JPS627161B2 - - Google Patents
Info
- Publication number
- JPS627161B2 JPS627161B2 JP59013492A JP1349284A JPS627161B2 JP S627161 B2 JPS627161 B2 JP S627161B2 JP 59013492 A JP59013492 A JP 59013492A JP 1349284 A JP1349284 A JP 1349284A JP S627161 B2 JPS627161 B2 JP S627161B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- oil
- fat
- cosmetics
- value
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002537 cosmetic Substances 0.000 claims description 11
- 235000013399 edible fruits Nutrition 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims 1
- 235000019197 fats Nutrition 0.000 description 16
- 241000282693 Cercopithecidae Species 0.000 description 11
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
- 239000005642 Oleic acid Substances 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- 235000015076 Shorea robusta Nutrition 0.000 description 4
- 229910052740 iodine Inorganic materials 0.000 description 4
- 239000011630 iodine Substances 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 238000007127 saponification reaction Methods 0.000 description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 description 4
- 239000008158 vegetable oil Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000003974 emollient agent Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000005457 triglyceride group Chemical group 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 244000166071 Shorea robusta Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 150000004667 medium chain fatty acids Chemical class 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/522—Antioxidants; Radical scavengers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
本発明は、主としてインド地方に群生、または
他種の森林にまじつて生えている沙羅双樹(Sal
Tree)と呼ばれる30〜50mの常緑の喬木の実
(Sal Seed)から抽出した油脂(サル脂Sal
Fat)または(および)その水素添加物を配合し
てなる化粧料に関する。
通常の植物油は、オレイン酸、リノール酸、リ
ノレン酸等の不飽和酸を多く含むため、酸化安定
性の面で問題がある。一般に化粧品の面で問題が
ある。一般に化粧品に使用される植物油は、オリ
ーブ油をはじめヒマシ油、大豆油、アボガド油、
アーモンド油、ツバキ油、ヤシ油等であるが、い
ずれもトリグリセリド構造を有しているものの、
その感触、物性等は種類により大きく異なり、必
ずしも満足のいくものではなかつた。
またヤシ油等の飽和脂肪酸主体の植物油は、酸
化安定性の面では良好なものの、ラウリン酸を主
体とした中鎖脂肪酸を含有しているため、分解時
の臭いの問題があり、また感触的にもやや重い傾
向を示す。
本発明者らは、上記の欠点を改良すべく研究の
結果、前記したサル脂が化粧用油脂として極めて
優れた特性を有することを見い出し、これに基づ
いて本発明を完成した。
以下に本発明を説明する。
沙羅双樹の実の核は水分4〜20%、油分13〜20
%で、採油は核の油分が低いのでこれを細粒にし
てヘキサン抽出するのが一般的である。得られた
サル脂原油は濃緑色の油で酸価10〜25、ケン化価
175〜190、ヨウ素価33〜40、不ケン化物1〜3
%、融点30〜40℃である。上記原油を通常の方法
で脱酸、脱色、脱臭することにより、白色ないし
淡黄色の固体状の精製サル脂が得られる。
サル脂はべたついた感じのない、さつぱりとし
た感触の油で皮膚に塗布すると非常に感じがよ
い。
サル脂は他の植物油と同様トリグリセリド構造
をもつているが40%程度を占める不飽和脂肪酸の
ほとんどがオレイン酸であることから酸化安定性
の面で有利であるとともに、飽和脂肪酸もパルミ
チン酸、ステアリン酸、アラキン酸であり、安定
性、臭いの面からも有利である。
また脂肪酸組成からも分る通りサル脂は常温で
は固体であるが、融点が30〜35℃であるため皮膚
上ですばやく溶解する。そのためメイクアツプ化
粧料、基礎化粧料にサル脂を油性原料として配合
すると化粧品の品質を改良し、感触のすぐれた化
粧品となる。
つぎに本発明の化粧料について、実施例により
説明する。
実施例 1
サル脂の製造
沙羅双樹の実100Kgを粉砕し、n−ヘキサンで
抽出後、脱溶剤して濃緑色のサル脂原油15.5Kgを
得た。性状は酸価17.5、ケン化価181.1、ヨウ素
価35.4、不ケン化物1.7%、融点34.7℃であつた。
次に脱ガム、アルカリ脱酸、白土、活性炭による
脱色後、水蒸気脱臭により精製サル脂12.1Kgを得
た。精製サル脂の性状は以下の通りであつた。
酸 価 0.1
過酸化物価 0.0
ヨウ素価 38.3
融点(℃) 31.5
ケン化価 187.3
不ケン化物(%) 0.1
脂肪酸組成 パルミチン酸 5.4%
ステアリン酸 45.2%
オレイン酸 40.5%
リノール酸 1.7%
アラキン酸 7.2%
実施例 2
水素添加サル脂の製造
実施例1で得た精製サル脂1Kgを3オートク
レーブに入れNi触媒0.2%、水素圧2.5Kg/cm2、
180℃の条件下で30分水素添加を行ない以下の性
状の水素添加サル脂を得た。
酸 価 0.1
過酸化物価 0.0
ヨウ素価 17.1
ケン化価 187.1
不ケン化物(%) 0.1
融点(℃) 47.5
脂肪酸組成 パルミチン酸 5.5%
ステアリン酸 69.2%
オレイン酸 18.1%
アラキン酸 7.2%
実施例 3
クレンジングクリーム
The present invention is directed to the Sal tree, which grows mainly in India in clusters or mixed with other species of forests.
Sal Seed is an evergreen tree with a height of 30 to 50 meters.
The present invention relates to cosmetics containing Fat) or (and) its hydrogenated product. Ordinary vegetable oils contain a large amount of unsaturated acids such as oleic acid, linoleic acid, and linolenic acid, and therefore have problems in terms of oxidative stability. There are problems with cosmetics in general. Vegetable oils commonly used in cosmetics include olive oil, castor oil, soybean oil, avocado oil,
Although almond oil, camellia oil, and coconut oil all have a triglyceride structure,
The feel, physical properties, etc. vary greatly depending on the type, and are not always satisfactory. In addition, although vegetable oils mainly composed of saturated fatty acids such as coconut oil have good oxidation stability, they contain medium-chain fatty acids mainly composed of lauric acid, so they have problems with odor when decomposed, and they also have a poor texture. It also shows a slightly heavier tendency. As a result of research to improve the above-mentioned drawbacks, the present inventors discovered that the above-mentioned monkey fat has extremely excellent properties as a cosmetic oil and fat, and based on this, completed the present invention. The present invention will be explained below. The core of the Sarashu tree fruit has a water content of 4-20% and an oil content of 13-20%.
%, and since the oil content of the kernel is low, it is common to make it into fine particles and extract it with hexane. The obtained sal fat crude oil is a dark green oil with an acid value of 10-25 and a saponification value.
175-190, iodine value 33-40, unsaponifiable matter 1-3
%, melting point 30-40℃. By deacidifying, decolorizing, and deodorizing the crude oil in a conventional manner, white to pale yellow solid purified monkey fat can be obtained. Monkey fat is a non-sticky, refreshing oil that feels very good when applied to the skin. Monkey fat has a triglyceride structure like other vegetable oils, but most of the unsaturated fatty acids, which account for about 40%, are oleic acid, which gives it an advantage in terms of oxidation stability, and the saturated fatty acids also include palmitic acid and stearic acid. It is an acid, arachidic acid, and is advantageous in terms of stability and odor. Furthermore, as can be seen from the fatty acid composition, monkey fat is solid at room temperature, but because it has a melting point of 30 to 35 degrees Celsius, it quickly dissolves on the skin. Therefore, when monkey fat is added as an oily raw material to make-up cosmetics and basic cosmetics, the quality of the cosmetics is improved and the cosmetics have an excellent texture. Next, the cosmetics of the present invention will be explained with reference to Examples. Example 1 Manufacture of sal fat 100 kg of the fruit of the salin tree was crushed, extracted with n-hexane, and the solvent was removed to obtain 15.5 kg of dark green sal fat crude oil. The properties were an acid value of 17.5, a saponification value of 181.1, an iodine value of 35.4, an unsaponifiable matter of 1.7%, and a melting point of 34.7°C.
Next, 12.1 kg of purified monkey fat was obtained by degumming, alkali deoxidation, decolorization with clay and activated carbon, and steam deodorization. The properties of the purified monkey fat were as follows. Acid value 0.1 Peroxide value 0.0 Iodine value 38.3 Melting point (℃) 31.5 Saponification value 187.3 Unsaponifiable matter (%) 0.1 Fatty acid composition Palmitic acid 5.4% Stearic acid 45.2% Oleic acid 40.5% Linoleic acid 1.7% Arachidic acid 7.2% Examples 2. Production of hydrogenated monkey fat 1 kg of purified monkey fat obtained in Example 1 was placed in an autoclave with a Ni catalyst of 0.2% and a hydrogen pressure of 2.5 Kg/cm 2 .
Hydrogenation was carried out at 180°C for 30 minutes to obtain hydrogenated monkey fat with the following properties. Acid value 0.1 Peroxide value 0.0 Iodine value 17.1 Saponification value 187.1 Unsaponifiable matter (%) 0.1 Melting point (℃) 47.5 Fatty acid composition Palmitic acid 5.5% Stearic acid 69.2% Oleic acid 18.1% Arachidic acid 7.2% Example 3 Cleansing cream
【表】【table】
【表】
調製法
油性成分を加熱混合して65℃に保ち、それを予
め65℃に加熱してある精製水中に加え撹拌する。
香料を添加後、ホモゲナイザーで十分乳化してか
きまぜながら35℃まで冷却する。
実施例 4
エモリエントクリーム[Table] Preparation method Heat and mix the oily ingredients and keep at 65℃, then add it to purified water that has been preheated to 65℃ and stir.
After adding the fragrance, thoroughly emulsify with a homogenizer and cool to 35°C while stirring. Example 4 Emollient cream
【表】
調製法
精製水にプロピレングリコールを加え、70℃に
保つ、他の成分を混合し加熱溶解し70℃とする。
この油相部を前述の水相部に加え予備乳化を行
い、ホモミキサーで均一に乳化し、熱交換器によ
り30℃まで冷却する。
実施例 5
エモリエントローシヨン[Table] Preparation method Add propylene glycol to purified water and keep at 70℃. Mix other ingredients and heat to dissolve and bring to 70℃.
This oil phase is added to the aqueous phase described above for preliminary emulsification, uniformly emulsified using a homomixer, and cooled to 30°C using a heat exchanger. Example 5 Emollient lotion
【表】
調製法
精製水にグリセリンを加え、実施例4と同様に
してエモリエントローシヨンを調製した。
実施例 6
口 紅[Table] Preparation method An emollient lotion was prepared in the same manner as in Example 4 by adding glycerin to purified water. Example 6 Lipstick
【表】
調製法
基剤原料を加熱融解し均一に混ぜる。これに色
材を加え、ロールミルで練り均一に分散させた
後、再融解して香料を加え、脱泡してから型に流
しこみ急冷して固める、固まつたものを型からと
り出し溶器に装填する。次にステイツクの外観を
整えてから炎の中を通し表面を均一にする。
実施例 7
ヘアーオイル[Table] Preparation method Heat and melt the base raw materials and mix uniformly. Coloring material is added to this, kneaded in a roll mill to uniformly disperse it, then remelted, flavor added, defoamed, poured into a mold, rapidly cooled and solidified, the solidified material is removed from the mold and placed in a melting pot. to be loaded. Next, the appearance of the stick is adjusted and passed through a flame to make the surface even. Example 7 Hair oil
【表】
調製法
実施例3と同様にしてヘアーオイルを調製し
た。
実施例2〜7は、いずれも感触および酸化安定
性のすぐれた化粧品であつた。[Table] Preparation method A hair oil was prepared in the same manner as in Example 3. Examples 2 to 7 were all cosmetics with excellent texture and oxidation stability.
Claims (1)
よびその水素添加物のいずれか一方あるいは両方
を含有することを特徴とする化粧料。1. A cosmetic product characterized by containing one or both of an oil and fat obtained by extraction from the fruit of the Salamantha tree and its hydrogenated product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59013492A JPS60158104A (en) | 1984-01-30 | 1984-01-30 | Cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59013492A JPS60158104A (en) | 1984-01-30 | 1984-01-30 | Cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60158104A JPS60158104A (en) | 1985-08-19 |
| JPS627161B2 true JPS627161B2 (en) | 1987-02-16 |
Family
ID=11834610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59013492A Granted JPS60158104A (en) | 1984-01-30 | 1984-01-30 | Cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60158104A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000319159A (en) * | 1999-05-10 | 2000-11-21 | Nonogawa Shoji Kk | External preparation for skin |
-
1984
- 1984-01-30 JP JP59013492A patent/JPS60158104A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60158104A (en) | 1985-08-19 |
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