JPS6334591B2 - - Google Patents
Info
- Publication number
- JPS6334591B2 JPS6334591B2 JP6973479A JP6973479A JPS6334591B2 JP S6334591 B2 JPS6334591 B2 JP S6334591B2 JP 6973479 A JP6973479 A JP 6973479A JP 6973479 A JP6973479 A JP 6973479A JP S6334591 B2 JPS6334591 B2 JP S6334591B2
- Authority
- JP
- Japan
- Prior art keywords
- active material
- anode active
- battery
- cathode active
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006183 anode active material Substances 0.000 claims description 32
- 239000006182 cathode active material Substances 0.000 claims description 25
- 239000007784 solid electrolyte Substances 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 8
- 239000008151 electrolyte solution Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- PWEBUXCTKOWPCW-UHFFFAOYSA-N squaric acid Chemical compound OC1=C(O)C(=O)C1=O PWEBUXCTKOWPCW-UHFFFAOYSA-N 0.000 claims description 5
- -1 alkali metal salt Chemical class 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 239000011149 active material Substances 0.000 claims description 2
- 239000010406 cathode material Substances 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 description 12
- 229910001220 stainless steel Inorganic materials 0.000 description 12
- 239000003792 electrolyte Substances 0.000 description 8
- 229910000833 kovar Inorganic materials 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000012300 argon atmosphere Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- RGBVWCQARBEPPW-UHFFFAOYSA-N cyclobut-3-ene-1,2-dione Chemical compound O=C1C=CC1=O RGBVWCQARBEPPW-UHFFFAOYSA-N 0.000 description 2
- CFBGXYDUODCMNS-UHFFFAOYSA-N cyclobutene Chemical compound C1CC=C1 CFBGXYDUODCMNS-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910001923 silver oxide Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Description
本発明は電池に関し、とくに有機物を陽極活物
質とする電池に関する。
従来の電池は、陽極活物質の材料として、Ag、
Hg等が用いられていた。従つてAgを素材として
AgOを陽極活物質とした酸化銀電池は、Agが希
少金属であり資源に限りがあるので、非常に高価
で工業的に将来性が憂慮されている。また資源上
から比較的に入手し易いHgの化合物であるHgO
を陽極活物質とした水銀電池は、使用後に廃棄す
る場合に公害問題がある。従つて広く民生電子機
器に使用した場合、回収する困難さのために、工
業的に将来好ましくない電池である。また、蓄積
エネルギー密度に関しても酸化銀電池、水銀電池
では、電子機器の小型・薄型軽量化の要求を満せ
ない。さらに高エネルギー密度の電池が要望され
ている。
本発明の目的は、上記欠点を除き、資源が充分
にあり将来枯渇の心配および価格上昇の心配が少
く、かつ公害問題の心配がなく、さらにエネルギ
ー密度の大きい陽極活物質を有する新規な電池を
提供することにある。
本発明によれば、アルカリ金属若しくはアルカ
リ土類金属又はこれらの金属を含む合金を陰極活
物質とし、一般式
（式中のR1、R2は同一もしくは異なり、水素、
ニトロ基、ハロゲン、シアノ基、アルキル基、ア
ルコオキシル基、フエニル基、アミノ基、水酸基
のいずれかを表わす）で示されるシクロブテン
1.2−ジオン、又はその誘導体を陽極活物質とし、
電解質溶液を前記陰極活物質と陽極活物質との間
に介在させたことを特徴とする電池が得られる。
さらに発明によればアルカリ金属を陰極活物質
とし、上記一般式で示されるシクロブテン1.2−
ジオン又はその誘導体を陽極活物質とし、前記陰
極活物質と陽極活物質との間に、固体電解質又は
前記陰極活物質と陽極活物質との反応によつて生
成したシクロブテン1.2ジオン又はその誘導体の
アルカリ金属塩を固体電解質として介在させたこ
とを特徴とする固体電池が得られる。
以下、本発明の電池の構成を図面を用いて説明
する。
第１図は本発明の電池の基本的構成を示す断面
図である。セラミツク製リング１の底面に陰極と
なるステンレス鋼製底板３をコバール製リング２
を介して溶着する。このようにして形成された容
器内のステンレス鋼製底板３の上に陰極活物質４
を充填する。この陰極活物質４上には電解質層５
を介して陽極活性物質が設けられる。以下では、
電解質層５として電解質溶液を採用する場合
（）と、固体電解質を採用する場合（）と、
陰極活物質４と陽極活物質６との反応で生成した
固体電解質を採用する場合（）との３通りにつ
いてそれぞれ実施例で説明する。なお、陰極活物
質４としては、上記（）（）の場合にはアル
カリ金属が選ばれ、（）の場合にはアルカリ金
属、アルカリ土類金属あるいはこれら金属を含む
合金のなかから選ばれる。充填される陰極活物質
の形状は紛末状でも板状でもさしつかえない。
また、陽極活物質６の代表例は第１表の通りで
ある。
The present invention relates to a battery, and particularly to a battery using an organic material as an anode active material. Conventional batteries use Ag,
Hg etc. were used. Therefore, using Ag as a material
Silver oxide batteries that use AgO as the anode active material are extremely expensive and have concerns about their future prospects industrially because Ag is a rare metal and resources are limited. In addition, HgO is a compound of Hg that is relatively easy to obtain from a resource perspective.
Mercury batteries that use mercury as the anode active material pose pollution problems when disposed of after use. Therefore, when widely used in consumer electronic devices, it is an industrially undesirable battery in the future due to the difficulty of recovering it. Furthermore, in terms of stored energy density, silver oxide batteries and mercury batteries cannot meet the demands for smaller, thinner, and lighter electronic devices. There is a demand for batteries with even higher energy density. The purpose of the present invention is to eliminate the above-mentioned drawbacks, to provide a new battery that has sufficient resources, has little fear of future depletion or price increases, is free from pollution problems, and has an anode active material with high energy density. It is about providing. According to the present invention, an alkali metal, an alkaline earth metal, or an alloy containing these metals is used as a cathode active material, and the general formula (R 1 and R 2 in the formula are the same or different, hydrogen,
Cyclobutene represented by any of the following: nitro group, halogen, cyano group, alkyl group, alkoxyl group, phenyl group, amino group, or hydroxyl group)
1.2-dione or its derivative as an anode active material,
A battery characterized in that an electrolyte solution is interposed between the cathode active material and the anode active material is obtained. Furthermore, according to the invention, an alkali metal is used as a cathode active material, and cyclobutene 1.2-
Dione or its derivative is used as an anode active material, and between the cathode active material and anode active material, an alkali of cyclobutene 1.2 dione or its derivative produced by the reaction between the solid electrolyte or the cathode active material and the anode active material is used. A solid battery characterized by intervening a metal salt as a solid electrolyte is obtained. Hereinafter, the structure of the battery of the present invention will be explained using the drawings. FIG. 1 is a sectional view showing the basic structure of the battery of the present invention. A stainless steel bottom plate 3 serving as a cathode is attached to the bottom of the ceramic ring 1, and a Kovar ring 2 is attached.
Weld through. A cathode active material 4 is placed on the stainless steel bottom plate 3 in the container thus formed.
Fill it with. An electrolyte layer 5 is formed on this cathode active material 4.
An anode active material is provided via the anode active material. Below,
When an electrolyte solution is used as the electrolyte layer 5 (), when a solid electrolyte is used (),
Three cases will be described in Examples, including a case () in which a solid electrolyte produced by a reaction between a cathode active material 4 and an anode active material 6 is employed. In addition, as the cathode active material 4, an alkali metal is selected in the above-mentioned cases () and (), and in the case of (), it is selected from alkali metals, alkaline earth metals, or alloys containing these metals. The shape of the cathode active material to be filled may be either powder or plate. Further, representative examples of the anode active material 6 are shown in Table 1.
【表】【table】
まず、電解質層５として電解質溶液を用いる場
合の実施例を説明する。
直径23mm、厚さ0.2mmの円板状ステンレス鋼製
底板３の周縁の封止部分に無電解ニツケルめつき
を施しておき、また外径24.0mm、内径23.6mm、厚
さ0.2mmのカツプ状ステンレス鋼製蓋７の内側周
縁の封止部分にも無電解ニツケルめつきを施して
おく。
外径23mm、内径20mm、高さ1.2mmのセラミツク
製リングの両周端部にメタライズしてコバール製
リング２，２′をろう付したものを用意し、コバ
ール製リング２とステンレス鋼製底板３をシーム
溶接する。
上述のように形成した容器内に外径20mm、厚さ
0.2mmの陰極活物質４（Li、Zn、Mg）を充填す
る。
次に、多孔質ポリプロピレン不織布（外径20
mm、厚さ0.2mm）のセパレータ５を陰極活物質４
の上に設ける。このセパレータ５に電解質の溶液
を含浸させる。本実施例では陰極活物質４とし
て、Li、Zn、Mgを用いているので、電解質とし
ては、各々濃度１セル／のLiclo4−炭酸プロピ
レン溶液、NH4Cl飽和水溶液、濃度１セル／
のMg（clo4）2−炭酸プロピレン溶液を使用した。
陽極活物質６は、前述の通り、シクロブテン
１，２−ジオン又はその誘導体を用いる。陽極活
物質６の粉末に10wt％のカーボンブラツクを混
合し、その250mgに全圧約５トンのプレス圧で加
圧成形して直径19.8mm、の円板状のタブレツト形
状にし、これをセパレータ５の上に充填する。そ
してステンレス鋼製蓋７を陽極活物質６の上にの
せ、全圧約10Kgの圧力をかけながら、ステンレス
鋼製蓋７と、コバール製リング２′をシーム溶接
し、気密封止する。なお、製作工程中、リチウム
を取り扱かう作業はすべて乾燥アルゴン雰囲気中
で行なつた。このように形成した電池の結果を第
−１表に示す。なお、以下に示す各表中の陽極
活性物質番号は第１表の番号と対応している。
First, an example in which an electrolyte solution is used as the electrolyte layer 5 will be described. Electroless nickel plating is applied to the peripheral sealing portion of the disc-shaped stainless steel bottom plate 3 with a diameter of 23 mm and a thickness of 0.2 mm, and a cup-shaped plate with an outer diameter of 24.0 mm, an inner diameter of 23.6 mm, and a thickness of 0.2 mm is applied. Electroless nickel plating is also applied to the sealing portion of the inner periphery of the stainless steel lid 7. A ceramic ring with an outer diameter of 23 mm, an inner diameter of 20 mm, and a height of 1.2 mm is metallized on both peripheral ends and Kovar rings 2 and 2' are brazed to them. Kovar ring 2 and stainless steel bottom plate 3 are prepared. Weld the seam. Inside the container formed as described above, an outer diameter of 20 mm and a thickness of
Fill with 0.2 mm of cathode active material 4 (Li, Zn, Mg). Next, porous polypropylene nonwoven fabric (outer diameter 20
mm, thickness 0.2 mm) separator 5 with cathode active material 4
Provided above. This separator 5 is impregnated with an electrolyte solution. In this example, since Li, Zn, and Mg are used as the cathode active material 4, the electrolytes include a Liclo 4 -propylene carbonate solution, a NH 4 Cl saturated aqueous solution, and a saturated aqueous solution of NH 4 Cl, each having a concentration of 1 cell/cell.
A Mg(clo 4 ) 2 -propylene carbonate solution was used. As described above, the anode active material 6 uses cyclobutene 1,2-dione or a derivative thereof. 10wt% carbon black is mixed with the powder of the anode active material 6, and 250mg of the mixture is pressure-molded at a total pressure of approximately 5 tons to form a disc-shaped tablet with a diameter of 19.8mm. Fill on top. Then, the stainless steel lid 7 is placed on the anode active material 6, and while applying a total pressure of about 10 kg, the stainless steel lid 7 and the Kovar ring 2' are seam welded and hermetically sealed. Note that during the manufacturing process, all operations involving lithium were performed in a dry argon atmosphere. The results of the batteries thus formed are shown in Table 1. Note that the anode active material numbers in each table shown below correspond to the numbers in Table 1.
次に電解質層５として固体電解質を用いた場合
の一実施例を説明する。
まず、コバール製リング２とステンレス鋼製底
板３をシーム溶接する工程までは実施例〔−
Ａ〕と同様である。次に露点60℃のAr雰囲気中
で活物質と固体電解質の積層プレス体を次のよう
にして作る。
厚さ0.2mmのリチウムシートを20mmφに打抜き
陰極活物質４とする。次に約100mgのLiIを外径20
mmのペレツト形状にプレス成形し固体電解質５と
する。次に、前述のシクロブテン１，２−ジオン
又は、その誘導体の粉末に10wt％のカーボンブ
ラツクを混合し、その250mgを全圧約５トンのプ
レス圧で加圧成形して直径19.8mmの円板状のタブ
レツト形状にし、これを陽極活物質６とする。
次に、分割ダイスの中に陰極活物質４、固体電
解質５、陽極活物質６を順次積層して全圧約100
Kgの圧力をかけ、ペレツト形状にし、これら３者
を充分に接触させた後、分割ダイスを取り去る。
次に上述の積層体を、前もつてシーム溶接され
たステンレス鋼製底板３の内底に陽極活物質６を
上面にして充填する。その後の気密封止工程は実
施例〔−Ａ〕と同様である。このように形成し
た電池の結果を第−１表に示す。
Next, an example in which a solid electrolyte is used as the electrolyte layer 5 will be described. First, the process of seam welding the Kovar ring 2 and the stainless steel bottom plate 3 is shown in Example [-
A] is the same. Next, a laminated pressed body of the active material and solid electrolyte is made in an Ar atmosphere with a dew point of 60°C as follows. A lithium sheet with a thickness of 0.2 mm is punched out to a size of 20 mmφ to form a cathode active material 4. Next, add approximately 100 mg of LiI to an outer diameter of 20 mm.
The solid electrolyte 5 is press-molded into a pellet shape of mm. Next, 10 wt% of carbon black was mixed with the powder of the aforementioned cyclobutene 1,2-dione or its derivative, and 250 mg of the mixture was pressure-molded at a total pressure of about 5 tons to form a disc with a diameter of 19.8 mm. This is made into a tablet shape, and this is used as the anode active material 6. Next, the cathode active material 4, the solid electrolyte 5, and the anode active material 6 are sequentially stacked in the divided die to create a total pressure of about 100.
After applying a pressure of Kg to form a pellet and bringing these three parts into sufficient contact, the dividing die is removed. Next, the above-described laminate is filled into the inner bottom of the stainless steel bottom plate 3, which was previously seam-welded, with the anode active material 6 facing upward. The subsequent hermetic sealing process is the same as in Example [-A]. The results of the batteries thus formed are shown in Table 1.
また、電解質層５として反応生成物を利用する
場合の一実施例を以下に説明する。
まず、陰極活物質４は、厚さ0.2mmのリチウム
シートより、20mmφの円板を打抜いて作る工程ま
では実施例〔−Ａ〕と同様である。
陽極活物質６は、前述のシクロブテン１，２−
ジオン又は、その誘導体の紛末250mgに約５トン
のプレス圧で加圧成形して直径19.8mmの円板状の
タブレツト形状とする。
次に、分割ダンスの中に前述の陰極活物質４と
陽極活物質６を順次積層して、全圧約100Kgの圧
力をかけ両者を充分に接触させ、その接合面に陰
極活物質４のアルカリ金属と陽極活物質６の反応
によつて陽極活物質のアルカリ金属塩からなる固
体電解質５の層を生成させた後、ペレツト形状の
積層体を取り出す。
次に上述の積層体を、前もつてシーム溶接され
たステンレス鋼製底板３の内底に、陽極活物質６
を上面にして充填する。その値の気密封止工程は
実施例〔−Ａ〕と同様である。なお、これらの
製作工程はすべて露点−60℃のアルゴン雰囲気中
で行つた。このように形成した電池の初期の開路
電圧と閉路電流値の結果を第−１表に示す。
Further, an example in which a reaction product is used as the electrolyte layer 5 will be described below. First, the cathode active material 4 was produced in the same manner as in Example [-A] up to the step of punching out a 20 mm diameter disk from a 0.2 mm thick lithium sheet. The anode active material 6 is the aforementioned cyclobutene 1,2-
250 mg of dione or its derivative powder is press-molded with a press pressure of about 5 tons to form a disc-shaped tablet with a diameter of 19.8 mm. Next, the above-mentioned cathode active material 4 and anode active material 6 are sequentially laminated in the split dance, and a total pressure of about 100 kg is applied to bring them into sufficient contact, and the alkali metal of the cathode active material 4 is applied to the joint surface. After a layer of solid electrolyte 5 made of an alkali metal salt of the anode active material is formed by the reaction between the anode active material 6 and the anode active material 6, the pellet-shaped laminate is taken out. Next, the above-mentioned laminate was placed on the inner bottom of the stainless steel bottom plate 3, which was previously seam welded.
Fill with the top side. The hermetic sealing process for that value is the same as in Example [-A]. All of these manufacturing steps were performed in an argon atmosphere with a dew point of -60°C. Table 1 shows the initial open circuit voltage and closed circuit current values of the battery thus formed.
【表】
上記各表の電圧は初期の開路電圧を示し、電流
は、初期の閉路電流を示す。
本発明の電池は、下記のような優れた効果を有
する。
(1) エネルギー密度は、200wh／Kgと通常のマン
ガン乾電池にくらべ３倍程度大きい。
(2) 小型・薄型・軽量化が実現できる。
(3) 実施例〔−Ａ〕、〔−Ａ〕では、電解質の
漏液という懸念もなく、長寿命が期待できる。[Table] The voltage in each table above indicates the initial open circuit voltage, and the current indicates the initial closed circuit current. The battery of the present invention has the following excellent effects. (1) The energy density is 200wh/Kg, which is about 3 times higher than normal manganese dry batteries. (2) It can be made smaller, thinner, and lighter. (3) In Examples [-A] and [-A], there is no fear of electrolyte leakage, and a long life can be expected.
第１図は本発明による電池の実施例を説明する
ための断面図。
１……セラミツク製リング、２，２′……コバ
ール製リング、３……ステンレス鋼製底板、４…
…陰極活物質、５……電解質層（セパレータ）、
６……陽極活物質、７……ステンレス鋼製蓋。
FIG. 1 is a sectional view for explaining an embodiment of a battery according to the present invention. 1... Ceramic ring, 2, 2'... Kovar ring, 3... Stainless steel bottom plate, 4...
... Cathode active material, 5 ... Electrolyte layer (separator),
6...Anode active material, 7...Stainless steel lid.
Claims (1)
これらの金属を含む合金を陰極活物質とし、陽極
活物質と前記陰極活物質との間に電解質溶液を介
在させた電池において、前記陽極活物質としてシ
クロブテン1.2−ジオン又はその誘導体を用いた
ことを特徴とする電池。 ２ アルカリ金属を陰極活物質とし、陽極活物質
と前記陰極活物質との間に固体電解質を介在させ
た電池において、前記陽極活物質としてシクロブ
テン1.2−ジオン又はその誘導体を用いたことを
特徴とする電池。 ３ アルカリ金属を陰極活物質とし、陽極活物質
と前記陰極活物質との間に前記陰極物質と陽極活
物質との反応によつて生成したアルカリ金属塩を
固体電解質として介在させた電池において、前記
陽極活物質としてシクロブテン1.2−ジオン、又
はその誘導体を用いたことを特徴とする電池。[Scope of Claims] 1. In a battery in which an alkali metal, an alkaline earth metal, or an alloy containing these metals is used as a cathode active material, and an electrolyte solution is interposed between the anode active material and the cathode active material, the anode A battery characterized in that cyclobutene 1,2-dione or a derivative thereof is used as an active material. 2. A battery in which an alkali metal is used as a cathode active material and a solid electrolyte is interposed between the anode active material and the cathode active material, characterized in that cyclobutene 1,2-dione or a derivative thereof is used as the anode active material. battery. 3. A battery in which an alkali metal is used as a cathode active material, and an alkali metal salt produced by a reaction between the cathode material and the anode active material is interposed between the anode active material and the cathode active material as a solid electrolyte, A battery characterized in that cyclobutene 1,2-dione or a derivative thereof is used as an anode active material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6973479A JPS55161377A (en) | 1979-06-04 | 1979-06-04 | Cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6973479A JPS55161377A (en) | 1979-06-04 | 1979-06-04 | Cell |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55161377A JPS55161377A (en) | 1980-12-15 |
| JPS6334591B2 true JPS6334591B2 (en) | 1988-07-11 |
Family
ID=13411335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6973479A Granted JPS55161377A (en) | 1979-06-04 | 1979-06-04 | Cell |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55161377A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2223562A1 (en) | 1997-12-02 | 1999-06-02 | Hydro-Quebec | New electrode material derived from ionic polyquinoid compounds, and their uses, especially in electrochemical generators |
| JP4935079B2 (en) * | 2005-01-12 | 2012-05-23 | 住友化学株式会社 | Polymer composition containing oxocarbons and use thereof |
| KR20070097569A (en) | 2005-01-12 | 2007-10-04 | 스미또모 가가꾸 가부시키가이샤 | Compositions containing oxocarbons and uses thereof |
| JP5112885B2 (en) * | 2006-01-30 | 2013-01-09 | 京セラ株式会社 | Container for power storage unit, battery and electric double layer capacitor using the same |
| JP5679448B2 (en) * | 2011-07-08 | 2015-03-04 | 国立大学法人九州大学 | Charge storage material, electrode active material, electrode and battery |
| CN104641504A (en) * | 2012-07-18 | 2015-05-20 | 株式会社村田制作所 | Secondary battery |
-
1979
- 1979-06-04 JP JP6973479A patent/JPS55161377A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55161377A (en) | 1980-12-15 |
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