JPS6241320B2 - - Google Patents
Info
- Publication number
- JPS6241320B2 JPS6241320B2 JP9056280A JP9056280A JPS6241320B2 JP S6241320 B2 JPS6241320 B2 JP S6241320B2 JP 9056280 A JP9056280 A JP 9056280A JP 9056280 A JP9056280 A JP 9056280A JP S6241320 B2 JPS6241320 B2 JP S6241320B2
- Authority
- JP
- Japan
- Prior art keywords
- plating
- wafer
- space chamber
- anode
- sealed space
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007747 plating Methods 0.000 claims description 55
- 238000005192 partition Methods 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims 2
- 235000012431 wafers Nutrition 0.000 description 18
- 239000000126 substance Substances 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 230000002159 abnormal effect Effects 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229910000679 solder Inorganic materials 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 239000005751 Copper oxide Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910000431 copper oxide Inorganic materials 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 229920002120 photoresistant polymer Polymers 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 239000005373 porous glass Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Landscapes
- Electroplating Methods And Accessories (AREA)
- Electrodes Of Semiconductors (AREA)
Description
【発明の詳細な説明】
本発明は、めつき装置に係り、特に、ウエハ
に、めつきをするめつき装置に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a plating apparatus, and particularly to a plating apparatus for plating wafers.
半導体素子のはんだ電極、銅電極等の突起電極
は、一般に第1図aないしdに示される方法によ
つて形成される。すなわち第1図aに示すごと
く、ベース3には、アルミ配線1及び窒化シリコ
ン等の保護膜2が形成され、これ等を銅などから
なる電極下地膜4が蒸着被包している。次に、第
1図bに示すごとく、ホトレジスト5を前記電極
下地膜4上に塗布し、露光、現像により所定の突
起電極パターンを形成する。ついで、第1図cに
示すごとくめつき装置によつて、はんだ、銅など
を所定の厚さにめつきし、突起電極6を形成す
る。最後に、第1図dに示すごとく、ホトレジス
ト5を除去し、更に、突起電極6の下側以外の不
要の電極下地膜4をエツチングによつて除去す
る。以上の説明におけるめつきを従来一般に用い
られている直方体状の浸漬式めつき装置によつて
行なう場合には、電気めつき特有のエツジ効果に
より、ウエハの外周部附近に電流が集中し、この
部分が他の部分に比較しめつき層が厚くなり、上
記の突起電極高さが高くなる傾向を生ずる。第2
図において、横軸はウエハ中心Cからの距離
(m/m)を示し、縦軸は、めつき厚さ(μm)
を示している。すなわち、従来の浸漬式めつき装
置の場合には、第2図中のaに示すごとく、ウエ
ハ中心Cより遠ざかるに従つてめつき厚が増大
し、平均めつき厚さ80μmの場合、ウエハ中心C
部とウエハ端Eとでは、約32μmのめつき厚みの
差が生じている。このように、一枚のウエハの中
で、めつき厚にばらつきがあると、ウエハを個々
のチツプに分割したとき、チツプごとに、またチ
ツプ内の電極間において、突起電極の高さが異な
ることになる。電極高さの異なるチツプを基板に
接合すると、チツプごとの接合強度が異なり、さ
らにチツプ内の電極高さが異なると、高い電極の
接合強度は大きいが、低い電極の接合強度は、小
さくなり、極端な場合は接合しなくなる。このよ
うに、電極高さが異なることは、接合強度及び接
合信頼性上きわめて好ましくない結果を生ずる。 Protruding electrodes such as solder electrodes and copper electrodes of semiconductor devices are generally formed by the method shown in FIGS. 1a to 1d. That is, as shown in FIG. 1A, an aluminum wiring 1 and a protective film 2 made of silicon nitride or the like are formed on the base 3, and these are covered by an electrode base film 4 made of copper or the like by vapor deposition. Next, as shown in FIG. 1B, a photoresist 5 is applied onto the electrode base film 4, and a predetermined protruding electrode pattern is formed by exposure and development. Next, using a plating device as shown in FIG. 1c, solder, copper, or the like is plated to a predetermined thickness to form the protruding electrodes 6. Finally, as shown in FIG. 1d, the photoresist 5 is removed, and the unnecessary electrode base film 4 other than the area below the protruding electrode 6 is removed by etching. When the plating described above is carried out using a rectangular parallelepiped type immersion plating apparatus that has been commonly used in the past, the electric current is concentrated near the outer periphery of the wafer due to the edge effect peculiar to electroplating. The tightening layer is thicker in some parts than in other parts, resulting in a tendency for the height of the protruding electrode to become higher. Second
In the figure, the horizontal axis shows the distance (m/m) from the wafer center C, and the vertical axis shows the plating thickness (μm).
It shows. That is, in the case of the conventional immersion plating apparatus, as shown in a in FIG. 2, the plating thickness increases as the distance from the wafer center C increases, and when the average plating thickness is 80 μm, C
There is a difference in plating thickness of about 32 μm between the wafer edge E and the wafer edge E. In this way, if the plating thickness varies within a single wafer, when the wafer is divided into individual chips, the height of the protruding electrodes will vary from chip to chip and between electrodes within a chip. It turns out. When chips with different electrode heights are bonded to a substrate, the bonding strength will differ for each chip, and if the electrode heights within the chip differ, the bonding strength of the high electrode will be high, but the bonding strength of the low electrode will be small. In extreme cases, they will not bond. The difference in electrode height as described above gives rise to extremely unfavorable results in terms of bonding strength and bonding reliability.
本発明は、上記の欠点を解消するために提案さ
れたもので、その目的としては、品質がよく、異
常突起がなく、かつ均一のめつき厚みの得られる
ウエハ用のめつき装置を提供することにある。 The present invention was proposed in order to eliminate the above-mentioned drawbacks, and its purpose is to provide a plating device for wafers that is of good quality, has no abnormal protrusions, and can provide a uniform plating thickness. There is a particular thing.
本発明は、上記の目的を達成するために、円筒
形状の密閉空間内に対峙して配置するウエハ及び
陽極を、多孔質の隔壁で区切り、この隔壁を介在
させた状態でめつきをするような構成をもつめつ
き装置を特徴とするものである。 In order to achieve the above object, the present invention has a method in which a wafer and an anode, which are arranged facing each other in a cylindrical sealed space, are separated by a porous partition wall, and plating is performed with the partition wall interposed. This device is characterized by a pinning device having a configuration.
以下、本発明の実施例を図に基づいて説明す
る。第3図及び第4図において、めつき槽本体7
は、アクリル製であり、7a及び7bに2分割さ
れている。めつき槽本体7の中央部には、3イン
チウエハ用の場合には、直径約76.2m/mの円筒
状孔からなる絶縁壁8が形成されている。めつき
槽本体7a及び7bは、ポリプロピレンの布から
なる多孔質状の隔壁14をはさんで重合されてい
る。めつき槽本体7a及び7bの開放端部は、ウ
エハ9を取付けたウエハ取付板10及び陽極11
を取付けた陽極取付板12によつて密閉され、密
閉空間室13を形成している。前記多孔質状の隔
壁14よつて区切られた密閉空間式13のそれぞ
れ室13a及び13bには、めつき槽本体7a及
び7bに形成される通路を介し、めつき液給入パ
イプ15a,15b及び排出パイプ16a,16
bが連通されている。 Embodiments of the present invention will be described below based on the drawings. In FIGS. 3 and 4, the plating tank body 7
is made of acrylic and is divided into two parts 7a and 7b. In the center of the plating tank body 7, in the case of a 3-inch wafer, an insulating wall 8 consisting of a cylindrical hole with a diameter of about 76.2 m/m is formed. The plating tank bodies 7a and 7b are polymerized with porous partition walls 14 made of polypropylene cloth in between. The open ends of the plating tank bodies 7a and 7b are connected to a wafer mounting plate 10 on which the wafer 9 is attached and an anode 11.
It is sealed by the anode mounting plate 12 to which the anode mounting plate 12 is attached, forming a sealed space chamber 13. Plating liquid supply pipes 15a, 15b and Discharge pipes 16a, 16
b is connected.
以上の構成に基づく本めつき装置の作用を次に
説明する。ウエハ9と、陽極11とは、平行に対
峙して配置され、かつ、ウエハ及び陽極とほぼ同
一直径を有する円筒状孔からなる絶縁壁8で囲ま
れているため電流は、陽極11からウエハ9に向
つて均一に、かつ直線的に流れることになる。従
つて、均一のめつき厚みを形成することが可能と
なる。一方、上記の円筒形状のめつき槽におい
て、はんだ、銅等のめつきを行なう場合には、陽
極で形成される酸化鉛、酸化銅などの不溶性の物
質が、陰極側に運ばれ、めつき膜内に共折し、め
つき膜の機械的特性などの品質を低下し、また、
異常突起を発生させる原因ともなる。そこで、前
記の多孔質状の隔壁14を介在させると、これ等
の不溶性物質が陽極側から陰極側へ流れることを
防止することができる。隔壁14は、前記のごと
く、めつき液に含有するイオンを通過させること
が可能な孔が形成されているため、上記不溶物質
の通過を防止できるが、めつき効果をそこなわし
めることはない。一方めつき液は、前記のごと
く、密閉空間室13のそれぞれの室13a及び1
3bにそれぞれ別々に給入されるため、密閉空間
室13内のめつき液の流れを円滑とし、良好なめ
つき膜の形成に役立つことになる。 The operation of the final plating device based on the above configuration will be explained next. The wafer 9 and the anode 11 are arranged parallel to each other and are surrounded by an insulating wall 8 consisting of a cylindrical hole having approximately the same diameter as the wafer and the anode, so that the current flows from the anode 11 to the wafer 9. It will flow uniformly and in a straight line towards. Therefore, it becomes possible to form a uniform plating thickness. On the other hand, when plating solder, copper, etc. in the above-mentioned cylindrical plating tank, insoluble substances such as lead oxide and copper oxide formed at the anode are carried to the cathode side, and the plating Co-fraction occurs within the film, reducing the mechanical properties and other qualities of the plated film, and
It can also cause abnormal protrusions. Therefore, by interposing the porous partition wall 14, it is possible to prevent these insoluble substances from flowing from the anode side to the cathode side. As described above, the partition wall 14 is formed with holes through which ions contained in the plating solution can pass, and therefore can prevent the insoluble substances from passing through, but does not impair the plating effect. . On the other hand, the plating liquid is supplied to each chamber 13a and 1 of the closed space chamber 13 as described above.
3b, the plating liquid flows smoothly in the closed space chamber 13, which helps in forming a good plating film.
次に、本実施例に基づくめつき装置よるめつき
膜形成の具体的例を記載する。めつき液として、
硫酸銅200g/、硫酸50g/からなる硫酸銅
めつき液を用いる。電流密度2A/dm2、液温30
℃、めつき液流速約2cm/secの条件でめつきを
実施した。この結果が前記第2図のbに示されて
いる。すなわち、ほぼ均一の80μmのめつき厚み
が得られ、陽極で発生する酸化銅の共折、それに
よる異常突起の発生は全くなく、きわめて良好な
めつき膜を得ることができた。なほ、めつき槽か
ら排出されためつき液は、外部に設置する5μm
のポリプロピレン製フイルター(図示しない)に
より連続的に過を行なつた。 Next, a specific example of forming a plating film using the plating apparatus based on this embodiment will be described. As a plating liquid,
A copper sulfate plating solution consisting of 200 g of copper sulfate and 50 g of sulfuric acid is used. Current density 2A/dm 2 , liquid temperature 30
Plating was carried out at a temperature of 0.degree. C. and a plating solution flow rate of about 2 cm/sec. The results are shown in FIG. 2b above. That is, a substantially uniform plating thickness of 80 μm was obtained, and there was no co-refraction of copper oxide generated at the anode and no abnormal protrusions caused thereby, making it possible to obtain an extremely good plating film. Naho, the plating liquid discharged from the plating tank is placed outside with a 5μm
Filtration was carried out continuously through a polypropylene filter (not shown).
以上の実施例における多孔質状の隔壁は、ポリ
プロピレンの布から構成されているが、これに限
るものではなく、多孔質のガラスフイルター、耐
薬品性の優れた布、イオン交換膜等であつても構
わない。また、めつき槽の大きさは、3インチウ
エハの寸法に限定しないことは勿論である。 The porous partition walls in the above embodiments are made of polypropylene cloth, but are not limited to this, and may be made of porous glass filters, cloth with excellent chemical resistance, ion exchange membranes, etc. I don't mind. Furthermore, it goes without saying that the size of the plating tank is not limited to the size of a 3-inch wafer.
以上の説明によつても明らかのごとく、本発明
により、均一のめつき膜の形成が可能となると共
に、不溶性物質の共折がなく、異常突起の生じな
い良質のめつき膜を形成することができ、かつめ
つき歩留の向上効果も上げることができた。 As is clear from the above explanation, the present invention makes it possible to form a uniform plated film, and also to form a high-quality plated film that is free from co-refraction of insoluble substances and free from abnormal protrusions. It was also possible to improve the plating yield.
第1図は、半導体素子の突起電極の形成工程を
示す断面図、第2図は従来法及び本発明の実施例
によるウエハのめつき厚さ分布を示す線図、第3
図は、本発明の実施例のめつき装置の構成を示す
断面図第4図は、その正面図である。
1……アルミ配線、2……保護膜、3……ベー
ス、4……電極下地膜、6……突起電極、7,7
a,7b……めつき槽本体、8……円筒形状絶縁
壁、9……ウエハ、10……ウエハ取付板、11
……陽極、12……陽極取付板、13,13a,
13b……密閉空間室、14……隔壁、15,1
5a,15b……めつき液給入用パイプ、16,
16a,16b……めつき液排出用パイプ。
FIG. 1 is a cross-sectional view showing the process of forming protruding electrodes of semiconductor elements, FIG. 2 is a diagram showing the plating thickness distribution of wafers according to the conventional method and the embodiment of the present invention, and FIG.
FIG. 4 is a sectional view showing the structure of a plating apparatus according to an embodiment of the present invention. FIG. 4 is a front view thereof. 1... Aluminum wiring, 2... Protective film, 3... Base, 4... Electrode base film, 6... Protruding electrode, 7, 7
a, 7b... plating tank body, 8... cylindrical insulating wall, 9... wafer, 10... wafer mounting plate, 11
... Anode, 12 ... Anode mounting plate, 13, 13a,
13b... Closed space chamber, 14... Partition wall, 15,1
5a, 15b...plating liquid supply pipe, 16,
16a, 16b... Plating liquid discharge pipe.
Claims (1)
閉空間室と、該密閉空間室の陰極端側に配置する
ウエハに対峙し、前記密閉空間室の他端陽極側に
配置する陽極と、前記密閉空間室内に、めつき液
を出入する給入及び排出部とを備えるめつき装置
において、前記密閉空間室内にあつて、前記ウエ
ハと陽極とに介在する多孔質の隔壁と、該隔壁に
よつて区切られる前記密閉空間室のそれぞれに、
めつき液を出入する給入及び排出部とを備えるこ
とを特徴とするめつき装置。 2 特許請求の範囲第1項に記載の隔壁が、前記
密閉空間室内に出入するめつき液に含まれるイオ
ンの通過可能な多孔部を有することを特徴とする
めつき装置。[Scope of Claims] 1. A cylindrical sealed space chamber having an inner diameter substantially the same as that of the wafer, and a cylindrical sealed space chamber located on the cathode end side of the sealed space chamber, facing the wafer, and located on the anode side at the other end of the sealed space chamber. In the plating apparatus, the plating apparatus is provided with an anode that is connected to the wafer, and an inlet/discharge section for supplying and discharging a plating solution into and out of the sealed space chamber, wherein the plating apparatus includes a porous partition wall interposed between the wafer and the anode in the closed space chamber; , each of the closed space chambers separated by the partition wall,
A plating device characterized by comprising an inlet and a discharge section for supplying and discharging a plating solution. 2. A plating apparatus, wherein the partition wall according to claim 1 has a porous portion through which ions contained in the plating liquid flowing into and out of the closed space chamber can pass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9056280A JPS5716199A (en) | 1980-07-04 | 1980-07-04 | Plating apparatus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9056280A JPS5716199A (en) | 1980-07-04 | 1980-07-04 | Plating apparatus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5716199A JPS5716199A (en) | 1982-01-27 |
| JPS6241320B2 true JPS6241320B2 (en) | 1987-09-02 |
Family
ID=14001857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9056280A Granted JPS5716199A (en) | 1980-07-04 | 1980-07-04 | Plating apparatus |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5716199A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61205129A (en) * | 1985-03-08 | 1986-09-11 | 日本鋼管株式会社 | Electric plated steel plate having gloss after coating |
| JP2007119926A (en) * | 2007-02-13 | 2007-05-17 | Ebara Corp | Substrate plating apparatus |
-
1980
- 1980-07-04 JP JP9056280A patent/JPS5716199A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5716199A (en) | 1982-01-27 |
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