【発明の詳細な説明】[Detailed description of the invention]
本発明は生すりみ類とその処理方法に関するも
ので、特に生すりみ類に凍結点降下剤を添加する
ことを特徴とする生すりみ類の処理方法およびそ
れによつて得られるところの凍結点降下剤を含有
し通常の凍結温度以下の低温度に未凍結のまま保
持されることを特徴とする生すりみ類に関するも
のである。
一般に冷凍すりみは、糖、糖アルコール、ポリ
燐酸塩、食塩等を添加して、魚肉の冷凍変性を防
止しているがその冷凍変性防止効果は充分でな
く、未凍結のすりみと比較すると収率の点だけで
なく、保水性やカマボコ形成能が劣り、水のばし
ができない等の欠点があるとされている。一方生
すりみは添加物を添加しないで水晒、脱水工程を
経て裏ろ機を通つて出てきたものをビニール袋に
つめ砕氷をかけて凍結しないようにして流通させ
ているが、生すりみの問題点は製造後4〜5日で
揮発性塩基物質が生成しアンモニア臭が強くなる
ために使用できなくなつてしまう点であつて生す
りみの需要が多いにも拘らず生産は冬期間に限ら
れている実情である。
従つて本発明の目的は生すりみ類の保存につい
て従来からの問題点を解消するための方法を開発
することであり、またそれによつて生すりみを提
供することである。
近年、生鮮魚類の保存法としてパーシヤルフリ
ージング(半凍結法)が一部で提唱されてきてい
るが本発明者の研究の結果によればこの方法すな
わち−3℃を中心とした温度帯で保存する方法は
なますりみ類に対しては効果がなくこの方法では
むしろすりみのカマボコ形成能が悪化する方向に
あることを知つた。本発明者はさらに研究を続け
た結果、生すりみ類に凍結点降下剤を含有させ生
すりみ類を低温度で未凍結状態に保持することに
よつて魚肉の変性を防止できカマボコ形成能も悪
化しないこと、ならびに生すりみの問題点とされ
る腐敗細菌の繁殖、アンモニア臭の発生を防止す
ることができることを発見した。
すなわち、本発明はなますりみ類に凍結点降下
剤を添加することを特徴とする生すりみ類の処理
方法を提供するものである。
本発明で使用される凍結点降下剤としては生す
りみ類の性質を損うものでなければ一般的な化学
量論的な観点から考えられる任意の物質でよく、
その添加量はすりみの物性との関連において自ら
限定されるべきものであることは当然であり、ま
た通常の凍結温度とは生すりみの凍結温度である
−0.4℃を指すものであり、さらに未凍結の状態
とはカマボコ形成能との関連において大部分が未
凍結であればよく、部分てきな凍結状態も含まれ
るものである。
以下に本発明の実施例を示す。
実施例 1
食塩をスケトウタラ生すりみに対して0.1M、
0.2M、0.3M、添加し、らいかい機で15分間らい
かいして、食塩が充分に混合するようにした。生
すりみ食塩無添加の凍結点は−0.4℃、食塩0.1M
添加区の凍結点は−1.1℃、食塩0.2M添加区の凍
結点は−1.8℃、食塩0.3M添加区の凍結点は−2.3
℃であつた(第1図)。
雰囲気温度−3℃で保存試験をした結果放置後
6日では揮発性塩基窒素量は5.0mg%前後で全く
増加しなかつた。凍結状態は生すりみはほぼ完全
に凍結0.1M食塩添加区は一部凍結0.2M食塩添加
区ではほぼ未凍結状態0.3M食塩添加区は未凍結
状態を示していた。座りは、0.1Mならびに0.2M
食塩添加区では全然進んでいなかつたが0.3M食
塩添加区では座りが進んでいてカマボコ形成不能
であつた。この足の強さは、第1表に示したよう
に、凍結状態を示した生すりみではカマボコの足
が劣化していたが、0.2M食塩添加区は、放置直
後の未凍結のものと全く差異が認められず、むし
ろ、足の強さが多少よくなつていた。
The present invention relates to raw surimi and a method for processing the same, and particularly to a method for processing raw surimi, which is characterized by adding a freezing point depressant to raw surimi, and the freezing point obtained thereby. The present invention relates to raw surimi, which contains a depressant and is kept unfrozen at a low temperature below the normal freezing temperature. Generally, frozen surimi is added with sugar, sugar alcohol, polyphosphate, salt, etc. to prevent freezing denaturation of fish meat, but the effect of preventing denaturation in freezing is not sufficient and compared to unfrozen surimi. It is said to have drawbacks not only in terms of yield, but also in poor water retention and kamaboko-forming ability, and inability to drain water. On the other hand, raw surimi is distributed without adding any additives, after being exposed to water and passed through a dehydration process and passed through a strainer, packed in plastic bags and covered with crushed ice to prevent it from freezing. The problem with raw surimi is that volatile basic substances are produced within 4 to 5 days after production, and the smell of ammonia becomes strong, making it unusable.Despite the high demand for raw surimi, production is limited to winter. The reality is that the period is limited. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to develop a method for overcoming the conventional problems in preserving fresh surimi, and thereby to provide fresh surimi. In recent years, partial freezing (semi-freezing method) has been proposed as a method for preserving fresh fish, but according to the results of the research conducted by the present inventors, this method, i.e., preservation at a temperature range centered around -3℃, has been proposed by some. I learned that this method was not effective against sloppy surimi, and that this method actually worsened the ability of surimi to form kamaboko. As a result of further research, the present inventor found that by containing a freezing point depressant in raw surimi and keeping the raw surimi in an unfrozen state at a low temperature, denaturation of fish meat can be prevented and the ability to form kamaboko. It was also discovered that the problem of fresh surimi, such as the growth of spoilage bacteria and the generation of ammonia odor, can be prevented. That is, the present invention provides a method for processing raw surimi, which is characterized by adding a freezing point depressant to raw surimi. The freezing point depressant used in the present invention may be any substance that can be considered from a general stoichiometric point of view as long as it does not impair the properties of raw surimi.
It goes without saying that the amount added should be limited by oneself in relation to the physical properties of surimi, and the normal freezing temperature refers to -0.4℃, which is the freezing temperature of raw surimi. Furthermore, the unfrozen state only needs to be mostly unfrozen in relation to the ability to form a pumpkin, and also includes a partially frozen state. Examples of the present invention are shown below. Example 1 Add 0.1M of salt to raw walleye surimi,
0.2M and 0.3M were added, and the salt was boiled for 15 minutes in a rice sieve machine to thoroughly mix the salt. The freezing point of raw surimi without salt added is -0.4℃, salt 0.1M
The freezing point of the added area is -1.1℃, the freezing point of the added area with 0.2M salt is -1.8℃, and the freezing point of the added area with 0.3M salt is -2.3.
℃ (Figure 1). As a result of a storage test at an ambient temperature of -3°C, the amount of volatile base nitrogen was around 5.0 mg% and did not increase at all after 6 days of storage. Regarding the frozen state, raw surimi was almost completely frozen, partially frozen in the 0.1M salt-added group, almost unfrozen in the 0.2M salt-added group, and unfrozen in the 0.3M salt-added group. Seating is 0.1M and 0.2M
In the salt-added area, no progress was made at all, but in the 0.3M salt-added area, sitting had progressed and it was impossible to form a kamaboko. As shown in Table 1, the legs of kamaboko in the frozen raw surimi were deteriorated, but in the 0.2M salt-added area, the legs were as strong as the unfrozen legs immediately after being left. There was no discernible difference; in fact, the strength of his legs had improved somewhat.
【表】
実施例 2
エチルアルコール(95%)をスケトウタラ生す
りみに対して、1.0、2.0、3.0%添加して、らいか
い機で10分間らいかいし、よく混合した。無添加
は−0.4℃、アルコール1.0%の添加区は凍結点−
1.1℃、2.0%の添加区の凍結点は−1.5℃、3.0%
の添加区の凍結点は−1.8℃であつた(第2図)。
雰囲気温度−3℃で保存試験した結果、放置後
6日では、揮発性塩基窒素量は5.0mg%前後で全
く増加しなかつた。凍結状態は生すりみはほぼ完
全に凍結し、1.0%アルコール添加区は一部凍結
していたが2.0%および3.0%添加区ではいづれも
未凍結状態を示しており、0.3M食塩添加区にみ
られた座りの進行ももちろんみられなかつた。カ
マボコの足の強さは第2表に示したが、凍結状態
を示した生すりみではカマボコの足の劣化は大き
かつたが、未凍結状態であつた2.0%および3.0%
アルコール添加区では放置直後の未凍結のものと
全く差異はみられなかつた。[Table] Example 2 Ethyl alcohol (95%) was added at 1.0, 2.0, and 3.0% to the raw surimi of walleye cod, and the mixture was crushed in a peeler for 10 minutes and mixed well. -0.4℃ without additives, freezing point with 1.0% alcohol
Freezing point of 1.1℃, 2.0% addition area is -1.5℃, 3.0%
The freezing point of the added area was -1.8°C (Figure 2). As a result of a storage test at an ambient temperature of -3°C, the amount of volatile base nitrogen did not increase at all at around 5.0 mg% after 6 days of standing. As for the frozen state, the fresh surimi was almost completely frozen, and although it was partially frozen in the 1.0% alcohol added group, it was unfrozen in both the 2.0% and 3.0% added groups, and the 0.3M salt added group was frozen. Of course, the progress of sitting that was observed was not observed. The strength of the kamaboko's legs is shown in Table 2. The deterioration of the kamaboko's legs was large in raw surimi that had been frozen, but in 2.0% and 3.0% that had not been frozen.
In the alcohol-added area, there was no difference at all between the unfrozen items that had just been left out.
【表】
実施例 3
スケトウタラ生すりみに食塩0.2M、アルコー
ル3.0%を併用した場合の凍結点ならびに放置後
のカマボコの足の影響などについて試験した。
スケトウタラ生すりみに食塩0.2Mとアルコー
ル3.0%併用添加の場合、それぞれの相乗効果が
でて凍結点−2.9℃になつた。もちろん腐敗細菌
の繁殖は完全にストツプし、しかも、未凍結状態
でかなり長期保存しても、カマボコの足が劣化し
ない条件が形成されていることが判明した(第3
図)。[Table] Example 3 When 0.2 M of common salt and 3.0% alcohol were used in combination with raw walleye surimi, the freezing point and the effect on the legs of kamaboko after being left were tested. When 0.2M salt and 3.0% alcohol were added together to raw walleye surimi, the synergistic effect of each was achieved, resulting in a freezing point of -2.9℃. Of course, the growth of spoilage bacteria was completely stopped, and it was also found that conditions were created in which the legs of kamaboko did not deteriorate even if they were stored unfrozen for quite a long time (Part 3).
figure).
【表】
以上の実施例からも明らかなように本発明によ
れば従来貯蔵上各種の問題点のあつた生すりみ類
を容易に利用できるという著しい利点が得られる
ものである。[Table] As is clear from the above examples, the present invention provides the remarkable advantage that raw surimi, which conventionally had various problems in storage, can be easily utilized.
【図面の簡単な説明】[Brief explanation of the drawing]
第1図は食塩を添加した生すりみの凍結曲線、
第2図はアルコールを添加した生すりみの凍結曲
線をそれぞれ示す。
Figure 1 shows the freezing curve of raw surimi with added salt.
Figure 2 shows the freezing curves of raw surimi to which alcohol has been added.