JPS6317868B2 - - Google Patents

Description

[Detailed description of the invention]

The present invention relates to novel pigments, more specifically, pigments produced by reacting clay minerals with divalent or trivalent metals and metal compounds, and then reacting this reaction product with organic pigments, and cosmetics containing the pigments. This is related to fees. The main purpose of the present invention is to develop a new colorant that exhibits the original color tone of organic pigments, has excellent PH resistance, light resistance, and dispersibility, and is suitable as a coloring agent for various products such as various cosmetics, printed packaging materials, paints, plastics, and ceramics. The goal is to provide pigments. Furthermore, another object of the present invention is to provide cosmetics having various quality characteristics by containing the above-mentioned novel pigments. Conventionally, commonly used organic dyes, especially tar dye aluminum lakes such as Yellow No. 4, Yellow No. 5, Blue No. 1, etc., have been used in various products due to their advantages, but due to the structure of the dye itself, there are some Although there are differences, it is difficult to obtain the original color tone of organic dyes because they tend to elute in water and oil agents, causing migration (color migration), and furthermore, the water contained in tar dye lakes can cause a large amount of damage to the product. This tends to impair dispersibility in the system and cause flocculation and aggregation, resulting in problems such as unstable color tone and difference between external color and coating color. Furthermore, in recent years, the safety of tar dyes has become more important than their usefulness, and the number of tar dyes that can be put to practical use is extremely limited. On the other hand, when cosmetics containing tar pigments, especially make-up cosmetics, are exposed to direct sunlight containing ultraviolet to infrared rays or indoor lighting while the cosmetics are applied to the skin when going out, the tar pigment is unstable to light. This tends to cause discoloration or fading, which significantly impairs the cosmetic appearance.
In addition, tar pigments are insufficiently laked, which causes staining of the skin or application materials (sponge puffs, etc.). Other disadvantages of using tar pigments include that when the concentration used in cosmetics reaches 2% or more, it lacks spreadability and has a lot of unevenness when applied to the skin. In addition to impairing the cosmetic effect, it is necessary to limit the concentration used to avoid this disadvantage, but it has been difficult to obtain a wide range of color tones. In order to eliminate the drawbacks of tar pigments as described above and to obtain pigments with unprecedented characteristics, the inventors have conducted extensive experiments, research, and creations, and have found that clay minerals, specific metals, and metals The inventors have discovered that a new clay mineral composite pigment obtained by first reacting a compound with an organic pigment and then reacting it with an organic pigment can certainly satisfy these conditions, and have thus arrived at the present invention. That is, the main objectives of the present invention are as follows: (1) Application to general products There is no need to worry about leaching into water or oil agents, it has excellent PH resistance, and the color tone inherent to organic dyes can be obtained. It has good dispersibility in the system, and there is no flocculation or aggregation. Therefore, the color tone is stable, and there is no difference between the external color and the coating color. (2) Application to cosmetics Good photostability and no risk of discoloration or fading. Does not stain the skin or the body to which it is applied. There are no restrictions on the concentration of use, and excellent cosmetic effects can be obtained. The purpose is to provide a pigment with the following characteristics, and its composition is clay mineral, divalent or trivalent metal, and metal compound, and if necessary, in addition to these, a basicity regulator is added at a ratio of 5:1:1.5 to 1:1. 9: React in the range of 20.0, then add organic dye to this reaction product in 1:
Pigment obtained by reacting in the range of 0.01 to 1:3.0,
The present invention also relates to cosmetics containing the pigment. The clay mineral that serves as the starting material in the present invention may be a normal natural untreated clay mineral, but it may be treated with an alkali containing a small amount of organic or inorganic deflocculant (gelling agent) or by acid treatment. The present invention can be made extremely effective. Specific clay minerals applicable to the present invention include kaolionite, nacrite,
Kaolin group clay minerals such as detsuite, halloysite, metahalloysite, montmorillonite group clay minerals such as montmorillonite, beidellite, nontronite, saponite, acid clay, Fuller's earth, bentonite, zeolite, sericite, pyrophyllite, hectorite, bar Illite group clay minerals such as miquiulite, prabellite, illite, phyllite, muscovite, sericite, red mica, phlogopite, lithian mica (lepidolite), leader mica, Chinwald mica,
It is a type of mica such as halide mica and synthetic mica, and has an average particle size of 0.01 to 50μ, but has good reactive bonding.
Illite group clay minerals are preferable because they are significantly superior to other clay minerals in that they do not require water washing, have a wide range of PH resistance, and are highly stable. The alkali used when treating clay minerals with alkali is an inorganic alkali agent such as sodium hydroxide or potassium hydroxide, and the deflocculant added in a small amount to this alkaline agent is an organic acid such as oxalic acid or Particularly preferred are those that dissociate oxalate ions, such as sodium and sodium hydrogen oxalate; examples of inorganic acids include phosphoric acid, sodium phosphate, disodium hydrogen phosphate, sodium dihydrogen phosphate, sodium ammonium hydrogen phosphate, and potassium phosphate. , dipotassium hydrogen phosphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate, and the like which dissociate phosphate ions are preferred. Examples of acids used when acid-treating clay minerals include inorganic acids such as hydrochloric acid, sulfuric acid, and nitric acid.
When such alkali treatment or acid treatment is performed, silica-based impurities, inorganic salts, and iron in the clay mineral can be removed, and the adsorption capacity can be improved, making it suitable for the purpose of the present invention. It also has the effect of expressing itself. The metals and metal compounds used in the present invention include one or more divalent or trivalent metals, preferably metal aluminum, aluminum hydroxide, aluminum sulfate, aluminum chloride, and sodium aluminate. Aluminum compounds such as , calcium aluminate, and barium aluminate are mentioned because of their excellent safety and reactivity, but iron, iron hydroxide, ferrous chloride, ferric chloride, ferrous sulfate, and sulfuric acid Iron compounds such as ferric iron, ferrous nitrate, and ferric nitrate, barium metal, and barium compounds such as barium hydroxide, barium sulfate, barium bromide, barium chloride, barium nitride, and barium carbonate, calcium metal, and hydroxide. Calcium, calcium compounds such as calcium chloride, calcium bromide, calcium sulfate, calcium carbonate, calcium nitrate, magnesium metal and magnesium compounds such as magnesium hydroxide, magnesium chloride, magnesium sulfate, magnesium carbonate, zirconium metal and zirconium chloride, bromide Zirconium and the like are also used. (In the case of a single metal, powder is usually used, but it also includes blocks and other various shapes.) In the present invention, a base is used to adjust the reaction between the clay mineral and the above-mentioned metals and metal compounds. A strength adjusting agent can be used. Such basicity regulators include alkali metal compounds such as sodium hydroxide, sodium carbonate, potassium hydroxide, potassium carbonate, lithium hydroxide, etc. or alkaline earth metal compounds such as magnesium hydroxide, magnesium carbonate, calcium hydroxide, etc. Calcium chloride, calcium carbonate, etc., other complex salts such as dolomite, magnesium hydroxide carbonate, etc., inorganic acids such as hydrochloric acid, nitric acid, etc. are selected as necessary. As mentioned above, calcium compounds and magnesium compounds can be used either as metal compounds or as basicity regulators in the reaction system with clay minerals, depending on the conditions. What should be noted in the present invention is that this basicity regulator may be used separately from the above-mentioned metals and metal compounds for the clay mineral that is the starting material, or it may be reacted with the above-mentioned metals and metal compounds in advance. It may also be used in the form of a basic metal compound that is polymerized. A higher basicity is preferable in consideration of ease of reaction in the aqueous solution of the present invention, but specifically, a range of basicity of 35 to 70% is preferable. Examples of organic dyes that are the third element applied to the present invention include tar dyes such as Red No. 104 (1), Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, and Blue No. 2.
No., Red No. 201, Red No. 227, Red No. 230 (1), Orange No. 206, Orange No. 207, Yellow No. 202 (1), Green 201
No., Green No. 204, Blue No. 201, Green No. 205, etc.
Natural pigments include calsamine, latukaic acid, brasilyl carminate, crocin, and the like. Next, the method for producing the novel pigment of the present invention will be described in detail. First, regarding the case of alkali treatment or acid treatment of clay minerals, 0.01 to 5.0% by weight of sodium hydroxide containing a small amount (0.01 to 0.5 parts) of an organic or inorganic peptizer per 1.0 part of clay minerals,
After adding 15 to 100 parts of an alkaline solution such as potassium hydroxide and stirring at 50 to 100°C for 15 minutes to 5 hours,
The supernatant liquid is removed, and clay minerals treated with alkali are obtained by repeatedly drying through filtration and water washing, or 20 to 100 parts of an inorganic acid such as hydrochloric acid, sulfuric acid, or nitric acid at 0.01 to 5% by weight per 1.0 part of clay minerals. Add and stir at room temperature for 15 minutes to 5 hours, remove the supernatant liquid,
An acid-treated clay mineral can be obtained by repeating filtration, washing with water, and drying. Method 1 Clay mineral (untreated), alkali-treated clay mineral,
Add 0.01 to 8.0 parts of one or more clay minerals selected from acid-treated clay minerals (methods 2 to 4 are the same below as described for clay minerals) to 3.5 to 8.0 parts of a mixed solution of a metal compound and a basicity regulator. 25 to 50 degrees Celsius.
Hold at °C and react with clay minerals to create a polymerized basic metal compound base. then a concentration of 0.1-10.0%,
Gradually inject 1 to 50 parts of an organic dye solution adjusted to 25 to 50°C to 1.0 part of this reaction base with stirring, and stir at 25 to 50°C, preferably 30 to 40°C, for 2 minutes to 2 hours. After that, it is filtered and dried to obtain the pigment targeted by the present invention. Method 2 A slurry of 1.0 part of the metal compound and 2.5 to 4.0 parts of purified water is placed in a reactor, and 1.9 to 3.3 parts of the inorganic acid are gradually added while stirring. The reactor is then held at 100-150°C for 0.5-5 hours to completely dissolve the metal compound. Then, gradually add 0.1 to 4.0 parts of clay mineral to completely disperse it, and add 2.5 parts of basicity regulator.
Add ~3.5 parts more slowly with stirring. After the addition is completed, the mixture is maintained at 25 to 50°C for 1 to 5 hours to obtain a clay mineral reaction polymerized basic metal compound base. The pigment targeted by the present invention is obtained in the same manner as in Method 1 below. Method 3: Add 10 to 15 parts of purified water to 1.0 part of the metal compound and dissolve in a reactor, then gradually add 0.1 to 5.0 parts of clay mineral to completely disperse and dissociate the acid that functions as a basicity regulator. 100-200℃
While introducing a certain amount of steam and maintaining the temperature at 100-150℃, add 1-3% of hydrophilic active agent (POE sorbitan fatty acid ester such as POE sorbitan monooleate, POE sorbitan triolate, POE sorbitol monolaurate, etc.). POE sorbitol fatty acid ester) treated with aqueous solution (0.1-3.0)
Gradually add 1.0 to 5.0 parts of the prepared metal (powder) to this,
The mixture is allowed to react for 0.5 to 5 hours, and after confirming that the metal (powder) is completely dissolved, it is cooled and then maintained at 25 to 50°C to obtain a clay mineral reaction polymerized basic metal compound base. The pigment targeted by the present invention is obtained in the same manner as in Method 1 below. Method 4 Add 0.01 to 4.0 parts of the polymerized basic metal compound itself to 0.01 to 2 parts of clay mineral and charge it into a reactor.
Introduce steam at about 100 to 200℃ and heat the reaction from 1 to
After 10 hours, the reactor is cooled and maintained at 25-50°C, and the clay mineral reaction polymerizes to produce a basic metal compound base. The pigment targeted by the present invention is obtained in the same manner as in Method 1 below. In order to improve the dispersibility of the pigment in particular into various products containing oily bases, the pigment of the present invention may be further added to oily silicone oils, metal soaps, higher fatty acids, fats and oils, etc.
Lipophilic treatment can be performed using one or more coating agents selected from higher alcohols, hydrocarbons, and the like. Such a lipophilic treatment method using a coating agent involves dispersing the pigment of the present invention in purified water, adding a solvent in which the coating agent is dissolved in an organic solvent, mixing and stirring,
The lipophilized pigment of the present invention is removed in water and the organic solvent is distilled off, and then dried at 40 to 60°C, and then heated to 65 to 100°C.
A method of performing baking treatment for 1 to 24 hours is suitable. Pigments that have been made lipophilic with such a coating agent are coated with a strong thin film that makes them lipophilic, so they can be used in cosmetics, plastics, containers, etc.
Needless to say, it is easily dispersed in various products such as packaging materials. To describe in detail the coating agent (oleophilic treatment agent) applied to the above pigments, oil-soluble silicone oils include polydimethylsiloxane, methylhydrodiene polysiloxane, methylphenyl silicone, modified silicone, and methylchlorinated silicone oil. enylsilicone and organopolysiloxane with a polymerization degree of 0 to 2500. Examples of metal soaps include aluminum laurate, aluminum myristate, aluminum oleate, magnesium laurate, magnesium myristate, magnesium palmitate, and stearin. magnesium acid, magnesium oleate, enene laurate, zinc myristate, enene palmitate, enene stearate, enene oleate, and higher fatty acids may be any linear, branched, saturated, or unsaturated fatty acids, such as caproic acid. , capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linoleic acid, lanolin fatty acid, lignoceric acid, cerotic acid, montanic acid,
Oils and fats such as melisic acid and isostearic acid include olive oil, almond oil, peanut oil, avocado oil, castor oil, cacao butter, coconut oil, cottonseed oil,
Palm oil, sesame oil, hydrogenated wood wax oil, hydrogenated castor oil, rice oil, carrot oil, etc. Waxes include beeswax, carnauba wax, gay wax, etc. Higher alcohols include cetanol, stearyl alcohol, lanolin alcohol, olive alcohol,
Batyl alcohol, etc., and hydrocarbons include squalane, squalene, liquid paraffin,
Vaseline, solid paraffin, ozokerite, ceresin, microcrystalline wax, etc.Esters include isopropyl myristate, isopropyl palmitate, myristyl myristate, sucrose fatty acid ester, myristyl palmitate, cetyl palmitate, stearic acid. Ethyl, ethylene glycol distearate, etc. Further, the volatile organic solvents used in the production by the above method may be common ones such as isopropyl alcohol, xylol, ethyl alcohol, hexane, toluene, octane, chloroform, ethyl acetate, acetone, and benzene. Here, to describe in more detail the method for producing the lipophilized pigment of the present invention, a coating agent dissolved in an organic solvent is added to the pigment of the present invention (untreated to be lipophilized) 1 dispersed in purified water. Mix and dissolve to a concentration of 0.1 to 10% by weight (if necessary, add sorbitan fatty acid ester, POE sorbitan fatty acid ester, POE sorbitol fatty acid ester, P.
Oil-soluble activators such as EO fatty acid ester, POE higher alcohol ether, P, OE alkyl allyl ether, glycerin monofatty acid ester, etc. 0.1~
You may mix and dissolve about 3%. ) After stirring and mixing for 5 to 180 minutes, water is removed and the organic solvent is distilled off, the coated (lipophilized) pigment is taken out, dried at 40 to 60°C, and then heated at 65 to 100°C for 1 to 24 hours. Baking is performed to obtain a new pigment with a coating agent (oleophilic agent) fixed thereon. A coating agent with a thickness of about 0.1 to 10 μm is formed on the pigment obtained in this way, which not only protects the pigment itself, but also makes the pigment surface completely lipophilic and improves its dispersibility in oily bases. It is better than . By the way
The degree of adhesion of the coating agent was measured by passing it through a pulverizer at 18,000 rpm three times, and as a result, no change in the degree of lipophilicity was observed. The pigment of the present invention obtained as described above (which has been subjected to lipophilic treatment) is first produced by a reaction between a clay mineral and a specific metal or metal compound, so that a base is formed in a polymerized form on the surface layer of the clay mineral. The polymerized basic metal compound acts as a medium through the second reaction between the organic dye and the reaction layer, and the polymerized basic metal compound acts as a medium to separate the clay mineral, the polymerized basic metal compound, and the organic dye. The three layers behave as a strong bond (by the way, in the case of a simple mixture of clay minerals, metals or metal compounds, and organic dyes, the dyes are liberated because each of the three components is adsorbed in an incomplete state in the system). It is of no practical use at all.)
In addition, it is brittle and easy to unravel, and is dispersed with a slight amount of force, making it suitable as a coloring agent for cosmetics, plastics, paints, containers and packaging, etc., and is completely free from migration and bleed in each system. , which prevents water tearing and has excellent PH resistance, improves color stability and exhibits the original color tone of organic pigments, and has strong adhesion of organic pigments to clay minerals, so it does not require regular washing with water. and
In addition to helping to save labor in the process, it is also possible to adjust the covering power by taking advantage of the properties of clay minerals, such as slipperiness, transparency, and adhesion.Also, by selecting organic pigments, not only can a wide range of color tones be obtained, but also light resistance. It is possible to obtain significantly superior properties. The clay mineral composite pigment of the present invention and the new lipophilic pigment have no skin irritation or toxicity, and in a patch test on the anterior apical area of 107 women with healthy skin,
No abnormalities were observed after 24 hours and 72 hours, and it can be said that the pigment is highly stable. Next, the main purpose of the new pigment of the present invention is (1) PH resistance
The results of tests conducted on pigment properties, (2) light resistance, and (3) dispersibility are shown in comparison with conventional pigments. (1) PH resistance test [Test method] After adding 0.1 g of each sample shown in Table 1 below to 50 ml of citric acid (0.1 M)-sodium citrate (0.1 M) buffer solution, stir it to 80°C. The temperature was then raised for about 5 minutes, and then allowed to cool and filtered. The liquid was measured with a color difference meter (trade name: Optical Tone Color Difference Meter), and the degree of color change was expressed as color difference (ΔE). Therefore, the larger the color difference value of ΔE, the weaker the PH resistance. The test results are shown in Table 1.

【table】

[Test method and results]

Size 1 containing magnetic balls for crushing and dispersion
90g of talc, 10g of titanium oxide, test
Charge approximately 100g of 0.1g meter powder, take it out after 15 hours of operation, fill it into a color difference meter powder cell, and measure it under sunlight irradiation conditions (ultraviolet 4280 counts, visible 46400 counts, infrared 13300 counts). Measured using The color difference (ΔE) is expressed by the degree of color fading, and the standard product that has not been irradiated with light is considered to have a degree of fading of 0, and is indicated by its increased value. (Units are NBS units) The test results are shown in Table 2 below, and since the △E of the present invention is in the range of 8.7 to 11.8, it is actually

While it can be used satisfactorily for the products shown in [Table], the conventional product has a markedly reduced light resistance, so when applied to the product, the value of the product is significantly impaired. (3) Dispersibility test Pour 20 ml of each solvent of purified water, isopropyl myristate, liquid paraffin, and ethyl alcohol into a sedimentation tube with a stopper (length 30 cm, inner diameter 1.5 cm).
The results obtained by dispersing 0.5 g of the sample in this are shown in Table 3 below.

[Table] ◎ Very good ○ Good △ Fair ×
Bad Next, a production example of the novel pigment of the present invention will be shown. Production Example 1 2 kg of sericite was stirred and dispersed in a mixed solution of 30 kg of 1% potassium hydroxide solution and 0.2 kg of 1% sodium oxalate solution, and the mixture was immersed at 65° C. for 60 minutes, and then the supernatant liquid was removed. After that, it was treated with 30kg of 1% hydrochloric acid at 40℃ for 1 hour, filtered, washed with water, and dried to produce 1.9kg of acid.
Alkali-treated sericite was obtained. Aluminum hydroxide 0.5Kg, 35% hydrochloric acid 0.90Kg,
0.42Kg of 20% aluminum sulfate and 1.0Kg of the treated sericite were charged into a reactor and steam was introduced.
After heating the reaction at 120℃ for 4 hours, the reactor was heated to 40℃.
Cool to 40°C and keep the reaction base at 40°C. Separately, 2 kg of a 1% dye solution of Yellow No. 4 and Red No. 201 (2:1) kept at 40°C was gradually added to the reaction base with stirring, and after stirring for 15 minutes, the mixture was filtered. After drying, 4.39 kg of the novel pigment of the present invention with skin color was obtained. Production Example 2 Put 0.5 kg of aluminum hydroxide and 1.4 kg of purified water into a reactor and make a slurry. Add 0.908 Kg of 98% sulfuric acid while stirring. After the addition is complete, the reactor is heated to 120°C.
After confirming that the aluminum hydroxide was completely dissolved, 1 kg of natural untreated talc was gradually added and completely dispersed. After that, 481g of calcium carbonate, 92g of magnesium hydroxide, 20%
Gradually add a mixed solution of 2.38 kg of calcium chloride to the above reactor and continue stirring. After the addition is complete, keep the reaction base in the reactor at 40°C. Separately, 4.5 kg of a dye solution containing 1% concentration of lacqueric acid and Blue No. 1 (1:1) kept at 40°C.
was gradually added to the above reaction base with stirring, stirred for 1 hour, filtered and dried to obtain 4.4 kg of a purple new pigment of the present invention. Production Example 3 2 kg of kaolin was stirred and dispersed in a mixed solution of 30 kg of 1% potassium hydroxide solution and 0.25 kg of 1% disodium hydrogen phosphate, and the mixture was immersed at 60° C. for 1 hour, and then the supernatant liquid was removed. Thereafter, it was treated with 30 kg of 1% hydrochloric acid at 40°C for 1 hour, filtered, washed with water, and dried to obtain 1.86 kg of alkali-treated kaolionite. After dissolving 1 kg of aluminum chloride and 10 kg of purified water in a reactor, 0.8 kg of the treated kaolin was gradually added and completely dispersed. Thereafter, steam was introduced and while the temperature was maintained at 130°C, 3 kg of metal aluminum whose surface had been treated with 1% POE sorbitan trioleate was gradually added and the mixture was heated for 2 hours to react.
Thereafter, it is cooled and maintained at 30°C to obtain a reaction base. Apart from this, (1) of yellow No. 5 and red No. 104 is 1:
3.4 kg of the 2% dye solution mixed in 1 was gradually added to the reaction base with stirring, stirred for 70 minutes, filtered and dried to obtain 3.78 kg of the orange new pigment of the present invention. Production Example 4 Fill a kneader with 1,500 ml of purified water, uniformly disperse 955 g of the novel pigment of the present invention from Production Example 1, and then add 20 g of dimethylpolysiloxane prepared separately to an organic solvent in which 10 g of myristic acid is dissolved in 1,000 ml of toluene. After stirring for 2 hours, the aqueous phase was removed, toluene was further distilled off, and the mixture was dried at 60°C.
After baking at 100°C for 5 hours, 987g of a new lipophilic pigment was obtained. Production example 5 Add 2.1 kg of purified water to 500 g of aluminum hydroxide, make a slurry, put it in a reactor, and stir until it reaches 98%
Add 960 g of H ₂ SO ₄ . After the addition was completed, the reactor was kept at 120℃ for 1.5 hours, and after confirming that the aluminum hydroxide was completely dissolved, 576g of calcium carbonate and 20% calcium chloride were added.
1575 g of the mixture is gradually added to the aluminum sulfate solution and stirred. After the addition is complete, the reactor is heated to 50°C.
Keep stirring for 3 hours. After that, the insoluble salt was separated, and 3.2 kg of polymerized basic aluminum solution itself was obtained. Pour this basic aluminum solution into a container and add 1.28 kg of kaolin and sericite while stirring.
Gradually add 1.28Kg and stir slowly at 110℃ for 7 hours. Then a 2% dye solution of Red No. 201,
19.2 kg was gradually added and washed with water to obtain 5.22 kg of the novel red pigment of the present invention. When the new pigment of the present invention is used in various products, it has excellent effects as described above, but when it is preferably contained in cosmetics in an amount of 0.01 to 10% by weight, in addition to these effects, it can be applied to the skin. It has the advantages of good photostability when applied, no risk of discoloration or fading, and does not stain the skin or the body to which it is applied.Moreover, there are no restrictions on the concentration of use, and excellent cosmetic effects can be obtained. Because of this, it is possible to achieve a more significant effect than when using conventional tar pigments. In addition, it does not pose any safety concerns like tar dyes. Examples State Foundation A Beads Wax Solid Paraffin Ceresin Ozokerite Perselin Carnauba Dibutyl Hydroxytoluene Sericite Liquid Paraffin Activator Titanium Oxide Pigment of the Invention of Production Example 1 8.0 5.0 3.2 0.6 5.0 0.7 0.05 8.0 32.0 1.7 25.0 9.9 B Fragrance 0.85 A was dissolved and dispersed in a melting pot at 80℃, then defoamed.
Add B and slowly stir and mix while maintaining the temperature at 80°C, fill it into a container, let it cool, and use it as a product. Examples Eyeliner A Activator Beeswax Behenate Dibutyl Hydroxytoluene Pigment of the present invention of Production Example 2 2.0 3.0 2.0 0.1 19.0 B Sodium hydroxide Thickener Purified water 0.7 3.6 37.0 C Water-soluble resin Ethyl alcohol Methyl paraben Purified water 5.0 2.0 0.2 25.4 Dissolve and disperse A and B separately in a melting pot at 80℃. Add B to A, stir thoroughly, and then heat to 40°C.
After cooling to a temperature of 100%, add C and stir for 10 minutes, then take it out and fill it into a container to prepare the product. Example Creme Rouge A Ozokerite Ceresine Petrolatum Liquid Paraffin Lanolin Derivative Dibutyl Hydroxy Toluene Titanium Oxide Liquid Paraffin Activator Kaolin Pigment of the Invention of Production Example 3 9.0 14.0 1.0 30.0 7.0 0.05 5.6 20.9 1.5 7.5 3.35 B [Fragrance 0.1 Dissolved A After dissolving and dispersing in a pot at 80°C, defoaming is performed, and B is added. Thereafter, the mixture is slowly stirred and mixed while maintaining the temperature at 80°C, and the mixture is filled into a container and left to cool before being used as a product. Examples Powder Foundation A Pigment Talc Sericite Metallic Soap of the Present Invention of Production Example 4 2.3 18.0 60.0 5.0 B Solid Paraffin Perselin Cetanol Liquid Lanolin Activator Stearic Acid 0.6 8.4 2.4 1.5 0.8 0.5 C [Fragrance 0.5 A in Ribbon Blender Mix for 30 minutes and then grind with a grinder. Thereafter, B, which had been charged into a kneader and melted at 80°C, was added and kneaded for 15 minutes. Next, C was added and kneaded for 5 minutes, then taken out and molded to form a product.

Claims (1)

[Scope of Claims] 1. A pigment made by reacting a clay mineral with a divalent or trivalent metal or a metal compound, and then reacting the reaction product with an organic dye. 2. A cosmetic comprising a pigment obtained by reacting a clay mineral with a divalent or trivalent metal or a metal compound, and then reacting the reaction product with an organic pigment.