JPS6250929B2 - - Google Patents
Info
- Publication number
- JPS6250929B2 JPS6250929B2 JP6997881A JP6997881A JPS6250929B2 JP S6250929 B2 JPS6250929 B2 JP S6250929B2 JP 6997881 A JP6997881 A JP 6997881A JP 6997881 A JP6997881 A JP 6997881A JP S6250929 B2 JPS6250929 B2 JP S6250929B2
- Authority
- JP
- Japan
- Prior art keywords
- copper
- wire
- stranded
- outer layer
- spray
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 21
- 239000007921 spray Substances 0.000 claims description 11
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 7
- 239000005751 Copper oxide Substances 0.000 claims description 7
- 229910000431 copper oxide Inorganic materials 0.000 claims description 7
- 230000001590 oxidative effect Effects 0.000 claims description 7
- 239000004020 conductor Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 description 12
- 239000010949 copper Substances 0.000 description 12
- 238000007254 oxidation reaction Methods 0.000 description 12
- 239000007788 liquid Substances 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 230000006698 induction Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000005671 trienes Chemical class 0.000 description 1
Landscapes
- Chemical Treatment Of Metals (AREA)
- Processes Specially Adapted For Manufacturing Cables (AREA)
Description
【発明の詳細な説明】
送電容量が増大し、導体サイズが大型化される
のに伴い、表皮効果や近接効果などによる損失が
大きな問題になる。DETAILED DESCRIPTION OF THE INVENTION As power transmission capacity increases and conductor size increases, losses due to skin effect, proximity effect, etc. become a major problem.
素線絶縁はその対策の一つであり、酸化銅の皮
膜によつて素線絶縁を行なうことがすでに提案さ
れている(特開昭56−9912号など参照)。 Wire insulation is one of the countermeasures against this problem, and it has already been proposed to insulate the wires with a film of copper oxide (see Japanese Patent Laid-Open No. 56-9912, etc.).
従来提案されている方法は、全部の素線に絶縁
皮膜を設ける方法であるが、この方法は、製造コ
ストが高くなる割りには、損失低減の効果が薄
い。 A conventionally proposed method is to provide an insulating film on all the wires, but this method has a low loss reduction effect even though the manufacturing cost is high.
また、導体接続に際して素線絶縁皮膜を除去し
なければならないが、全部の素線の皮膜を除去す
るのは、作業がたいへんである。特に内層のもの
ほど、除去作業がしにくくなる。 Further, when connecting conductors, it is necessary to remove the wire insulation coating, but it is difficult to remove the coating from all the wires. In particular, the inner layer is more difficult to remove.
本発明は銅より線(セグメントも含む)の外層
部にだけ酸化銅を形成して素線絶縁することによ
り全部の素線に絶縁皮膜を設けた場合と同等の効
果の得られる素線絶縁導体の製造方法を提供する
ものである。 The present invention provides an insulated wire conductor that insulates the wire by forming copper oxide only on the outer layer of the copper stranded wire (including segments), thereby achieving the same effect as when an insulating film is provided on all the wires. The present invention provides a method for manufacturing.
なお、外層部というのは銅より線またはセグメ
ントとの外層からかぞえて第1層、および第2層
程度という意味で使用している。 Note that the term "outer layer" is used to mean the first layer and the second layer from the outer layer with the copper stranded wire or segment.
発明の概要
銅より線の回りから酸化処理液をスプレー状に
して吹き付けることを考えてみる。SUMMARY OF THE INVENTION Let us consider spraying an oxidizing treatment liquid around a stranded copper wire in the form of a spray.
そのとき、スプレーの圧が非常に弱ければ、酸
化処理液は銅より線の表面をぬらすだけにとどま
る。またスプレーの圧が非常に強ければ、酸化処
理液は銅より線の中心層まで浸透する。 If the spray pressure is very low, the oxidizing solution only wets the surface of the stranded copper wire. Also, if the spray pressure is very strong, the oxidizing solution will penetrate into the center layer of the copper strands.
そこでスプレーの圧を適当に制御することによ
つて、銅より線の外層部だけが酸化処理液にぬ
れ、その部分に酸化銅の皮膜が形成されるように
することができる。 Therefore, by appropriately controlling the spray pressure, it is possible to wet only the outer layer of the copper stranded wire with the oxidizing solution and form a copper oxide film on that part.
実施例(第1図)
10は銅素線をより合わせた銅より線(セグメ
ントも含む)で、矢印12の方向に連続して進行
する。Embodiment (FIG. 1) Reference numeral 10 is a copper stranded wire (including segments) made by twisting copper wires together, and the wire 10 continuously advances in the direction of an arrow 12.
14は加熱室で不活性ふん囲気例えば水蒸気が
充満させている。16は高周波誘導加熱装置。 14 is a heating chamber filled with an inert atmosphere, such as water vapor. 16 is a high frequency induction heating device.
18は酸化処理室。 18 is an oxidation treatment chamber.
20はスプレー筒で、銅より線10はその中心
幅に沿つて進行する。 20 is a spray barrel, and the stranded copper wire 10 runs along its center width.
22はたとえば、5%亜塩素酸テトリウムと5
%水酸化ナトリウムの混合水溶液などからなり、
ヒーター24で90〜100℃程度に加熱される。 22 is, for example, 5% tetrium chlorite and 5
It consists of a mixed aqueous solution of % sodium hydroxide, etc.
It is heated to about 90 to 100°C by the heater 24.
26はポンプ、28は圧力制御弁である。 26 is a pump, and 28 is a pressure control valve.
作 用
まず銅より線10は前処理としてトリエン、ト
リクロロエタン、カセイソーダ水容液等で各素線
表面の脱脂、洗浄が行なわれる。それから高周波
誘導加熱装置16により、
銅より線10の特にその外層部120〜300℃くら
いに加熱する。Function: First, the copper stranded wire 10 is pretreated by degreasing and cleaning the surface of each strand with triene, trichloroethane, caustic soda aqueous solution, or the like. Then, the high-frequency induction heating device 16 heats the stranded copper wire 10, especially its outer layer, to about 120 to 300°C.
それから圧力制御弁28によつて、酸化処理液
22を、銅より線10の外層部だけぬらす程度の
圧に制御して、スプレー筒20から吹き付け、外
層部にだけ酸化銅の皮膜を形成する。 Then, the pressure of the oxidizing treatment liquid 22 is controlled by the pressure control valve 28 to a level that only wets the outer layer of the copper stranded wire 10, and is sprayed from the spray barrel 20 to form a copper oxide film only on the outer layer.
なお、スプレー筒20内を通過する間に酸化反
応を完了させずに、その後、銅より線10を高温
(100℃くらい)の気中に維持して、その間に酸化
反応を進行させ、かつ完了させるようにしてもよ
い。 Note that the oxidation reaction is not completed while passing through the spray tube 20, and the stranded copper wire 10 is then maintained in the air at a high temperature (about 100°C) to allow the oxidation reaction to proceed and complete. You may also do so.
また、高周波誘導加熱装置16による銅より線
10の加熱を行なわず、スプレー筒20において
銅より線10の外層部にだけ酸化処理液を吹き付
けておき、その後高周波誘導加熱装置16によつ
て加熱して酸化反応を促進させるようにすること
もできる。 Alternatively, the stranded copper wire 10 is not heated by the high-frequency induction heating device 16, but the oxidation treatment liquid is sprayed only on the outer layer of the stranded copper wire 10 using the spray tube 20, and then heated by the high-frequency induction heating device 16. It is also possible to accelerate the oxidation reaction.
上記工程後銅より線10は水洗され、各素線表
面に付着していた酸化処理液は完全に除去され
る。 After the above step, the copper stranded wire 10 is washed with water to completely remove the oxidation treatment liquid adhering to the surface of each strand.
発明の効果
銅より線10の回りから酸化処理液22をスプ
レー状にして吹き付けるのであるから、酸化処理
液22の中に浸せきするのに比べ、スプレー圧さ
え適当に調節すれば、スプレーの時間が少し長く
なつても、酸化処理液22は銅より線10の内層
まで浸透してゆかない。Effects of the Invention Since the oxidation treatment liquid 22 is sprayed around the copper stranded wire 10, compared to immersing it in the oxidation treatment liquid 22, the spraying time can be shortened by adjusting the spray pressure appropriately. Even if it becomes a little longer, the oxidation treatment liquid 22 will not penetrate into the inner layer of the copper stranded wire 10.
したがつて酸化処理液22内に浸せきするのに
比べて、反応が容易になる。 Therefore, compared to immersion in the oxidation treatment liquid 22, the reaction becomes easier.
第1図は本発明の実施例の説明図。
10:銅より線、16:高周波誘導加熱装置、
18:酸化処理室、20:スプレー筒、22:酸
化処理液、28:圧力制御弁。
FIG. 1 is an explanatory diagram of an embodiment of the present invention. 10: Copper stranded wire, 16: High frequency induction heating device,
18: Oxidation treatment chamber, 20: Spray barrel, 22: Oxidation treatment liquid, 28: Pressure control valve.
Claims (1)
吹き付けるとともに、 そのスプレーの圧を制御することによつて、 銅より線の外層部だけが酸化処理液にぬれ、か
つその部分にのみ酸化銅の皮膜が形成されるよう
にしたことを特徴とする酸化銅皮膜素線絶縁導体
の製造方法。[Claims] 1. By spraying an oxidizing solution from around the stranded copper wire and controlling the pressure of the spray, only the outer layer of the stranded copper wire is wetted with the oxidizing solution, and A method for producing a copper oxide film-coated wire insulated conductor, characterized in that a copper oxide film is formed only on portions of the copper oxide film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6997881A JPS57185615A (en) | 1981-05-08 | 1981-05-08 | Method of producing copper oxide film strand insulated conductor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6997881A JPS57185615A (en) | 1981-05-08 | 1981-05-08 | Method of producing copper oxide film strand insulated conductor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57185615A JPS57185615A (en) | 1982-11-15 |
| JPS6250929B2 true JPS6250929B2 (en) | 1987-10-27 |
Family
ID=13418251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6997881A Granted JPS57185615A (en) | 1981-05-08 | 1981-05-08 | Method of producing copper oxide film strand insulated conductor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57185615A (en) |
-
1981
- 1981-05-08 JP JP6997881A patent/JPS57185615A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57185615A (en) | 1982-11-15 |
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