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JPS6350382B2 - - Google Patents
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JPS6350382B2 - - Google Patents

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Publication number
JPS6350382B2
JPS6350382B2 JP3881486A JP3881486A JPS6350382B2 JP S6350382 B2 JPS6350382 B2 JP S6350382B2 JP 3881486 A JP3881486 A JP 3881486A JP 3881486 A JP3881486 A JP 3881486A JP S6350382 B2 JPS6350382 B2 JP S6350382B2
Authority
JP
Japan
Prior art keywords
paint
zeolite
fine
condensation
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP3881486A
Other languages
Japanese (ja)
Other versions
JPS62197469A (en
Inventor
Kimio Yoshimi
Masaru Tamori
Taketo Yamamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Mining and Cement Co Ltd
Original Assignee
Mitsubishi Mining and Cement Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Mining and Cement Co Ltd filed Critical Mitsubishi Mining and Cement Co Ltd
Priority to JP3881486A priority Critical patent/JPS62197469A/en
Publication of JPS62197469A publication Critical patent/JPS62197469A/en
Publication of JPS6350382B2 publication Critical patent/JPS6350382B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Building Environments (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Paints Or Removers (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

〔産業上の利用分野〕 本発明は、壁面結露防止用塗料に関し、建築物
の外気に面する壁面が外気温度により冷却されて
室内の壁面が室内雰囲気の露点温度以下となつた
場合に、室内の過剰水分が壁面に凝結して生ずる
結露を防止するための、ペースト状の壁面結露防
止用塗料に関する。 〔従来の技術〕 建築物壁面の結露を防止するには従来、外壁と
内壁との間にガラスウールやロツクウール、発泡
合成樹脂ボード等の断熱材を入れることによつて
断熱性を高めて結露を防止する技術や、新築コン
クリート建築物構造の場合コンクリート打設時に
型枠内面に発泡合成樹脂ボードを取り付けてコン
クリートを流し込み、コンクリートと断熱材と一
体化した構造により結露を防ぐ技術などが知られ
ており、また、コンクリート自体に湿気の流入を
防ぐ目的で例えばステリアリン酸塩等の撥水剤等
を添加混合して打設する等の施策がある。 既存のコンクリート建築物に対しては結露を防
止する改善技術は知られていない。 〔発明が解決しようとする問題点〕 このように室内壁の結露防止策として、外壁と
内壁との間に断熱材を入れることによつて、室内
の壁面温度の低下を防ぎ結露発生を防止する技術
は、断熱材を全く使用しない場合よりは効果は認
められるが完全策とはならない。すなわち、内壁
の表面での結露の発生は減少するが、外壁と断熱
材との間には空間層が存在し、内壁面には結露は
発生していないが外壁と断熱材との間には結露が
発生している。この原因は壁と断熱材とは密着し
ておらず空間層が存在するためと考えられる。こ
れを解決するためには、壁面と断熱材とを密着し
て、しかも断熱層の厚さを大きくしなければなら
ず、構造的にも制約を受けるばかりでなく経済的
にも高価なものとなる。 またコンクリート建築物の場合最近ステリアリ
ン酸塩等の撥水材等を添加混合して打設すること
等が提案されているがステリアリン酸塩等の撥水
剤そのものの化学的安定性に問題があり実用化さ
れていない。 本発明者等は、このような実情に鑑み、安価で
有効な結露防止材の開発について鋭意研究を行つ
た結果、ペースト状の新規な塗料を開発した。本
発明は壁面に塗装することによつて結露防止に有
効な壁面結露防止用塗料を提供するものである。 〔問題点を解決するための手段〕 本発明の要旨とするところは、有機質または無
機質展色剤、体質顔料、希釈剤、アルカリ性薬
品、顔料、および防かび剤剤から構成される塗料
と、吸湿性のある微粉パーライトおよび微粉ゼオ
ライトとの混合物から成ることを特徴とする壁面
結露防止用塗料である。 上記微粉パーライトおよび微粉ゼオライトの添
加量を15〜40重量%の範囲内とすると効果的であ
り、また微粉パーライトと微粉ゼオライトとの混
合割合を2:1〜4:1の範囲内とする。 有機質または無機質展色剤としては、ミルクン
カゼイン、大豆カゼイン、ニカワ、ゼラチン、フ
ノリ、小麦粉、メチルセルローズ、酢酸ビニル粉
末、その他水溶性合成樹脂、ケイ酸ソーダ、ケイ
酸カリ等の公知な展色材料から選択したものを用
いればよく、その中でもメチルセルローズがよ
い。 展色材料としてメチルセルローズを選択し、メ
チルセルローズ2%、希釈剤として水を用いて2
重量%の水溶液とし、その量は55〜80重量%の範
囲とし、好適には60〜70重量%である。55重量%
未満では塗料の展性不十分、吸湿時付着性の劣化
などの問題があり80重量%を越えると他の材料が
過少となり好ましくない。 体質顔料としては、白亜、重質炭酸カルシウ
ム、軽質炭酸カルシウム、ごふん、バライト粉、
クレーイ等がある。 吸湿性のある微粉パーライトおよび微粉ゼオラ
イトの量は合量で40〜15重量%がよく、さらに好
適には20〜15重量%である。15重量%未満では湿
分を吸収する能力が小さく経済的でなく、40重量
%を越えると塗装が容易でなくなり作業性が劣
り、また吸湿時に塗料が流下するおそれが生ず
る。微粉パーライトとゼオライトとの混合割合は
2:1〜4:1で、好適には2:1〜3:1であ
る。微粉パーライトは比表面積が2.5m2/g、微
粉ゼオライトは比表面積が25m2/g前後のものが
好ましい。 防かび剤としてはペンチクロロフエノール、ペ
ンタクロロフエノールナトリウム、パラクロロメ
タキシレノール等が使用され、その添加量は展色
材料、希釈剤、体質顔料、微粉パーライトおよび
微粉ゼオライトの合量に対して0.05〜1.5重量%
とし、0.3重量%が最も好ましい。 展色材料の溶解材としてアルカリ剤、例えば、
消石灰を用い、必要によつては消泡剤が混合され
る。 〔作用〕 以上の材料を充分に均一に添加混合して得られ
たペースト状塗料を内壁面にハケやコテで均一に
1〜5mm程度の厚さに塗装することによつて結露
の発生が防止される。 本発明の結露防止用塗料が一般の塗料と特に異
なる点は、微粉パーライトおよび微粉ゼオライト
を含有していることにあり、この微粉パーライト
および微粉ゼオライトは微細孔が抜け殻構造とな
つているために、呼吸作用を有し、大気中の湿分
を吸入し、また乾燥時には吸入した湿分を放出す
る。この塗料を内壁面に塗装するとこの塗料の呼
吸作用により、室内の湿気は壁面に結露を生ずる
ことなく、塗膜内に吸収される。 パーライト単味は湿気の吸放出性が大きく、塗
料化したとき塗料の流動性、塗膜性、作業性が悪
くなる。一方ゼオライト単味では塗料が硬質とな
り塗料としての適性が劣る。パーライトとゼオラ
イトとを前記比率で混合して用いることによつ
て、好適な湿気の吸放出性を保持し、塗料として
好適な性質を保有する。 展色剤として使用されるメチルセルローズは塗
料の接着性改善のため有効に働き、また難溶性な
メチルセルローズはアリカリ剤の添加によつて溶
解される。 次に実施例によつて更に詳しく説明するが、本
発明はこの実施例に限定されるものではない。 〔実施例〕 実験室を厚さ2mmのガラス板で室内側と室外側
とに区切り、室内側を25℃、相対湿度80%、室外
側を0℃に設定した。 上記実験室は、ガラス壁が無処理の場合は1分
以内に室内側表面に結露が発生し、液滴がガラス
面を流下した。 一方、展色剤としてメチルセルローズ(2%
液)、体質顔料として炭酸カルシウム、白色顔料
として酸化チタン、アルカリ剤として消石灰を用
い、これに消泡剤、パーライト、ゼオライトを加
えて実験した。上記原料をそれぞ第1表に示す比
率で混合した3種の実施例塗料をガラス板の室内
側に1mm厚さに塗布した。塗布後の塗膜の状態も
良好であり、上記試験条件にさらした場合3時間
以上経過しても結露の発生はなく、塗膜の付着強
度も良好であつた。
[Industrial Application Field] The present invention relates to a paint for preventing dew condensation on walls, and the present invention relates to a paint for preventing dew condensation on walls. This invention relates to a paste-like wall surface dew condensation prevention paint for preventing dew condensation caused by condensation of excess moisture on a wall surface. [Conventional technology] Conventionally, to prevent condensation on the walls of buildings, insulation materials such as glass wool, rock wool, or foamed synthetic resin boards are inserted between the exterior and interior walls to improve insulation and prevent condensation. There are known technologies to prevent condensation, and in the case of new concrete building structures, a foamed synthetic resin board is attached to the inner surface of the formwork during concrete pouring, and concrete is poured into the formwork to prevent condensation through a structure that integrates the concrete and insulation material. Furthermore, in order to prevent moisture from entering the concrete itself, there are measures such as adding and mixing a water repellent such as stearic acid salt and pouring it. There are no known improvement techniques for preventing dew condensation in existing concrete buildings. [Problems to be Solved by the Invention] As described above, as a measure to prevent condensation on indoor walls, by inserting a heat insulating material between the outer wall and the inner wall, the temperature of the indoor wall surface decreases and the occurrence of condensation is prevented. Although this technique is more effective than not using any insulation at all, it is not a perfect solution. In other words, although the occurrence of condensation on the inner wall surface is reduced, there is a space layer between the outer wall and the insulation material, and although there is no condensation on the inner wall surface, there is a space layer between the outer wall and the insulation material. Condensation is occurring. The reason for this is thought to be that the wall and the heat insulating material are not in close contact with each other and a space layer exists. In order to solve this problem, it is necessary to bond the wall surface and the insulation material closely and to increase the thickness of the insulation layer, which not only imposes structural constraints but also becomes economically expensive. Become. In addition, in the case of concrete buildings, it has recently been proposed to add and mix water repellent materials such as steria phosphate, but there are problems with the chemical stability of the water repellent agents themselves, such as steria phosphate. Not put into practical use. In view of these circumstances, the inventors of the present invention conducted extensive research into developing an inexpensive and effective anti-condensation material, and as a result, developed a new paste-like paint. The present invention provides a wall surface dew condensation prevention paint that is effective in preventing dew condensation when applied to a wall surface. [Means for Solving the Problems] The gist of the present invention is to provide a paint composed of an organic or inorganic color vehicle, an extender, a diluent, an alkaline chemical, a pigment, and a fungicide; This is a paint for preventing dew condensation on walls, which is characterized by being made of a mixture of finely powdered perlite and finely powdered zeolite. It is effective to set the amount of the fine pearlite and zeolite to be in the range of 15 to 40% by weight, and the mixing ratio of the fine pearlite and zeolite to be in the range of 2:1 to 4:1. Examples of organic or inorganic color vehicles include milk casein, soybean casein, glue, gelatin, fluff, wheat flour, methyl cellulose, vinyl acetate powder, other water-soluble synthetic resins, sodium silicate, potassium silicate, and other known color vehicles. Any material selected from among them may be used, among which methylcellulose is preferable. Select methylcellulose as the coloring material, and use 2% methylcellulose and water as the diluent.
% by weight aqueous solution, the amount being in the range 55-80% by weight, preferably 60-70% by weight. 55% by weight
If it is less than 80% by weight, there will be problems such as insufficient paint spreadability and deterioration of adhesion upon moisture absorption, and if it exceeds 80% by weight, the amount of other materials will be too small, which is not preferable. Extender pigments include chalk, heavy calcium carbonate, light calcium carbonate, dung, barite powder,
Clay et al. The total amount of hygroscopic fine pearlite and fine zeolite is preferably 40 to 15% by weight, more preferably 20 to 15% by weight. If it is less than 15% by weight, the ability to absorb moisture is low and it is not economical, and if it exceeds 40% by weight, it will not be easy to paint, resulting in poor workability, and there is a risk that the paint will run down when absorbing moisture. The mixing ratio of fine pearlite and zeolite is 2:1 to 4:1, preferably 2:1 to 3:1. It is preferable that the fine powder pearlite has a specific surface area of 2.5 m 2 /g, and the fine powder zeolite has a specific surface area of about 25 m 2 /g. Pentichlorophenol, sodium pentachlorophenol, parachloromethaxylenol, etc. are used as fungicides, and the amount added is 0.05 to 0.05 to the total amount of coloring material, diluent, extender pigment, fine perlite, and fine zeolite. 1.5% by weight
and 0.3% by weight is most preferred. An alkaline agent is used as a dissolving agent for the coloring material, e.g.
Slaked lime is used, and if necessary, an antifoaming agent is mixed. [Function] Condensation is prevented by uniformly applying the paste paint obtained by adding and mixing the above materials uniformly to the inner wall surface with a brush or trowel to a thickness of about 1 to 5 mm. be done. The dew condensation prevention paint of the present invention is particularly different from general paints in that it contains fine pearlite and fine zeolite, and since the fine pearlite and fine zeolite have a shell structure with micropores, It has a respiratory effect, inhaling moisture from the atmosphere and releasing the inhaled moisture when dry. When this paint is applied to an interior wall surface, due to the breathing effect of this paint, indoor moisture is absorbed into the paint film without forming dew condensation on the wall surface. Single pearlite has a high moisture absorbing and releasing property, and when it is made into a paint, the fluidity, coating properties, and workability of the paint are poor. On the other hand, if zeolite is used alone, the paint becomes hard and is less suitable as a paint. By using a mixture of pearlite and zeolite in the above ratio, suitable moisture absorbing and releasing properties are maintained and properties suitable as a paint are maintained. Methylcellulose, which is used as a color vehicle, works effectively to improve the adhesion of paints, and methylcellulose, which is sparingly soluble, can be dissolved by adding an alkali agent. Next, the present invention will be explained in more detail with reference to examples, but the present invention is not limited to these examples. [Example] A laboratory was divided into an indoor side and an outdoor side by a 2 mm thick glass plate, and the indoor side was set at 25°C and the relative humidity was 80%, and the outdoor side was set at 0°C. In the above laboratory, when the glass walls were untreated, condensation occurred on the indoor surface within one minute, and droplets flowed down the glass surface. On the other hand, methyl cellulose (2%
An experiment was conducted using calcium carbonate as an extender pigment, titanium oxide as a white pigment, slaked lime as an alkali agent, and adding an antifoaming agent, perlite, and zeolite. Three types of Example paints prepared by mixing the above-mentioned raw materials in the ratios shown in Table 1 were applied to the indoor side of a glass plate to a thickness of 1 mm. The condition of the coating film after application was also good; no dew condensation occurred even after 3 hours or more when exposed to the above test conditions, and the adhesion strength of the coating film was also good.

〔発明の効果〕〔Effect of the invention〕

本発明の壁面結露防止用塗料は、新築コンクリ
ート建築物は無論のこと、解決策が全くなかつた
既設コンクリート建築物にも建築用内壁面に塗装
するだけで結露を防止することができる。また木
造家屋においても同様の効果があり、一般塗料と
しても使用できる。安価で作業性も良好である。
The paint for preventing condensation on wall surfaces of the present invention can prevent dew condensation not only in newly constructed concrete buildings but also in existing concrete buildings for which no solution has been available by simply applying the paint to the interior walls of the building. It also has the same effect on wooden houses and can be used as a general paint. It is inexpensive and has good workability.

Claims (1)

【特許請求の範囲】[Claims] 1 有機質または無機質展色剤、体質顔料、アル
カリ性薬品、希釈剤、顔料、および防かび剤から
構成される塗料と、吸湿性のある微粉パーライト
および微粉ゼオライトとの混合物から成り、微粉
パーライトおよび微粉ゼオライトの添加量が15〜
40重量%の範囲内で、かつ微粉パーライトと微粉
ゼオライトとの混合割合が2:1〜4:1の範囲
内であることを特徴とする壁面結露防止用塗料。
1 Consists of a mixture of a paint consisting of an organic or inorganic color vehicle, an extender pigment, an alkaline chemical, a diluent, a pigment, and a fungicide, and a hygroscopic fine powder perlite and a fine powder zeolite. The amount added is 15~
A paint for preventing dew condensation on a wall surface, characterized in that the mixing ratio of fine pearlite and fine zeolite is within the range of 40% by weight and within the range of 2:1 to 4:1.
JP3881486A 1986-02-24 1986-02-24 Paint for use in preventing moisture condensation on wall surface Granted JPS62197469A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3881486A JPS62197469A (en) 1986-02-24 1986-02-24 Paint for use in preventing moisture condensation on wall surface

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3881486A JPS62197469A (en) 1986-02-24 1986-02-24 Paint for use in preventing moisture condensation on wall surface

Publications (2)

Publication Number Publication Date
JPS62197469A JPS62197469A (en) 1987-09-01
JPS6350382B2 true JPS6350382B2 (en) 1988-10-07

Family

ID=12535740

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3881486A Granted JPS62197469A (en) 1986-02-24 1986-02-24 Paint for use in preventing moisture condensation on wall surface

Country Status (1)

Country Link
JP (1) JPS62197469A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU780369B2 (en) * 2000-11-10 2005-03-17 Mitsubishi Shoji Construction Materials Corporation Composition for building material and building material
IT1392857B1 (en) * 2009-02-20 2012-04-02 Spring Color S R L "ARTISTIC OR BUILDING MATERIALS"

Also Published As

Publication number Publication date
JPS62197469A (en) 1987-09-01

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