JPS6339762B2 - - Google Patents
Info
- Publication number
- JPS6339762B2 JPS6339762B2 JP6102985A JP6102985A JPS6339762B2 JP S6339762 B2 JPS6339762 B2 JP S6339762B2 JP 6102985 A JP6102985 A JP 6102985A JP 6102985 A JP6102985 A JP 6102985A JP S6339762 B2 JPS6339762 B2 JP S6339762B2
- Authority
- JP
- Japan
- Prior art keywords
- retainer
- outlet
- catalyst
- exhaust gas
- housing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2846—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for granular supports, e.g. pellets
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features
- F01N13/18—Construction facilitating manufacture, assembly, or disassembly
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/10—Fitting temporarily exhaust apparatus on exhaust conduit, e.g. in confined environment, garage or the like
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas After Treatment (AREA)
Description
【発明の詳細な説明】
本発明は内然機関からの排気ガスの処理に関
し、更に詳細には排気ガスを処理してその望まし
くない成分を無害な形態に変換するための触媒変
換器に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to the treatment of exhaust gas from a domestic engine, and more particularly to a catalytic converter for treating exhaust gas to convert its undesirable components into harmless forms.
かゝる触媒変換器はエンジンの排気系内に連結
されて、エンジンからの排気ガスを変換器内に保
持された触媒物質のベツドを通過させ、該ベツド
により排気ガス中の一酸化炭素および未燃焼の炭
化水素を酸化させて二酸化炭素および水を形成さ
せ且つ(または)窒素酸化物を減少させるもので
ある。 Such catalytic converters are connected within the exhaust system of an engine to pass exhaust gases from the engine through a bed of catalytic material held within the converter, which removes carbon monoxide and non-carbon monoxide from the exhaust gases. It oxidizes the hydrocarbons of combustion to form carbon dioxide and water and/or reduces nitrogen oxides.
触媒を多孔触媒保持器の内部に保持し、これを
ハウジング内に収容して、ハウジングの上部と触
媒保持器の上部にて形成される空間に、処理され
るべき排気ガスを導入し、ハウジングの下部と触
媒保持器の下部にて形成される空間へ該排気ガス
を流すことによつて、排気ガスを多孔触媒保持器
を通過する様にした触媒変換器は種々提案されて
いるが、いずれもガスリークの発生に関し耐久性
の問題がある。 A catalyst is held inside a porous catalyst holder, which is housed in a housing, and exhaust gas to be treated is introduced into a space formed between the upper part of the housing and the upper part of the catalyst holder, and the exhaust gas to be treated is introduced into the space formed by the upper part of the housing and the upper part of the catalyst holder. Various catalytic converters have been proposed in which the exhaust gas passes through a porous catalyst holder by flowing the exhaust gas into a space formed between the lower part and the lower part of the catalyst holder, but none of them have been proposed. There are durability issues regarding gas leaks.
この様な公知の触媒変換器の例として、触媒保
持器を、多孔上部板、多孔下部板、その上流端部
でこれら上部板と下部板とを密封的に閉鎖する垂
直板、および同様に下流側を閉鎖する垂直板で構
成したものがある。この場合、排気ガスを触媒保
持器を通過して流れる様にするために、該上部お
よび下部板をガス流方向に対して横方向に延長し
て、その外部のハウジング板のフランジ間に挾持
し、上流側で前記垂直板の下端部をハウジングに
密封接触させ、同様に下流端部では垂直板の上端
部を密封接触させている。構成上、この様な密封
接触で密封状態を達成せざるを得ないものである
(例えば米国特許第3600142号)。 Examples of such known catalytic converters include a catalytic retainer comprising a perforated upper plate, a perforated lower plate, a vertical plate sealingly closing these upper and lower plates at their upstream ends, and also a perforated lower plate at their upstream ends. Some consist of vertical plates that close off the sides. In this case, the upper and lower plates extend transversely to the gas flow direction and are sandwiched between the flanges of the outer housing plate in order to allow the exhaust gas to flow past the catalyst holder. , the lower end of the vertical plate is in sealing contact with the housing at the upstream end, and similarly the upper end of the vertical plate is in sealing contact at the downstream end. Due to the construction, it is necessary to achieve a sealed state through such a sealed contact (for example, US Pat. No. 3,600,142).
他の公知の触媒変換器としては例えば米国特許
第3146073号があり、この発明ではハウジングの
構造に関して傾斜した触媒ベツドを示しており、
該ベツドは変換器の軸方向の全長に亘り全ての点
でガスの流れに対しほぼ一様な断面を有してい
る。然しこの変換器ではハウジング部材のフラン
ジ部間で端部を挾持し該端部で固着し密封される
ような触媒保持器部材を有していない。又この特
許では、入つてくる排気ガスの下部で入口流路に
無孔状態で延在し、排出する排気ガスの上部で出
口通路に無孔状態で延在する触媒保持器部材を有
していない。更に又この特許では、排気ガスの入
口から排気ガス出口へ向つて深さがそれぞれ増加
および減少する側壁部をもつた傾斜する触媒ベツ
ドを形成する頂部および底部保持器部材を有して
いない。従つてこの米国特許の変換器では、触媒
変換器において不可避の温度勾配と急激な温度変
化による熱応力に耐えうる装置において問題とな
る変換器の固着、密封、流れの均一性及び耐久力
についての考慮に欠けている。 Other known catalytic converters include, for example, U.S. Pat.
The bed has a substantially uniform cross-section for gas flow at all points along the entire axial length of the transducer. However, this converter does not have a catalyst retainer member whose ends are sandwiched between the flanges of the housing member and which are secured and sealed at the ends. This patent also includes a catalyst retainer member extending imperforately into the inlet passageway at the bottom of the incoming exhaust gas and extending imperforately into the outlet passageway at the top of the exiting exhaust gas. do not have. Furthermore, this patent does not have top and bottom retainer members forming sloped catalyst beds with sidewalls that respectively increase and decrease in depth from the exhaust gas inlet to the exhaust gas outlet. The converter of this U.S. patent thus addresses the problems of transducer sticking, sealing, flow uniformity, and durability, which are issues in devices that withstand the thermal stress caused by the inevitable temperature gradients and rapid temperature changes in catalytic converters. lack of consideration.
しかし、触媒変換器は非常に大きな温度変化を
受けるため、板には「そり」、「撓曲」が生ずるの
で、これら公知の構造で密封状態を維持すること
は実際上できない。即ち、この様な密封部は使用
するにしたがつて、板部片の「そり」、「撓曲」に
よつて容易に開いてしまい、これは触媒を迅回す
るリークパスとなつて大気に有害ガスを放出し、
効果的な排ガス処理の障害となる。触媒変換器の
基本的機能を考えれば、触媒を迅回するリークの
発生は変換器が使用不能、即ち、破損したことを
意味する。したがつて、公知の触媒変換器には、
耐久性に欠ける欠点があつた。 However, since the catalytic converter is subject to such large temperature changes that the plates "warp" and "bend", it is practically impossible to maintain a sealed state with these known structures. In other words, as such a sealed part is used, it easily opens due to "warping" or "bending" of the plate part, which becomes a leak path that quickly circulates the catalyst and is harmful to the atmosphere. release gas,
It becomes an obstacle to effective exhaust gas treatment. Considering the basic function of a catalytic converter, the occurrence of a leak that quickly bypasses the catalyst means that the converter is unusable or damaged. Therefore, known catalytic converters include:
The drawback was that it lacked durability.
本発明は、強固な構造で、触媒を迅回するリー
ク発生の可能性がなく、耐久性の高い内燃機関用
触媒変換器を得ることを目的とする。 An object of the present invention is to obtain a catalytic converter for an internal combustion engine that has a strong structure, is free from the possibility of leakage that quickly circulates the catalyst, and is highly durable.
本発明に係る変換器は、触媒ベツドを通る排気
ガスに均一な流れと低圧力損失を与える。その高
さの低い外形構造は、車輛の下に配置するために
制限された空間という条件に適合し、又変換器の
保持器の上向及び下向の延在部は排気ガスが容易
に流入し流出する。従つて本発明の特徴により、
ハウジングと保持器とが一緒に固着され密封さ
れ、ガス流れに対し低い抵抗しか与えない。頂部
および底部保持器部材の側壁部の深さがそれぞれ
増加および減少して若干の傾斜を与えるという簡
単な保持器構造で均一な圧力勾配を与える傾斜し
た触媒ベツドが得られる。 The converter according to the invention provides a uniform flow and low pressure drop of the exhaust gas through the catalyst bed. Its low profile conforms to the limited space requirements for placement under the vehicle, and the upward and downward extensions of the converter retainer facilitate the inflow of exhaust gases. and leaks out. Accordingly, according to the features of the invention:
The housing and retainer are secured and sealed together and provide low resistance to gas flow. A sloped catalyst bed providing a uniform pressure gradient is obtained with a simple cage construction in which the sidewall depths of the top and bottom cage members increase and decrease, respectively, to provide a slight slope.
本発明の内燃機関用排気ガス触媒変換器は、触
媒保持器が頂部および底部保持器部材によつて形
成され、該頂部および底部保持器部材はそれぞれ
頂部および底部多孔部とともに前記触媒収容部を
形成する側壁部を有しており;前記頂部保持器部
材はその側壁部の一端部から前記入口流路に向つ
て無孔状態で延在する上向凹部を有し、頂部保持
器部材の該上向凹部は底部ハウジング部材14の
入口半円筒部66に沿つてさらに軸方向に無孔状
態で延在しかつ頂部ハウジング部材12の入口半
円筒部64と共に排気ガス入口円筒部56を形成
して頂部保持器部材の上向凹部と頂部ハウジング
部材の入口半円筒部とが排気系統の入口側円筒部
材に直接接続されるようにし;前記底部保持器部
材はその側壁部の一端部から入口流路に向つて延
在する上向凹部を有し、底部保持器部材の該上向
凹部はさらに軸方向に底部ハウジング部材の入口
半円筒部66に沿つて延在しかつ該入口半円筒部
66と重合して、頂部保持器部材の前記さらに軸
方向に延在した上向凹部の部分と底部ハウジング
部材の入口半円筒部とによつて挾持されており;
前記底部保持器部材はその側壁部の他端部から前
記出口流路に向つて無孔状態で延在する下向凹部
を有し、底部保持器部材の該下向凹部は頂部ハウ
ジング部材12の出口半円筒部64に沿つてさら
に軸方向に無孔状態で延在しかつ底部ハウジング
部材14の出口半円筒部66と共に排気ガス出口
円筒部58を形成して底部保持器部材の下向凹部
と底部ハウジング部材の出口半円筒部とが排気系
統の出口側円筒部材に直接接続されるようにし;
前記頂部保持器部材はその側壁部の他端部から出
口流路に向つて延在する下向凹部を有し、頂部保
持器部材の該下向凹部はさらに軸方向に頂部ハウ
ジング部材の出口半円筒部64に沿つて延在しか
つ該出口半円筒部と重合して、底部保持器部材の
前記さらに軸方向に延在した下向凹部の部分と頂
部ハウジング部材の出口半円筒部とによつて挾持
されており;前記頂部及び底部ハウジング部材を
構成する前記入口半円筒部、皿形部及び出口半円
筒部は、それぞれ同一の素材により一体に形成さ
れ;頂部及び底部ハウジング部材の周縁部には排
気ガス入口縁部と出口縁部とを除く全周縁にわた
り前記ハウジングのフランジ部が一体に設けら
れ;また頂部及び底部保持器部材の周縁部には排
気ガス入口縁部と出口縁部とを除く全周縁にわた
り前記触媒保持器のフランジ部が一体に設けられ
ており、前記両保持器部材の周縁部に設けたフラ
ンジ部が前記両ハウジング部材の周縁部に設けた
フランジ部によつて挾着されており;更に前記頂
部および底部保持器部材の前記触媒収容部は排気
ガス入口56から排気ガス出口58に向つて上向
に傾斜しかつ実質的に均一な深さを有しており、
そして頂部および底部保持器部材の側壁部は排気
ガス入口56から排気ガス出口58へ向つて、深
さがそれぞれ増加および減少していることを特徴
とする。 In the exhaust gas catalytic converter for an internal combustion engine of the present invention, the catalyst retainer is formed by top and bottom retainer members, and the top and bottom retainer members form the catalyst housing portion together with the top and bottom porous portions, respectively. the top retainer member has an upwardly recessed portion extending from one end of the side wall portion toward the inlet channel in a nonporous manner; The facing recess extends axially further along the inlet half cylinder 66 of the bottom housing member 14 and forms an exhaust gas inlet cylinder 56 with the inlet half cylinder 64 of the top housing member 12 to form the exhaust gas inlet cylinder 56. The upward recess of the retainer member and the inlet semi-cylindrical portion of the top housing member are directly connected to the inlet cylindrical member of the exhaust system; the bottom retainer member is connected to the inlet flow path from one end of its side wall. and an upwardly extending recess in the bottom retainer member that further extends axially along and overlaps the inlet half-cylinder 66 of the bottom housing member. the further axially extending upwardly recessed portion of the top retainer member and the inlet semi-cylindrical portion of the bottom housing member;
The bottom retainer member has a downwardly directed recess extending from the other end of the sidewall toward the outlet passageway in a nonporous manner, and the downwardly directed recess of the bottom retainer member is connected to the top housing member 12. The exhaust gas outlet cylinder 58 further extends axially in a non-porous manner along the outlet semi-cylindrical portion 64 and forms an exhaust gas outlet cylinder 58 with the outlet semi-cylindrical portion 66 of the bottom housing member 14 to form a downward recess of the bottom retainer member. the outlet semi-cylindrical portion of the bottom housing member is directly connected to the outlet cylindrical member of the exhaust system;
The top retainer member has a downwardly directed recess extending from the other end of the side wall toward the outlet passage, the downwardly recessed portion of the top retainer member further axially extending into the outlet half of the top housing member. extending along the cylindrical portion 64 and overlapping the outlet semi-cylindrical portion with said further axially extending downwardly recessed portion of the bottom retainer member and the outlet semi-cylindrical portion of the top housing member. The inlet semi-cylindrical part, the dish-shaped part and the outlet semi-cylindrical part constituting the top and bottom housing members are each integrally formed of the same material; The flange portion of the housing is integrally provided over the entire periphery except for the exhaust gas inlet edge and the outlet edge; and the exhaust gas inlet edge and the outlet edge are provided on the periphery of the top and bottom retainer members. A flange portion of the catalyst holder is integrally provided over the entire periphery except for the flange portion of the catalyst holder, and the flange portion provided on the periphery of both the cage members is clamped by the flange portion provided on the periphery of both the housing members. further, the catalyst receiving portions of the top and bottom retainer members slope upwardly from the exhaust gas inlet 56 toward the exhaust gas outlet 58 and have a substantially uniform depth;
The sidewalls of the top and bottom retainer members are then characterized by increasing and decreasing depths, respectively, from the exhaust gas inlet 56 to the exhaust gas outlet 58.
更に触媒ベツドを通るガスの流れはベツドを通
しほぼ均一に分散されることが最大の触媒寿命と
最適の変換をうるために望ましい。一般に均一な
分布は頂部および底部保持器部材により形成され
る触媒収容部により達成される。即ちこの触媒収
容部は、排ガスの入口と出口との間で上向に傾斜
するほぼ均一な深さを有しているからである。こ
の僅かに傾斜した触媒収容部は、入口及び出口ガ
ス流路が一定の高さである場合に比較して変換器
の全体の高さを減少させる。 Additionally, it is desirable that the flow of gas through the catalyst bed be substantially uniformly distributed throughout the bed to obtain maximum catalyst life and optimum conversion. Generally uniform distribution is achieved by the catalyst containment formed by the top and bottom cage members. That is, this catalyst accommodating portion has a substantially uniform depth that slopes upward between the exhaust gas inlet and outlet. This slightly sloped catalyst housing reduces the overall height of the converter compared to if the inlet and outlet gas flow paths were of constant height.
特に本発明の変換器は、触媒を迅回するガスリ
ークに対する耐久性が高く、高さの低い外形を有
し、そしてガスの流れを規制しないものである。 In particular, the converter of the present invention is highly resistant to gas leaks that quickly displace the catalyst, has a low profile profile, and does not restrict gas flow.
高さの低い外形は、頂部及び底部保持器部材が
その全周縁部にわたり頂部及び底部ハウジング部
材の間に挾持され、頂部及び底部保持器部材の深
さをハウジング部材に対しガスの入口と出口との
間で逆比例して変化させることによつて、ハウジ
ングに対し若干傾斜する実質的に均一な深さの触
媒収容部を規定することにより達成される。 The low profile profile allows the top and bottom retainer members to be sandwiched between the top and bottom housing members over their entire periphery, and the depth of the top and bottom retainer members to be limited to the gas inlet and outlet relative to the housing member. This is accomplished by defining a substantially uniform depth of catalyst receptacle that is slightly inclined relative to the housing by varying inversely between
耐久性は、頂部保持器部材の側壁部の一端部か
ら入口流路に向つて無孔状態で上向凹部を延在さ
せ、該上向凹部を底部ハウジング部材の入口半円
筒部に沿つてさらに軸方向に無孔状態で延在させ
て排気系統の入口側円筒部材に直接接続されるよ
うにし、また底部保持器部材のその側壁部の他端
部から出口流路に向つて下向凹部を無孔状態で延
在させ、該下向凹部を頂部ハウジング部材の出口
半円筒部に沿つてさらに軸方向に無孔状態で延在
させて排気系統の出口側円筒部材に直接接続され
るようにすることにより達成される。耐久性はま
た底部保持器部材にその側壁部から入口流路に向
つて上向凹部を延在させ、該上向凹部を頂部保持
器部材の前記さらに軸方向に延在した上向凹部の
部分と底部ハウジング部材の入口半円筒部とによ
つて挾持することにより、そして、頂部保持器部
材にその側壁部から出口流路に向つて下向凹部を
延在させ、該下向凹部を底部保持器部材の前記さ
らに軸方向に延在した下向凹部の部分と頂部ハウ
ジング部材の出口半円筒部とによつて挾持するこ
とにより達成される。そして又耐久性は、保持器
部材の横方向に延びるフランジ部分をハウジング
部材の一体のフランジ部分の間で重合状態に挾持
することによつても達成される。即ち保持器の横
方向に延びるフランジ部分と頂部及び底部保持器
部材の軸方向にのびる部分とが協働して触媒を迅
回するガスリークを防止し耐久性を増大せしめ
る。 Durability is achieved by extending an upward recess in a non-porous state from one end of the side wall of the top retainer member toward the inlet flow path, and extending the upward recess further along the inlet semi-cylindrical portion of the bottom housing member. The bottom retainer member has a downwardly recessed portion extending from the other end of the side wall thereof toward the outlet flow path so as to extend in an axial direction without holes so as to be directly connected to the inlet side cylindrical member of the exhaust system. the downwardly recessed portion extending further axially along the outlet semi-cylindrical portion of the top housing member in a non-porous manner so as to be directly connected to the outlet side cylindrical member of the exhaust system; This is achieved by Durability also includes having an upwardly extending recess in the bottom retainer member extending from its sidewall toward the inlet flow path, and connecting the upwardly recessed portion of the top retainer member to the further axially extending upwardly recessed portion of the top retainer member. and an inlet semi-cylindrical portion of the bottom housing member, and the top retainer member has a downwardly recessed portion extending from a side wall thereof toward the outlet passageway, and the downwardly directed recessed portion is held by the bottom retaining member. This is accomplished by sandwiching the further axially extending downwardly recessed portion of the container member and the outlet semi-cylindrical portion of the top housing member. Durability is also achieved by sandwiching the laterally extending flange portions of the retainer member in an overlapping manner between integral flange portions of the housing member. That is, the laterally extending flange portions of the retainer and the axially extending portions of the top and bottom retainer members cooperate to prevent gas leaks that would quickly displace the catalyst and increase durability.
ガスの流れの規制を限少させることは、変換器
にガスを流入し、変換器からガスを流出させる部
分に相当する延在する触媒保持器構造によつても
達成される。この触媒変換器の構造は、流線型の
内部を提供し排ガスが容易に変換器内へ流入し、
変換器から流出しうるようにする。頂部及び底部
保持器部材は、頂部及び底部ハウジング部材の内
側に変化する間隔をおいて配置されているが、そ
の深さはほぼ一定の若干傾斜する触媒収容部を構
成する。即ち頂部保持器部材と頂部ハウジング部
材との間に間隔はガス入口から出口に向つて順次
減少し、それによつて流入するガスの流れに対し
順次減少する断面を形成し、ほぼ一定の圧力勾配
を付与する。同様に底部保持器部材と底部ハウジ
ング部材との間の間隔は、ガス入口から出口に向
つて順次増大し、排出するガスに対し順次増大す
る断面を形成し、こゝでもほぼ一定の圧力勾配を
付与する。このことは本発明の保持器において、
ガス入口から出口に向つて頂部及び底部保持器部
材の皿形部の深さをそれぞれ増大及び減少するこ
とにより達成される。 Minimizing gas flow restriction is also achieved by an elongated catalyst retainer structure that corresponds to the portions that flow gas into and out of the converter. The structure of this catalytic converter provides a streamlined interior for exhaust gases to easily flow into the converter.
Allow it to flow out of the transducer. The top and bottom retainer members define a slightly sloped catalyst receptacle spaced at varying spacings within the top and bottom housing members but having a substantially constant depth. That is, the spacing between the top retainer member and the top housing member decreases from the gas inlet to the outlet, thereby creating a decreasing cross-section for the incoming gas flow and providing a substantially constant pressure gradient. Give. Similarly, the spacing between the bottom retainer member and the bottom housing member increases progressively from the gas inlet to the outlet, creating a progressively increasing cross-section for the exiting gas, again providing a substantially constant pressure gradient. Give. This means that in the cage of the present invention,
This is accomplished by increasing and decreasing the depth of the dish-shaped portions of the top and bottom retainer members, respectively, from the gas inlet to the outlet.
以下本発明およびその実施方法を図面を参照し
て詳細に説明する。 The present invention and its implementation method will be explained in detail below with reference to the drawings.
図中、小さな相違点は別として類似する部分に
は同様な参照符号を付してある。 In the figures, similar parts, apart from minor differences, are given the same reference numerals.
第4図〜第12図は排気系統入口側円筒部材6
0および同出口側円筒部材62に接続される触媒
変換器の実施例を示しこの触媒変換器の好ましい
実施例はハウジング10を有し、該ハウジング1
0は高温の塩およびガスの腐食性に耐えるように
高クローム・ステンレス鋼または被覆またはめつ
きした鋼で好ましくは形成される。このハウジン
グ10は頂部ハウジング部材12と底部ハウジン
グ部材14とからなり、該部材の各々はそれぞれ
皿形部を有し、該皿形部は既ね垂直な側壁部分1
6,18を有する。 Figures 4 to 12 show the cylindrical member 6 on the exhaust system inlet side.
A preferred embodiment of the catalytic converter has a housing 10, which is connected to the outlet cylindrical member 62.
0 is preferably formed of high chromium stainless steel or coated or plated steel to withstand the corrosive effects of hot salts and gases. The housing 10 consists of a top housing member 12 and a bottom housing member 14, each of which has a respective dish-shaped portion, which already has a vertical side wall portion 1.
6,18.
頂部ハウジング部材12は上流側で入口半円筒
部64(第6,12図の左側)を、また、下流側
で出口半円筒部64(同右側)を備え、頂部ハウ
ジング部材12の前記皿形部とこれらの入口半円
筒部64、出口半円筒部64は同一の素材により
一体に形成されている。また底部ハウジング部材
14は上流側で入口半円筒部66(第6,12図
の左側)を、また、下流側で出口半円筒部66
(同右側)を有し、底部ハウジング部材14の前
記皿形部とこれらの入口半円筒部66、出口半円
筒部66は同一の素材により一体に形成されてい
る。さらに、頂部及び底部ハウジング部材12,
14の周縁部にはその排気ガス入口縁部と出口縁
部とを除く全周縁にわたり、後述の保持器部材の
フランジを挾着するためのフランジ部20,22
が一体に設けられている。 The top housing member 12 has an inlet semi-cylindrical portion 64 (on the left in FIGS. 6 and 12) on the upstream side and an outlet semi-cylindrical portion 64 on the downstream side (on the right in FIGS. 6 and 12). The inlet semi-cylindrical portion 64 and the outlet semi-cylindrical portion 64 are integrally formed of the same material. The bottom housing member 14 also has an inlet semi-cylindrical portion 66 (left side in FIGS. 6 and 12) on the upstream side and an outlet semi-cylindrical portion 66 on the downstream side.
The dish-shaped portion of the bottom housing member 14, the inlet semi-cylindrical portion 66, and the outlet semi-cylindrical portion 66 are integrally formed of the same material. Additionally, top and bottom housing members 12,
Flange portions 20 and 22 are provided on the peripheral edge of 14 over the entire periphery except for the exhaust gas inlet edge and outlet edge for clamping a flange of a retainer member, which will be described later.
are integrated.
ハウジング10内には頂部保持器部材26と底
部保持器部材28とから成る傾斜した触媒保持器
24が装着されている(傾斜については後述す
る)。 Mounted within the housing 10 is a sloped catalyst retainer 24 consisting of a top retainer member 26 and a bottom retainer member 28 (the tilt will be discussed below).
頂部および底部保持器部材26,28は排気ガ
ス通過用の頂部多孔部30および底部多孔部34
をそれぞれ有しており、頂部および底部保持器部
材26,28はさらにこれら頂部多孔部30およ
び底部多孔部34とともに触媒収容部46を形成
する無孔側壁部38,40を有している。 The top and bottom retainer members 26, 28 have a top porous section 30 and a bottom porous section 34 for passage of exhaust gases.
The top and bottom retainer members 26, 28 further have non-porous sidewalls 38, 40 which together with the top porous portion 30 and bottom porous portion 34 form a catalyst receiving portion 46.
頂部保持器部材26の頂部多孔部30は頂部ハ
ウジング部材12から離隔しており、該頂部多孔
部は大きさ約1/16インチ(約1.6mm)の複数の規
則的に離隔した小孔32′を有する。同様に、底
部保持器部材28の底部多孔部34は底部ハウジ
ング部材14から離隔しており、該底部多孔部に
は貫通小孔36′が形成されている。開口32′,
36′は別の形態のものでよい。例えば、頂部あ
るいは底部保持器部材を貫通する孔の形態にして
もよく、あるいは頂部もしくは底部保持器部材か
ら外方へ突出し入射ガス流の方向に凹んだ(第1
図〜第3図に例示した実施例では32,36で示
されているごとく)突起を形成する槍状開口とし
て形成してもよく、あるいはまた第4図〜第11
図に示した好ましい実施例の場合のごとく、板の
平面から金属分を切り裂いて該部分をプレスして
数列の規則的に離隔した弧状のよろい窓を形成す
ることにより作られたよろい窓32′,36′とし
て形成してもよくその高さは約0.065インチ
(1.65mm)、幅約0.15インチ(3.81mm)および長さ
約0.5インチ(12.7mm)で、順次の整列したよろ
い窓間の間隔を約0.25インチ(6.35mm)とし各列
間の間隔を0.15インチ(3.81mm)とする。 A top aperture 30 of the top retainer member 26 is spaced apart from the top housing member 12 and includes a plurality of regularly spaced perforations 32' approximately 1/16 inch in size. has. Similarly, the bottom aperture 34 of the bottom retainer member 28 is spaced apart from the bottom housing member 14 and has a small aperture 36' formed therethrough. opening 32',
36' may take other forms. For example, they may be in the form of holes extending through the top or bottom retainer member, or projecting outwardly from the top or bottom retainer member and recessed in the direction of the incident gas flow (first
It may be formed as a lance-shaped aperture forming a protrusion (as indicated at 32, 36 in the embodiment illustrated in FIGS. 4-11), or alternatively as shown in FIGS.
As is the case with the preferred embodiment shown in the figures, the armor window 32' is made by cutting out a metal section from the plane of the plate and pressing the section to form several rows of regularly spaced arcuate armor windows. , 36' with a height of approximately 0.065 inches (1.65 mm), a width of approximately 0.15 inches (3.81 mm) and a length of approximately 0.5 inches (12.7 mm), with a spacing between successive aligned armor windows. is approximately 0.25 inches (6.35 mm) and the spacing between each row is 0.15 inches (3.81 mm).
触媒収容部46は後述するように所望の触媒物
質48で満たされ、該触媒物質48はその中に緊
包されて触媒ベツドを形成している。 Catalyst housing 46 is filled with a desired catalytic material 48, which is packaged therein to form a catalytic bed, as described below.
触媒は任意の形態で用いてよいが、好ましくは
大きさ約1/8インチ(3.17mm)のペレツト状、押
出し状または球形のもので、支持体またはキヤリ
ヤは有しても有さなくてもよい。また触媒は支持
体またはキヤリヤ上に分布させるかあるいはそれ
に含浸させるのが好ましいが、この支持体または
キヤリヤは物質の触媒的活動には寄与してもしな
くてもよい。触媒としては、任意適宜の酸化また
は還元用触媒か、あるいは酸化も還元もなしうる
触媒で870℃の作動温度まで長期間にわたつて有
効なものを用いるとよい。触媒ベツドは排気系内
の背圧を最小にするように比較的浅くするのが望
ましい。深さ約2インチ(50.8mm)のベツドが適
切であると判明している。第8図に示したよう
に、触媒物質48は各弧状よろい窓32′間の空
間を占めるが、該よろい窓により形成された開口
によつて拘留されそこを通過しないように充分な
大きさとする。 The catalyst may be used in any form, but is preferably in the form of pellets, extrudates, or spheres about 1/8 inch (3.17 mm) in size, with or without a support or carrier. good. The catalyst is also preferably distributed on or impregnated with a support or carrier, which may or may not contribute to the catalytic activity of the material. As the catalyst, any suitable oxidation or reduction catalyst, or a catalyst that can perform both oxidation and reduction, and is effective for a long period of time up to an operating temperature of 870° C., may be used. It is desirable that the catalyst bed be relatively shallow to minimize back pressure within the exhaust system. A bed approximately 2 inches (50.8 mm) deep has been found to be suitable. As shown in FIG. 8, the catalytic material 48 occupies the space between each arcuate armor window 32', but is of sufficient size so that it is confined by and does not pass through the opening formed by the armor window. .
頂部保持器部材26はその側壁部の上流側の一
端部から入口流路に向つて無孔状態で延在する上
向凹部を有し、頂部保持器部材26の該上向凹部
は底部ハウジング部材14の入口半円筒部66に
沿つてさらに軸方向に無孔状態で延在し68かつ
頂部ハウジング部材12の入口半円筒部64と共
に排気ガス入口円筒部56を形成して頂部保持器
部材26の上向凹部と頂部ハウジング部材の入口
半円筒部とが排気系統の入口側円筒部材60に直
接接続されるようになつている。また、底部保持
器部材28はその側壁部の上流側の一端部から入
口流路に向つて延在する上向凹部を有し、底部保
持器部材の該上向凹部はさらに軸方向に底部ハウ
ジング部材14の入口半円筒部66に沿つて延在
し70かつ該入口半円筒部66と重合して、頂部
保持器部材26の前記さらに軸方向に延在した上
向凹部の部分68と底部ハウジング部材14の入
口半円筒部とによつて挾持されている。 The top retainer member 26 has an upwardly recessed portion extending from one upstream end of its side wall toward the inlet flow path in a nonporous manner, and the upwardly recessed portion of the top retainer member 26 is connected to the bottom housing member. 14 further extends axially in a nonporous manner 68 along the inlet half cylinder 66 of the top housing member 12 and forms an exhaust gas inlet cylinder 56 with the inlet half cylinder 64 of the top housing member 12 . The upward recess and the inlet semi-cylindrical portion of the top housing member are adapted to be directly connected to the inlet cylindrical member 60 of the exhaust system. The bottom retainer member 28 also has an upwardly recessed portion extending from one upstream end of the sidewall toward the inlet flow path, and the upwardly recessed portion of the bottom retainer member further extends axially toward the bottom housing. The further axially extending upwardly recessed portion 68 of the top retainer member 26 extends 70 along and overlaps the inlet half-cylinder section 66 of the member 14 and the bottom housing. and the inlet semi-cylindrical portion of member 14.
底部保持器部材28はその側壁部の他端部から
出口流路に向つて無孔状態で延在する下向凹部を
有し、底部保持器部材28の該下向凹部は頂部ハ
ウジング部材12の出口半円筒部64に沿つてさ
らに軸方向に延在し74かつ底部ハウジング部材
14の出口半円筒部66と共に排気ガス出口円筒
部58を形成して底部保持器部材28の下向凹部
と底部ハウジング部材の出口半円筒部66とが排
気系統の出口側円筒部材に直接接続されるように
している。 The bottom retainer member 28 has a downwardly directed recess extending from the other end of the side wall toward the outlet flow path in a nonporous manner, and the downwardly directed recess of the bottom retainer member 28 is connected to the top housing member 12 . Further axially extending 74 along the outlet semi-cylindrical portion 64 and forming an exhaust gas outlet cylindrical portion 58 with the outlet semi-cylindrical portion 66 of the bottom housing member 14 to form a downwardly recessed portion of the bottom retainer member 28 and the bottom housing. The outlet semi-cylindrical portion 66 of the member is directly connected to the outlet side cylindrical member of the exhaust system.
頂部保持器部材26はその側壁部の他端部から
出口流路に向つて延在する下向凹部を有し、頂部
保持器部材の該下向凹部はさらに軸方向に頂部ハ
ウジング部材26の出口半円筒部64に沿つて延
在し72かつ該出口半円筒部と重合して底部保持
器部材の前記さらに軸方向に延在した下向凹部の
部分74と頂部ハウジング部材の出口半円筒部と
によつて挾持されている。 The top retainer member 26 has a downwardly directed recess extending from the other end of the sidewall toward the outlet flow path, the downwardly recessed portion of the top retainer member further extending axially toward the outlet of the top housing member 26. a portion 74 of the further axially extending downwardly recessed portion of the bottom retainer member extending along and overlapping the exit half-cylinder portion 64; and an exit half-cylinder portion of the top housing member. is held by.
前述のごとく頂部ハウジング部材12は、第1
2図に最も明瞭に示される様に上流側及び下流側
において半円筒部64をそれぞれ備えている。ま
た、底部ハウジング部材14は、上流側及び下流
側において半円筒部66をそれぞれ備えている。 As mentioned above, the top housing member 12 includes a first
As shown most clearly in FIG. 2, semi-cylindrical portions 64 are provided on the upstream and downstream sides, respectively. The bottom housing member 14 also includes semi-cylindrical portions 66 on the upstream and downstream sides.
第6図(左側)に示される様に、上流側では、
両保持器部材の上向凹部の一部は底部ハウジング
部材14の入口半円筒部66と重合して軸方向に
延在し、頂部ハウジング部材12の入口半円筒部
64と共に円筒形の排気ガス入口半円筒部56を
形成する。したがつて、頂部ハウジング部材12
と触媒保持器24の両方がその端部において排気
系統の入口側円筒部材60に溶接部106によつ
て直接接続される(第4図および第6図)。 As shown in Figure 6 (left side), on the upstream side,
A portion of the upwardly recessed portions of both retainer members overlap and extend axially with the inlet half-cylinder portion 66 of the bottom housing member 14 and together with the inlet half-cylinder portion 64 of the top housing member 12 form a cylindrical exhaust gas inlet. A semi-cylindrical portion 56 is formed. Therefore, the top housing member 12
and catalyst retainer 24 are connected directly at their ends to the inlet cylindrical member 60 of the exhaust system by a weld 106 (FIGS. 4 and 6).
一方、下流側では、第6図の右側に示される様
に、両保持器部材の下向凹部の一部は頂部ハウジ
ング部材12の出口半円筒部64と重合して軸方
向に延在し、底部ハウジング部材14の出口半円
筒部66と共に円筒形の排気ガス出口円筒部58
を形成する。したがつて、底部ハウジング部材1
4と触媒保持器24の両方がその端部において排
気系統の出口側円筒部材62に溶接部106によ
つて直接接続される(第4図および第6図)。 On the other hand, on the downstream side, as shown on the right side of FIG. 6, a portion of the downward recessed portions of both retainer members overlaps the outlet semi-cylindrical portion 64 of the top housing member 12 and extends in the axial direction, A cylindrical exhaust gas outlet cylinder 58 along with an outlet semi-cylindrical part 66 of the bottom housing member 14
form. Therefore, the bottom housing member 1
4 and catalyst retainer 24 are directly connected at their ends to the exhaust system outlet cylindrical member 62 by a weld 106 (FIGS. 4 and 6).
この様にして、この実施例においては、入口側
において底部保持器部材28は該溶接部106に
よつて頂部保持器部材26に取付られるととも
に、排気系統の入口側円筒部材60にも接続さ
れ、出口側においては、頂部保持器部材26は該
溶接部106によつて底部保持器部材28に取付
られるとともに、排気系統の出口側円筒部材62
にも接続される。 Thus, in this embodiment, on the inlet side, the bottom retainer member 28 is attached to the top retainer member 26 by the weld 106 and is also connected to the inlet cylindrical member 60 of the exhaust system, On the outlet side, the top retainer member 26 is attached to the bottom retainer member 28 by the weld 106 and is attached to the outlet side cylindrical member 62 of the exhaust system.
is also connected to.
次に、触媒保持器24の頂部及び底部保持器部
材26,28の周縁部にはその排気ガス入口縁部
と出口縁部とを除く全周縁にわたり前記フランジ
20,22にて挾着されるべきフランジ部42,
44が一体に設けられており、両保持器部材2
6,28の無孔側壁部38,40はそこから横方
向に延びる前記フランジ部42,44へと連続
し、該側壁の深さは頂部保持器部材26の一端側
から他端側へかけて増大し、底部保持器部材28
の該一端側から該他端側へかけて逆に減少し、両
保持器部材26,28を互いに組合わせると両者
間に触媒収容部46を形成するようになつてお
り、該収容部は第6図および第11図に示すごと
く深さはほぼ均等であるが両ハウジング部材1
2,14に対して傾斜して該両ハウジング部材1
2,14と共に流入排気ガスに対して断面漸次減
少形の充満室を与え、これによりかなり一定の圧
力勾配を保証すると共に、逆に流出排気ガスに対
して断面漸次増大形の充満室を与え、これにより
ほぼ一定の圧力勾配を与えるようになつている。 Next, the flanges 20 and 22 should be attached to the peripheral edges of the top and bottom retainer members 26 and 28 of the catalyst retainer 24 over the entire periphery of the catalyst retainer 24 except for the exhaust gas inlet and outlet edges. flange portion 42,
44 is integrally provided, and both retainer members 2
Imperforate sidewalls 38, 40 of 6, 28 continue therefrom to the laterally extending flange portions 42, 44, the depth of the sidewalls increasing from one end of the top retainer member 26 to the other. Increased bottom retainer member 28
conversely decreases from the one end side to the other end side, and when both the retainer members 26 and 28 are combined with each other, a catalyst accommodating part 46 is formed between them, and the accommodating part As shown in Figures 6 and 11, both housing members 1 have approximately the same depth.
2 and 14, both housing members 1
2 and 14 to provide a filling chamber with a progressively decreasing cross section for the incoming exhaust gas, thereby ensuring a fairly constant pressure gradient, and conversely provide a filling chamber with a gradually increasing cross section for the outgoing exhaust gas, This provides a nearly constant pressure gradient.
頂部および底部ハウジング部材12,14なら
びに頂部および底部保持器部材26,28の前記
フランジ部20,22,42,44は外方へ突出
してこれらの部材にほぼその全周にわたつて相互
係合可能な表面20′,22′,42′,44′(第
12図)を与える。第6図、第7図および第11
図に示したように、触媒保持器24のフランジ部
42,44はハウジング10のフランジ部20,
22間に4層サンドイツチ構造のフランジ部を形
成するように配置され、該サンドイツチはほぼ連
続的な外周溶接50により適宜密封されて内外密
封を行なう。したがつて、両保持器部材26,2
8の周縁部に設けたフランジ部42,44が両ハ
ウジング部材の周縁部に設けたフランジ部20,
22によつて挾着される。触媒保持器24内の触
媒物質はこのようにしてハウジング10内に保持
され、触媒保持器24の少なくとも両端における
側壁部38,40はハウジング10の側壁部分1
6,18から内方へ離隔しており両者間にそれぞ
れ空間52,54(第6図)を形成させている。 The flange portions 20, 22, 44 of the top and bottom housing members 12, 14 and the top and bottom retainer members 26, 28 project outwardly and are interengageable with these members over substantially their entire circumference. surfaces 20', 22', 42', 44' (FIG. 12). Figures 6, 7 and 11
As shown in the figure, the flange portions 42 and 44 of the catalyst holder 24 are connected to the flange portions 20 and 44 of the housing 10, respectively.
22 to form a flange portion of a four-layer sandwich structure, and the sandwich trench is suitably sealed by a substantially continuous outer periphery weld 50 to provide internal and external sealing. Therefore, both retainer members 26,2
The flange portions 42 and 44 provided on the periphery of both housing members are the flange portions 20 and 44 provided on the periphery of both housing members.
22. The catalytic material in the catalyst holder 24 is thus retained within the housing 10 , with the sidewalls 38 , 40 at least at both ends of the catalyst holder 24 meeting the sidewall portions 1 of the housing 10 .
6 and 18, forming spaces 52 and 54 (FIG. 6) between them, respectively.
前記上向凹部、下向凹部およびフランジ部は、
該保持器24の多孔部とともにこのようにして、
ガス入口に導入される排気ガスを、触媒保持器2
4に収容される触媒48を通過せしめる。 The upward recess, the downward recess, and the flange portion are
In this way, together with the porous portion of the retainer 24,
The exhaust gas introduced into the gas inlet is transferred to the catalyst holder 2.
It passes through a catalyst 48 housed in 4.
好ましい形態においては、排気ガス入口円筒部
56は触媒変換器の軸方向に対して僅かに上方に
変位され、一方排気ガス出口円筒部58は僅かに
下方に変位されて、ガス流をなめらかにするよう
になつている。排気ガス入口円筒部56と出口円
筒部58間の変位角度は排気系内における触媒変
換器の位置に応じて変えてよい。 In a preferred form, the exhaust gas inlet cylinder 56 is displaced slightly upward relative to the axial direction of the catalytic converter, while the exhaust gas outlet cylinder 58 is displaced slightly downward to smooth the gas flow. It's becoming like that. The angle of displacement between the exhaust gas inlet cylinder 56 and the outlet cylinder 58 may vary depending on the position of the catalytic converter within the exhaust system.
この構成によりハウジング10内には第6図お
よび第7図に示したように排気ガス入口円筒部5
6と連通した入口充満室76が形成され、これは
頂部保持器部材26のまわりに延びる空間52を
含む。同様にハウジング10内には排気ガス出口
円筒部58と連通した出口充満室78が形成さ
れ、これは底部保持器部材28のまわりに延びる
空間54を含む。 With this configuration, an exhaust gas inlet cylindrical portion 5 is provided in the housing 10 as shown in FIGS. 6 and 7.
An inlet plenum 76 is formed in communication with 6 and includes a space 52 extending around the top retainer member 26 . Similarly, an outlet fill chamber 78 is formed within the housing 10 that communicates with the exhaust gas outlet barrel 58 and includes a space 54 that extends around the bottom retainer member 28 .
上述した触媒変換器は傾斜した触媒ベツドを有
し、これは第6図に示したように入口円筒部56
から出口円筒部58へかけて上方に傾斜している
ので、入口から触媒変換器へ進入する排気ガスは
入口充満室76から両保持器部材26,28およ
び該部材内に保持された触媒物質48を通過して
下方へ通過するはずである。一般に、自動車の乗
員室の下部はトランク部の下部に比べて低く、道
路上の障害物との衝突を避けるために、深さの小
さいものが必要とされることを考慮すると、上述
の傾斜した触媒ベツドは深さは比較的浅いが容積
は比較的大きなベツドを与えるため、長さに比し
て高さが比較的小さいので、エンジンに比較的近
接した排気ガス系内の位置において自動車上に容
易に装着することができる触媒変換器が形成さ
れ、これは通常の排気マフラー位置に配置させね
ばならない触媒変換器に比して触媒変換器の迅速
なウオーム・アツプを確実ならしめるので効果的
な(排ガス規制の基準を満足し得る)排ガス処理
を行ないうるものである。傾斜した触媒ベツドお
よび排気ガスの下向きに流れにより触媒変換器内
には排気ガスの均等な流れ分布が確実に得られる
と同時に触媒粒子の流動化や運動も最小限に抑え
られる。上記においては触媒変換器は排気ガスが
入口から出口へ向けて上向きに傾斜した触媒ベツ
ドを下向きに貫流するものとして説明されたが、
ガス流を逆方向にして排気ガスが入口から出口へ
かけて下向きに傾斜するベツドを上向きに貫流す
るようにしてもよい。 The catalytic converter described above has an inclined catalytic bed which is connected to the inlet cylinder 56 as shown in FIG.
from the inlet to the outlet cylindrical portion 58 so that exhaust gas entering the catalytic converter from the inlet is directed from the inlet plenum 76 to both retainer members 26, 28 and the catalytic material 48 held therein. It should pass through and pass downward. In general, the lower part of the passenger compartment of a car is lower than the lower part of the trunk, and considering that a small depth is required to avoid collisions with obstacles on the road, the above-mentioned sloping Because the catalyst bed has a relatively shallow depth but a relatively large volume, its height is relatively small compared to its length, so it can be placed on the vehicle at a location in the exhaust gas system relatively close to the engine. A catalytic converter is formed that is easy to install and is effective because it ensures rapid warm-up of the catalytic converter compared to a catalytic converter that must be placed in a conventional exhaust muffler location. It is capable of treating exhaust gas (satisfying exhaust gas regulation standards). The slanted catalyst bed and downward flow of exhaust gas ensure an even flow distribution of exhaust gas within the catalytic converter while minimizing fluidization and movement of catalyst particles. Although the catalytic converter has been described above as having exhaust gas flowing downwardly from the inlet to the outlet through an upwardly sloping catalytic bed,
The gas flow may be reversed so that the exhaust gas flows upwardly through the downwardly sloping bed from the inlet to the outlet.
第5図〜第10図に示したように、頂部ハウジ
ング部材12および底部ハウジング部材14には
複数の凹部80が形成され、これを開口82が貫
通しており、該凹部は対応開口83を有する頂部
および底部保持器部材26,28に当接している
(第10図)。支持スタツド84が触媒保持器2
4、触媒48、触媒保持器24内の開口83およ
びハウジング10の凹部80の開口82を貫通し
ている。スタツド84の各端には肩部86が形成
され、この上に両保持器部材26,28の頂部多
孔部および底部多孔部30,34が着座してい
る。開口82は頂部および底部ハウジング部材1
2,14から外方へ延びる環状リツプ部分88に
よつて包囲されている。このリツプ部分88には
それとスタツド84との間の嵌合が比較的緩いも
のとなるように穴が形成され、スタツド84に該
リツプ部分88を溶接し、次いでこの環状リツプ
部分88のまわりの凹部80内に補強座金90を
はめ込んで連続的な環状溶接部94(第9図)に
より固着せしめると両部材は互いに溶接される。
スタツドと補強座金を使用することによりハウジ
ング10と触媒保持器がかなり強化されることに
なり高い温度や圧力においても変形に対する高い
強度と耐性を有する構造が得られる。第2図およ
び第3図に例示した本発明の他の実施例に示され
るように、保持器部材26,28の頂部多孔部お
よび底部多孔部30,34には所望に応じて剛化
リブ96を形成してもよい。しかし高温下での触
媒保持器24の垂みおよび排気ガス流の阻害は第
5図に示したように前記リブを用いずよろい窓3
2′の数を減少させることによつても低下させう
ることが判明している。 As shown in FIGS. 5-10, the top housing member 12 and the bottom housing member 14 are formed with a plurality of recesses 80 through which openings 82 extend, the recesses having corresponding openings 83. It abuts the top and bottom retainer members 26, 28 (FIG. 10). The support stud 84 is attached to the catalyst holder 2
4, the catalyst 48 passes through the opening 83 in the catalyst holder 24 and the opening 82 in the recess 80 of the housing 10. Each end of the stud 84 is formed with a shoulder 86 upon which the top and bottom porous portions 30, 34 of both retainer members 26, 28 are seated. Openings 82 are located in the top and bottom housing members 1
It is surrounded by an annular lip portion 88 extending outwardly from 2,14. The lip portion 88 is bored to provide a relatively loose fit between it and the stud 84, the lip portion 88 is welded to the stud 84, and a recess around the annular lip portion 88 is then formed. A reinforcing washer 90 is fitted within 80 and secured by a continuous annular weld 94 (FIG. 9), thereby welding the members together.
The use of studs and reinforcing washers significantly strengthens the housing 10 and catalyst retainer, resulting in a structure with high strength and resistance to deformation even at elevated temperatures and pressures. As shown in another embodiment of the invention illustrated in FIGS. 2 and 3, the top and bottom pores 30, 34 of the retainer members 26, 28 optionally include stiffening ribs 96. may be formed. However, the sagging of the catalyst holder 24 and the obstruction of the exhaust gas flow at high temperatures can be avoided by using the armored window 3 without using the ribs, as shown in FIG.
It has been found that it can also be reduced by reducing the number of 2'.
頂部ハウジング部材12の上方には頂部カバー
98が設けられ、これらの間には触媒変換器を熱
損失から防ぎ且つ自動車の下部本体を触媒変換器
の熱から保護するために例えばセラミツク・ウー
ル等の熱絶縁層100が介装されている。同様
に、底部ハウジング部材14の下方にも底部カバ
ー99が設けられ、底部ハウジング部材14と底
部カバー99の間には触媒変換器底部を介しての
熱損失を低下させるために他の熱絶縁層101が
介装されている。頂部カバー98にはU字形フラ
ンジ102が、また底部カバー99にはフランジ
部97が設けられ、該U字形フランジ102はハ
ウジング10の縁密封したフランジ部20,22
と底部カバー99のフランジ部97を蔽つてクリ
ンプされ、これによつて、頂部および底部カバー
98,99はハウジング10に適宜固定されてい
る。頂部カバー98はまたその剛性を増すための
リブ103をそなえている。 A top cover 98 is provided above the top housing member 12 and therebetween is a material such as ceramic wool, for example, to protect the catalytic converter from heat loss and to protect the lower body of the vehicle from the heat of the catalytic converter. A thermal insulation layer 100 is interposed. Similarly, a bottom cover 99 is provided below the bottom housing member 14 with another thermally insulating layer between the bottom housing member 14 and the bottom cover 99 to reduce heat loss through the bottom of the catalytic converter. 101 is interposed. The top cover 98 is provided with a U-shaped flange 102 and the bottom cover 99 is provided with a flange portion 97, which U-shaped flange 102 is provided with an edge-sealed flange portion 20, 22 of the housing 10.
and crimped over flange portion 97 of bottom cover 99, thereby securing top and bottom covers 98, 99 to housing 10 accordingly. Top cover 98 also includes ribs 103 to increase its rigidity.
上述の触媒変換器の製造組立てにおいては、ハ
ウジング10の頂部ハウジング部材12および底
部ハウジング部材14をほぼ同一の押抜体として
形成するが、これは凹部80とその貫通開口82
とを含めて単一のダイス形成作業によつて作られ
得るものである。両部材はほぼ同一であるから同
様なダイスで適宜形成してもよく、この場合部品
の生産および貯蔵を経済的に行ないうることにな
る。同様に両保持器部材26,28も同一ダイス
で形成してもよく、この場合両保持器部材は組立
時に相互交換可能である。所望ならば、組立て前
にハウジング部材12,14の一方およびそれに
近い方の保持器部材とカバー98,99の一方と
に、第12図に示したように、側壁にそれぞれ欠
104,105,107を設け、組立て後にこれ
らの穴を介してプローブを通し触媒ベツドの温度
またはその活動を監視しうるようにしてもよい。
本発明の好ましい実施例においては、この点が、
これらの部材が互いに異なる唯一の点である。 In manufacturing and assembling the catalytic converter described above, the top housing member 12 and the bottom housing member 14 of the housing 10 are formed as substantially identical stampings, which include the recess 80 and its through opening 82.
and can be made by a single die-forming operation. Since both parts are substantially identical, they may be suitably formed using similar dies, making it possible to produce and store the parts economically. Similarly, both cage members 26, 28 may be formed from the same die, in which case both cage members are interchangeable during assembly. If desired, prior to assembly, one of the housing members 12, 14 and the proximal retainer member and one of the covers 98, 99 may have cutouts 104, 105, 107, respectively, in the side walls, as shown in FIG. may be provided to allow probes to be passed through these holes to monitor the temperature of the catalyst bed or its activity after assembly.
In a preferred embodiment of the invention, this point is
This is the only point in which these members differ from each other.
次いで4個の部材12,14および26,28
をこれにスタツド84を通して組立てて取付装置
にセツトすると前記フランジ部の表面20′,2
2′,42′,44′が衝合して4層サンドイツチ
を形成し、次いでその外周縁にほぼ連続的な単一
の周縁溶接を行なつて密封し内外密封を与える。 Then the four members 12, 14 and 26, 28
When assembled through the stud 84 and set in the mounting device, the surfaces 20', 2 of the flange portion
2', 42', and 44' abut to form a four layer sandwich trench, which is then sealed with a single, generally continuous peripheral weld to its outer periphery to provide an internal and external seal.
溶接順序は好ましくは自動的であつて、取付装
置上でこれらの部材を横に立ててその周縁を垂直
方向に装着した電子ビーム溶接機に対向して露出
させ、部材をまわすとほぼ連続的な溶接が形成さ
れる。 The welding sequence is preferably automatic, with the parts standing sideways on a mounting device with their periphery exposed facing a vertically mounted electron beam welder, and turning the parts to produce a nearly continuous welding process. A weld is formed.
次に座金90を定位置に置きリツプ部分88の
溶接部94によりスタツド84およびリツプ部分
88に固着させるが、その際電子ビーム溶接作業
が好ましい。 Washer 90 is then placed in position and secured to stud 84 and lip portion 88 by weld 94 of lip portion 88, preferably using an electron beam welding operation.
次いで排気系統の入口側および出口側円筒部材
60,62を変換器の入口円筒部56および出口
円筒部58内にそれぞれ挿入した後連続的な周縁
溶接を行ない(106第4図)、入口円筒部56
においては、入口側円筒部材60を、頂部ハウジ
ング部材12、頂部保持器部材26、底部保持器
部材28および底部ハウジング部材14のそれぞ
れに対して溶接で直接接続させ(第6図の左端)、
一方出口円筒部58においては出口側円筒部材6
2を、底部ハウジング部材14、頂部保持器部材
26、底部保持器部材28および頂部ハウジング
部材12のそれぞれに対して溶接で直接接続させ
る(第6図の右端)。これにより、頂部保持器部
材26と底部保持器部材28とはその全周におい
て連続溶接接続された触媒保持器24を構成する
ことになる。 The inlet and outlet cylindrical members 60, 62 of the exhaust system are then inserted into the inlet cylindrical section 56 and the outlet cylindrical section 58 of the converter, respectively, and continuous peripheral welding is then performed (106, FIG. 4) to remove the inlet cylindrical sections. 56
, the inlet side cylindrical member 60 is directly connected to each of the top housing member 12, top retainer member 26, bottom retainer member 28, and bottom housing member 14 by welding (left end in FIG. 6),
On the other hand, in the outlet cylindrical portion 58, the outlet side cylindrical member 6
2 are welded directly to each of the bottom housing member 14, top retainer member 26, bottom retainer member 28, and top housing member 12 (far right in FIG. 6). Thereby, the top holder member 26 and the bottom holder member 28 constitute the catalyst holder 24, which is continuously welded and connected along the entire circumference thereof.
最後に充填穴108(第6図、第12図)を介
して触媒保持器24の触媒収容部46内へ触媒物
質48を入れ、前記充填穴内にねじブツシユ10
9を溶接により固定する。触媒変換器はその中の
物質が完全に詰め込まれるように充填作業時に振
動させるのが好ましい。次にブツシユ内へ着脱自
在プラグ110をねじ込む構成とすると、触媒変
換器を自動車に装着する場合でも触媒変換器の底
部に該プラグを設けることにより触媒を取替える
ことができる。 Finally, the catalyst substance 48 is introduced into the catalyst housing portion 46 of the catalyst holder 24 through the filling hole 108 (FIGS. 6 and 12), and the threaded bush 10 is inserted into the filling hole.
9 is fixed by welding. Preferably, the catalytic converter is vibrated during the filling operation to ensure that the material therein is completely packed. Next, if the removable plug 110 is screwed into the bush, even when the catalytic converter is installed in an automobile, the catalyst can be replaced by providing the plug at the bottom of the catalytic converter.
次にハウジング10の上下に絶縁層100,1
01を設置した後、溶接部50の周縁および底部
カバー99のフランジ部分97のまわりに頂部カ
バー98のU字形フランジ部102をクリンプす
ればよい。 Next, insulation layers 100 and 1 are formed on the top and bottom of the housing 10.
01, the U-shaped flange portion 102 of the top cover 98 may be crimped around the periphery of the weld 50 and the flange portion 97 of the bottom cover 99.
作動について述べると、内燃機関からのガスは
入口側円筒部材60により入口円筒部56内およ
び入口充満室76内へ運ばれ、ガスは触媒保持器
24の頂部保持器部材26を封包した後触媒保持
器24の頂部多孔部30の開口32を介して下方
へ流れ、触媒物質48を貫流しその中で酸化およ
び(または)還元反応が生じる。処理されたガス
は触媒保持器24の底部多孔部34の開口36か
ら流出して出口充満室78内に集められ、次いで
処理ずみガスは出口円筒部58から出口側円筒部
材62および排気系の尾管を介して大気中へ排出
される。 In operation, gas from the internal combustion engine is conveyed by the inlet cylindrical member 60 into the inlet cylindrical portion 56 and into the inlet plenum 76, and after sealing the top retainer member 26 of the catalyst retainer 24, the gas is transferred to the catalyst retainer 24. It flows downwardly through the openings 32 in the top porous portion 30 of the vessel 24 and across the catalyst material 48 in which the oxidation and/or reduction reactions occur. The treated gas exits through the opening 36 in the bottom porous portion 34 of the catalyst retainer 24 and is collected in the outlet plenum 78, and the treated gas then flows from the outlet barrel 58 to the outlet cylindrical member 62 and the tail of the exhaust system. Exhausted into the atmosphere via pipes.
第1図〜第3図に示した本発明実施例は第4図
〜第12図に示した実施例と同様ではあるが、底
部カバー板および熱絶縁層を有さず触媒保持器内
に圧入されたリブ96を有し、また、第1〜2図
からも明らかな如く、底部保持器部材の排気ガス
入口縁部は頂部保持器部材及び底部ハウジング部
材の排気ガス入口縁部に達しておらず、この実施
例では底部保持器部材はその排気ガス入口縁部近
傍において頂部保持器部材と底部ハウジング部材
によつて狭まれることによつて頂部保持器部材に
取付られており、同様に、頂部保持器部材の排気
ガス出口縁部は底部保持器部材及び頂部ハウジン
グ部材の排気ガス出口縁部に達しておらず、この
実施例では頂部保持器部材はその排気ガス出口縁
部近傍において底部保持器部材と頂部ハウジング
部材によつて狭まれることによつて底部保持器部
材に取付られ、したがつて、第1図の左下部およ
び右上部において、2層がそれぞれ排気系統の円
筒部材に溶接される。即ち、排気系統の入口側円
筒部材60に直接接続される上向凹部は頂部保持
器部材26のみが、また、排気系統の出口側円筒
部材62に直接接続される下向凹部は底部保持器
部材28のみが備えている。そして底部保持器部
材のフランジ部の排気ガス入口縁部も頂部保持器
部材および底部ハウジング部材のフランジ部の排
気ガス入口縁部に達しておらず、頂部保持器部材
のフランジ部の排気ガス出口縁部も底部保持器部
材および頂部ハウジング部材のフランジ部の排気
ガス出口縁部に達しておらず、したがつて、入口
側では頂部保持器部材のフランジ部のみが、ま
た、出口側では、底部保持器部材のフランジ部の
みが頂部ハウジング部材および底部ハウジング部
材のフランジ部によつて狭まれている。この場合
頂部保持器部材および底部保持器部材は排気ガス
入口縁部および同出口縁部において互いに連続溶
接されることにならないが、この部分において例
えガスリークが生じたとしても、触媒を迅回する
リークにならないので問題はない。その他の点お
よび第4〜12図実施例の説明で特記した点以外
については第4〜12図の実施例と同様である。 The embodiment of the invention shown in FIGS. 1-3 is similar to the embodiment shown in FIGS. 4-12, but without the bottom cover plate and thermal insulation layer, which is pressed into the catalyst retainer. 1-2, and the exhaust gas inlet edge of the bottom retainer member does not extend to the exhaust gas inlet edges of the top retainer member and the bottom housing member. First, in this embodiment, the bottom retainer member is attached to the top retainer member by being narrowed by the top retainer member and the bottom housing member near its exhaust gas inlet edge; The exhaust gas outlet edge of the top retainer member does not reach the exhaust gas outlet edges of the bottom retainer member and the top housing member, and in this embodiment the top retainer member has a bottom retainer near its exhaust gas outlet edge. The two layers are each welded to the cylindrical member of the exhaust system at the lower left and upper right in FIG. be done. That is, only the top retainer member 26 has an upward recess that is directly connected to the inlet cylindrical member 60 of the exhaust system, and the bottom retainer member has a downward recess that is directly connected to the outlet cylindrical member 62 of the exhaust system. Only 28 have it. Also, the exhaust gas inlet edge of the flange portion of the bottom retainer member does not reach the exhaust gas inlet edge of the flange portion of the top retainer member and the bottom housing member, and the exhaust gas outlet edge of the flange portion of the top retainer member The part also does not reach the exhaust gas outlet edge of the flanged part of the bottom retainer member and the top housing part, so that on the inlet side only the flange part of the top retainer member and on the outlet side only the flange part of the bottom retainer member Only the flange portion of the vessel member is narrowed by the flange portions of the top and bottom housing members. In this case, the top and bottom cage members are not continuously welded to each other at the exhaust gas inlet and outlet edges, but even if a gas leak were to occur in these areas, the leak would quickly circulate the catalyst. There is no problem because it does not. This embodiment is the same as the embodiment shown in FIGS. 4 to 12 except for the other points and the points specially noted in the description of the embodiment shown in FIGS. 4 to 12.
以下本発明による作用効果を説明する。 The effects of the present invention will be explained below.
第1に、本発明の変換器は次の問題を解決した
ものである。 First, the converter of the present invention solves the following problems.
(1) 触媒の保持器をハウジング内により強固に支
持すること
(2) 保持器と両方のハウジング部材を直接排気系
統に接続する。これによつて強固な支持を助長
し、又触媒を迅回するリーグがないので、入口
の有害な排ガスと出口のきれいな排ガスを確実
に分離できる。(1) Supporting the catalyst retainer more firmly within the housing (2) Connecting the retainer and both housing members directly to the exhaust system. This promotes a strong support, and since there is no league to speed up the catalyst, it is possible to reliably separate the harmful exhaust gases at the inlet from the clean exhaust gases at the outlet.
即ち、
(1) 特許請求の範囲に記載の如く、頂部保持器部
材はその側壁部の一端部から前記入口流路に向
つて無孔状態で延在する上向凹部を有し、頂部
保持器部材の該上向凹部は底部ハウジング部材
の入口半円筒部に沿つてさらに軸方向に無孔状
態で延在しかつ頂部ハウジング部材の入口半円
筒部と共に排気ガス入口円筒部を形成して頂部
保持器部材の上向凹部と頂部ハウジング部材の
入口半円筒部とが排気系統の入口側円筒部材に
直接接続されるようにし、底部保持器部材はそ
の側壁部の一端部から入口流路に向つて延在す
る上向凹部を有し、底部保持器部材の該上向凹
部はさらに軸方向に底部ハウジング部材の入口
半円筒部に沿つて無孔状態で延在しかつ該入口
半円筒部と重合して、頂部保持器部材の前記さ
らに軸方向に延在した上向凹部の部分と底部ハ
ウジング部材の入口半円筒部とによつて挾持さ
れており、底部保持器部材はその側壁部の他端
部から出口流路に向つて無孔状態で延在する下
向凹部を有し、底部保持器部材の該下向凹部は
頂部ハウジング部材の出口半円筒部に沿つてさ
らに軸方向に無孔状態で延在しかつ底部ハウジ
ング部材の出口半円筒部と共に排気ガス出口円
筒部を形成して底部保持器部材の下向凹部と底
部ハウジング部材の出口半円筒部とが排気系統
の出口側円筒部材に直接接続されるようにし、
頂部保持器部材はその側壁部の他端部から出口
流路に向つて延在する下向凹部を有し、頂部保
持器部材の該下向凹部はさらに軸方向に頂部ハ
ウジング部材の出口半円筒部に沿つて延在しか
つ該出口半円筒部と重合して、底部保持器部材
の前記さらに軸方向に延在した下向凹部の部分
と頂部ハウジング部材の出口半円筒部とによつ
て挾持されており、そして頂部及び底部ハウジ
ング部材の周縁部には排気ガス入口縁部と出口
縁部とを除く全周縁にわたりハウジングのフラ
ンジ部が一体に設けられ;また頂部及び底部保
持器部材の周縁部には排気ガス入口縁部と出口
縁部とを除く全周縁にわたり触媒保持器のフラ
ンジ部が一体に設けられており、両保持器部材
の周縁部に設けたフランジ部が両ハウジング部
材の周縁部に設けたフランジ部によつて挾着さ
れている。この利点は極めて重要である。即ち
(i) 強固にということは、変換器の自已支持性
と排気系統内に正しく支持するために重要な
要件である。何故ならば、変換器の入口は車
輛のフレームに対する機関の振動に伴つて運
動し、該フレームには変換器の出口が直接接
続されているからである。触媒保持器は溶接
により直接排気系統の円筒形部材の1つに接
続され、各ハウジング部材は溶接により直接
排気系統の円筒形部材の1つに接続されてい
ることにより触媒変換器は自己支持性がえら
れる。それによつて、排気系統の高い剛性が
えられ、自已持性の触媒保持器自体の高い耐
久性がえられる。 That is, (1) as described in the claims, the top retainer member has an upwardly recessed portion extending from one end of its side wall portion toward the inlet channel in a non-porous state; The upwardly recessed portion of the member further extends axially in an unperforated manner along the inlet half-cylinder of the bottom housing member and forms an exhaust gas inlet barrel with the inlet half-cylinder of the top housing member for top retention. The upwardly recessed portion of the retainer member and the inlet semi-cylindrical portion of the top housing member are directly connected to the inlet side cylindrical member of the exhaust system, and the bottom retainer member is connected from one end of the side wall portion toward the inlet flow path. an extending upwardly recessed portion of the bottom retainer member, the upwardly extending recessed portion of the bottom retainer member further extending axially in a non-porous manner along and overlapping an inlet half-cylinder portion of the bottom housing member; and is sandwiched between the further axially extending upwardly recessed portion of the top retainer member and the inlet semi-cylindrical portion of the bottom housing member, and the bottom retainer member is held at the other end of the side wall portion thereof. a downwardly directed recess extending imperforately from the bottom toward the outlet flow path, the downwardly directed recess in the bottom retainer member being further axially imperforate along the outlet semi-cylindrical portion of the top housing member; and together with the outlet semi-cylindrical portion of the bottom housing member form an exhaust gas outlet cylindrical portion such that the downward recess of the bottom retainer member and the outlet semi-cylindrical portion of the bottom housing member form an exhaust gas outlet cylindrical portion of the exhaust system. be connected directly,
The top retainer member has a downwardly directed recess extending from the other end of the sidewall toward the outlet flow passage, the downwardly recessed portion of the top retainer member further extending axially into the outlet semi-cylinder of the top housing member. extending along the section and overlapping the outlet semi-cylindrical section and sandwiched by the further axially extending downwardly recessed section of the bottom retainer member and the exit semi-cylindrical section of the top housing member. and the periphery of the top and bottom housing members is integrally provided with a housing flange portion over the entire periphery except the exhaust gas inlet and outlet edges; and the periphery of the top and bottom retainer members is integrally provided. The flange portion of the catalyst holder is integrally provided over the entire periphery except for the exhaust gas inlet edge and outlet edge, and the flange portion provided on the periphery of both holder members is connected to the periphery of both housing members. It is clamped by a flange section provided on the. This advantage is extremely important. Namely: (i) Being strong is an important requirement for the converter to be self-supporting and properly supported within the exhaust system. This is because the inlet of the converter moves with the vibrations of the engine relative to the vehicle frame, to which the outlet of the converter is directly connected. The catalytic converter is self-supporting in that the catalyst retainer is connected directly to one of the cylindrical members of the exhaust system by welding, and each housing member is connected directly to one of the cylindrical members of the exhaust system by welding. It can be grown. This results in high rigidity of the exhaust system and high durability of the self-supporting catalyst holder itself.
(ii) 自己支持性の触媒変換器の剛性は、保持器
がハウジングを補強し、機関と車のフレーム
との間の相対運動によるハウジング破損を防
止することにより向上される。このハウジン
グ補強は、各頂部と底部ハウジング部材は触
媒保持器の延在部と直接接続される延在部を
有し、かつその部分で排気系統の円筒部材に
変換器が接続されていることにより達成され
る。触媒保持器の延在部が各端部でハウジン
グ部材のそれぞれの延在部と重合して軸方向
に延在し、これらが各端部で溶接により直接
に排気系統の円筒部材に接続されていること
により剛性は一層強化される。 (ii) The stiffness of the self-supporting catalytic converter is improved by the retainer reinforcing the housing and preventing housing failure due to relative movement between the engine and the vehicle frame. This housing reinforcement is achieved by the fact that each top and bottom housing member has an extension that is directly connected to an extension of the catalyst retainer and where the transducer is connected to the cylindrical member of the exhaust system. achieved. The extensions of the catalyst retainer overlap and extend axially at each end with respective extensions of the housing member, which are connected at each end directly by welding to the cylindrical member of the exhaust system. The rigidity is further strengthened by this.
本発明によれば、まず第2に高さの低い比較的
浅い深さの外形の変換器がえられる。即ち、
(1) 特許請求の範囲に示す如く、頂部及び底部保
持器部材は、実質的に均一な深さを有し、かつ
排気ガス入口から排気ガス出口に向つて上向に
傾斜した触媒収容部を形成する。この利点は極
めて重要である。何故ならばこの変換器は乗用
車の下部に取付けるべく設計されたものだから
である。即ち乗客ののる部分の底部はトランク
の底部よりも低いので、地上の障害物にぶつか
らないような浅い変換器が必要である。本発明
の触媒保持器は、4個の部材即ち頂部及び底部
保持器部材と頂部及び底部ハウジング部材とを
組合せるだけで簡単に形成される。この組合せ
により、比較的浅い深さで比較的大容量の触媒
ベツドが提供され、変換器のハウジングは長さ
に対し比較的低い高さで構成されるので、この
変換器を機関に比較的近接する排ガスシステム
内の所望の位置で車に容易に取り付けることが
でき、通常排気マフラー部分におかねばならな
かつた触媒変換器に比し変換器のウオームアツ
プを迅速に行うことができ、有効な排ガス処理
ができる。(即ち排ガスの規制基準に合致す
る。)
第3に、本発明の変換器は、若干傾斜した触媒
ベツドにより均一な圧力勾配とガスの流れに対す
る抵抗の減少がえられる。即ち
(1) 特許請求の範囲に示す如く、頂部及び底部保
持器部材の側壁部は排ガス入口から出口に向つ
て深さがそれぞれ増大及び減少する。 According to the invention, firstly, a transducer with a low profile and a relatively shallow depth is obtained. That is, (1) as shown in the claims, the top and bottom retainer members each have a substantially uniform depth and a catalyst housing that slopes upwardly from the exhaust gas inlet to the exhaust gas outlet; form a section. This advantage is extremely important. This is because this converter is designed to be mounted on the underside of a passenger car. That is, since the bottom of the passenger area is lower than the bottom of the trunk, a shallow transducer is required to avoid hitting obstacles on the ground. The catalyst retainer of the present invention is simply formed by assembling four members: top and bottom retainer members and top and bottom housing members. This combination provides a relatively high capacity catalyst bed at a relatively shallow depth, and the transducer housing is configured with a relatively low height relative to its length, allowing the transducer to be placed relatively close to the engine. It can be easily installed in the vehicle at the desired location in the exhaust gas system to provide effective exhaust gas warm-up compared to catalytic converters, which normally have to be placed in the exhaust muffler area. Can be processed. Third, the converter of the present invention provides a uniform pressure gradient and reduced resistance to gas flow due to the slightly sloped catalyst bed. That is, (1) as shown in the claims, the depths of the side wall portions of the top and bottom retainer members increase and decrease, respectively, from the exhaust gas inlet to the outlet.
この利点は重要である。何故ならば、触媒ベツ
ドを通るガスの流れがほぼ均一に分散され最大の
触媒寿命と最適の触媒変換ができるからである。
頂部及び底部保持器部材は、頂部及び底部ハウジ
ング部材からの間隔は位置によつて異るが、ほぼ
均一の深さの若干傾斜する触媒収容部を構成す
る。頂部保持器部材と頂部ハウジング部分との間
の間隔は排ガス入口から出口へ向つて順次減少
し、流入する排ガスの流れに対し順次に減少する
断面を形成し、ほぼ一定の圧力勾配を付与する。
同様に底部保持器部材と底部ハウジング部材との
間の間隔はガス入口から出口に向つて順次増大
し、流入する排ガスの流れに対し順次増大する断
面を形成し、ほぼ一定の圧力勾配を付与する。ガ
スの流れに対する抵抗を減少することは又ガスを
保護器内に流入し又排出する部分を規定する入口
及び出口部分における延在する保持器構造により
達成される。この触媒変換器の構造は、流線型の
ガス流れを形成し、流れる排ガスの流入、流出を
容易とする。本発明において、これらの効果は、
頂部及び底部保持器部材の側壁部が排ガスの入口
から出口へ向つてその深さがそれぞれ増大及び減
少することにより達成される。 This advantage is important. This is because the flow of gas through the catalyst bed is nearly uniformly distributed for maximum catalyst life and optimum catalytic conversion.
The top and bottom retainer members define slightly sloping catalyst receptacles of substantially uniform depth with varying spacing from the top and bottom housing members. The spacing between the top retainer member and the top housing portion decreases progressively from the exhaust gas inlet to the outlet, creating a progressively decreasing cross-section and a substantially constant pressure gradient for the incoming exhaust gas flow.
Similarly, the spacing between the bottom retainer member and the bottom housing member increases progressively from the gas inlet to the outlet, creating a progressively increasing cross-section for the incoming exhaust gas flow, imparting a substantially constant pressure gradient. . Reducing the resistance to gas flow is also achieved by extending retainer structures at the inlet and outlet sections that define the flow of gas into and out of the protector. The structure of this catalytic converter creates a streamlined gas flow and facilitates the inflow and outflow of flowing exhaust gas. In the present invention, these effects are as follows.
This is achieved by the side walls of the top and bottom retainer members increasing and decreasing in depth, respectively, from the exhaust gas inlet to the outlet.
第4に、本発明の変換器では、若干傾斜する触
媒収容部内に収容される触媒を迅回するリークが
ないことである。即ち、
(1) 特許請求の範囲に示す如く、頂部保持器部材
はその側壁部の一端部から入口流路に向つて無
孔状態で延在する上向凹部を有し、頂部保持器
部材の該上向凹部は底部ハウジング部材の入口
半円筒部に沿つてさらに軸方向に無孔状態で延
在しかつ頂部ハウジング部材の入口半円筒部と
共に排気ガス入口円筒部を形成して頂部保持器
部材の上向凹部と頂部ハウジング部材の入口半
円筒部とが排気系統の入口側円筒部材に直接接
続されるようにし、底部保持器部材はその側壁
部の他端部から出口流路に向つて無孔状態で延
在する下向凹部を有し、底部保持器部材の該下
向凹部は頂部ハウジング部材の出口半円筒部に
沿つてさらに軸方向に無孔状態で延在しかつ底
部ハウジング部材の出口半円筒部と共に排気ガ
ス出口円筒部を形成して底部保持器部材の下向
凹部と底部ハウジング部材の出口半円筒部とが
排気系統の出口側円筒部材に直接接続されるよ
うにし、そして頂部及び底部保持器部材の周縁
部には排気ガス入口縁部と出口縁部とを除く全
周縁にわたりフランジ部が一体に設けられてお
り、前記両保持器部材の周縁部に設けおフラン
ジ部が前記両ハウジング部材の周縁部に設けた
フランジ部によつて挾着されている。 Fourth, in the converter of the present invention, there is no leakage that would quickly dislodge the catalyst housed in the slightly inclined catalyst housing. That is, (1) As shown in the claims, the top retainer member has an upwardly recessed portion extending in a non-porous state from one end of the side wall portion toward the inlet flow path; The upwardly directed recess further extends axially in a nonporous manner along the inlet half-cylinder of the bottom housing member and forms an exhaust gas inlet barrel with the inlet half-cylinder of the top housing member. The upward recess and the inlet semi-cylindrical portion of the top housing member are directly connected to the inlet cylindrical member of the exhaust system, and the bottom retainer member is connected directly to the inlet cylindrical member of the exhaust system from the other end of the side wall thereof toward the outlet flow path. a downwardly extending recess in the bottom retainer member, the downwardly facing recess in the bottom retainer member extending further axially in a nonporous manner along the exit semi-cylindrical portion of the top housing member; together with the outlet semi-cylindrical part, an exhaust gas outlet cylinder is formed such that the downward recess of the bottom retainer member and the outlet semi-cylindrical part of the bottom housing member are directly connected to the outlet cylinder of the exhaust system; A flange portion is integrally provided on the periphery of the bottom cage member over the entire periphery except for the exhaust gas inlet edge and the outlet edge. Both housing members are clamped by flanges provided at their peripheral edges.
(2) 特許請求の範囲に記載の如く、頂部及び底部
保持器部材は、排ガスの入口から出口へ向つて
上向に傾斜する実質的に均一な深さの傾斜した
触媒収容部を形成し、そして頂部及び底部保持
器部材の側壁部は、排ガス入口から出口に向つ
てそれぞれ増大及び減少する深さを有する。(2) as described in the claims, the top and bottom retainer members define a substantially uniform depth sloped catalyst receptacle that slopes upwardly from the exhaust gas inlet to the exhaust gas outlet; The sidewall portions of the top and bottom retainer members have depths that increase and decrease, respectively, from the exhaust gas inlet to the outlet.
この利点は極めて重要である。即ち
(i) もし触媒を迅回するリークが触媒保持器の
周りで発生すると、有害な未処理ガスがその
まま外気に放散され、
(ii) 触媒を迅回するリークがないことは変換器
の寿命をのばす。 This advantage is extremely important. (i) If a catalyst fast leak occurs around the catalyst retainer, harmful untreated gases will be released into the atmosphere, and (ii) the absence of a catalyst fast leak will reduce the lifetime of the converter. Extend.
本発明は、又新らしい重要な特徴を有してい
る。保持器は流入排ガスの下で触媒収容部をこえ
て無孔に上流方向に延在し、それによつて触媒収
容空間を減少させることなく、又保持器は排出ガ
スの上で触媒収容部をこえて無孔に下流方向に延
在し、それによつて触媒収容部を減少せしめるこ
となく、従つて触媒保持空間の有効容積を充分に
維持し、かつ排ガスが触媒を迅回するリークがな
い点である。 The present invention also has novel and important features. The holder extends upstream beyond the catalyst accommodating part under the inflowing exhaust gas, without thereby reducing the catalyst accommodating space; The structure extends in the downstream direction without any holes, thereby not reducing the catalyst accommodating portion, thus maintaining a sufficient effective volume of the catalyst holding space, and without leaking the exhaust gas through the catalyst. be.
(A) 延在部は
(1) 適正な触媒容量と
(2) フランジ部と相俟つて排ガスがガス入口に
流入し触媒を必ず通過する、
(3) 触媒変換器に不可避の温度勾配と急激な温
度変化による熱応力に充分に耐える極めて頑
丈な装置を提供する。(A) The extended section has (1) appropriate catalyst capacity, (2) combined with the flange section to ensure that exhaust gas flows into the gas inlet and passes through the catalyst, and (3) avoids the inevitable temperature gradients and sudden changes in the catalytic converter. To provide an extremely robust device that can sufficiently withstand thermal stress caused by severe temperature changes.
(B) 頂部と底部の保持器部材は、
(1) 頂部と底部ハウジング部材と組合わされ
て、若干傾斜した触媒収容部を提供し、
(2) 排ガス入口から出口へ向つてそれぞれ深さ
が増大及び減少する側壁部を有し、前記延在
部と協働して、変換器内に容易に流入し、又
容易に流出しうるようにする。この特徴は、
ガス流入に対し抵抗を少くする。(B) The top and bottom retainer members (1) in combination with the top and bottom housing members provide a slightly sloped catalyst housing, and (2) each increase in depth from the exhaust gas inlet to the outlet. and a decreasing sidewall portion which cooperates with said extension portion to facilitate entry into and exit from the transducer. This feature is
Reduce resistance to gas inflow.
本発明に係る触媒変換器は、その最終組立段階
で4つの主要部材を単に組合せるだけで製造でき
るので、接続部の数を減少し、したがつて継目を
最小数に減少できる。それによつて使用による破
損の可能性と触媒を迅回するリークの可能性を減
少できる。更に、簡単な構造と設計により鋼材の
使用量が減少し、触媒を加温し有効な操作温度に
達するまでのウオームアツプの時間を減少する。
然も構造が簡単なため大量生産における誤りの可
能性が減少する。 Since the catalytic converter according to the invention can be manufactured by simply assembling four main parts in its final assembly stage, the number of connections and therefore the number of seams can be reduced to a minimum. This reduces the possibility of wear-and-tear damage and the possibility of leaks that can rapidly deactivate the catalyst. Additionally, the simple construction and design reduces steel usage and reduces warm-up time to warm up the catalyst and reach effective operating temperatures.
However, the simple structure reduces the possibility of errors in mass production.
以上本発明は特許請求の範囲に記載の発明に係
り、更に実施上次の特徴の1つ又はそれ以上を有
しうるものである。 As described above, the present invention relates to the invention described in the claims, and may further have one or more of the following features in practice.
(1) 各保持部材は単一の一体素材からなつてい
る。(1) Each retaining member shall consist of a single unitary piece of material.
(2) 保持器の有孔部は円弧状にプレスで形成され
た保持器の一部である。(2) The perforated part of the cage is a part of the cage that is press-formed into an arc shape.
(3) 頂部ハウジング部材上におかれる頂部カバー
はハウジング部材と保持器部材の密封された周
縁端部上にクリンプされる周縁フランジを有
し、熱絶縁材料の層100は、頂部カバーとハ
ウジング部材の間に配置される。(3) A top cover that rests on the top housing member has a peripheral flange that is crimped onto the sealed peripheral ends of the housing member and retainer member, and the layer 100 of thermally insulating material is attached to the top cover and the housing member. placed between.
(4) 底部ハウジング部材に底部カバーがとり付け
られ熱絶縁材料の層は底部ハウジング部材と底
部カバーとの間におかれる。(4) A bottom cover is attached to the bottom housing member and a layer of thermally insulating material is disposed between the bottom housing member and the bottom cover.
第1図は本発明に係る触媒変換器の一実施例の
一部断面側面図(第2図の−断面図)、第2
図は第1図の縮小平面図で内部構造を示すために
一部切欠いた図、第3図は第1図の−線にお
ける断面図、第4図は本発明に係る触媒変換器の
別の好ましい実施例の側面図、第5図は第4図の
平面図で内部構造を示すために一部切欠いた図、
第6図は第5図の−線における断面図、第7
図は第4図の−線における断面図、第8図は
第5図の−線における拡大断片的断面図、第
9図は第5図の一部の拡大平面図で内部の溶接の
一部を示す図、第10図は第9図の−線にお
ける断面図、第11図は第5図のXI−XI線におけ
る拡大断片的側面図、第12図は第4図〜第11
図に示した触媒変換器実施例の展開斜視図であ
る。
〔主要部分の参照符号の説明〕、10……ハウ
ジング、12,14……頂部および底部ハウジン
グ部材、24……触媒保持器、26,28……頂
部および底部保持器部材、30,34……多孔頂
部および底部、46……触媒収容部、48……触
媒物質、56……排気ガス入口円筒部、58……
排気ガス出口円筒部、64……頂部ハウジング部
材の半円筒部、66……底部ハウジング部材の半
円筒部、60……排気系統の入口側円筒部材、6
2……排気系統の出口側円筒部材、20,22…
…ハウジングのフランジ部、42,44……触媒
保持器のフランジ部。
FIG. 1 is a partially cross-sectional side view (-cross-sectional view in FIG. 2) of an embodiment of a catalytic converter according to the present invention;
The drawing is a reduced plan view of Fig. 1 with a part cut away to show the internal structure, Fig. 3 is a sectional view taken along the - line in Fig. 1, and Fig. 4 is another view of the catalytic converter according to the present invention. FIG. 5 is a side view of the preferred embodiment; FIG. 5 is a plan view of FIG. 4, with a portion cut away to show the internal structure;
Figure 6 is a sectional view taken along the - line in Figure 5;
The figure is a sectional view taken along the - line in Fig. 4, Fig. 8 is an enlarged fragmentary sectional view taken along the - line in Fig. 5, and Fig. 9 is an enlarged plan view of a part of Fig. 5, showing a part of the internal welding. FIG. 10 is a sectional view taken along the - line in FIG. 9, FIG. 11 is an enlarged fragmentary side view taken along the line XI--XI in FIG. 5, and FIG.
1 is an exploded perspective view of the illustrated catalytic converter embodiment; FIG. [Explanation of reference symbols of main parts], 10... Housing, 12, 14... Top and bottom housing members, 24... Catalyst retainer, 26, 28... Top and bottom retainer members, 30, 34... Porous top and bottom, 46...catalyst housing part, 48...catalyst material, 56...exhaust gas inlet cylindrical part, 58...
Exhaust gas outlet cylindrical part, 64... Semi-cylindrical part of top housing member, 66... Semi-cylindrical part of bottom housing member, 60... Inlet side cylindrical member of exhaust system, 6
2...Exhaust system outlet side cylindrical member, 20, 22...
...Flange portion of the housing, 42, 44...Flange portion of the catalyst holder.
Claims (1)
収容された触媒を通過して流れ;該ハウジングが
頂部および底部ハウジング部材を有し、該両ハウ
ジング部材はそれぞれ皿形部を有し、該両皿形部
で前記触媒保持器を囲い;該両皿形部は円筒形の
排気ガス入口流路および出口流路を形成するため
の半円筒部を有し、該入口流路および出口流路は
前記触媒保持器の触媒収容部から軸方向に離され
てそれぞれ配置され;前記触媒保持器の触媒収容
部は、触媒を通過する排気ガス路を形成する頂部
および底部多孔部を有し、更に、前記触媒保持器
はハウジング部材の周縁に延在するフランジ部の
間に挾まれるフランジ部を有する内燃機関用排気
ガス触媒変換器において; 前記触媒保持器24は頂部および底部保持器部
材26,28によつて形成され;該頂部および底
部保持器部材はそれぞれ前記頂部および底部多孔
部とともに前記触媒収容部を形成する側壁部を有
しており; 前記頂部保持器部材はその側壁部の一端部から
前記入口流路に向つて無孔状態で延在する上向凹
部を有し; 頂部保持器部材の該上向凹部は底部ハウジング
部材14の入口半円筒部66に沿つてさらに軸方
向に無孔状態で延在しかつ頂部ハウジング部材1
2の入口半円筒部64と共に排気ガス入口円筒部
56を形成して頂部保持器部材の上向凹部と頂部
ハウジング部材の入口半円筒部とが排気系統の入
口側円筒部材に直接接続されるようにし; 前記底部保持器部材はその側壁部の一端部から
入口流路に向つて延在する上向凹部を有し; 底部保持器部材の該上向凹部はさらに軸方向に
底部ハウジング部材の入口半円筒部66に沿つて
延在しかつ該入口半円筒部66と重合して、頂部
保持器部材の前記さらに軸方向に延在した上向凹
部の部分と底部ハウジング部材の入口半円筒部と
によつて挾持されており; 前記底部保持器部材はその側壁部の他端部から
前記出口流路に向つて無孔状態で延在する下向凹
部を有し; 底部保持器部材の該下向凹部は頂部ハウジング
部材12の出口半円筒部64に沿つてさらに軸方
向に無孔状態で延在しかつ底部ハウジング部材1
4の出口半円筒部66と共に排気ガス出口円筒部
58を形成して底部保持器部材の下向凹部と底部
ハウジング部材の出口半円筒部とが排気系統の出
口側円筒部材に直接接続されるようにし; 前記頂部保持器部材はその側壁部の他端部から
出口流路に向つて延在する下向凹部を有し; 頂部保持器部材の該下向凹部はさらに軸方向に
頂部ハウジング部材の出口半円筒部64に沿つて
延在しかつ該出口半円筒部と重合して、底部保持
器部材の前記さらに軸方向に延在した下向凹部の
部分と頂部ハウジング部材の出口半円筒部とによ
つて挾持されており; 前記頂部及び底部ハウジング部材を構成する前
記入口半円筒部、皿形部及び出口半円筒部は、そ
れぞれ同一の素材により一体に形成され; 頂部及び底部ハウジング部材の周縁部には排気
ガス入口縁部と出口縁部とを除く全周縁にわたり
前記ハウジングのフランジ部が一体に設けられ;
また頂部及び底部保持器部材の周縁部には排気ガ
ス入口縁部と出口縁部とを除く全周縁にわたり前
記触媒保持器のフランジ部が一体に設けられてお
り、前記両保持器部材の周縁部に設けたフランジ
部が前記両ハウジング部材の周縁部に設けたフラ
ンジ部によつて挾着されており;更に 前記頂部および底部保持器部材の前記触媒収容
部は排気ガス入口56から排気ガス出口58に向
つて上向に傾斜しかつ実質的に均一な深さを有し
ており;そして頂部および底部保持器部材の側壁
部は排気ガス入口56から排気ガス出口58へ向
つて、深さがそれぞれ増加および減少しているこ
とを特徴とする内燃機関用排気ガス触変変換器。Claims: 1. Exhaust gas flows past a catalyst contained within a catalyst retainer within a housing; the housing has top and bottom housing members, each housing member having a dish-shaped portion. said plate-shaped portions surround said catalyst retainer; said plate-shaped portions have a semi-cylindrical portion for forming a cylindrical exhaust gas inlet flow path and an outlet flow path; and an outlet flow path are each arranged axially spaced from a catalyst receiving portion of the catalyst holder; the catalyst receiving portion of the catalyst holder has top and bottom porous portions forming an exhaust gas passage through the catalyst. and further comprising: an exhaust gas catalytic converter for an internal combustion engine, wherein the catalyst retainer has a flange portion sandwiched between flange portions extending around a periphery of a housing member; formed by vessel members 26, 28; the top and bottom cage members each have sidewalls that together with the top and bottom pores form the catalyst housing; the top cage member has sidewalls thereof; the upper retainer member has an upwardly extending recess extending imperforately from one end of the portion toward the inlet flow path; The top housing member 1 extends axially in a non-perforated manner.
The exhaust gas inlet cylindrical portion 56 is formed together with the inlet semi-cylindrical portion 64 of No. 2 so that the upwardly recessed portion of the top retainer member and the inlet semi-cylindrical portion of the top housing member are directly connected to the inlet side cylindrical member of the exhaust system. the bottom retainer member has an upwardly recessed portion extending from one end of the side wall portion toward the inlet channel; the upwardly recessed portion of the bottom retainer member further extends axially toward the inlet of the bottom housing member; a portion of the further axially extending upwardly recessed portion of the top retainer member and an inlet semi-cylinder portion of the bottom housing member extending along and overlapping the inlet half-cylinder portion 66; the bottom retainer member has a downward recess extending in a non-porous manner from the other end of the side wall toward the outlet flow path; The facing recess extends axially further along the outlet semi-cylindrical portion 64 of the top housing member 12 and in a non-porous manner
The exhaust gas outlet cylindrical portion 58 is formed together with the outlet semi-cylindrical portion 66 of 4 so that the downward recess of the bottom retainer member and the outlet semi-cylindrical portion of the bottom housing member are directly connected to the outlet side cylindrical member of the exhaust system. the top retainer member has a downwardly recessed portion extending from the other end of the side wall portion toward the outlet flow passage; the downwardly directed recessed portion of the top retainer member further extends axially into the top housing member; a portion of the further axially extending downwardly recessed portion of the bottom retainer member and an exit half-cylinder portion of the top housing member extending along and overlapping the outlet half-cylinder portion 64; The inlet semi-cylindrical part, the dish-shaped part, and the outlet semi-cylindrical part constituting the top and bottom housing members are each integrally formed of the same material; and the peripheral edges of the top and bottom housing members a flange portion of the housing is integrally provided on the entire periphery except for the exhaust gas inlet edge and the outlet edge;
Further, the flange portion of the catalyst retainer is integrally provided on the entire peripheral edge of the top and bottom retainer members except for the exhaust gas inlet edge and the outlet edge, and the flange portion of the catalyst retainer is integrally provided on the entire peripheral edge of the top and bottom retainer members, flange portions provided on the housing members are clamped by flange portions provided on the peripheral edges of both housing members; and the sidewall portions of the top and bottom retainer members each have a depth from exhaust gas inlet 56 to exhaust gas outlet 58; An exhaust gas catalytic converter for an internal combustion engine characterized by increasing and decreasing exhaust gas.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17794771A | 1971-09-07 | 1971-09-07 | |
| US211306 | 1971-12-23 | ||
| US262708 | 1972-06-14 | ||
| US177947 | 1988-04-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6165009A JPS6165009A (en) | 1986-04-03 |
| JPS6339762B2 true JPS6339762B2 (en) | 1988-08-08 |
Family
ID=22650565
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8304180A Expired JPS5911724B2 (en) | 1971-09-07 | 1980-06-20 | Exhaust gas catalytic converter for internal combustion engines |
| JP6102985A Granted JPS6165009A (en) | 1971-09-07 | 1985-03-27 | Exhaust gas catalytic converter for internal combustion engines |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8304180A Expired JPS5911724B2 (en) | 1971-09-07 | 1980-06-20 | Exhaust gas catalytic converter for internal combustion engines |
Country Status (4)
| Country | Link |
|---|---|
| JP (2) | JPS5911724B2 (en) |
| AU (1) | AU448890B2 (en) |
| BR (1) | BR7206004D0 (en) |
| GB (1) | GB1344969A (en) |
-
1972
- 1972-08-03 AU AU45275/72A patent/AU448890B2/en not_active Expired
- 1972-08-24 GB GB3939572A patent/GB1344969A/en not_active Expired
- 1972-08-31 BR BR600472A patent/BR7206004D0/en unknown
-
1980
- 1980-06-20 JP JP8304180A patent/JPS5911724B2/en not_active Expired
-
1985
- 1985-03-27 JP JP6102985A patent/JPS6165009A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| GB1344969A (en) | 1974-01-23 |
| JPS5911724B2 (en) | 1984-03-17 |
| JPS6165009A (en) | 1986-04-03 |
| BR7206004D0 (en) | 1973-08-21 |
| AU4527572A (en) | 1974-03-07 |
| JPS56156410A (en) | 1981-12-03 |
| AU448890B2 (en) | 1974-05-30 |
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