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JPS6260607B2 - - Google Patents
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JPS6260607B2 - - Google Patents

Info

Publication number
JPS6260607B2
JPS6260607B2 JP20163685A JP20163685A JPS6260607B2 JP S6260607 B2 JPS6260607 B2 JP S6260607B2 JP 20163685 A JP20163685 A JP 20163685A JP 20163685 A JP20163685 A JP 20163685A JP S6260607 B2 JPS6260607 B2 JP S6260607B2
Authority
JP
Japan
Prior art keywords
burner
combustion
air ratio
radiant
zone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP20163685A
Other languages
Japanese (ja)
Other versions
JPS6176814A (en
Inventor
Akira Baba
Iwao Akyama
Kunio Okiura
Toshiharu Kikuchi
Shigeki Morita
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Mitsubishi Power Ltd
Tokyo Electric Power Co Holdings Inc
Original Assignee
Babcock Hitachi KK
Tokyo Electric Power Co Inc
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Babcock Hitachi KK, Tokyo Electric Power Co Inc, Hitachi Ltd filed Critical Babcock Hitachi KK
Priority to JP20163685A priority Critical patent/JPS6176814A/en
Publication of JPS6176814A publication Critical patent/JPS6176814A/en
Publication of JPS6260607B2 publication Critical patent/JPS6260607B2/ja
Granted legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C6/00Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
    • F23C6/04Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
    • F23C6/045Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure
    • F23C6/047Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure with fuel supply in stages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2201/00Staged combustion
    • F23C2201/10Furnace staging
    • F23C2201/101Furnace staging in vertical direction, e.g. alternating lean and rich zones

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)

Description

【発明の詳細な説明】 <産業上の利用分野> この発明はボイラ等の燃焼装置の排ガス中の
NOx等有害物質の低減をはかる燃焼方法に関す
る。
[Detailed Description of the Invention] <Industrial Application Field> This invention is directed to
Concerning combustion methods that aim to reduce harmful substances such as NOx.

<従来の技術及びその問題点> 従来の排ガス中の有害成分たるNOx低減手段
としては排ガス再循環、2段燃焼、分割火炎、水
注入、又はNH3等の還元剤の注入等であつた。こ
れらはNOxの発生は高温ガス中におけるN2とO2
との反応、燃料中のN2(フユエル窒素)との反
応が主たるNO発生の原因とするもので、その対
策としてガス温度の低下、O2分圧の低下のため
の排ガス再循環、又は直接還元剤との反応による
NOの分解等によりするものである。
<Prior art and its problems> Conventional methods for reducing NOx, which is a harmful component in exhaust gas, include exhaust gas recirculation, two-stage combustion, split flame, water injection, or injection of a reducing agent such as NH 3 . These are because the generation of NOx is caused by N 2 and O 2 in high temperature gas.
The main cause of NO generation is the reaction with N 2 (fuel nitrogen) in the fuel, and countermeasures include lowering the gas temperature, exhaust gas recirculation to lower the O 2 partial pressure, or direct Due to reaction with reducing agent
This is done by decomposing NO.

しかし近時NOの発生の機構に対する実験考察
により格別の還元剤を使用することなく燃焼装置
に対する空気供給量、即ち空気比を変えたバーナ
配置によりNOxを低減する方法が行なわれてい
る。
However, recent experimental studies on the mechanism of NOx generation have led to a method of reducing NOx by changing the amount of air supplied to the combustion device, that is, the air ratio, by changing the burner arrangement without using any particular reducing agent.

即ち火炉の下側に主バーナを位置させて空気比
を1以下好ましくは0.85〜0.95にして稍不完全燃
焼をさせるものである。この場合サーマルNOx
(Thermal NOx)としてNO、燃料過剰域で重油
の熱分解によりH,C,N2がCN,NH2等のラジ
カルを生じこれにO2が反応してプロンプトNOを
生成する。ついでこの主バーナの上方に副バーナ
を位置させ、空気比0.4程度にして気相還元域を
形成させ、NH2,CN,CO等により前記のNOを
還元してNとCO,CO2,H2Oにしてしまうもの
である。しかしこの気相還元域で必ずしも充分に
NOをN2にすることができず、HCNの残留もあ
り、かつCOを含むことより副バーナの後流に酸
化バーナを設けこれと組合せる空気供給口(NO
ポート.NO)を設けて酸化バーナNO組を形成さ
せている。酸化バーナはアフタバーナとも言う。
またアフタバーナとも言う。またこの区域を完全
燃焼域と称する。この区域における空気比は1以
上好ましくは1.3にしてこの区域以降の排ガス中
にNOx,COの含有のないようにしている。この
場合燃料の配分は主バーナで約65%、副バーナ
(プラネツトバーナとも称する)で約30%、酸化
バーナ(アフタバーナ)で約5%とするときは
NOxの低下は大であつた。
That is, the main burner is located below the furnace, and the air ratio is set to 1 or less, preferably 0.85 to 0.95, to achieve slightly incomplete combustion. In this case thermal NOx
(Thermal NOx) is produced by thermal decomposition of heavy oil in the fuel excess region, where H, C, and N 2 produce radicals such as CN and NH 2 , and O 2 reacts with these radicals to produce prompt NO. Next, an auxiliary burner is placed above the main burner to form a gas phase reduction zone with an air ratio of about 0.4, and the above-mentioned NO is reduced with NH 2 , CN, CO, etc. to form N, CO, CO 2 , H 2 O. However, this gas phase reduction region is not necessarily sufficient.
Since NO cannot be converted to N2 , there is residual HCN, and it also contains CO, an oxidation burner is installed downstream of the sub-burner and an air supply port (NO
port. NO) is provided to form an oxidation burner NO group. Oxidation burners are also called afterburners.
It is also called afterbana. This area is also referred to as the complete combustion area. The air ratio in this zone is set to 1 or more, preferably 1.3, so that NOx and CO are not contained in the exhaust gas after this zone. In this case, the fuel distribution is approximately 65% for the main burner, approximately 30% for the auxiliary burner (also called a planet burner), and approximately 5% for the oxidation burner (afterburner).
The reduction in NOx was significant.

<発明の目的> この発明はこのようなNOx低減をはかるバー
ナ配置をしてバーナを燃焼させる方法を提案し更
にNOx低減の効果を大にするような燃焼方法を
提供することを目的とする。
<Purpose of the Invention> The object of the present invention is to propose a method of arranging burners and combusting the burners so as to reduce NOx, and further to provide a combustion method that increases the effect of reducing NOx.

<手段の概要> 要するにこの発明は火炉内下部に稍不完全燃焼
域を形成し、その上方に気相還元域を形成して燃
焼する方法において、火炉内下部に輻射部材を設
け、さらに前記稍不完全燃焼域を形成するバーナ
に供給する燃焼用空気についての第1の空気比を
1未満とし、前記気相還元域を形成するバーナへ
供給する燃焼用空気についての第2空気比を前記
第1の空気比より小とした低NOx燃焼方法であ
ることを特徴とする。
<Summary of the Means> In short, the present invention provides a method for combustion in which a slightly incomplete combustion zone is formed in the lower part of the furnace and a gas phase reduction zone is formed above it, in which a radiant member is provided in the lower part of the furnace, and A first air ratio for the combustion air supplied to the burner forming the incomplete combustion zone is less than 1, and a second air ratio for the combustion air supplied to the burner forming the gas phase reduction zone is set to the second air ratio for the combustion air supplied to the burner forming the gas phase reduction zone. It is characterized by a low NOx combustion method in which the air ratio is lower than 1.

<実施例> 以下図面を使用してこの発明の一実施例を説明
する。第1図はこの発明の一実施例を示す装置の
縦断面図であり、第2図はその正面図である。燃
焼装置の火炉9の前壁8と後壁8′には下部より
上方に順に主バーナ1、副バーナ2、酸化バーナ
3、NOポート3′が位置し、これらを囲み風箱5
を設ける。図示例では各バーナは横方向に各4本
が並ぶように配置するものである。この配置によ
り空気比1未満(第1の空気比)稍不完全燃焼域
M、第1の空気比より小なる第2の空気比の気相
還元域P、完全燃焼域Oが形成される。排ガスを
再投入する管路(図示せず)により排ガスダクト
(図示せず)より取り出された排ガスは再循環ガ
ス4として炉底より炉内に供給される。この発明
の第1実施例たる第1図においては主バーナ1の
火炎の下部と炉底との間に断面「ヘ」の字状山型
の輻射部材6を位置させるものである。
<Example> An example of the present invention will be described below using the drawings. FIG. 1 is a longitudinal sectional view of an apparatus showing an embodiment of the present invention, and FIG. 2 is a front view thereof. A main burner 1, an auxiliary burner 2, an oxidation burner 3, and an NO port 3' are located in the order above from the bottom on the front wall 8 and rear wall 8' of the furnace 9 of the combustion device, and surrounding these are a wind box 5.
will be established. In the illustrated example, each burner is arranged so that four of each burner are lined up in the horizontal direction. This arrangement forms a slightly incomplete combustion region M with an air ratio less than 1 (first air ratio), a gas phase reduction region P with a second air ratio smaller than the first air ratio, and a complete combustion region O. Exhaust gas is taken out from an exhaust gas duct (not shown) through a pipe (not shown) for reintroducing the exhaust gas and is supplied into the furnace from the bottom of the furnace as recirculation gas 4. In FIG. 1, which is a first embodiment of the present invention, a radiant member 6 having a chevron-shaped cross section is positioned between the lower part of the flame of the main burner 1 and the bottom of the furnace.

この輻射部材はプラスチツククロームオアー等
の耐火材で形成され主バーナ1の熱を受け高温に
に加熱され熱線を輻射する。一方再循環ガス4は
図示MX部で渦流をなし火炎の一部をまき込みこ
の混合ガス中の未燃物たるカーボン粒子等を輻射
部材の輻射熱によりO2と反応させ焼却する。ま
た稍不完全燃焼域の未燃物にも強い熱線を輻射し
て与えO2との反応処理を促進する効果をもつ。
これは主バーナ1a〜1d相互間に離隔してお
り、この空間を熱線が透過しこのガス体に輻射熱
を与えるものである。
This radiant member is made of a refractory material such as plastic chrome ore, receives heat from the main burner 1, is heated to a high temperature, and radiates heat rays. On the other hand, the recirculating gas 4 forms a vortex in the MX section shown in the figure, entraining a portion of the flame, and causes unburned carbon particles in the mixed gas to react with O 2 and incinerate them by the radiant heat of the radiant member. It also has the effect of radiating strong heat rays to the unburned materials in the slightly incomplete combustion region and promoting the reaction process with O 2 .
The main burners 1a to 1d are spaced apart from each other, and heat rays pass through this space to give radiant heat to the gas body.

第3図は他の輻射部材配置の一実施例を示すも
ので炉底水壁上に輻射部材6aを位置させたもの
である。
FIG. 3 shows another embodiment of the radiant member arrangement, in which the radiant member 6a is positioned on the bottom water wall of the reactor.

第4図は第1図に対応するもので輻射部材6b
の上面を部分筒状の曲面とし、その断面(筒状面
の一部をなし断面弧状となる)の中心C1,C2
主バーナ1と副バーナ2の間のレベルにあるよう
にするものである。
FIG. 4 corresponds to FIG. 1 and shows the radiation member 6b.
The upper surface is a partially cylindrical curved surface, and the centers C 1 and C 2 of its cross section (which forms part of the cylindrical surface and has an arcuate cross section) are located at the level between the main burner 1 and the sub-burner 2. It is something.

第5図は第3図に対応する輻射部材6cに同様
に部分筒状の曲面を形成しその曲面の中心C1′,
C2′を主バーナ1と副バーナ2の間のレベルに位
置させたものである。
In FIG. 5, a partially cylindrical curved surface is similarly formed on the radiating member 6c corresponding to FIG. 3, and the center of the curved surface is C 1 ',
C 2 ' is located at a level between the main burner 1 and the auxiliary burner 2.

輻射部材を曲面にすることは光源たる火炎がち
らつきかつ振れることにより部分筒状曲鏡面と平
行光線により焦点を結ぶような関係は成立しない
が一応輻射部材からの輻射線の集合ということは
期待できる。これはストーカ焚きの場合に形成す
る輻射用の耐火れんが壁からの輻射熱が石炭の揮
発分を給炭機側ストーカ面上で生ぜしめ着火を容
易にしていると同様の効果をもつものである。
When the radiating member is made into a curved surface, the flame that is the light source flickers and oscillates, so a relationship such as focusing on the partially cylindrical curved mirror surface and parallel rays does not hold, but it can be expected that the radiant rays from the radiating member will gather together. . This has the same effect as when radiant heat from the radiant refractory brick wall that is formed during stoker firing generates the volatile content of the coal on the stoker surface on the coal feeder side, making ignition easier.

この発明を実施することにより稍不完全燃焼域
M、気相還元域Pにおける未燃成分の焼却反応処
理が促進され、輻射部材の配置による燃焼条件を
保持できるという効果を奏することができる。ま
た特に短炎のガスを燃料とするときは輻射部材に
よる反応確保の効果は大である。
By carrying out this invention, the incineration reaction treatment of unburned components in the slightly incomplete combustion zone M and the gas phase reduction zone P is promoted, and the combustion conditions due to the arrangement of the radiant member can be maintained. In addition, the radiant member is particularly effective in ensuring a reaction when short flame gas is used as fuel.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は第1実施例を示す装置の縦断面図、第
2図はその正面図、第3図は輻射部材配置の一実
施例を示す炉底部の縦断面図、第4図は他の輻射
部材配置の例を示す縦断面図、第5図はまた別の
輻射部材配置例を示す縦断面図である。 1…主バーナ、2…副バーナ、3…酸化バー
ナ、3′…NOポート、4…再循環ガス、5…風
箱、6,6a,6b,6c…輻射部材。
Fig. 1 is a longitudinal sectional view of the apparatus showing the first embodiment, Fig. 2 is a front view thereof, Fig. 3 is a longitudinal sectional view of the bottom of the furnace showing one embodiment of the arrangement of the radiant members, and Fig. 4 is FIG. 5 is a longitudinal sectional view showing an example of radiant member arrangement. FIG. 5 is a longitudinal sectional view showing another example of radiant member arrangement. 1... Main burner, 2... Sub burner, 3... Oxidation burner, 3'... NO port, 4... Recirculating gas, 5... Wind box, 6, 6a, 6b, 6c... Radiation member.

Claims (1)

【特許請求の範囲】[Claims] 1 火炉内下部に稍不完全燃焼域を形成し、その
上方に気相還元域を形成して燃焼する方法におい
て、火炉内下部に輻射部材を設け、さらに前記稍
不完全燃焼域を形成するバーナに供給する燃焼用
空気についての第1の空気比を1未満とし、前記
気相還元域を形成するバーナへ供給する燃焼用空
気についての第2の空気比を前記第1の空気比よ
り小としたことを特徴とする低NOx燃焼方法。
1. A method of combustion in which a slightly incomplete combustion zone is formed in the lower part of the furnace and a gas phase reduction zone is formed above the burner, in which a radiant member is provided in the lower part of the furnace, and the burner that further forms the slightly incomplete combustion zone is provided. A first air ratio for combustion air supplied to the burner is less than 1, and a second air ratio for combustion air supplied to the burner forming the gas phase reduction zone is smaller than the first air ratio. A low NOx combustion method characterized by:
JP20163685A 1985-09-13 1985-09-13 Low nox combustion Granted JPS6176814A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20163685A JPS6176814A (en) 1985-09-13 1985-09-13 Low nox combustion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20163685A JPS6176814A (en) 1985-09-13 1985-09-13 Low nox combustion

Publications (2)

Publication Number Publication Date
JPS6176814A JPS6176814A (en) 1986-04-19
JPS6260607B2 true JPS6260607B2 (en) 1987-12-17

Family

ID=16444361

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20163685A Granted JPS6176814A (en) 1985-09-13 1985-09-13 Low nox combustion

Country Status (1)

Country Link
JP (1) JPS6176814A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62106160U (en) * 1985-12-24 1987-07-07
JPH0511089U (en) * 1991-07-23 1993-02-12 日本道路興業株式会社 Self-luminous windsock

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7168947B2 (en) * 2004-07-06 2007-01-30 General Electric Company Methods and systems for operating combustion systems

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62106160U (en) * 1985-12-24 1987-07-07
JPH0511089U (en) * 1991-07-23 1993-02-12 日本道路興業株式会社 Self-luminous windsock

Also Published As

Publication number Publication date
JPS6176814A (en) 1986-04-19

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