JPS6317594B2 - - Google Patents
Info
- Publication number
- JPS6317594B2 JPS6317594B2 JP54016545A JP1654579A JPS6317594B2 JP S6317594 B2 JPS6317594 B2 JP S6317594B2 JP 54016545 A JP54016545 A JP 54016545A JP 1654579 A JP1654579 A JP 1654579A JP S6317594 B2 JPS6317594 B2 JP S6317594B2
- Authority
- JP
- Japan
- Prior art keywords
- abrasive grains
- rubber
- composite abrasive
- whetstone
- pores
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Polishing Bodies And Polishing Tools (AREA)
Description
本発明は、複合砥粒を用いたゴム弾性砥石とそ
の製法に係り、特に凹凸の激しい複雑な形態を有
する屈曲面加工において良好ななじみ性と、均一
な研摩加工に優れたものの提供に関する。
従来の弾性砥石には各種公知の可撓性、可弾性
の砥石が開発されて、その構造や素材など製法も
多様ではあるが、弾性砥石という字句から一般的
にゴム弾性またはプラスチツクフオームの如き弾
性を連想され、従来の弾性砥石もこれらと同一の
弾性を有するものと考えられがちであるが、回転
研摩具として用いられる弾性砥石は一般的に考え
られる弾性とは全くほど遠い所在の弾性砥石とな
つているため、凹凸の激しい複雑な形態を有する
屈曲面加工に用いられる適切な弾性砥石の開発が
急がれていた。
そこで、所望の気孔を有する柔軟なスポンジゴ
ムの如き弾性は、曲面加工用には全く好適な組織
構造であり、なじみ性追従の目的に適うものであ
るが、回転砥石として実用上使用条件に耐えうる
弾性限界と、しかも最も重要な課題は砥粒と多孔
性ゴム質との接合をうまく結合させることが見い
だせなかつたためである。
そこで本件発明者は、この重要な課題について
基礎的な実験を試みた結果、次のような結論を見
いだした。
すなわち、砥粒と多孔性ゴム質との結合方法に
おいて、先ず、化学的に見た場合無極性のゴム質
と、極性を有する砥粒とを結びつけるには、極性
部分と無極性部分との両方を備えた物質の介在が
必要であり、なおかつ、それに接着効果が優れた
物質でなければならないが、それらの物質がゴム
弾性を損なつたり、また、発泡を阻害するような
物質では目的を得ることができない。
このような相反する極性物質を強固に結びつけ
るには、砥粒の粒子が余りにも大きいだけに所望
の有機結合剤を見いだすことが困難であつた。
次に、物理的に接合するには適当数の砥粒がセ
ラミツク質焼結剤で塊状に集合し、気孔を生成し
た適当な大きさの顆粒となつた複合砥粒を先ず製
造し、そのものをゴムの練生地に加え、さらに、
発泡剤を添加して加圧、加硫工程によつて得られ
た多孔性ゴム質が該複合砥粒の気孔内に入り込
み、さらに、相溶性の良好なテルペン変性フエノ
ール樹脂をゴム100%に対し5ないし20%添加す
ることにより、砥粒とゴム質との“ぬれ”の改良
による接着性向上と若干ながらメチロール基によ
るゴム質の架橋ないしはゴム質との結合により一
層強固に結合することを見いだした。
これによつて、実用上使用条件に耐え得る従来
の弾性砥石とは全く異なつた複合砥粒を用いたゴ
ム弾性砥石の開発に成功したもので、この発明の
要旨について説明すると次のとおりである。
すなわち本発明の第一は、砥石の本体が、スポ
ンジ化された気孔組織のゴム弾性配合物に外表面
へ気孔を有する無機質複合砥粒を一体に結合して
なる複合砥粒を用いたゴム弾性砥石であり、さら
に第二は、適量のゴムに加硫剤、加硫促進剤、軟
化剤、無機質充填剤、テルペン変性フエノール樹
脂及び発泡剤等を入れ、これらのなかに外表面へ
気孔を有する無機質複合砥粒の適量を加えて混合
した練生地を加硫して発泡成形するか、もしくは
加硫発泡したのち砥石主体を成形することにより
該砥石主体をスポンジ化された気孔組織のものと
する複合砥粒を用いたゴム弾性砥石の製法であ
る。
なお、本発明における無機質複合砥粒とは、適
当数の砥粒に無機質結合剤の適量と、焼成によつ
て気孔を形成する気孔生成剤とを加え焼成して、
前記結合剤の外表面等へ多数の気孔を備えてなる
適当な粒径の顆粒(塊状集合体)になつているも
のを指称したものであり、さらに、ここで無機質
結合剤としたのは、複合砥粒に有機質結合剤を用
いると、有機薬品(硬化剤、促進剤)が原因で砥
石本体の発泡を阻害し、スポンジ化されず、ま
た、複合砥粒を顆粒状に製造するためのコストが
高くなるためである。
前記した本発明の各要旨において、砥粒に気孔
を有した無機質複合砥粒とするとともに、砥石本
体をスポンジ化された連続気孔組織のものとした
のは、このようにすると次のような優れた作用効
果が期待できるようになるからである。
(1) 外表面に気孔を備えた無機質複合砥粒を用い
たので、砥石成形の際テルペン変性フエノール
樹脂の介在により前記複合砥粒の気孔内にゴム
弾性配合物が入り込みやすく、かつ、加硫と相
俟つて複合砥粒へ入り込んだゴム弾性配合物が
相互一体のものとなり、砥粒とゴム質との結合
力が非常に強固で、使用中に脱離して飛散する
虞れがなくなる。
(2) 砥石本体がスポンジ化された連続気孔組織の
ものになつているので、クツシヨン性に優れ、
屈曲面へのなじみ性追従が理想的なものとな
る。
また、反発弾性に優れたものとなるので、砥
材が粗であつても被研摩物へのあたりがソフト
で均一な研摩面とともに良好な仕上面を得るこ
とができる。
(3) 連続気孔組織による多孔性となつているた
め、放熱効果に優れていて研摩焼けや目詰まり
などの発生が起こらない。
(4) 多孔性特有のクツシヨン効果により、使用時
に振動や抵抗等が少いので、作業員が疲労感の
ない快適な研摩作業をすることができるととも
に、使用中砥石に接触しても負傷する等の危険
性がない。
上記したこの発明の要旨を明白にするととも
に、この発明の構成と効果を具体的に説明するた
め、この発明による複合砥粒を用いたゴム弾性砥
石の一実施例をあげて詳述すると次のとおりであ
る。
なお、本発明は下記実施例のものに限定される
ものでないことは申すまでもない。
すなわち、出願人が先に開発し特願昭53―
69665号(特公昭56―52714号)で開示したところ
の適量の砥粒に、無機質結合剤の適量と、焼成に
より気孔を形成する気孔生成剤の適量とを加え、
適当な粒径の顆粒とし、これを焼成して、結合剤
の外表面等へ多数の気孔を備えてなる無機質複合
砥粒と、ゴム弾性配合物とを下記配合比(いずれ
も重量比)にして混合しよく混練した。
The present invention relates to a rubber elastic grindstone using composite abrasive grains and a method for manufacturing the same, and particularly to providing a grindstone that has good conformability and excellent uniform polishing when processing curved surfaces having complex shapes with severe irregularities. Various known flexible and elastic grindstones have been developed as conventional elastic grindstones, and although their structures and materials are manufactured in a variety of ways, the term "elastic grindstone" generally refers to rubber-elastic or elastic grindstones such as plastic foam. It is often thought that conventional elastic whetstones have the same elasticity as these, but the elastic whetstones used as rotary abrasive tools have an elasticity that is far from what is commonly thought of. Therefore, there was an urgent need to develop an elastic grindstone suitable for machining curved surfaces with highly uneven and complex shapes. Therefore, an elastic material such as a flexible sponge rubber with desired pores has a completely suitable structure for curved surface machining and is suitable for the purpose of following the conformability, but it cannot withstand the conditions of practical use as a rotary grindstone. The most important problem is that it has not been possible to find a good bond between the abrasive grains and the porous rubber material. Therefore, the inventor of the present invention conducted basic experiments regarding this important issue and found the following conclusion. That is, in the method of bonding abrasive grains and porous rubber, first, in order to bond a chemically non-polar rubber with a polar abrasive, both the polar and non-polar parts must be bonded. It is necessary to use a substance that has the following characteristics, and the substance must have an excellent adhesive effect.However, if such a substance impairs rubber elasticity or inhibits foaming, the purpose cannot be achieved. I can't. It has been difficult to find a desired organic binder to firmly bind such contradictory polar substances because the particles of the abrasive grains are too large. Next, in order to physically join, an appropriate number of abrasive grains are aggregated into a lump using a ceramic sintering agent to form granules of an appropriate size with pores. In addition to the rubber dough,
The porous rubber obtained through the pressurization and vulcanization process with the addition of a foaming agent enters the pores of the composite abrasive grains, and the terpene-modified phenol resin with good compatibility is added to the 100% rubber. It has been found that by adding 5 to 20% of the abrasive grains, the adhesion is improved by improving the "wetting" between the abrasive grains and the rubber material, and the bond is slightly stronger due to the crosslinking of the rubber material or the bonding with the rubber material by the methylol group. Ta. As a result, we succeeded in developing a rubber elastic grindstone using composite abrasive grains that is completely different from conventional elastic grindstones and can withstand practical use conditions.The gist of this invention is as follows. . That is, the first aspect of the present invention is that the main body of the grinding wheel is made of a rubber-elastic compound using composite abrasive grains, which is made by integrally bonding inorganic composite abrasive grains having pores on the outer surface to a rubber-elastic compound having a spongy pore structure. The second type is a grindstone, in which a suitable amount of rubber is mixed with a vulcanizing agent, a vulcanization accelerator, a softening agent, an inorganic filler, a terpene-modified phenolic resin, a blowing agent, etc., and there are pores on the outer surface. The dough mixed with an appropriate amount of inorganic composite abrasive grains is vulcanized and foam-molded, or after vulcanization and foaming, the grinding wheel itself is formed into a spongy pore structure. This is a method for manufacturing rubber elastic grindstones using composite abrasive grains. Note that the inorganic composite abrasive grains in the present invention are obtained by adding and firing an appropriate amount of an inorganic binder and a pore-forming agent that forms pores to an appropriate number of abrasive grains, and
This term refers to the binder that has a large number of pores on its outer surface, etc., and is in the form of granules (agglomerates) of a suitable particle size. Furthermore, the inorganic binder here is: If an organic binder is used for composite abrasive grains, the organic chemicals (hardening agent, accelerator) will inhibit the foaming of the whetstone body, preventing it from becoming spongy, and the cost of manufacturing the composite abrasive grains in granular form will increase. This is because the amount increases. In each of the above-mentioned aspects of the present invention, the abrasive grains are made of inorganic composite abrasive grains with pores, and the main body of the whetstone is made of a spongy continuous pore structure. This is because the effects can be expected. (1) Since inorganic composite abrasive grains with pores on the outer surface are used, the rubber elastic compound easily enters into the pores of the composite abrasive grains due to the intervention of terpene-modified phenolic resin when forming the abrasive stone, and the vulcanization process Together with this, the rubber elastic compound that has entered the composite abrasive grains becomes one with each other, and the bonding force between the abrasive grains and the rubber material is very strong, eliminating the risk of them coming off and scattering during use. (2) The main body of the whetstone has a spongy continuous pore structure, so it has excellent cushioning properties.
The conformability to curved surfaces is ideal. In addition, since it has excellent rebound resilience, even if the abrasive material is rough, it is possible to obtain a soft, uniform polished surface and a good finished surface even if the abrasive material is rough. (3) Since it is porous due to its continuous pore structure, it has excellent heat dissipation effects and does not cause polishing burns or clogging. (4) Due to the cushioning effect unique to the porous material, there is little vibration or resistance during use, allowing workers to perform comfortable polishing work without feeling fatigued, and also preventing injury if they come into contact with the grindstone during use. There is no such danger. In order to clarify the above-mentioned gist of the present invention and to specifically explain the structure and effects of the present invention, an example of a rubber elastic grindstone using composite abrasive grains according to the present invention will be described in detail as follows. That's right. It goes without saying that the present invention is not limited to the following examples. In other words, the applicant first developed the patent application in 1973.
69665 (Japanese Patent Publication No. 56-52714), by adding an appropriate amount of an inorganic binder and an appropriate amount of a pore-forming agent that forms pores by firing,
The granules are made into granules of an appropriate particle size, which are fired, and the inorganic composite abrasive grains having a large number of pores on the outer surface of the binder and the rubber elastic compound are mixed in the following compounding ratio (all weight ratios). The mixture was mixed and kneaded well.
【表】【table】
【表】
上記のようにした練生地を適当な大きさに破砕
するか又は適当な厚さのシート状のものを砥石大
にカツトして金型の中に入れ、139℃の温度で一
次加硫を行なつた後、更にこれを二次金型に移行
して160℃の温度で二次加硫を施こすと発泡倍率
2.4倍のクツシヨン性に優れた平板状の複合砥粒
を用いたゴム弾性砥石となつた。
以上のようにして製造された複合砥粒を用いた
ゴム弾性砥石は、前記した数々の優れた効果を有
したものとなつて、回転研摩具として実用性を具
備し、該ゴム弾性砥石を実際に使用したところ従
来予測し得なかつた顕著な効果を発揮した。
よつてその効果の一例を示すと次のとりであ
る。
碗、皿などの陶磁器は焼成工程において融着防
止の観点から無釉の素地部を有しており、従来は
該素地部を手作業によつて後加工(研摩加工)を
施しているが、肉厚の薄い陶磁器を従前の弾性の
乏しい砥石で圧接加工を施す作業は陶磁器の破損
によつて起こる人体への危険性と、曲面へのなじ
み性がないので研摩加工も不充分であること、及
び研摩粉塵の発生が多いことなどにより作業者が
忌避する工程である。
前記実施例の複合砥粒を用いたゴム弾性砥石
を、従前の研摩手作業方法で従来使用されていた
弾性砥石とを比較したところ下表のような優れた
効果が確認できた。[Table] Crush the kneaded dough as described above into suitable sizes, or cut sheets of suitable thickness into grindstone-sized pieces, place them in a mold, and perform primary processing at a temperature of 139°C. After vulcanization, this is transferred to a secondary mold and subjected to secondary vulcanization at a temperature of 160℃, which increases the foaming ratio.
This is a rubber elastic grindstone that uses flat composite abrasive grains that have 2.4 times better cushioning properties. The rubber elastic grindstone using the composite abrasive grains produced as described above has many of the excellent effects described above, and is practical as a rotary abrasive tool. When used for this purpose, it exhibited remarkable effects that could not have been predicted previously. Therefore, an example of this effect is as follows. Ceramics such as bowls and plates have an unglazed base part to prevent fusion during the firing process, and conventionally, the base part is post-processed (polished) by hand. Pressure welding of thin ceramics using conventional grindstones with poor elasticity poses a danger to the human body due to damage to the ceramics, and the grinding process is also insufficient because it does not conform to curved surfaces. This is a process that workers avoid because it generates a lot of abrasive dust. When the rubber elastic grindstone using the composite abrasive grains of the above example was compared with the elastic grindstone conventionally used in the conventional manual polishing method, excellent effects as shown in the table below were confirmed.
【表】【table】
【表】
又従前の弾性砥石を用いて作業環境の改善とコ
スト高に悩む前記工程の陶磁器自動研摩化とを、
従来幾度となく試みられたことがあつたが、上表
によつて明白なように様々な欠点と自動化に対応
できる適切な砥石の開発が自動研摩機の実現を遅
らす原因となつていた。
ここに発泡倍率2.4倍の前記した本願発明によ
るゴム弾性砥石の開発によつて自動研摩が可能と
なり、生産性も従来の手作業による場合350個/
時に対して700乃至800個/時と大幅に加工生産が
向上し、研摩仕上り面も従前のものと比較になら
ないほどの優れた好結果を得るようになつた。
また発泡倍率を変化させることにより、なじみ
性及び研摩性も変化し、上記陶磁器研摩以外に例
えば木目の浮き彫り加工やステンレス鋼板の切削
において、前者は焦げが生ずることなく木目の立
体感をリアルに表出でき、後者はバリ状の切削屑
の発生がなくシヤープな切れ味を示すなど良好な
切削効果が確認できた。
なお、この発明において無機質複合砥粒、ゴム
弾性配合物の夫々成分や砥石主体の成形ならびに
加硫方法などは、この発明の前記した目的と上記
した作用効果の達成される範囲内において夫々適
当に定められてよいことは申すまでもない。
上述の説明によつて明白となるように、この発
明によれば従前の弾性砥石に関し生じている欠点
がきわめて簡易且つ効果的に改善されるととも
に、砥粒の粒度と顆粒粒径を加工用途に応じて
夫々適当な発泡倍率の選択により、極めて広汎に
わたり使用することができるものとなるので、こ
の発明によつてもたらされる実益は大きいと申さ
ねばならない。[Table] In addition, we have improved the work environment using conventional elastic grindstones and automated ceramic polishing, which is a process that suffers from high costs.
Many attempts have been made in the past, but as is clear from the table above, various drawbacks and the development of an appropriate grinding wheel that can be automated have delayed the realization of an automatic polishing machine. The development of the rubber elastic grindstone according to the present invention, which has a foaming ratio of 2.4 times, has made automatic grinding possible, and the productivity has been reduced to 350 pieces/grinding compared to conventional manual grinding.
Processing production has significantly improved to 700 to 800 pieces per hour, and the polished surface has achieved excellent results that are incomparable to previous models. In addition, by changing the foaming ratio, the conformability and abrasiveness also change, and in addition to the above-mentioned ceramic polishing, the former can realistically express the three-dimensional effect of the wood grain without causing burns, for example, in embossing the wood grain or cutting stainless steel plates. The latter showed a good cutting effect, with no burr-like cutting debris and sharp cutting ability. In addition, in this invention, the respective components of the inorganic composite abrasive grains and rubber elastic compound, as well as the molding and vulcanization method of the grinding wheel, etc., may be appropriately selected within the scope of achieving the above-mentioned objectives and the above-mentioned effects of this invention. Needless to say, it is fine to have such regulations. As will become clear from the above description, according to the present invention, the drawbacks of conventional elastic grinding wheels can be very easily and effectively improved, and the particle size and granule size of the abrasive grains can be adjusted to suit processing purposes. It must be said that the practical benefits brought about by this invention are great because it can be used in a very wide range by selecting an appropriate expansion ratio.
Claims (1)
ゴム弾性配合物に外表面へ気孔を有する無機質複
合砥粒を一体に結合してなることを特徴とする複
合砥粒を用いたゴム弾性砥石。 2 適量のゴムに加硫剤、加硫促進剤、軟化剤、
無機質充填剤、テルペン変性フエノール樹脂及び
発泡剤等を入れ、これらのなかに外表面へ気孔を
有する無機質複合砥粒の適量を加えて混合した練
生地を加硫して発泡成形するか、もしくは加硫発
泡したのち砥石主体を成形することにより該砥石
主体をスポンジ化された気孔組織のものとするこ
とを特徴とする複合砥粒を用いたゴム弾性砥石の
製法。[Scope of Claims] 1. Composite abrasive grains characterized in that the main body of the whetstone is formed by integrally bonding inorganic composite abrasive grains having pores on the outer surface to a rubber elastic compound having a sponge-like pore structure. Rubber elastic grindstone used. 2 Add a vulcanizing agent, a vulcanization accelerator, a softening agent to an appropriate amount of rubber,
An inorganic filler, a terpene-modified phenolic resin, a foaming agent, etc. are added thereto, and an appropriate amount of inorganic composite abrasive grains having pores on the outer surface are added thereto, and the mixed dough is vulcanized and foam-molded, or vulcanized. A method for producing a rubber elastic grindstone using composite abrasive grains, which comprises foaming the whetstone with sulfur, and then molding the main body of the whetstone, thereby making the main body of the whetstone have a spongy pore structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1654579A JPS55112773A (en) | 1979-02-15 | 1979-02-15 | Elastic grinding rubber using composite abrasive particle and its manufaxturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1654579A JPS55112773A (en) | 1979-02-15 | 1979-02-15 | Elastic grinding rubber using composite abrasive particle and its manufaxturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55112773A JPS55112773A (en) | 1980-08-30 |
| JPS6317594B2 true JPS6317594B2 (en) | 1988-04-14 |
Family
ID=11919225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1654579A Granted JPS55112773A (en) | 1979-02-15 | 1979-02-15 | Elastic grinding rubber using composite abrasive particle and its manufaxturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55112773A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62173175A (en) * | 1986-01-23 | 1987-07-30 | Daiwa Kasei Kogyo Kk | Rotary elastic abrasive stone |
| JPH01210500A (en) * | 1988-02-17 | 1989-08-24 | Imari Denso Kiki:Kk | Material capable of removing foreign matter adhering to vehicle outside plate |
| JP4555580B2 (en) * | 2004-01-19 | 2010-10-06 | 旭ダイヤモンド工業株式会社 | Super abrasive wheel for precision grinding of hard and brittle materials, method for producing the same, and grinding method using the super abrasive wheel |
-
1979
- 1979-02-15 JP JP1654579A patent/JPS55112773A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55112773A (en) | 1980-08-30 |
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