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JPS627161B2 - - Google Patents
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JPS627161B2 - - Google Patents

Info

Publication number
JPS627161B2
JPS627161B2 JP59013492A JP1349284A JPS627161B2 JP S627161 B2 JPS627161 B2 JP S627161B2 JP 59013492 A JP59013492 A JP 59013492A JP 1349284 A JP1349284 A JP 1349284A JP S627161 B2 JPS627161 B2 JP S627161B2
Authority
JP
Japan
Prior art keywords
acid
oil
fat
cosmetics
value
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP59013492A
Other languages
Japanese (ja)
Other versions
JPS60158104A (en
Inventor
Juzo Higaki
Mieko Saito
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nisshin Oillio Group Ltd
Original Assignee
Nisshin Oil Mills Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nisshin Oil Mills Ltd filed Critical Nisshin Oil Mills Ltd
Priority to JP59013492A priority Critical patent/JPS60158104A/en
Publication of JPS60158104A publication Critical patent/JPS60158104A/en
Publication of JPS627161B2 publication Critical patent/JPS627161B2/ja
Granted legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52Stabilizers
    • A61K2800/522Antioxidants; Radical scavengers

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は、主としてインド地方に群生、または
他種の森林にまじつて生えている沙羅双樹(Sal
Tree)と呼ばれる30〜50mの常緑の喬木の実
(Sal Seed)から抽出した油脂(サル脂Sal
Fat)または(および)その水素添加物を配合し
てなる化粧料に関する。 通常の植物油は、オレイン酸、リノール酸、リ
ノレン酸等の不飽和酸を多く含むため、酸化安定
性の面で問題がある。一般に化粧品の面で問題が
ある。一般に化粧品に使用される植物油は、オリ
ーブ油をはじめヒマシ油、大豆油、アボガド油、
アーモンド油、ツバキ油、ヤシ油等であるが、い
ずれもトリグリセリド構造を有しているものの、
その感触、物性等は種類により大きく異なり、必
ずしも満足のいくものではなかつた。 またヤシ油等の飽和脂肪酸主体の植物油は、酸
化安定性の面では良好なものの、ラウリン酸を主
体とした中鎖脂肪酸を含有しているため、分解時
の臭いの問題があり、また感触的にもやや重い傾
向を示す。 本発明者らは、上記の欠点を改良すべく研究の
結果、前記したサル脂が化粧用油脂として極めて
優れた特性を有することを見い出し、これに基づ
いて本発明を完成した。 以下に本発明を説明する。 沙羅双樹の実の核は水分4〜20%、油分13〜20
%で、採油は核の油分が低いのでこれを細粒にし
てヘキサン抽出するのが一般的である。得られた
サル脂原油は濃緑色の油で酸価10〜25、ケン化価
175〜190、ヨウ素価33〜40、不ケン化物1〜3
%、融点30〜40℃である。上記原油を通常の方法
で脱酸、脱色、脱臭することにより、白色ないし
淡黄色の固体状の精製サル脂が得られる。 サル脂はべたついた感じのない、さつぱりとし
た感触の油で皮膚に塗布すると非常に感じがよ
い。 サル脂は他の植物油と同様トリグリセリド構造
をもつているが40%程度を占める不飽和脂肪酸の
ほとんどがオレイン酸であることから酸化安定性
の面で有利であるとともに、飽和脂肪酸もパルミ
チン酸、ステアリン酸、アラキン酸であり、安定
性、臭いの面からも有利である。 また脂肪酸組成からも分る通りサル脂は常温で
は固体であるが、融点が30〜35℃であるため皮膚
上ですばやく溶解する。そのためメイクアツプ化
粧料、基礎化粧料にサル脂を油性原料として配合
すると化粧品の品質を改良し、感触のすぐれた化
粧品となる。 つぎに本発明の化粧料について、実施例により
説明する。 実施例 1 サル脂の製造 沙羅双樹の実100Kgを粉砕し、n−ヘキサンで
抽出後、脱溶剤して濃緑色のサル脂原油15.5Kgを
得た。性状は酸価17.5、ケン化価181.1、ヨウ素
価35.4、不ケン化物1.7%、融点34.7℃であつた。
次に脱ガム、アルカリ脱酸、白土、活性炭による
脱色後、水蒸気脱臭により精製サル脂12.1Kgを得
た。精製サル脂の性状は以下の通りであつた。 酸 価 0.1 過酸化物価 0.0 ヨウ素価 38.3 融点(℃) 31.5 ケン化価 187.3 不ケン化物(%) 0.1 脂肪酸組成 パルミチン酸 5.4% ステアリン酸 45.2% オレイン酸 40.5% リノール酸 1.7% アラキン酸 7.2% 実施例 2 水素添加サル脂の製造 実施例1で得た精製サル脂1Kgを3オートク
レーブに入れNi触媒0.2%、水素圧2.5Kg/cm2
180℃の条件下で30分水素添加を行ない以下の性
状の水素添加サル脂を得た。 酸 価 0.1 過酸化物価 0.0 ヨウ素価 17.1 ケン化価 187.1 不ケン化物(%) 0.1 融点(℃) 47.5 脂肪酸組成 パルミチン酸 5.5% ステアリン酸 69.2% オレイン酸 18.1% アラキン酸 7.2% 実施例 3 クレンジングクリーム
The present invention is directed to the Sal tree, which grows mainly in India in clusters or mixed with other species of forests.
Sal Seed is an evergreen tree with a height of 30 to 50 meters.
The present invention relates to cosmetics containing Fat) or (and) its hydrogenated product. Ordinary vegetable oils contain a large amount of unsaturated acids such as oleic acid, linoleic acid, and linolenic acid, and therefore have problems in terms of oxidative stability. There are problems with cosmetics in general. Vegetable oils commonly used in cosmetics include olive oil, castor oil, soybean oil, avocado oil,
Although almond oil, camellia oil, and coconut oil all have a triglyceride structure,
The feel, physical properties, etc. vary greatly depending on the type, and are not always satisfactory. In addition, although vegetable oils mainly composed of saturated fatty acids such as coconut oil have good oxidation stability, they contain medium-chain fatty acids mainly composed of lauric acid, so they have problems with odor when decomposed, and they also have a poor texture. It also shows a slightly heavier tendency. As a result of research to improve the above-mentioned drawbacks, the present inventors discovered that the above-mentioned monkey fat has extremely excellent properties as a cosmetic oil and fat, and based on this, completed the present invention. The present invention will be explained below. The core of the Sarashu tree fruit has a water content of 4-20% and an oil content of 13-20%.
%, and since the oil content of the kernel is low, it is common to make it into fine particles and extract it with hexane. The obtained sal fat crude oil is a dark green oil with an acid value of 10-25 and a saponification value.
175-190, iodine value 33-40, unsaponifiable matter 1-3
%, melting point 30-40℃. By deacidifying, decolorizing, and deodorizing the crude oil in a conventional manner, white to pale yellow solid purified monkey fat can be obtained. Monkey fat is a non-sticky, refreshing oil that feels very good when applied to the skin. Monkey fat has a triglyceride structure like other vegetable oils, but most of the unsaturated fatty acids, which account for about 40%, are oleic acid, which gives it an advantage in terms of oxidation stability, and the saturated fatty acids also include palmitic acid and stearic acid. It is an acid, arachidic acid, and is advantageous in terms of stability and odor. Furthermore, as can be seen from the fatty acid composition, monkey fat is solid at room temperature, but because it has a melting point of 30 to 35 degrees Celsius, it quickly dissolves on the skin. Therefore, when monkey fat is added as an oily raw material to make-up cosmetics and basic cosmetics, the quality of the cosmetics is improved and the cosmetics have an excellent texture. Next, the cosmetics of the present invention will be explained with reference to Examples. Example 1 Manufacture of sal fat 100 kg of the fruit of the salin tree was crushed, extracted with n-hexane, and the solvent was removed to obtain 15.5 kg of dark green sal fat crude oil. The properties were an acid value of 17.5, a saponification value of 181.1, an iodine value of 35.4, an unsaponifiable matter of 1.7%, and a melting point of 34.7°C.
Next, 12.1 kg of purified monkey fat was obtained by degumming, alkali deoxidation, decolorization with clay and activated carbon, and steam deodorization. The properties of the purified monkey fat were as follows. Acid value 0.1 Peroxide value 0.0 Iodine value 38.3 Melting point (℃) 31.5 Saponification value 187.3 Unsaponifiable matter (%) 0.1 Fatty acid composition Palmitic acid 5.4% Stearic acid 45.2% Oleic acid 40.5% Linoleic acid 1.7% Arachidic acid 7.2% Examples 2. Production of hydrogenated monkey fat 1 kg of purified monkey fat obtained in Example 1 was placed in an autoclave with a Ni catalyst of 0.2% and a hydrogen pressure of 2.5 Kg/cm 2 .
Hydrogenation was carried out at 180°C for 30 minutes to obtain hydrogenated monkey fat with the following properties. Acid value 0.1 Peroxide value 0.0 Iodine value 17.1 Saponification value 187.1 Unsaponifiable matter (%) 0.1 Melting point (℃) 47.5 Fatty acid composition Palmitic acid 5.5% Stearic acid 69.2% Oleic acid 18.1% Arachidic acid 7.2% Example 3 Cleansing cream

【表】【table】

【表】 調製法 油性成分を加熱混合して65℃に保ち、それを予
め65℃に加熱してある精製水中に加え撹拌する。
香料を添加後、ホモゲナイザーで十分乳化してか
きまぜながら35℃まで冷却する。 実施例 4 エモリエントクリーム
[Table] Preparation method Heat and mix the oily ingredients and keep at 65℃, then add it to purified water that has been preheated to 65℃ and stir.
After adding the fragrance, thoroughly emulsify with a homogenizer and cool to 35°C while stirring. Example 4 Emollient cream

【表】 調製法 精製水にプロピレングリコールを加え、70℃に
保つ、他の成分を混合し加熱溶解し70℃とする。
この油相部を前述の水相部に加え予備乳化を行
い、ホモミキサーで均一に乳化し、熱交換器によ
り30℃まで冷却する。 実施例 5 エモリエントローシヨン
[Table] Preparation method Add propylene glycol to purified water and keep at 70℃. Mix other ingredients and heat to dissolve and bring to 70℃.
This oil phase is added to the aqueous phase described above for preliminary emulsification, uniformly emulsified using a homomixer, and cooled to 30°C using a heat exchanger. Example 5 Emollient lotion

【表】 調製法 精製水にグリセリンを加え、実施例4と同様に
してエモリエントローシヨンを調製した。 実施例 6 口 紅
[Table] Preparation method An emollient lotion was prepared in the same manner as in Example 4 by adding glycerin to purified water. Example 6 Lipstick

【表】 調製法 基剤原料を加熱融解し均一に混ぜる。これに色
材を加え、ロールミルで練り均一に分散させた
後、再融解して香料を加え、脱泡してから型に流
しこみ急冷して固める、固まつたものを型からと
り出し溶器に装填する。次にステイツクの外観を
整えてから炎の中を通し表面を均一にする。 実施例 7 ヘアーオイル
[Table] Preparation method Heat and melt the base raw materials and mix uniformly. Coloring material is added to this, kneaded in a roll mill to uniformly disperse it, then remelted, flavor added, defoamed, poured into a mold, rapidly cooled and solidified, the solidified material is removed from the mold and placed in a melting pot. to be loaded. Next, the appearance of the stick is adjusted and passed through a flame to make the surface even. Example 7 Hair oil

【表】 調製法 実施例3と同様にしてヘアーオイルを調製し
た。 実施例2〜7は、いずれも感触および酸化安定
性のすぐれた化粧品であつた。
[Table] Preparation method A hair oil was prepared in the same manner as in Example 3. Examples 2 to 7 were all cosmetics with excellent texture and oxidation stability.

Claims (1)

【特許請求の範囲】[Claims] 1 沙羅双樹の実から抽出により得られる油脂お
よびその水素添加物のいずれか一方あるいは両方
を含有することを特徴とする化粧料。
1. A cosmetic product characterized by containing one or both of an oil and fat obtained by extraction from the fruit of the Salamantha tree and its hydrogenated product.
JP59013492A 1984-01-30 1984-01-30 Cosmetic Granted JPS60158104A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59013492A JPS60158104A (en) 1984-01-30 1984-01-30 Cosmetic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59013492A JPS60158104A (en) 1984-01-30 1984-01-30 Cosmetic

Publications (2)

Publication Number Publication Date
JPS60158104A JPS60158104A (en) 1985-08-19
JPS627161B2 true JPS627161B2 (en) 1987-02-16

Family

ID=11834610

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59013492A Granted JPS60158104A (en) 1984-01-30 1984-01-30 Cosmetic

Country Status (1)

Country Link
JP (1) JPS60158104A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000319159A (en) * 1999-05-10 2000-11-21 Nonogawa Shoji Kk External preparation for skin

Also Published As

Publication number Publication date
JPS60158104A (en) 1985-08-19

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