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JPS6256391B2 - - Google Patents
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JPS6256391B2 - - Google Patents

Info

Publication number
JPS6256391B2
JPS6256391B2 JP6236583A JP6236583A JPS6256391B2 JP S6256391 B2 JPS6256391 B2 JP S6256391B2 JP 6236583 A JP6236583 A JP 6236583A JP 6236583 A JP6236583 A JP 6236583A JP S6256391 B2 JPS6256391 B2 JP S6256391B2
Authority
JP
Japan
Prior art keywords
refrigerant
packing
rubber
ring
pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP6236583A
Other languages
Japanese (ja)
Other versions
JPS59190578A (en
Inventor
Tsuneo Nakatsuka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IIGURU KOGYO KK
Original Assignee
IIGURU KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IIGURU KOGYO KK filed Critical IIGURU KOGYO KK
Priority to JP6236583A priority Critical patent/JPS59190578A/en
Publication of JPS59190578A publication Critical patent/JPS59190578A/en
Publication of JPS6256391B2 publication Critical patent/JPS6256391B2/ja
Granted legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16JPISTONS; CYLINDERS; SEALINGS
    • F16J15/00Sealings
    • F16J15/002Sealings comprising at least two sealings in succession
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16JPISTONS; CYLINDERS; SEALINGS
    • F16J15/00Sealings
    • F16J15/16Sealings between relatively-moving surfaces
    • F16J15/34Sealings between relatively-moving surfaces with slip-ring pressed against a more or less radial face on one member
    • F16J15/38Sealings between relatively-moving surfaces with slip-ring pressed against a more or less radial face on one member sealed by a packing

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Mechanical Sealing (AREA)
  • Gasket Seals (AREA)

Description

【発明の詳細な説明】 本発明は冷媒を使用する機器類における密封装
置に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a sealing device for equipment that uses a refrigerant.

従来、冷媒を使用する機器類、たとえば各種エ
アコンデイシヨニング装置、冷凍機等の各種シス
テムには多数の密封装置が使用されており、回転
用軸封装置としてはメカニカルシールが、固定用
密封装置としてはゴム製Oリングまたはパツキン
グが使用され、またこれらOリング等の材質は各
システムに使用される冷媒および潤滑油の種類、
雰囲気温度の組み合わせなどを考慮して選定され
る。たとえば、高温雰囲気用としては特殊弗素ゴ
ム材をフレオンR−22(CHClF2)などの低温雰
囲気用としてはネオプレン製ゴム等を使用してい
る。しかし、近年コンプレツサー等の高効率化、
省資源等を目的として各種ゴム部材の配置される
冷媒雰囲気条件がフレオンガスの変更、雰囲気温
度の上昇、システム内の圧力変動等により厳しく
なつている。また重ねて冷媒はきわめて透過性の
強いガスであり、ゴム材に対しても浸透し易いた
めにゴム材の劣化現象が生じる。たとえば、冷媒
液中に浸漬されたゴム材の劣化現象としては、硬
化、収縮、膨潤および発泡、亀裂等を生じ中でも
発泡、亀裂がシール機能を致命的に破壊するもの
であり、現在、耐熱性、耐油性、耐冷媒性、耐密
封性の上記四耐性を兼備するゴム材は存在しない
のが実態であり上記のいずれかに対して妥協して
使用している。本発明者は上記した四耐性のうち
とくに重要な発泡、亀裂の発生メカニズムを究明
して来た。その結果ゴム材の冷媒による発泡、亀
裂の主原因はゴム材の冷媒および潤滑油による膨
潤または収縮に代表される劣化現象にゴム雰囲気
中の圧力変動が急激に相乗した場合にある事を注
目した。
Conventionally, a large number of sealing devices have been used in various systems such as equipment that uses refrigerants, such as various air conditioning devices and refrigerators. Rubber O-rings or packings are used, and the material of these O-rings depends on the type of refrigerant and lubricant used in each system,
Selection is made taking into consideration the combination of ambient temperature, etc. For example, special fluoro rubber materials such as Freon R-22 (CHClF 2 ) are used for high-temperature environments, and neoprene rubbers are used for low-temperature environments. However, in recent years, compressors, etc. have become more efficient,
In order to save resources, the refrigerant atmosphere conditions in which various rubber members are placed have become more severe due to changes in Freon gas, increases in ambient temperature, and pressure fluctuations within the system. Additionally, the refrigerant is a highly permeable gas and easily permeates into the rubber material, causing deterioration of the rubber material. For example, the deterioration phenomena of rubber materials immersed in refrigerant liquid include hardening, shrinkage, swelling, foaming, and cracking, which can fatally destroy the sealing function. The reality is that there is no rubber material that has all of the above-mentioned four resistances: oil resistance, refrigerant resistance, and sealing resistance, and the rubber material is used by compromising on any of the above. The present inventor has investigated the mechanism of foaming and cracking, which is particularly important among the four resistances mentioned above. As a result, we found that the main cause of foaming and cracking in rubber materials caused by refrigerants is when pressure fluctuations in the rubber atmosphere combine rapidly with deterioration phenomena represented by swelling or contraction of rubber materials due to refrigerants and lubricating oils. .

本発明は、上記の点に鑑みて冷媒等を用いる機
器類において、密封装置内のゴム材への冷媒雰囲
気中の圧力変動を防禦し、ゴム材の発泡および亀
裂を防止するとともに、併わせて耐熱ゴム材の使
用を可能とする密封装置を提供するものである。
その要旨は、冷媒を使用する機器の冷媒密封装置
において、ゴム製のOリングまたはパツキングの
冷媒側前面に耐油性および耐冷媒性の優れたゴム
製あるいは合成樹脂製のOリングもしくはパツキ
ングまたはテフロン製のガスケツトを装着し、前
記ゴム製のOリングまたはパツキングと複合して
設置する構造とするものである。
In view of the above points, the present invention prevents pressure fluctuations in the refrigerant atmosphere to the rubber material in a sealing device in equipment using refrigerant, etc., prevents foaming and cracking of the rubber material, and also The present invention provides a sealing device that allows the use of heat-resistant rubber materials.
The gist is that in refrigerant sealing devices for equipment that use refrigerants, the front surface of the rubber O-ring or packing on the refrigerant side is made of rubber or synthetic resin O-ring or packing, or Teflon, which has excellent oil and refrigerant resistance. The gasket is installed in combination with the rubber O-ring or packing.

本発明を図示の実施例にもとづいて詳述する。 The present invention will be explained in detail based on illustrated embodiments.

第1図は本発明に係る第1の実施例を示すもの
であり、1は冷媒を使用する機器類のコンプレツ
サーに使用されるメカニカルシールであり、ハウ
ジング2に固定された固定側摺動体3と、回転軸
4に圧着されて、該回転軸4とともに回転する回
転側摺動体5の摺接によつて、当該メカニカルシ
ール1の外周aに封入された冷媒と潤滑油(以下
冷媒等とする)の漏洩を阻止せんとするものであ
り、前記固定側摺動体3にはハウジング2の内周
面に沿わせて中央部にOリング6と、冷媒側前面
に合成樹脂製パツキング7が受圧面をOリング6
側に向けて装着されており、また前記回転側摺動
体5には回転軸4を纒着する面の中央部にOリン
グ8と、冷媒側前面には同じく合成樹脂製パツキ
ング9がその受圧面をOリング8方向にして装着
されている。
FIG. 1 shows a first embodiment of the present invention, in which 1 is a mechanical seal used in compressors of equipment that uses refrigerant, and a fixed side sliding body 3 fixed to a housing 2 and a , refrigerant and lubricating oil (hereinafter referred to as refrigerant, etc.) sealed in the outer periphery a of the mechanical seal 1 by sliding contact of the rotating side sliding body 5 that is crimped onto the rotating shaft 4 and rotates together with the rotating shaft 4. The fixed side sliding body 3 has an O-ring 6 in the center along the inner peripheral surface of the housing 2, and a synthetic resin packing 7 on the front surface on the refrigerant side to cover the pressure receiving surface. O-ring 6
The rotary side sliding body 5 has an O-ring 8 in the center of the surface to which the rotary shaft 4 is attached, and a synthetic resin packing 9 on the front surface on the refrigerant side. The O-ring is installed in 8 directions.

上記構成を有するメカニカルシール1におい
て、メカニカルシールの外周aに封入されている
冷媒の圧力が増大するとともに、パツキング7,
9がハウジング2および回転軸4と剥離し、Oリ
ング6,8とパツキング7,9の隙間が冷媒によ
り充満し高圧状態となる。後に、運転停止または
冷媒雰囲気温度の急変等により、冷媒側の圧力が
急激に低下した場合には、Oリング6,8とパツ
キング7,9間は、パツキング7,9がその受圧
面を高圧側に向けられているためにリツプが各各
ハウジング2および回転軸4側に圧接されて、急
激な圧力低下が防止される。したがつて、ゴム材
からなるOリング6,8は急激な圧力変動に遭遇
することが回避されるために、耐冷媒性が著しく
向上し、併わせて耐熱性ゴムの使用が可能とな
る。なお、パツキング7,9は冷媒等の流入、圧
力変動を阻止するものであり、たとえばテフロン
等の耐冷媒性、耐油性に優れている材質であれば
充分で積極的シール機能は必要がない。
In the mechanical seal 1 having the above configuration, as the pressure of the refrigerant sealed in the outer periphery a of the mechanical seal increases, the packing 7,
9 separates from the housing 2 and rotating shaft 4, and the gaps between the O-rings 6, 8 and the packings 7, 9 are filled with refrigerant, resulting in a high pressure state. Later, if the pressure on the refrigerant side suddenly drops due to a stoppage of operation or a sudden change in the refrigerant ambient temperature, the packings 7, 9 will move their pressure-receiving surfaces to the high-pressure side between the O-rings 6, 8 and the packings 7, 9. Since the lip is oriented toward the housing 2 and the rotating shaft 4 side, a sudden drop in pressure is prevented. Therefore, since the O-rings 6 and 8 made of rubber material are prevented from encountering sudden pressure fluctuations, their refrigerant resistance is significantly improved, and it is also possible to use heat-resistant rubber. The packings 7 and 9 are used to prevent the inflow of refrigerant and pressure fluctuations, and any material having excellent refrigerant resistance and oil resistance, such as Teflon, is sufficient and an active sealing function is not necessary.

第2図は、本発明に係る第2の実施例を示すも
のであり、以下図面において同一符号は同一部材
を示す。固定側摺動体3のハウジング2に周接す
る面の冷媒側前面に合成樹脂製U字パツキング1
0が凹部をハウジング2に向けそのリツプを冷媒
側に傾斜させて装着されている。また、回転側摺
動体5には回転軸4を纒着する面の中央部にOリ
ング8と冷媒側前面には同じく合成樹脂製パツキ
ング11が受圧面を冷媒側に向けて装着されてい
る。
FIG. 2 shows a second embodiment of the present invention, and the same reference numerals indicate the same members in the drawings. A U-shaped packing 1 made of synthetic resin is provided on the front surface of the fixed side sliding body 3 on the refrigerant side of the surface that is in contact with the housing 2.
0 is installed with the concave portion facing the housing 2 and its lip slanting toward the refrigerant side. Further, an O-ring 8 is mounted on the rotating side sliding body 5 at the center of the surface to which the rotating shaft 4 is attached, and a synthetic resin packing 11 is mounted on the front surface on the refrigerant side with the pressure-receiving surface facing the refrigerant side.

上記構成を有するメカニカルシール1におい
て、冷媒の圧力が増大した場合も、パツキング1
0のリツプが冷媒側に傾斜し、またパツキング1
1も同じくその受圧面を冷媒側に向けているため
に、Oリング6,8とパツキング10,11の隙
間には冷媒等が急激に流入しない。したがつて、
ゴム材の発泡発生の主原因である冷媒等への浸漬
と冷媒雰囲気圧力の急変をパツキング10,11
により防禦し、Oリング6,8に与えるこれらの
影響を阻止することが可能となる。
In the mechanical seal 1 having the above configuration, even when the pressure of the refrigerant increases, the packing 1
The lip of 0 is inclined toward the refrigerant side, and the lip of packing 1
1 also has its pressure-receiving surface facing the refrigerant side, so that the refrigerant etc. does not suddenly flow into the gaps between the O-rings 6, 8 and the packings 10, 11. Therefore,
Packing for immersion in refrigerant, etc. and sudden changes in refrigerant atmosphere pressure, which are the main causes of foaming of rubber materials10,11
This makes it possible to prevent these effects on the O-rings 6 and 8.

第3図は本発明に係る第3の実施例を示すもの
であり、メカニカルシール1において固定側摺動
体3のハウジング2に周接する面の冷媒側前面に
合成樹脂製U字パツキング12が凹部である受圧
面を冷媒側に向け装着されている。また、回転側
摺動体5の冷媒側前面に合成樹脂製Y字パツキン
グ13が受圧面を冷媒側に向けて装着され、該受
圧面には金属プレート14の下部をOリング8方
向に屈曲させた先端が挿入されている。
FIG. 3 shows a third embodiment of the present invention, in which a U-shaped packing 12 made of synthetic resin is formed in a recess on the front surface of the fixed side sliding body 3 on the refrigerant side of the surface circumferentially contacting the housing 2 of the mechanical seal 1. It is installed with one pressure-receiving surface facing the refrigerant side. Furthermore, a Y-shaped packing 13 made of synthetic resin is attached to the front surface of the rotating side sliding body 5 on the refrigerant side with the pressure receiving surface facing the refrigerant side, and the lower part of the metal plate 14 is bent in the O ring 8 direction on the pressure receiving surface. The tip is inserted.

上記構成を有する本実施例は、第2実施例と同
様に冷媒の圧力が増大すると、パツキング12,
13の受圧面が完全に冷媒方向にあるためにリツ
プがハウジング2および回転軸4を圧接し、冷媒
等がOリング6,8とパツキング12,13の隙
間に流入するのを防禦することができる。本実施
例の構成は前記第2実施例より顕著に冷媒等のO
リング6,8に与える種種の影響を小さくするこ
とができる。なお、第4図に示すように固定側摺
動体3のパツキング15は第2図に示す状態に、
また回転側摺動体5のパツキング16は第1図に
示される状態に装着される場合も考えられる。
In the present embodiment having the above configuration, when the pressure of the refrigerant increases as in the second embodiment, the packing 12,
Since the pressure-receiving surface of 13 is completely in the direction of the refrigerant, the lip presses the housing 2 and the rotating shaft 4, and can prevent refrigerant etc. from flowing into the gap between the O-rings 6, 8 and the packings 12, 13. . The configuration of this embodiment is more conspicuous than the second embodiment.
The influence of different types on the rings 6 and 8 can be reduced. In addition, as shown in FIG. 4, the packing 15 of the fixed side sliding body 3 is in the state shown in FIG.
It is also conceivable that the packing 16 of the rotating sliding body 5 is installed in the state shown in FIG.

第5図に示す第4実施例は、固定用密封装置1
7において、第1密封部材18および第2密封部
材19にOリング20と合成樹脂製U字パツキン
グ21が、第2密封部材19の凸部に隔離されて
挾装されており、Oリング20は第2密封部材1
9の中央部にU字パツキング21は冷媒が密封さ
れている側bの窪みに凹部を第1密封部材18方
向にしてリツプを冷媒側に傾斜させて装着されて
いる。
The fourth embodiment shown in FIG.
7, an O-ring 20 and a U-shaped packing 21 made of synthetic resin are isolated and sandwiched between the first sealing member 18 and the second sealing member 19 by the convex portion of the second sealing member 19, and the O-ring 20 is Second sealing member 1
A U-shaped packing 21 is installed in the center of the refrigerant 9 in a recess on the side b where the refrigerant is sealed, with the concave portion facing toward the first sealing member 18 and the lip inclined toward the refrigerant side.

上記構成を有する固定用密封装置17の上記U
字パツキング21は、第2実施例のパツキング1
0と冷媒等に対し同様の機能を奏するものであ
り、第6図に示すように第2密封部材19の凹部
に大気側をOリング20とし、冷媒側にU字パツ
キング22が凹部を第1密封部材18方向にして
前記Oリング20と隣接して密封部材18,19
に挾装される場合も本実施例に含まれるものとす
る。なお、上記パツキング7,10,12,1
5,21,22の代わりに断面略角形状のテフロ
ン製ガスケツトを用いてもよい。
The above U of the fixing sealing device 17 having the above configuration
The character packing 21 is the packing 1 of the second embodiment.
As shown in FIG. 6, an O-ring 20 is placed in the concave part of the second sealing member 19 on the atmosphere side, and a U-shaped packing 22 is placed in the concave part on the refrigerant side. Sealing members 18 and 19 are adjacent to the O-ring 20 in the direction of the sealing member 18.
This embodiment also includes the case where the device is sandwiched between the devices. In addition, the above packing 7, 10, 12, 1
5, 21, and 22 may be replaced by Teflon gaskets having a substantially rectangular cross section.

以上より、本発明は冷媒を使用する機器におい
て、回転用密封装置および固定用密封装置のゴム
製Oリングまたはパツキングの冷媒側前面に耐冷
媒性、耐油性の各種ゴムまたは合成樹脂製のパツ
キングまたはテフロン製ガスケツトを複合して装
着することにより、前記ゴム製Oリングまたはパ
ツキングが冷媒の圧力変動の影響を受け、また冷
媒と潤滑油に浸漬するのを防禦し、ゴム材の劣化
現象とくにシール機能を破壊する発泡、亀裂等を
防止することが可能となり、併わせて耐熱ゴム材
の使用、たとえば従来冷媒フレオンR−22に対し
て、高温用の弗素ゴム等を使用するなどを可能と
する密封装置を提供するものであり、併わせて従
来各種コンプレツサーの密封装置において耐熱
性、耐油性、耐冷媒用、耐密封性のいずれかを犠
牲にして選択されたゴム材の選択範囲を拡張する
ものであり、本発明は実用的効果のきわめて高い
密封装置を提供するものである。
In view of the above, the present invention provides equipment that uses refrigerants, in which rubber O-rings or packings of rotary sealing devices and fixed sealing devices are provided with various types of rubber or synthetic resin packing or By installing a Teflon gasket in combination, it prevents the rubber O-ring or packing from being affected by pressure fluctuations of the refrigerant and from being immersed in the refrigerant and lubricating oil, and prevents deterioration of the rubber material, especially the sealing function. It is possible to prevent foaming, cracking, etc. that would destroy the refrigerant, and it also allows the use of heat-resistant rubber materials, such as the use of high-temperature fluoro rubber instead of the conventional refrigerant Freon R-22. In addition to providing equipment, it also expands the selection range of rubber materials that have traditionally been selected at the expense of heat resistance, oil resistance, refrigerant resistance, or sealing resistance in sealing devices for various compressors. Therefore, the present invention provides a sealing device with extremely high practical effects.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は本発明に係る実施例を示すものであり、
第1図から第4図まではメカニカルシールにおけ
る実施例の半裁断面図、第5図および第6図は固
定用密封装置における実施例の半裁断面図であ
る。 1……メカニカルシール、2……ハウジング、
3……固定側摺動体、4……回転軸、5……回転
側摺動体、6,8,20……ゴム製Oリング、
7,9,10,11,12,13,15,16,
21,22……パツキング、17……固定用密封
装置、18……第1密封部材、19……第2密封
部材、a,b……冷媒および潤滑油の密封箇所。
The drawings show embodiments of the invention,
1 to 4 are half-cut sectional views of an embodiment of a mechanical seal, and FIGS. 5 and 6 are half-cut sectional views of an embodiment of a fixing sealing device. 1... Mechanical seal, 2... Housing,
3... Fixed side sliding body, 4... Rotating shaft, 5... Rotating side sliding body, 6, 8, 20... Rubber O-ring,
7, 9, 10, 11, 12, 13, 15, 16,
21, 22... Packing, 17... Fixed sealing device, 18... First sealing member, 19... Second sealing member, a, b... Sealing location for refrigerant and lubricating oil.

Claims (1)

【特許請求の範囲】[Claims] 1 冷媒を使用する機器の冷媒密封装置におい
て、ゴム製のOリングまたはパツキングの冷媒側
前面に耐油性および耐冷媒性の優れたゴム製ある
いは合成樹脂製のパツキングまたはテフロン製の
ガスケツトを装着し、前記ゴム製のOリングまた
はパツキングと複合して設置する構造としたこと
を特徴とする密封装置。
1. In a refrigerant sealing device for equipment that uses refrigerant, a rubber or synthetic resin packing or Teflon gasket with excellent oil and refrigerant resistance is attached to the front surface of the rubber O-ring or packing on the refrigerant side. A sealing device characterized by having a structure that is installed in combination with the rubber O-ring or packing.
JP6236583A 1983-04-11 1983-04-11 Sealing device Granted JPS59190578A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6236583A JPS59190578A (en) 1983-04-11 1983-04-11 Sealing device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6236583A JPS59190578A (en) 1983-04-11 1983-04-11 Sealing device

Publications (2)

Publication Number Publication Date
JPS59190578A JPS59190578A (en) 1984-10-29
JPS6256391B2 true JPS6256391B2 (en) 1987-11-25

Family

ID=13198015

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6236583A Granted JPS59190578A (en) 1983-04-11 1983-04-11 Sealing device

Country Status (1)

Country Link
JP (1) JPS59190578A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992014080A1 (en) * 1991-02-08 1992-08-20 Nippon Pillar Packing Co., Ltd. Mechanical seal

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2582373B1 (en) * 1985-05-24 1990-03-02 Gueytron Jean Claude LATERAL FRICTION SEALING DEVICE
JPS6435175A (en) * 1987-07-31 1989-02-06 Tokyo Electron Ltd Semiconductor processing device
US5873574A (en) * 1996-07-18 1999-02-23 John Crane Sealol Inc. Bellows seal with reverse pressure capability
JP4814031B2 (en) * 2006-09-14 2011-11-09 三菱電線工業株式会社 Sealing material
JP4949492B2 (en) * 2010-02-15 2012-06-06 川崎重工業株式会社 Gas seal structure
CN107206596B (en) * 2014-12-03 2020-11-17 Abb瑞士股份有限公司 Protection device, end effector and robot
DE102015016220A1 (en) * 2015-12-10 2017-06-14 Kaco Gmbh + Co. Kg Mechanical seal, in particular gas-lubricated mechanical seal
JP2021067241A (en) * 2019-10-25 2021-04-30 愛三工業株式会社 EGR valve device
WO2025047672A1 (en) * 2023-08-31 2025-03-06 イーグル工業株式会社 Mechanical seal

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992014080A1 (en) * 1991-02-08 1992-08-20 Nippon Pillar Packing Co., Ltd. Mechanical seal
EP0528029B1 (en) * 1991-02-08 1996-08-28 Nippon Pillar Packing Co., Ltd. Mechanical seal

Also Published As

Publication number Publication date
JPS59190578A (en) 1984-10-29

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