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JPS6335756B2 - - Google Patents
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JPS6335756B2 - - Google Patents

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Publication number
JPS6335756B2
JPS6335756B2 JP59021479A JP2147984A JPS6335756B2 JP S6335756 B2 JPS6335756 B2 JP S6335756B2 JP 59021479 A JP59021479 A JP 59021479A JP 2147984 A JP2147984 A JP 2147984A JP S6335756 B2 JPS6335756 B2 JP S6335756B2
Authority
JP
Japan
Prior art keywords
carpet
backing
lining
foamable
resin beads
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP59021479A
Other languages
Japanese (ja)
Other versions
JPS60167979A (en
Inventor
Jun Okada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OOTSUKA BOSEKI KOJO KK
Original Assignee
OOTSUKA BOSEKI KOJO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OOTSUKA BOSEKI KOJO KK filed Critical OOTSUKA BOSEKI KOJO KK
Priority to JP59021479A priority Critical patent/JPS60167979A/en
Publication of JPS60167979A publication Critical patent/JPS60167979A/en
Publication of JPS6335756B2 publication Critical patent/JPS6335756B2/ja
Granted legal-status Critical Current

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Landscapes

  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Moulding By Coating Moulds (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

この発明は保形性、断熱性、吸音性、軽量性等
に優れた裏打ちカーペツトの製造方法に関する。 車両、主に乗用車に対する居住性改善の要望が
強くなり、これにともなつて車内の装飾効果、防
音効果等に優れた内装材が普及してきた。この種
の内装材として、たとえばタフテツドカーペツ
ト、ニードルパンチカーペツト等のようなカーペ
ツトの裏面に無機充填剤等を含有するエチレン・
酢酸ビニール共重合体からなる熱可塑性合成樹脂
シートを裏打ちしたカーペツトが実用に供せられ
ている。しかるに、この場合吸音性の増加と材料
費の低下等の点から無機充填剤の含有量を高める
と抜糸強度が低下したり、脱毛が発生し易いとい
う欠点がある。 また上記カーペツトの裏面にアクリル酸エステ
ル系ラテツクスとか、スチレン−ブタジエン共重
合体(SBR)からなるラテツクスを裏打ちした
ものが提案されているが、いづれもカーペツトと
しての機能のみを発揮するもので、二次裏打ちし
ないかぎり保形性、断熱性、吸音性等の性質が不
十分であるという欠点がある。 更に、敷物原反の裏面に、発泡性ポリスチレン
粒子を含有する樹脂水性エマルジヨンを塗布し、
その塗布面を加熱して発泡性ポリスチレン粒子の
発泡を行つて、敷物原反の裏面にポリスチレン発
泡体粒子が突出したバツキング層を形成して、ク
ツシヨン性を有する敷設材が提案されている(例
えば特開昭60−59183号公報参照・本願出願時未
公開)。しかし、このような敷設材は、プレス成
形による付形時に折曲げ部分にひび割れが生じ易
いという問題があつた。 この発明は上記にかんがみて、保形性、断熱
性、吸音性、軽量性等に優れた裏打ちカーペツト
の製造方法の提供を目的とする。 この発明の要旨は、(1)重量比率で、粒径0.1〜
2.5mmの発泡性樹脂ビーズ65〜85%と高分子ラテ
ツクス(固形分)35〜15%と短繊維0.8〜4%と
を配合混練した発泡性裏打ち用組成物を、カーペ
ツトの裏面へ少なくとも0.2mmの厚さに塗着し、
これを90〜150℃の温度領域で発泡処理、たとえ
ば自由発泡または加圧発泡処理する裏打ちカーペ
ツトの製造方法である。 そして、この発明における発泡性樹脂ビーズと
はたとえばBASF社のスチロポール、ヒートポー
ル(商品名)で脂肪族炭化水素等の発泡剤を含有
する発泡ポリスチレンである。また高分子ラテツ
クスとは分散質であるポリマーを分散媒である水
中へ均一分散させたエマルジヨンラテツクスであ
つて、カーペツトの抜糸防止、毛抜け防止および
発泡ポリスチレン樹脂ビーズの接着剤としての機
能を果たすものである。短繊維とはたとえば親水
性をもつ低融点多分岐繊維(SWP)、リサイクル
繊維等である。これら発泡性樹脂ビーズ、高分子
ラテツクス、短繊維等の適正な配合率と、これを
混練してカーペツトの裏面塗着後における発泡処
理条件を特定することにより裏打ちカーペツトと
しての保形性、断熱性、吸音性、軽量性等を用途
に応じて調整可能にしたものである。 つぎにこの発明における配合原材料および製造
条件の限定理由を説明する。 (1) 発泡ポリスチレン樹脂ビーズの粒径 後述のような温度領域で発泡処理するとき、
粒径が0.1mm以下の小粒では含有されている脂
肪族炭化水素ガスの保持安定性が劣り、逆に
2.5mm以上の大粒では発泡裏打ち用組成物の塗
着面に占める発泡ポリスチレン樹脂ビーズが粗
になり、仕上がり面が不均一となつてフラツト
な仕上がり面が得られ難くなるため、0.1〜2.5
mmと定めた。 (2) 発泡ポリスチレン樹脂ビーズ、高分子ラテツ
クス(固形分)および短繊維の配合比率 参照例を含めて数十回の基礎実験のうち、数
例を示せば第1表のとおり、実験No.11、No.45に
属する裏打ちカーペツトの加圧発泡処理後にお
ける仕上がり状態、巻回状態の裏打ちカーペツ
トを展開した場合裏打ち発泡層に生ずる微細な
クラツクの発生傾向等から評価した総合成積は
優、実験No.4、No.18に属する裏打ちカーペツト
のそれは良、実験No.26、No.38に属する裏打ちカ
ーペツトのそれは可であつた。なお、実験No.
4、No.11、No.18、No.26、No.38は参照例である。
The present invention relates to a method for manufacturing a carpet lining that has excellent shape retention, heat insulation, sound absorption, lightness, etc. 2. Description of the Related Art There has been a strong demand for improvements in the comfort of vehicles, mainly passenger cars, and with this, interior materials with excellent interior decoration effects, soundproofing effects, etc., have become popular. This type of interior material includes, for example, ethylene-based carpets containing inorganic fillers on the back side of carpets such as tufted carpets and needle punch carpets.
Carpets lined with a thermoplastic synthetic resin sheet made of vinyl acetate copolymer are in practical use. However, in this case, if the content of the inorganic filler is increased in order to increase sound absorption and reduce material costs, there are disadvantages in that the suture removal strength decreases and hair removal tends to occur. In addition, it has been proposed to line the back side of the carpet with acrylate latex or latex made of styrene-butadiene copolymer (SBR), but these only function as a carpet. It has the disadvantage that properties such as shape retention, heat insulation, and sound absorption are insufficient unless it is backed with a lining. Furthermore, an aqueous resin emulsion containing expandable polystyrene particles is applied to the back side of the original rug,
A laying material has been proposed that has cushioning properties by heating the coated surface to foam the expandable polystyrene particles to form a backing layer with protruding polystyrene foam particles on the back side of the original rug (for example, (See Japanese Patent Application Laid-open No. 60-59183 (unpublished at the time of filing). However, such laying materials have a problem in that they tend to crack at bent portions when shaped by press molding. In view of the above, an object of the present invention is to provide a method for manufacturing a carpet lining that has excellent shape retention, heat insulation, sound absorption, lightness, etc. The gist of this invention is (1) weight ratio, particle size 0.1~
A foam backing composition made by mixing and kneading 65-85% of 2.5 mm foamable resin beads, 35-15% of polymer latex (solid content), and 0.8-4% of short fibers is applied to the back side of the carpet by at least 0.2 mm. Apply to the thickness of
In this method, the carpet lining is subjected to foaming treatment, such as free foaming or pressure foaming, in a temperature range of 90 to 150°C. The expandable resin beads in this invention are, for example, Styropol and Heatpol (trade names) manufactured by BASF, which are expanded polystyrene containing a blowing agent such as an aliphatic hydrocarbon. Polymer latex is an emulsion latex made by uniformly dispersing a polymer as a dispersoid in water as a dispersion medium, and has the functions of preventing thread removal from carpets, preventing hair loss, and as an adhesive for foamed polystyrene resin beads. It is something that we fulfill. The short fibers include, for example, hydrophilic low melting point multi-branched fibers (SWP), recycled fibers, and the like. By determining the appropriate blending ratio of these foamable resin beads, polymer latex, short fibers, etc. and the foaming treatment conditions after kneading them and applying them to the back side of the carpet, we can improve the shape retention and heat insulation properties of the carpet backing. , sound absorption, lightweight, etc. can be adjusted depending on the application. Next, the reasons for limiting the blended raw materials and manufacturing conditions in this invention will be explained. (1) Particle size of expanded polystyrene resin beads When performing foaming treatment in the temperature range described below,
Small particles with a particle size of 0.1 mm or less have poor retention stability of the aliphatic hydrocarbon gas they contain;
If the beads are larger than 2.5 mm, the foamed polystyrene resin beads occupying the surface to which the foamed backing composition is applied will become coarse, making the finished surface uneven and difficult to obtain a flat finished surface.
mm. (2) Mixing ratio of expanded polystyrene resin beads, polymer latex (solid content), and short fibers Among the dozens of basic experiments including reference examples, Table 1 shows a few examples, Experiment No. 11. , the overall composite product was evaluated from the finished state of the backing carpet belonging to No. 45 after pressure foaming treatment, the tendency for fine cracks to occur in the backing foam layer when the rolled backing carpet is rolled out, etc. The carpet linings belonging to No. 4 and No. 18 had good results, and the carpet linings belonging to Experiment No. 26 and No. 38 had good results. In addition, experiment no.
4, No. 11, No. 18, No. 26, and No. 38 are reference examples.

【表】 これらの基礎実験結果によれば、発泡ポリス
チレン樹脂ビーズの配合比率が65%以下では裏
打ち発泡層が薄肉となつて上記の諸機能が劣
り、逆に85%以上では見掛け粘度が高くなつて
混練が困難となり、均一分散し難くなるため65
〜85%と定めた。 またエマルジヨンラテツクス(固形分)の配
合比率が35%以上では裏打ち発泡層が薄肉とな
つて上記の諸機能が劣り、逆に15%以下では発
泡ポリスチレン樹脂ビーズがカーペツトの裏面
との結合度合が弱くなるため、35〜15%と定め
た。 つぎに上記発泡ポリスチレン樹脂ビーズ65〜
85%とエマルジヨンラテツクス(固形分)35〜
15%に対して上記短繊維を混入するとクラツク
の発生傾向が解消されるが、その配合比率は
0.8〜4%の範囲が好適であることを確認して
いる。 (3) 発泡処理温度 90℃以下の低温では発泡ポリスチレン樹脂ビ
ーズの発泡が不均一になり易く、また150℃を
超える高温ではカーペツトに悪影響を及ぼし、
裏打ち発泡層が収縮するため90〜150℃と定め
た。 (4) 発泡性裏打ち組成物の塗着厚さ 発泡ポリスチレン樹脂ビーズとエマルジヨン
ラテツクス、または発泡ポリスチレン樹脂ビー
ズとエマルジヨンラテツクスと短繊維からなる
発泡性裏打ち用組成物をカーペツトの裏面へ塗
着するにあたり、その塗着厚さがあまりにも薄
いと発泡処理後における保形性、断熱性、吸音
性、軽量性等が劣るため、少なくとも0.2mm以
上の厚さに塗着する必要がある。 以下、この発明に関連する参照例を説明する。 すなわち、第2表に示すような配合比率で混練
した発泡性裏打ち用組成物を調製後、これを図示
しない手段によりカーペツトの裏面へ約1.5mmの
厚さに塗着する。つぎに第2表に併記した加熱発
泡条件により無加圧発泡、加圧発泡(たとえば加
熱ロールまたはホツトプレスなど)した。こうし
て第1図に示すように表面側にパイル層2をもつ
カーペツト1の裏面側に裏打ち発泡層3が形成さ
れた裏打ちカーペツトを製造した。
[Table] According to the results of these basic experiments, when the blending ratio of expanded polystyrene resin beads is less than 65%, the foam backing layer becomes thin and the above functions are inferior, whereas when it is more than 85%, the apparent viscosity becomes high. 65
It was set at ~85%. Furthermore, if the blending ratio of emulsion latex (solid content) is more than 35%, the foam backing layer will become thin and the above functions will be inferior; It was set at 35% to 15% because the Next, the above expanded polystyrene resin beads 65~
85% and emulsion latex (solid content) 35~
If the short fibers mentioned above are mixed in at 15%, the tendency for cracks to occur will be eliminated, but the mixing ratio is
It has been confirmed that a range of 0.8 to 4% is suitable. (3) Foaming treatment temperature At low temperatures below 90°C, foaming of expanded polystyrene resin beads tends to become uneven, and at high temperatures over 150°C, it has a negative effect on the carpet.
The temperature was set at 90 to 150°C because the foam lining layer would shrink. (4) Application thickness of foamable backing composition A foamable backing composition consisting of foamed polystyrene resin beads, emulsion latex, or foamed polystyrene resin beads, emulsion latex, and short fibers is applied to the back side of the carpet. When applying the product, it is necessary to apply the product to a thickness of at least 0.2 mm, as if the coating thickness is too thin, the shape retention, heat insulation, sound absorption, lightness, etc. after foaming treatment will be poor. Reference examples related to this invention will be described below. That is, after preparing a foamable backing composition kneaded in the proportions shown in Table 2, it is applied to the back surface of the carpet to a thickness of about 1.5 mm by means not shown. Next, non-pressure foaming and pressure foaming (for example, using a heated roll or hot press) were carried out under the heating and foaming conditions listed in Table 2. In this way, as shown in FIG. 1, a carpet lining was produced in which a foam lining layer 3 was formed on the back side of a carpet 1 having a pile layer 2 on the front side.

【表】 そして上記第2表に示す裏打ちカーペツトにつ
いて保形性、断熱性、吸音性等の調査結果を第3
表に示す。
[Table] The results of the investigation on shape retention, heat insulation, sound absorption, etc. of the carpet lining shown in Table 2 above are shown in Table 3.
Shown in the table.

【表】 つぎに第2表に示す連続製造期間記号XBに属
する裏打ちカーペツトから採取した試料の断熱性
(内部と外部との温度差1℃で測定面積1m2から
1時間に失われる熱量を1kcalに抑制するに必要
な厚さ)を調査したところ、第2図に示すように
この発明に関連する裏打ちカーペツトは薄くても
断熱効果が優れていることがわかつた。 なお第2表に示す連続製造期間記号YAに属す
る裏打ちカーペツトから採取した試料の吸音率
(設置位置と測定位置との空間距離:80mm)を測
定したところ、第3図に示すように従来材(厚さ
約2.0mmのSBR裏打ち材、上記空間距離:40mm)
にくらべて、1000ヘルツ以下の領域における吸音
性(防音性)が優れていることがわかつた。この
理由は詳細に検討していないが、裏打ち発泡層内
に形成された無数の独立気泡によるものと推定し
ている。 以上のとおり、この発明によれば上記参照例の
効果に短繊維の配合効果が結合して、カーペツト
の裏面へ発泡性樹脂からなる裏打ち発泡層が強固
に固着されるため、上記のような従来の裏打ち層
にくらべて保形性、断熱性、吸音性等が優れてお
り、ポリエチレンフイルム等による二次裏打ちが
不要となるとともに、発泡性裏打ち用組成物内の
短繊維が該組成物のバインダー的機能を発揮し
て、プレス成形による付形時に、折曲げ部分にひ
び割れを発生することのない成形性の良好な裏打
ちカーペツトを得ることができる。また一次裏打
ち時に発泡性樹脂ビーズを発泡させない、つまり
未発泡状態の裏打ち発泡層を成形加工時に加熱発
泡させる(第4図参照)と、諸機能を発揮させる
ための工程簡略化も可能である。かくして得られ
た裏打ちカーペツトは繰返し外部応力による変形
回復力が大きく緩衝性に富む内装部材となり得る
ものである。したがつて自動車、主に乗用車の床
材、ドアサイド材、天井材等のような車両内装材
のほか、建築内装材としても好適である。
[Table] Next, the heat insulation properties of the samples taken from the carpet lining belonging to the continuous production period code XB shown in Table 2 (1 kcal of heat lost in 1 hour from a measurement area of 1 m 2 at a temperature difference of 1°C between the inside and outside) As shown in FIG. 2, it was found that the carpet lining related to the present invention has an excellent heat insulating effect even if it is thin. In addition, when we measured the sound absorption coefficient (spatial distance between the installation position and measurement position: 80 mm) of the sample taken from the backing carpet belonging to the continuous manufacturing period code YA shown in Table 2, it was found that the conventional material ( SBR backing material with a thickness of approximately 2.0 mm, above spatial distance: 40 mm)
It was found that the sound absorbing properties (soundproofing properties) in the region below 1000 Hz are superior compared to the previous one. Although the reason for this has not been investigated in detail, it is presumed that it is due to the countless closed cells formed within the foam lining layer. As described above, according to the present invention, the effect of the above-mentioned reference example is combined with the blending effect of short fibers, and the backing foam layer made of a foamable resin is firmly fixed to the back surface of the carpet. It has superior shape retention, heat insulation, sound absorption, etc. compared to the backing layer of It is possible to obtain a backing carpet with good moldability, which exhibits the desired function and does not cause cracks at the bent portion during shaping by press molding. In addition, by not foaming the expandable resin beads during the primary lining, that is, by heating and foaming the unfoamed foamed lining layer during the molding process (see Figure 4), it is possible to simplify the process for achieving various functions. The thus obtained carpet lining can be used as an interior member having a large deformation recovery force due to repeated external stress and having excellent cushioning properties. Therefore, it is suitable not only for vehicle interior materials such as floor materials, door side materials, ceiling materials, etc. of automobiles, mainly passenger cars, but also as architectural interior materials.

【図面の簡単な説明】[Brief explanation of the drawing]

図はこの発明の実施例を示し、第1図はカーペ
ツトの裏面へ不整線固着された裏打ち発泡層の拡
大断面図、第2図、第3図は従来材とこの発明に
関連する発泡裏打ちカーペツトの参照例との断熱
性、吸音性とを対比したグラフ、第4図は成形加
工時に未発泡状態の裏打ち発泡層を加熱発泡させ
た状態を示す断面図である。 1……カーペツトの裏面、3……裏打ち発泡
層。
The figures show an embodiment of the present invention. Figure 1 is an enlarged sectional view of a foam backing layer fixed in irregular lines to the back side of a carpet, and Figures 2 and 3 are a conventional material and a foam backing carpet related to the present invention. FIG. 4 is a graph comparing the thermal insulation properties and sound absorption properties with the reference example of 1. FIG. 4 is a cross-sectional view showing a state in which the unfoamed backing foam layer is heated and foamed during molding. 1...Back side of the carpet, 3...Backing foam layer.

Claims (1)

【特許請求の範囲】[Claims] 1 重量比率で、粒径0.1〜2.5mmの発泡性樹脂ビ
ーズ65〜85%と高分子ラテツクス(固形分)35〜
15%と短繊維0.8〜4%とを混練して発泡性裏打
ち用組成物を調製後、該発泡性裏打ち用組成物を
カーペツトの裏面へ少なくとも0.2mmの厚さに塗
着し、これを90〜150℃の温度領域で発泡処理す
ることを特徴とする裏打ちカーペツトの製造方
法。
1 Weight ratio: 65-85% foamable resin beads with a particle size of 0.1-2.5 mm and polymer latex (solid content) 35-85%
After preparing a foamable backing composition by kneading 15% and 0.8-4% short fibers, the foamable backing composition is applied to the back side of the carpet to a thickness of at least 0.2mm, and the foamed backing composition is mixed with 90% A method for producing carpet lining, characterized by carrying out foaming treatment in a temperature range of ~150°C.
JP59021479A 1984-02-07 1984-02-07 Production of back-lining carpet Granted JPS60167979A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59021479A JPS60167979A (en) 1984-02-07 1984-02-07 Production of back-lining carpet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59021479A JPS60167979A (en) 1984-02-07 1984-02-07 Production of back-lining carpet

Publications (2)

Publication Number Publication Date
JPS60167979A JPS60167979A (en) 1985-08-31
JPS6335756B2 true JPS6335756B2 (en) 1988-07-15

Family

ID=12056104

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59021479A Granted JPS60167979A (en) 1984-02-07 1984-02-07 Production of back-lining carpet

Country Status (1)

Country Link
JP (1) JPS60167979A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0611530B2 (en) * 1986-04-25 1994-02-16 日本バイリーン株式会社 Skin material for interior materials
WO1994002678A1 (en) * 1992-07-28 1994-02-03 The Dow Chemical Company Carpet backing latex composition and process for production

Also Published As

Publication number Publication date
JPS60167979A (en) 1985-08-31

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