0.25〜0.3mmの溶射
で、その加工取代は0.05〜0.10mmですむことにな
り、従来の加工取代の1/4以下となり研削加工を
大巾に節減できる。 When obtaining a product ring with a thermal spray coating thickness of 0.2 mm or more, in the conventional method, the ring groove needs to be 0.25 to 0.3 mm, taking into account machining allowance, and the thermal spray thickness needs to be 0.25 mm or more. . At this time, the sprayed coating adheres to areas other than the ring groove as shown in Figure 3B, so the grinding allowance after spraying is equal to the thickness of the sprayed layer.
The total machining allowance for the ring is 0.3-0.4mm, which is 0.25-0.3mm and the machining allowance of 0.05-0.1mm for the ring, and the grinding process is time-consuming. On the other hand, according to the present invention, by thermal spraying of 0.25 to 0.3 mm, the machining allowance is only 0.05 to 0.10 mm, which is less than 1/4 of the conventional machining allowance, and the grinding process can be greatly reduced.
以下本発明を実施例によつて更に詳細に説明す
る。 The present invention will be explained in more detail below with reference to Examples.
実施例 1
第4図Aに示すように外周面端部に面取り5を
した断面形状を持つ球状黒鉛鋳鉄製のピストンリ
ング母材1を複数個準備し、これらを重ね合せて
筒状体11にし、その筒状体11を軸線のまわり
に回転させながらテフロンコーテイングし、コー
テイング後、リング外周面を研削加工して溶射皮
膜厚さを見込んだ所定の寸法に加工し、リング外
周端面5にのみテフロンコートの表面処理層6が
残された筒状体を得る。次にこの筒状体を回転さ
せながら予熱し、NiAlの下地溶射を厚さ20〜60
μ施し、さらに63.3Cr−6.6C−1.9Si−0.02P−
0.04S−残部Feからなる合金粉末をプラズマ溶射
によつて研削加工取代を見込んだ所定の厚さまで
コーデイングし、外周面を円筒研削盤によつて研
削加工し、製品寸法に仕上げてピストンリングを
完成した。Example 1 As shown in FIG. 4A, a plurality of piston ring base materials 1 made of spheroidal graphite cast iron having a cross-sectional shape with a chamfer 5 on the outer circumferential end are prepared, and these are stacked to form a cylindrical body 11. The cylindrical body 11 is coated with Teflon while rotating around its axis, and after coating, the outer circumferential surface of the ring is ground to a predetermined size that takes into account the thickness of the sprayed coating, and only the outer circumferential end surface 5 of the ring is coated with Teflon. A cylindrical body in which the surface treatment layer 6 of the coat remains is obtained. Next, this cylindrical body is preheated while rotating, and a NiAl base is thermally sprayed to a thickness of 20 to 60 mm.
μ applied and further 63.3Cr−6.6C−1.9Si−0.02P−
The alloy powder consisting of 0.04S with the remainder being Fe is coated by plasma spraying to a predetermined thickness that allows for grinding machining allowance, and the outer circumferential surface is ground using a cylindrical grinder to finish the piston ring to product dimensions. completed.
このピストンリングの製品寸法および溶射条件
は下記の通りである。 The product dimensions and thermal spraying conditions for this piston ring are as follows.
ピストンリングの呼び径90mm、厚さ3mm、巾
2.5mm、外周面取り0.2c、溶射皮膜厚さ0.20〜0.25
mmプラズマ溶射は米国METCO社“3MB”に同社
のGHノズルおよび2番パウダポートを取付け下
記の条件で行つた。 Piston ring nominal diameter 90mm, thickness 3mm, width
2.5mm, outer circumferential chamfering 0.2c , thermal spray coating thickness 0.20~0.25
mm plasma spraying was carried out using METCO's ``3MB'' in the United States with the company's GH nozzle and No. 2 powder port installed under the following conditions.
Arガス流量 80SCFH
H2ガス流量 15SCFH
アーク電流 450〜500Amp
ピストンリング筒状体の回転数 200〜500rpm
溶射ガン送り速度 0.8〜2.0m/分
粉末供給量 40g/分
参考例
実施例1と同様にしてピストンリングの筒状体
を作り、これにテフロンコーテイングしない状態
で、NiAlの下地溶射、続いて実施例1で用いた
Cr−Fe系合金粉末を溶射し、同様を研削加工し
たが、リング外周の両端面取り部に溶射皮膜が付
着し、リングを1本づつに切り離すことができな
かつた。Ar gas flow rate 80SCFH H 2 gas flow rate 15SCFH Arc current 450~500Amp Piston ring cylinder rotation speed 200~500rpm Thermal spray gun feed rate 0.8~2.0m/min Powder supply rate 40g/min Reference example Same as Example 1 A cylindrical body of a piston ring was made, and without Teflon coating, a base coat of NiAl was sprayed and then used in Example 1.
Although Cr-Fe alloy powder was sprayed and the same was ground, the sprayed coating adhered to the chamfered portions of both ends of the outer periphery of the ring, making it impossible to separate the rings one by one.
実施例 2
実施例1のテフロンコーテイングの代りにピス
トンリングの表面に四三酸化鉄を生成させる水蒸
気処理を施したのち、以下実施例1と同様に
NiAlの下地溶射に続いてCr−Fe系合金の溶射を
施し、研削加工して所定のピストンリングを得
た。Example 2 In place of the Teflon coating in Example 1, the surface of the piston ring was subjected to steam treatment to generate triiron tetroxide, and then the same procedure as in Example 1 was carried out.
Following the NiAl base spraying, a Cr-Fe alloy was sprayed and ground to obtain the desired piston ring.
第1図はピストンリング筒状体の側面図、第2
図は従来法によるピストンリングの一部欠損斜視
図、第3図A,Bは従来法を説明するための筒状
体の要部aの断面図、第4図A〜Eは本発明方法
を説明するための筒状体の要部aの断面図を表わ
す。
図中、1……ピストンリング母材、11……ピ
ストンリング筒状体、2……溝、3……溶射層、
5……面取り、6……表面処理層。
Figure 1 is a side view of the piston ring cylindrical body, Figure 2 is a side view of the piston ring cylindrical body;
The figure is a partially cutaway perspective view of a piston ring according to the conventional method, FIGS. 3A and 3B are cross-sectional views of the main part a of the cylindrical body for explaining the conventional method, and FIGS. A sectional view of a main part a of a cylindrical body is shown for purposes of explanation. In the figure, 1... Piston ring base material, 11... Piston ring cylindrical body, 2... Groove, 3... Thermal spray layer,
5... Chamfering, 6... Surface treatment layer.
Claims (1)
該筒状体の全外周面に溶射粒子が付着しにくい表
面処理を施したのち、該筒状体の溶射すべき部分
の表面処理層を機械加工等により除去して、金属
またはセラミツクを溶射することを特徴とする溶
射ピストンリングの製造方法。1 A large number of piston rings are stacked to form a cylindrical body,
After applying a surface treatment to the entire outer peripheral surface of the cylindrical body to prevent thermal spray particles from adhering to it, the surface treatment layer on the part of the cylindrical body to be thermally sprayed is removed by machining, etc., and metal or ceramic is thermally sprayed. A method for manufacturing a thermal sprayed piston ring, characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3997179A JPS55134167A (en) | 1979-04-03 | 1979-04-03 | Manufacture of piston ring by spray process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3997179A JPS55134167A (en) | 1979-04-03 | 1979-04-03 | Manufacture of piston ring by spray process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55134167A JPS55134167A (en) | 1980-10-18 |
| JPS6240425B2 true JPS6240425B2 (en) | 1987-08-28 |
Family
ID=12567833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3997179A Granted JPS55134167A (en) | 1979-04-03 | 1979-04-03 | Manufacture of piston ring by spray process |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55134167A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100655366B1 (en) * | 2005-07-04 | 2006-12-08 | 한국과학기술연구원 | Coating agent with heat resistance, abrasion resistance, low friction and coating method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5322130A (en) * | 1976-08-12 | 1978-03-01 | Sumitomo Chemical Co | Masking method for plasma metallization |
-
1979
- 1979-04-03 JP JP3997179A patent/JPS55134167A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55134167A (en) | 1980-10-18 |
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