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JPS6357552B2 - - Google Patents
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JPS6357552B2 - - Google Patents

Info

Publication number
JPS6357552B2
JPS6357552B2 JP59168845A JP16884584A JPS6357552B2 JP S6357552 B2 JPS6357552 B2 JP S6357552B2 JP 59168845 A JP59168845 A JP 59168845A JP 16884584 A JP16884584 A JP 16884584A JP S6357552 B2 JPS6357552 B2 JP S6357552B2
Authority
JP
Japan
Prior art keywords
adhesive
cloth
powder
fabric
photoreceptor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP59168845A
Other languages
Japanese (ja)
Other versions
JPS6147776A (en
Inventor
Chiharu Okada
Masayuki Mishima
Juichi Ueda
Iwao Myashita
Takahiro Yonemoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Agency of Industrial Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology
Priority to JP59168845A priority Critical patent/JPS6147776A/en
Publication of JPS6147776A publication Critical patent/JPS6147776A/en
Publication of JPS6357552B2 publication Critical patent/JPS6357552B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/002Joining methods not otherwise provided for
    • B29C65/008Joining methods not otherwise provided for making use of electrostatic charges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/481Non-reactive adhesives, e.g. physically hardening adhesives
    • B29C65/4815Hot melt adhesives, e.g. thermoplastic adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/486Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by their physical form being non-liquid, e.g. in the form of granules or powders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/47Joining single elements to sheets, plates or other substantially flat surfaces
    • B29C66/472Joining single elements to sheets, plates or other substantially flat surfaces said single elements being substantially flat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/729Textile or other fibrous material made from plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/83General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/834General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools moving with the parts to be joined
    • B29C66/8341Roller, cylinder or drum types; Band or belt types; Ball types
    • B29C66/83421Roller, cylinder or drum types; Band or belt types; Ball types band or belt types
    • B29C66/83423Roller, cylinder or drum types; Band or belt types; Ball types band or belt types cooperating bands or belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C69/00Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore
    • B29C69/005Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore cutting-off or cutting-out a part of a strip-like or sheet-like material, transferring that part and fixing it to an article
    • B29C69/006Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore cutting-off or cutting-out a part of a strip-like or sheet-like material, transferring that part and fixing it to an article rotating transfer means

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)
  • Decoration Of Textiles (AREA)
  • Fixing For Electrophotography (AREA)
  • Dry Development In Electrophotography (AREA)
  • Combination Of More Than One Step In Electrophotography (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

〔産業上の利用分野〕 本発明は粉末状の接着剤を電子写真方式により
布又はニツト製品に任意のパターン状に塗布し接
着布を製造する方法に関する。 〔従来の技術及び問題点〕 衣服の縫製工程では1枚以上の布又はニツト製
品を折り曲げたり重ね合せたりして縫製する。そ
の際、折り曲げ部分もしくは重ね合せ部分がずれ
ないように仕付け縫い(仮縫い)をする。仕付け
縫いには仕付け用ミシンを使用し、布又はニツト
製品を二次元上で広い範囲に渡つて動かさねばな
らない。又、美観上の問題から本縫いの後で仕付
け糸を抜く必要がある。一方、接着剤により上記
の折り曲げ部分や重ね合せ部分を(仮)接着する
場合はテープ状の接着剤をはさみ込んで熱圧着す
るなどの方法がとられている。いずれの方法でも
人手を要するため縫製工程の高速化、自動化は困
難であつた。 又、縫製加工製品分野において接着剤が多用さ
れる分野として、接着芯地等がある。接着芯地と
しては、一般に一定のドツトパターンもしくは、
ランダムに粉末状熱可塑性樹脂を散布、融着され
たものが使用されている。しかしながらこれらの
芯地は、一様に接着剤が布全面に融着されたもの
であり、種々の形状及び大きさの布地に、必要な
部位に、必要な濃度の接着剤を自由に融着させ、
少量多品種の接着加工に応えるには十分なもので
はない。 このように、縫製加工製品分野においては、布
の前処理等の工程において、様々な形状に裁断さ
れた布地に対し、任意の一定パターンで接着剤を
付着させ、接着加工する方法の考案が要望されて
いる。 〔問題点を解決するための手段〕 本発明者らはこれらの従来の問題点を解決すべ
く鋭意研究の結果、本発明に到つた。即ち、本発
明は、導電性導体の上に設けられた導電性感光体
層をコロナ放電で一様に帯電せしめ、該感光体帯
電表面を任意のパターンで露光することにより該
帯電表面上の露光部分の電荷を減少せしめて、該
感光体層表面上に表面電荷が多く残存した非露光
部分である当該パターンの静電潜像を形成せしめ
該静電潜像とは反対の極性に帯電せしめた粉体状
接着剤を用いるか、あるいは、表面電荷が減少し
た露光部分である当該パターンの静電潜像を形成
せしめ、該静電潜像と同じ極性に帯電せしめた粉
体状接着剤を用いて該静電潜像を顕像化すること
により感光体表面上に形成された粉体状接着剤に
よる像を、直接、布又はニツト製品に静電転写さ
せるか、もしくは他の媒体表面に静電転写させた
後、布又はニツト製品に再転写させることによ
り、接着剤が当該パターンで付着した接着布を調
製し、該接着剤を布又はニツト製品に加熱融着さ
せるか又はさせないで、該接着布の一部を折曲げ
て重ねるか又は別の布もしくはニツト製品を重ね
合わせて加熱し、接着剤を融着せしめることを特
徴とする布の接着方法を提供するものである。 本発明において、複写印字装置の原理を用いる
ことにより、例えば、レーザープリンターの如
く、電子写真方式を利用した、印字印画システム
として、任意の図形を高速で潜像形成する方法を
用いることができ、パターンジエネレーターから
発生される電気信号を光信号に変換し、レーザー
ビームを感光体上に照射することにより、静電潜
像を形成することが可能である。レーザー光を照
射する以外の方法としては光フアイバーチユーブ
により光シグナルを照射する方法等を利用するこ
とができる。 又、複写機を用いることにより、例えば、一定
図形の原画の拡大、縮小された潜像を利用する技
術を利用することにより、例えば、縫製加工分野
において使用される型紙等の原図において、接着
剤を塗布させたい部位の明暗化の区別の処理等を
行い、これによるオリジナルパターンの反射光を
光学的に、感光体上に静電潜像として形成するこ
とも可能である。その他画像のデジタル化によ
り、様々なオリジナルパターンを複合・合成した
画像とか、画像認識装置により読取られた様々な
パターン情報により感光体上に形成された静電潜
像等を用いることも可能である。 本発明方法は、これらの電子写真方式を利用
し、感光体上に形成された静電潜像を利用して、
布に接着剤を付着させた後、加熱により布を接着
するための方法である。 静電潜像の顕像化には、感光体上に形成された
静電潜像の表面電荷の極性と反対の極性の帯電極
性を有する粉体を用いる方法(いわゆる正規現像
法)と、感光体上の潜像の極性と同極性の帯電極
性を有する粉体を用いる方法(いわゆる反転現像
法)とがある。 一般にプリンターにおいては、文字図形等の黒
地に相当する部分を光らせ、感光体上に電気信号
を光信号に変換させた形で光ビームを照射させ、
背景部の白地に相当する部位を暗部として光を当
てない方式が用いられている。この方式において
は、背景部の表面電位の方が、文字図形部よりも
高く、潜像の顕像化には、感光体の表面の極性と
同極性の粉体を用いなければならない。 これに対し、オリジナル画像の反射光を用いる
複写機のシステムにおいては、文字図形の黒地相
当部は、背景部の表面電位よりも高く、感光体上
の表面電位極性と反対の帯電極性を有する粉体に
より顕像化される。 粉体への帯電性の付与は、鉄粉等の磁性粉体及
びその他の無機粉体と接着剤粉末とを摩擦させる
ことにより行われるが、粉体を構成する樹脂の骨
格構造、官能基等によつても帯電極性と帯電量が
制御される。更に必要な場合には各種の染料等を
添加することにより、樹脂の帯電極性と帯電量を
制御することも可能であり、望ましくは無色乃至
淡色乃至白色の帯電制御剤を用いる。磁性粉の表
面処理剤を調整することによつても、帯電量の制
御が可能である。 一般に用いられる感光体としては、アモルフア
スセレン及びその合金類(例えばセレン/テル
ル)、硫化カドミウム、有機染料複合系、アモル
フアスシリコン等であり、これらの感光体は、表
面で発生した電子又は正孔の感光体背面の導電層
への到達の容易さの程度により、表面電荷の極性
が選択使用されている。例えば、アモルフアスセ
レン系の感光体においては、正極性に一様帯電さ
せた感光体表面に、明部の光照射により正極性の
静電潜像を形成する方法がとられる。このような
場合には、負極性の帯電粉末により正規現像が行
なわれる。 本発明においては、粉末状接着剤を構成する樹
脂として、負極性に帯電する樹脂(例えばポリエ
ステル系樹脂)もしくは、正極性に帯電する樹脂
(例えばアミノアクリル系変性樹脂)を選ぶが、
電荷調整機能を有する染料類を樹脂に適当量添加
する等の方法により、粉体状接着剤の帯電極性の
制御は可能であり、いずれの感光体及び現像方式
の組合せにおいても、適用は可能である。顕像化
に必要な粉体状接着剤の平均粒径は布を構成する
繊維の太さ、織布又は不織布等の平滑性、目の荒
さ等にもよるが、5〜1000μmのものを用い、好
ましくは10〜300μmのものである。感光体へ付
着させる粉体の付着量は、感光体の表面電位、露
光量(露光波長、露光強度、露光時間等による)、
現像時におけるバイアス電圧及び粉体の帯電量粒
径等により調整される。 感光体上に顕像化されて付着した粉体の布又は
ニツト製品への転写の方法は、感光体に布(又は
ニツト製品)を接近させ、布の反対側よりコロナ
放電の印荷等の方法により、布を粉体の帯電極性
と反対の極性に帯電させ、静電引力により、粉体
を布へ転写する方法、感光体に絶縁性表面を有す
る媒体を接近させ、媒体表面の反対側よりコロナ
放電の印荷等の方法により、触体を粉体の帯電極
性と反対の極性に帯電させ、静電引力により、粉
体を媒体へ静電転写し、更にこの媒体に布(又は
ニツト製品)を接近させ、同様に布の反対側よ
り、コロナ放電の印荷等の方法により、粉体を布
へ静電転写する方法、感光体に離型性表面を有す
る媒体を接近させ、媒体の面の反対側より、コロ
ナ放電の印荷等の方法により、粉体を媒体へ静電
転写し、更にこの媒体に布(又はニツト製品)を
接触させ、媒体の上から加熱することにより、粉
体を布へ融着させ、熱もしくは圧力転写する方法
等があり、布又はニツト製品の材質、形状に応じ
た転写方法を選ぶことが出来る。 このようにして、布等へ粉体状接着剤がパター
ン状に付着したものが得られるが、このまま別の
布等を重ね熱接着する場合以外で、未融着の状態
で布を取扱う必要のある場合には、粉体を布へ固
着させなければ、布の後加工等の取扱い作業の際
に脱落するので、例えば接着剤粉末の乗つた状態
の布を、赤外ランプとかキセノンフラツシユラン
プとかヒートオーブン等の輻射熱により粉体を布
へ融着させるか、離型処理した加熱ローラーの間
を通すか、離型処理したヒートプレスにより融着
させるか等の方法により、布へ粉体を固着させる
ことが出来る。 粉体状接着剤は、容易に熱融着するものが好ま
しいが、潜像の顕像化の段階で、磁性粉等との摩
擦により、粉体を帯電させるため、常用温度にお
いて、ケーキング等が発生し粉末の流動性が低下
するものであつてはならない。顕像化の際には、
通常、内部に複数の磁極を有する回転ロールによ
り、磁性粉と粉体からなるスリーブを形成させ、
この回転するスリーブにより、粉体を感光体と接
触させることにより、粉体を感光体へ付着させ
る。従つて、粉体は常用温度において、一定以上
の弾性率を保持しなければならない。 その他、無機粉を重力落下による摩擦帯電によ
る顕像化の方法として、ガラス、鉄球等のビーズ
を用いるカスケード式現像法も用いることが出
来、この場合も粉体の耐摩耗性は同様に要求され
る。このカースケード方式の特性は、ビーズの粒
径の大きなものが使用出来る点であり、粒径の大
きな粉体状接着剤の摩擦帯電と顕像化に有効であ
る。 このように、粉体状接着剤は磁性粉等の無機粉
末もしくはビーズと混合、撹拌使用されるので、
粉体が容易に融着するものは避けねばならない。 布等の接着は、このように調製した、粉体状の
接着剤が付着もしくは融着した、第一の基質であ
る布と、第2の基質とを重ね合せるか、あるいは
第一の基質の一部を折り曲げる等の方法により、
これらを熱プレスもしくは熱ローラーを通すこと
により接着に至る。 布への樹脂の熱融着においては、布(もしくは
繊維)の特性をそこなわない、温度、圧力、時間
において加熱融着させなければならない。軟化点
の低すぎる樹脂は、融着は容易ではあるが、常用
温度における粉体の流動性が劣る。軟化点の高す
ぎるものは、より高温での加熱融着が必要であ
り、好ましくない。粉体の付着した布を直接ヒー
トローラーにより熱融着させる場合には、ヒート
ローラーへの接着剤の移行があつてはならない。
このためには、溶融粘度、特に動的粘度の選択が
必要である。又布の接着においては、出来るだけ
低い温度で熱変形し、且つ、必要以上の溶融流動
による布の背面への接着剤のしみ出しのないもの
でなければならない。 本発明において、布を感光体へ接近させ、感光
体より粉体像を布へ直接転写させる方法として
は、例えば、第1図に示すような方法がある。即
ち、セレン、セレン/テルル、セレン/ヒ素、ア
モルフアスシリコン、硫化カドミウム、酸化亜鉛
等の無機感光体及び染料複合物等の有機感光体中
から選ばれる厚さ5〜100μの光導電性感光体層
を持つ導電性ドラム1を回転させながら暗所でコ
ロナ放電により該感光体層を一様帯電させる。そ
の上に任意のパターン2を露光し、露光した感光
体面の電荷を背面の導電性基体に抜けさせること
により上記のパターンの静電潜像を感光体上に形
成する。粉体状の接着剤は接着剤ボツクス3に貯
えられ、回転する金属ブラシもしくは磁性粉より
成るブラシ4によつて上記の静電潜像とは反対の
電荷に帯電させられ、クーロン力によつてドラム
上の静電潜像に付着する。ドラム上の静電潜像に
付着した接着剤はローラー5によつてドラム1と
同周速で駆動するベルト6に載せられた布又はニ
ツト製品8上に、ベルト6をはさんでドラム1と
反対側にあり、接着剤とは反対極性に帯電した電
極7からのクーロン力によつて転写される。そし
てベルト6上を移動しながら赤外線加熱、高周波
誘電加熱、熱風等の熱源9により加熱された被着
体上に固着する。あるいは第2図に示すように加
熱装置を通過することもなくもしくは通過してか
らガイド11により上記の布又はニツト製品を折
り曲げながらもしくは折り曲げてから熱ロール1
0によつて加熱圧着することにより折り曲げ接着
をする。 更に又、第3図に示すように別の布又はニツト
製品8′を重ね合せて熱ロール10によつて加熱
圧着することにより接着布が製造される。 本発明において、絶縁性媒体を感光体へ接近さ
せ、感光体より粉体像を絶縁性媒体上へ転写させ
た後、この媒体上の粉体像を布へ再転写する方法
による接着布の製造法の例を第4図に示す。 絶縁性ベルト12に転写された粉体状接着剤
は、内部にコロナ帯電器を有する転写ローラー1
3,13′により、布8へ静電転写され、別の布
8′と熱ローラー14,14′により熱融着され、
15の接着布が得られる。 本発明において、離型性媒体を感光体へ接近さ
せ、感光体より粉体像を離型性媒体へ転写させた
後、この媒体上の粉体像を布へ再転写する方法に
よる接着布の製造方法として、例えば第5図に示
すものがある。即ち、ドラム1上の静電潜像に付
着した粉体状接着剤は電極7によつてドラム1と
同じ周速で動く離型ベルト16上に静電転写され
る。そして支持ベルト17上に固定された布又は
ニツト製品8を熱ロール18と加圧ロール19に
よつて該離型ベルト16上の接着剤に接触させて
接着剤を布又はニツト製品上に感熱転写させる。 本発明で用いられる電子写真技術は、公知の方
法が利用できる。現像法としては従来公知である
磁気ブラシ法又はカスケード法の両者を適時に使
い分ける事が可能である。塗布する接着剤の粒径
により、両方法は使い分けられ、例えば50μ以上
の平均粒径を有する接着剤を帯電させ、感光体層
表面に付着せしめるためには、平均粒径200μ以
上のキヤリヤーを使用することが好ましい。この
場合、磁気ブラシ法を用いると、通常使われてい
る程度の磁力の磁極では、キヤリヤーの重力とう
まくつりあいがとれず、感光体層表面に任意に接
着剤を顕像化することは困難な場合がある。しか
しながら、重力により現像剤(キヤリアーと粉体
状接着剤の混合物)を流下させて現像するカスケ
ード法を用いると任意のパターンに感光体層表面
に顕像化させることが比較的容易である。 接着剤の平均粒径が50μ以下の場合には、キヤ
リアーとして平均粒径が50〜200μのものを使用
する事が好ましく、コンパクトで汎用性のある磁
気ブラシ法を用いることができる。 更に接着剤として加水分解性有機珪素官能基を
有する湿気架橋型の熱可塑性樹脂の粉末を用いる
ことにより、加熱接着後に水分を与えてシロキサ
ン結合による架橋構造を形成せしめ耐熱性、耐溶
剤性、耐熱水性に優れた接着布を製造することも
できる。かかる加水分解性有機珪素官能基を有す
る湿気架橋型の熱可塑性樹脂は、例えば一般式(1) (ただしXは加水分解性基でアルコキシ基、アル
ケニルオキシ基、アシロキシ基、アミノオキシ
基、アミノ基、オキシム基、R′はC1〜C4のアル
キル基、R″は炭化水素基もしくはN、O、Sの
異種原子を1種類以上含む炭化水素基、aは0〜
2の整数、nは0又は1、QはH、NH2、SH、
NCO、
[Industrial Field of Application] The present invention relates to a method for producing adhesive cloth by applying a powdered adhesive to a cloth or knit product in an arbitrary pattern using an electrophotographic method. [Prior Art and Problems] In the process of sewing clothes, one or more pieces of cloth or knitted products are folded or overlapped to be sewn. At that time, basting stitches are applied to prevent the folded or overlapping parts from shifting. For basting, a basting sewing machine is used and the fabric or knit product must be moved over a wide range in two dimensions. Also, for aesthetic reasons, it is necessary to remove the basting thread after lock stitching. On the other hand, when the above-mentioned folded portions or overlapping portions are (temporarily) bonded using an adhesive, a method such as sandwiching a tape-shaped adhesive and bonding under heat is used. Both methods require manual labor, making it difficult to speed up and automate the sewing process. In addition, adhesive interlining is a field in which adhesives are frequently used in the field of sewn products. Adhesive interlining generally has a fixed dot pattern or
A material in which powdered thermoplastic resin is randomly sprinkled and fused is used. However, with these interlinings, adhesive is uniformly fused to the entire surface of the fabric, and adhesive can be freely fused at the required concentration to fabrics of various shapes and sizes in the required areas. let me,
It is not sufficient to meet the needs of small-lot, high-mix adhesive processing. In this way, in the field of sewn products, there is a need to devise a method for applying adhesive in a predetermined pattern to fabrics cut into various shapes during processes such as fabric pre-treatment. has been done. [Means for Solving the Problems] The present inventors have conducted intensive research to solve these conventional problems, and have arrived at the present invention. That is, the present invention uniformly charges a conductive photoreceptor layer provided on a conductive conductor by corona discharge, and exposes the charged surface of the photoreceptor to light in an arbitrary pattern, thereby reducing the exposure on the charged surface. An electrostatic latent image of the pattern, which is an unexposed area with a large amount of surface charge remaining on the surface of the photoreceptor layer, is formed by reducing the electric charge of the area, and the electrostatic latent image is charged to a polarity opposite to that of the electrostatic latent image. Use a powder adhesive, or use a powder adhesive that forms an electrostatic latent image of the pattern, which is the exposed portion with reduced surface charge, and is charged to the same polarity as the electrostatic latent image. The powdered adhesive image formed on the surface of the photoreceptor by visualizing the electrostatic latent image is directly electrostatically transferred to cloth or knitted products, or electrostatically transferred to the surface of another medium. After electrotransferring, the pattern is retransferred to a cloth or knitted product to prepare an adhesive cloth with the adhesive attached in the pattern, and the adhesive can be heat-fused to the cloth or knitted product or not. To provide a fabric bonding method characterized in that a part of the bonded fabric is folded and stacked, or another fabric or knit product is stacked and heated to fuse the adhesive. In the present invention, by using the principle of a copy printing device, a method of forming a latent image of an arbitrary figure at high speed can be used as a printing system using an electrophotographic method, such as a laser printer, for example. It is possible to form an electrostatic latent image by converting an electrical signal generated from a pattern generator into an optical signal and irradiating the photoreceptor with a laser beam. As a method other than irradiating with laser light, a method of irradiating an optical signal with an optical fiber tube, etc. can be used. In addition, by using a copying machine, for example, by using technology that utilizes enlarged or reduced latent images of an original image of a certain shape, adhesives can be applied to original images such as patterns used in the sewing field. It is also possible to perform processing to distinguish between brightness and darkness of the area to be coated, and to optically form the reflected light of the original pattern as an electrostatic latent image on the photoreceptor. In addition, by digitizing images, it is also possible to use images that are composites and composites of various original patterns, electrostatic latent images formed on photoreceptors based on various pattern information read by image recognition devices, etc. . The method of the present invention utilizes these electrophotographic methods and utilizes an electrostatic latent image formed on a photoreceptor,
This is a method for attaching an adhesive to cloth and then bonding the cloth by heating. To visualize an electrostatic latent image, there are two methods: a method using a powder having a charge polarity opposite to the polarity of the surface charge of the electrostatic latent image formed on the photoreceptor (so-called normal development method), and a method using photosensitive material. There is a method (so-called reversal development method) using a powder having the same polarity as the polarity of the latent image on the body. Generally, in printers, parts corresponding to black backgrounds such as characters and figures are illuminated, and a light beam is irradiated onto a photoreceptor in the form of an electrical signal converted into an optical signal.
A method is used in which the area corresponding to the white background area is treated as a dark area and is not exposed to light. In this method, the surface potential of the background area is higher than that of the character/graphic area, and a powder having the same polarity as the surface of the photoreceptor must be used to visualize the latent image. On the other hand, in a copying machine system that uses reflected light from the original image, the part corresponding to the black background of the character figure has a higher surface potential than the background part, and the powder has a charge polarity opposite to the surface potential polarity on the photoreceptor. Manifested by the body. Electrification is imparted to the powder by rubbing adhesive powder with magnetic powder such as iron powder or other inorganic powder, but depending on the skeletal structure, functional groups, etc. of the resin that makes up the powder, The charge polarity and charge amount are also controlled by. Furthermore, if necessary, the charge polarity and charge amount of the resin can be controlled by adding various dyes, etc., and desirably a colorless to light-colored to white charge control agent is used. The amount of charge can also be controlled by adjusting the surface treatment agent for the magnetic powder. Commonly used photoreceptors include amorphous selenium and its alloys (such as selenium/tellurium), cadmium sulfide, organic dye composites, and amorphous silicon. The polarity of the surface charge is selected and used depending on the degree of ease of access of the holes to the conductive layer on the backside of the photoreceptor. For example, in the case of an amorphous selenium-based photoreceptor, a method is used in which a positive electrostatic latent image is formed on the surface of the photoreceptor which is uniformly charged to a positive polarity by irradiating light in a bright area. In such a case, regular development is performed using negatively charged powder. In the present invention, as the resin constituting the powder adhesive, a negatively charged resin (for example, a polyester resin) or a positively charged resin (for example, an aminoacrylic modified resin) is selected.
It is possible to control the charge polarity of a powder adhesive by adding an appropriate amount of dyes with a charge adjustment function to the resin, and this method can be applied to any combination of photoreceptor and development method. be. The average particle size of the powder adhesive required for visualization depends on the thickness of the fibers constituting the cloth, the smoothness of the woven or non-woven fabric, the roughness of the weave, etc., but a particle size of 5 to 1000 μm is used. , preferably 10 to 300 μm. The amount of powder attached to the photoreceptor depends on the surface potential of the photoreceptor, the amount of exposure (exposure wavelength, exposure intensity, exposure time, etc.),
It is adjusted by the bias voltage during development, the charge amount of the powder, and the particle size. The method of transferring the visualized powder adhered on the photoreceptor to a cloth or knitted product is to bring the cloth (or knitted product) close to the photoreceptor, and apply a corona discharge, etc. from the opposite side of the cloth. A method in which the cloth is charged to a polarity opposite to that of the powder, and the powder is transferred to the cloth by electrostatic attraction.A medium having an insulating surface is brought close to the photoreceptor, and the opposite side of the medium surface is charged. By applying a method such as corona discharge, the contact body is charged to a polarity opposite to that of the powder, and the powder is electrostatically transferred to a medium by electrostatic attraction. A method of electrostatically transferring the powder onto the cloth by applying a method such as corona discharge from the opposite side of the cloth; By electrostatically transferring the powder onto a medium using a method such as applying corona discharge from the opposite side of the surface of There are methods such as fusing powder to cloth and transferring it with heat or pressure, and the transfer method can be selected depending on the material and shape of the cloth or knit product. In this way, it is possible to obtain a cloth with powdered adhesive adhered in a pattern, but it is not necessary to handle the cloth in an unfused state unless you are stacking another cloth, etc. and thermally bonding it. In some cases, if the powder is not fixed to the fabric, it will fall off during post-processing or other handling of the fabric. The powder can be fused to the fabric using radiant heat from a heat oven, passed through heated rollers that have been treated to release the powder, or fused using a heat press that has been treated to release the powder. It can be fixed. The powder adhesive is preferably one that can be easily heat-fused, but since the powder is charged by friction with magnetic powder etc. at the stage of visualizing the latent image, caking etc. may occur at normal temperatures. It must not occur and reduce the fluidity of the powder. When visualizing,
Usually, a sleeve made of magnetic powder and powder is formed using a rotating roll that has multiple magnetic poles inside.
The rotating sleeve brings the powder into contact with the photoreceptor, thereby causing the powder to adhere to the photoreceptor. Therefore, the powder must maintain an elastic modulus above a certain level at ordinary temperatures. In addition, a cascade development method using beads such as glass or iron balls can also be used to visualize inorganic powder by frictional charging caused by gravity falling, and in this case, the abrasion resistance of the powder is also required. be done. A characteristic of this cascade method is that beads with large particle sizes can be used, and it is effective for triboelectrification and visualization of powder adhesives with large particle sizes. In this way, powdered adhesive is mixed with inorganic powder such as magnetic powder or beads and stirred, so
Materials that allow powder to easily fuse must be avoided. For adhesion of cloth, etc., the first substrate cloth, to which the powdered adhesive has been adhered or fused, prepared in this manner is superimposed on the second substrate, or the first substrate is bonded to the second substrate. By a method such as bending a part,
Bonding is achieved by passing these through a hot press or a hot roller. When heat-sealing resin to cloth, the heat-sealing must be carried out at a temperature, pressure, and time that will not damage the properties of the cloth (or fibers). A resin whose softening point is too low may be easily fused, but the fluidity of the powder at ordinary temperatures is poor. A material with a softening point that is too high is undesirable because it requires heating and fusing at a higher temperature. When directly heat-sealing powder-adhered cloth using a heat roller, the adhesive must not transfer to the heat roller.
This requires selection of the melt viscosity, especially the dynamic viscosity. In addition, when bonding cloth, it must be able to undergo thermal deformation at as low a temperature as possible, and must not seep out of the adhesive onto the back surface of the cloth due to excessive melt flow. In the present invention, as a method of bringing the cloth close to the photoreceptor and directly transferring the powder image from the photoreceptor to the cloth, there is a method as shown in FIG. 1, for example. That is, a photoconductive photoreceptor with a thickness of 5 to 100 μm selected from inorganic photoreceptors such as selenium, selenium/tellurium, selenium/arsenic, amorphous silicon, cadmium sulfide, and zinc oxide, and organic photoreceptors such as dye composites. While rotating the conductive drum 1 having the layer, the photoreceptor layer is uniformly charged by corona discharge in a dark place. An arbitrary pattern 2 is exposed thereon, and the charges on the exposed surface of the photoreceptor are discharged to the conductive substrate on the back side, thereby forming an electrostatic latent image of the above pattern on the photoreceptor. Powdered adhesive is stored in an adhesive box 3, charged with a rotating metal brush or brush 4 made of magnetic powder to an opposite charge to the electrostatic latent image, and is then charged by Coulomb force. It adheres to the electrostatic latent image on the drum. The adhesive adhered to the electrostatic latent image on the drum is transferred by a roller 5 onto a cloth or knit product 8 placed on a belt 6 driven at the same circumferential speed as the drum 1, with the belt 6 sandwiched between the drum 1 and the adhesive. The image is transferred by the Coulomb force from the electrode 7 on the opposite side, which is charged with the opposite polarity to that of the adhesive. Then, while moving on the belt 6, it is fixed onto an adherend heated by a heat source 9 such as infrared heating, high-frequency dielectric heating, or hot air. Alternatively, as shown in FIG. 2, the fabric or knit product is folded by the guide 11 without passing through the heating device or after passing through the heating device, or after being folded, the heated roll 1
Bending and adhering is performed by heat-pressing with 0. Furthermore, as shown in FIG. 3, a bonded fabric is produced by overlapping another fabric or knit product 8' and heat-pressing it with a hot roll 10. In the present invention, an adhesive cloth is manufactured by a method of bringing an insulating medium close to a photoreceptor, transferring a powder image from the photoreceptor onto the insulating medium, and then retransferring the powder image on the medium to the cloth. An example of the method is shown in Figure 4. The powdered adhesive transferred to the insulating belt 12 is transferred to the transfer roller 1 which has a corona charger inside.
3, 13', and is electrostatically transferred to cloth 8, and thermally fused to another cloth 8' by heat rollers 14, 14'.
15 adhesive fabrics are obtained. In the present invention, a releasable medium is brought close to a photoreceptor, a powder image is transferred from the photoreceptor to the releasable medium, and then the powder image on the medium is retransferred to the cloth. As a manufacturing method, there is one shown in FIG. 5, for example. That is, the powder adhesive adhered to the electrostatic latent image on the drum 1 is electrostatically transferred by the electrode 7 onto the release belt 16 which moves at the same circumferential speed as the drum 1. Then, the cloth or knitted product 8 fixed on the support belt 17 is brought into contact with the adhesive on the release belt 16 by a heat roll 18 and a pressure roll 19, and the adhesive is thermally transferred onto the cloth or knitted product. let As the electrophotographic technique used in the present invention, known methods can be used. As the developing method, it is possible to appropriately use both the conventionally known magnetic brush method and cascade method. Both methods are used depending on the particle size of the adhesive to be applied.For example, in order to charge an adhesive with an average particle size of 50μ or more and attach it to the surface of the photoreceptor layer, a carrier with an average particle size of 200μ or more is used. It is preferable to do so. In this case, when using the magnetic brush method, the magnetic poles with the magnetic force normally used cannot balance well with the gravity of the carrier, making it difficult to visualize the adhesive on the surface of the photoreceptor layer. There are cases. However, if a cascade method is used in which a developer (a mixture of carrier and powder adhesive) is caused to flow down by gravity for development, it is relatively easy to visualize an arbitrary pattern on the surface of the photoreceptor layer. When the average particle size of the adhesive is 50 μm or less, it is preferable to use a carrier with an average particle size of 50 to 200 μm, and a compact and versatile magnetic brush method can be used. Furthermore, by using a moisture-crosslinking thermoplastic resin powder with a hydrolyzable organosilicon functional group as an adhesive, moisture is added after heat bonding to form a crosslinked structure with siloxane bonds, resulting in heat resistance, solvent resistance, and heat resistance. It is also possible to produce adhesive fabrics with excellent water resistance. Such a moisture-crosslinkable thermoplastic resin having a hydrolyzable organosilicon functional group is, for example, represented by the general formula (1). (However, X is a hydrolyzable group such as an alkoxy group, an alkenyloxy group, an acyloxy group, an aminooxy group, an amino group, an oxime group, R' is a C 1 to C 4 alkyl group, R'' is a hydrocarbon group or N, Hydrocarbon group containing one or more different atoms of O and S, a is 0 to
2 integer, n is 0 or 1, Q is H, NH 2 , SH,
N.C.O.

【式】【formula】

【式】【formula】

【式】である) で表わされる化合物を共重合反応、グラフト重合
反応、付加反応等により熱可塑性樹脂骨格中もし
くは末端に導入する方法等によつて得られる。 本発明で用いられる粉末状の接着剤は粒径5〜
1000μ、好ましくは10〜300μの熱可塑性樹脂であ
る。軟化点60〜160℃、好ましくは80℃〜140℃の
共重合ポリエステル樹脂、共重合ポリアミド樹
脂、ポリエチレン、エチレン−酢酸ビニル共重合
体、エチレン−エチルアクリレート共重合体、ス
チレン−アクリル酸エステル共重合体、可塑剤を
含有するポリ塩化ビニルより選ばれる一種類以上
の熱可塑性樹脂の粉末が用いられる。 又、外部と内部の構造の異なるマイクロカプセ
ル化した粉体接着剤を用いることにより、加圧に
よる布への固着転写も可能である。この場合、外
部は比較的、軟化点の高い樹脂からなり、内部に
柔かい樹脂を用いることにより、摩擦帯電に安定
で圧力転写が容易な接着剤が得られる。 更に接着剤として加水分解性有機珪素官能基を
有する湿気架橋型の熱可塑性樹脂の粉末を用いる
ことにより、加熱接着後に水分を与えてシロキサ
ン結合による架橋構造を形成せしめ耐熱性、耐溶
剤性、耐熱水性に優れた接着布を製造することも
できる。かかる加水分解性有機珪素官能基を有す
る湿気架橋型の熱可塑性樹脂は、例えば一般式(1) (ただし、Xは加水分解性基でアルコキシ基、ア
ルケニルオキシ基、アシロキシ基、アミノオキシ
基、アミノ基、オキシム基、R′はC1〜C4のアル
キル基、R″は炭化水素基もしくはN、O、Sの
異種原子を1種類以上含む炭化水素基、aは0〜
2の整数、nは0又は1、QはH、NH2、SH、
NCO、
It can be obtained by a method in which a compound represented by the following formula is introduced into the thermoplastic resin skeleton or at its terminal end by copolymerization reaction, graft polymerization reaction, addition reaction, etc. The powder adhesive used in the present invention has a particle size of 5 to
1000μ, preferably 10-300μ thermoplastic resin. Copolymerized polyester resin, copolyamide resin, polyethylene, ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, styrene-acrylic acid ester copolymer with a softening point of 60 to 160°C, preferably 80°C to 140°C Powders of one or more thermoplastic resins selected from polyvinyl chloride containing plasticizers and plasticizers are used. Furthermore, by using a micro-encapsulated powder adhesive with different internal and external structures, it is possible to transfer the adhesive onto cloth by applying pressure. In this case, by using a resin with a relatively high softening point on the outside and a soft resin on the inside, it is possible to obtain an adhesive that is stable against frictional charging and easy to transfer under pressure. Furthermore, by using a moisture-crosslinking thermoplastic resin powder with a hydrolyzable organosilicon functional group as an adhesive, moisture is added after heat bonding to form a crosslinked structure with siloxane bonds, resulting in heat resistance, solvent resistance, and heat resistance. It is also possible to produce adhesive fabrics with excellent water resistance. Such a moisture-crosslinkable thermoplastic resin having a hydrolyzable organosilicon functional group is, for example, represented by the general formula (1). (However, X is a hydrolyzable group such as an alkoxy group, an alkenyloxy group, an acyloxy group, an aminooxy group, an amino group, an oxime group, R' is a C 1 to C 4 alkyl group, and R'' is a hydrocarbon group or N , O, S, a hydrocarbon group containing one or more types of heteroatoms, a is 0 to
An integer of 2, n is 0 or 1, Q is H, NH 2 , SH,
N.C.O.

【式】【formula】

【式】【formula】

〔発明の効果〕〔Effect of the invention〕

本発明の方法によれば布又はニツト製品に点、
線、面あるいはそれらの集合からなる任意のパタ
ーンにしたがつて粉末状の接着剤を付着させ、そ
のまま加熱固着させることにより芯地を用いずに
布の保型効果をもたせることができる。あるいは
接着剤を付着させた後、布を折り曲げながら加熱
圧着したり、他の布を重ね合せながら加熱圧着、
加圧圧着することにより接着布を連続的に効率よ
く製造することができる。その結果、芯地貼り付
け工程乃至芯地縫い込み工程の省略、仕付け工程
の簡略化、一部の縫製組立て工程を接着へおきか
え等が可能となり、縫製工程の自動化、高速化に
果す役割りが大きい。 〔実施例〕 以下に実施例を示すが、本発明の実施の態様は
これに限定されるものではない。尚、例中の部は
重量部である。 実施例 1 (絶縁性媒体で転写する方法) 平均粒径35μの粉体状接着剤1部と平均粒径約
400μの鉄粉100部とから現像剤を調製した。粉体
状接着剤はε−カプロラクタム、アジピン酸、セ
バチン酸、ピラジン酸、ヘキサメチレンジアミン
から得られる環球法による軟化点130℃の共重合
ポリアミド樹脂を粗砕し、樹脂100部に対しアニ
リンブラツク塗料(オリエント化学(株)製ニグロシ
ンBK)を3部加え、溶融混練後、冷凍粉砕し、
風力分級により、調整した。この現像剤のブロー
オフ法による帯電量は7μc/gの正帯電性のもの
であつた。このようにして得られた現像剤4000部
を、十分予備撹拌した後、光フアイバーチユーブ
方式で、パターン発生機能を有する市販のプリン
ター(昭和情報機器S−840−Kプリンターシス
テム)を改造した電子写真式印画装置の現像部に
入れ、現像剤をカスケード式現像機内で十分撹拌
した。プリンターの制御装置を調整し、インチ当
り32ドツトに分割されたドツトにより線幅0.8mm、
線と線の間の空白が2.8mmの縦横の線からなる格
子状のパターンが発生するように、パターンジエ
ネレーターを調整した(この場合、格子状パター
ン部は、オプチカルフアイバーにより、光照射さ
れる)。 アモルフアスセレン系よりなる感光体の表面を
一様に正に帯電させ、B4版大に裁断したポリエ
ステルフイルム(体積固有抵抗1016Ω・cm)を給
紙部にセツトし、パターン制御された光シグナル
を光フアイバーチユーブによりドツト状に、プロ
セススピード64mm/sec、露光時間4.3secにて、
A4版大の格子状パターンを照射させ、正に帯電
した粉体状接着剤により、現像し、感光体上に粉
体像を付着させた後、感光体と同周速によりポリ
エステルフイルムを接触移動する際に、ポリエス
テルフイルムの裏側に置かれたコロナ放電線より
負のコロナチヤージにより粉体像をポリエステル
フイルム上に転写した。ポリエステルフイルムを
除電した後、搬送部に移動された粉体の付着した
フイルム上にA4版大に裁断したポリエステル/
綿(65/35)ブロード布(表面比抵抗1014Ωcm)
をのせ、ブロード布上に設置したコロナチヤージ
ヤーを移動させることにより、同時に、ブロード
布に粉体像を転写させた。このブロード布を粉体
像がくずれないように注意しながらポリエステル
フイルムより剥離し、粉体のブロード布への付着
量をしらべたところ、3.8g/cm2であつた。粉体
の付着したブロード布の上に、更に別のA4版に
裁断したブロード布を重ね、表面温度180℃に調
整された熱ローラー(42mm/secの周速度)を通
過させることにより、布同志を接着させた。この
接触布の一部を幅25mm、長さ100mmの試片に裁断
し、20℃にて100mm/分の引張速度で、剥離試験
をしたところ、平均135g/25mmの剥離強度を示
した。 実施例 2 (離型性媒体で転写する方法) 現像剤を実施例1の方法で調製し、実施例1に
用いた電子写真式印画装置の現像機部に入れ、同
様な格子状パターンの発生の調整を行つた。 感光体の表面を一様に正に帯電させ、B4版大
に裁断した表面をシリコン処理した離型紙(特種
製紙(株)製、体積固有抵抗8×1014Ωcm、臨界表面
張力23.2dyne/cm)を給紙部にセツトし、A4版
大の格子状パターンを照射し、正に帯電した粉体
接着剤により感光体上に粉体像を付着させ、感光
体と同周速により、離型紙を接触移動させる際
に、離型紙の裏側から負のコロナチヤージによ
り、粉体像を離型紙上に転写させた。 搬送部に移動された粉体の付着した離型紙の上
にA4版大に裁断したポリエステル/綿(65/35)
のブロード布をのせ、表面温度180℃に調整した
熱ローラーを通し、離型紙を剥離し、粉体状接着
剤をブロード布へ熱溶融転写させることにより、
接着剤が格子状パターンで固着した布を得た。接
着剤の付着量は、4.3g/m2であつた。このブロ
ード布に別のA4版大のブロード布を重ね、ヒー
トプレス(150℃、20秒)することにより、布同
志を接着させた。剥離強度は平均165g/25mmで
あつた。 実施例 3 環球法によつて測定される軟化点が115℃、平
均粒径が20μの分子末端を3−イソシアナトプロ
ピルトリエトキシシランによりトリエトキシシリ
ル変成した共重合ポリエステル樹脂粉末10重量部
と平均粒径100μの鉄粉100重量部をドライブレン
ドして現像剤を調製した。該現像剤を市販の複写
機(三田工業(株)DC−162)を改造した装置のトナ
ーボツクスに入れ、A4サイズの紙の上にセロテ
ープでふちを固定したポリエステル/綿=65/35
ブロード布(表面比抵抗1014Ωcm)を通して該布
上に上記の変成共重合ポリエステル樹脂粉末を一
様に転写したものを取出し赤外線ランプにより軽
く布上に固着させた。続いて該布上に同種の布を
重ね160℃に加熱した2本の熱ロールの間を通過
させて圧着することにより接着布を得た。 該接着布の一部を直ちに幅25mm、長さ100mmの
試片に裁断し、20℃にて100mm/分の引調速度で
剥離試験をしたところ、平均約130g/25mmの剥
離強度を示した。 該接着布に直ちに160℃のアイロンを当て1分
間おさえておいたところ、接着剤が布の表面にし
み出し、風合いも硬くなるという欠点が見られ
た。該接着布の残りを温度25℃、湿度65%の恒温
恒湿試験室に3週間放置した後で同様のアイロン
掛けによる耐熱試験を行つた。この場合は接着剤
のしみ出しはなく、風合いの変化もほとんど感じ
られなかつた。剥離強度は平均約160g/25mmで
あつた。これらの結果から吸湿による接着剤の架
橋により熱可塑性が消滅し、耐熱性が向上したこ
とが確かめられた。
According to the method of the present invention, dots are applied to cloth or knit products.
By applying a powdered adhesive according to an arbitrary pattern consisting of lines, planes, or a set of these, and heating and fixing the adhesive as it is, it is possible to create a shape-retaining effect on the cloth without using an interlining. Alternatively, after applying the adhesive, heat and press the fabric while folding it, or heat and press it while overlapping other fabrics.
By pressure bonding, adhesive cloth can be manufactured continuously and efficiently. As a result, it has become possible to omit the interlining pasting process and interlining sewing process, simplify the sewing process, and replace some sewing assembly processes with adhesive, which will play a role in automating and speeding up the sewing process. big. [Example] Examples are shown below, but the embodiments of the present invention are not limited thereto. Note that parts in the examples are parts by weight. Example 1 (Method of transferring with an insulating medium) 1 part of powder adhesive with an average particle size of 35μ and an average particle size of approx.
A developer was prepared from 100 parts of 400μ iron powder. The powder adhesive is made by coarsely crushing a copolyamide resin with a softening point of 130°C by the ring and ball method obtained from ε-caprolactam, adipic acid, sebacic acid, pyrazine acid, and hexamethylene diamine, and adding aniline black paint to 100 parts of the resin. Add 3 parts of Nigrosine BK (manufactured by Orient Chemical Co., Ltd.), melt and knead, freeze and crush,
Adjustment was made by wind classification. The charge amount of this developer by the blow-off method was 7 μc/g, which was a positive charge. After thoroughly pre-stirring 4,000 parts of the developer thus obtained, an electrophotographic photograph was taken using an optical fiber tube method using a commercially available printer (Showa Information Equipment S-840-K Printer System) modified with a pattern generation function. The developer was placed in the developing section of a type printing device, and the developer was sufficiently stirred in the cascade type developing machine. By adjusting the printer's control device, the line width is 0.8 mm, with dots divided into 32 dots per inch.
The pattern generator was adjusted so that a grid pattern consisting of vertical and horizontal lines with a space of 2.8 mm between lines was generated (in this case, the grid pattern part was irradiated with light by an optical fiber). ). The surface of the photoreceptor made of amorphous selenium is uniformly positively charged, and a polyester film cut into B4 size (volume resistivity 10 16 Ω cm) is set in the paper feed section, and pattern-controlled light is applied. The signal was converted into dots using an optical fiber tube at a process speed of 64 mm/sec and an exposure time of 4.3 seconds.
After irradiating an A4 size grid pattern, developing it with a positively charged powder adhesive, and adhering the powder image onto the photoreceptor, move the polyester film into contact with the photoreceptor at the same peripheral speed. At this time, the powder image was transferred onto the polyester film by negative corona charge from a corona discharge wire placed on the back side of the polyester film. After removing static electricity from the polyester film, the polyester cut into A4 size paper is placed on the film with powder attached to it, which is moved to the conveyance section.
Cotton (65/35) broad cloth (surface resistivity 10-14 Ωcm)
At the same time, the powder image was transferred to the broad cloth by placing the powder on the broad cloth and moving the corona charger set on the broad cloth. This broadcloth was peeled off from the polyester film, taking care not to disturb the powder image, and the amount of powder adhering to the broadcloth was determined to be 3.8 g/cm 2 . On top of the powder-adhered broadcloth, another broadcloth cut into an A4 size sheet is layered, and passed through a heated roller (circumferential speed of 42 mm/sec) whose surface temperature is adjusted to 180°C. was glued. A part of this contact cloth was cut into specimens with a width of 25 mm and a length of 100 mm, and a peel test was performed at 20° C. at a tensile rate of 100 mm/min, which showed an average peel strength of 135 g/25 mm. Example 2 (Method of transferring with a releasable medium) A developer was prepared by the method of Example 1, and put into the developing unit of the electrophotographic printing device used in Example 1, and a similar grid pattern was generated. Adjustments were made. The surface of the photoreceptor was charged uniformly and positively, and the surface cut into B4 size sheets was silicon-treated release paper (manufactured by Tokushu Paper Co., Ltd., volume resistivity 8 x 10 14 Ωcm, critical surface tension 23.2 dyne/cm). ) in the paper feed section, irradiate it with an A4 size grid pattern, adhere the powder image onto the photoreceptor using the positively charged powder adhesive, and release the release paper at the same peripheral speed as the photoreceptor. When the particles were brought into contact with each other, the powder image was transferred onto the release paper by negative corona charge from the back side of the release paper. Polyester/cotton (65/35) cut into A4 size paper is placed on the release paper with powder attached to the transport section.
A broad cloth is placed on the adhesive, passed through a heated roller whose surface temperature is adjusted to 180℃, the release paper is peeled off, and the powder adhesive is transferred to the broad cloth by thermal melting.
A cloth to which the adhesive was adhered in a grid pattern was obtained. The amount of adhesive adhered was 4.3 g/m 2 . This broadcloth was layered with another A4-sized broadcloth and heat-pressed (150°C, 20 seconds) to adhere the fabrics together. The average peel strength was 165 g/25 mm. Example 3 10 parts by weight of a copolymerized polyester resin powder with a softening point of 115°C and an average particle size of 20μ as measured by the ring and ball method and triethoxysilyl modified with 3-isocyanatopropyltriethoxysilane at the molecular end A developer was prepared by dry blending 100 parts by weight of iron powder with a particle size of 100 μm. The developer was placed in a toner box of a commercially available copying machine (DC-162, manufactured by Sanda Kogyo Co., Ltd.), and the edges were fixed with sellotape on A4 size paper (polyester/cotton = 65/35).
The above-mentioned modified copolymerized polyester resin powder was uniformly transferred onto the cloth through a broad cloth (surface specific resistance: 10 14 Ωcm), and was lightly fixed onto the cloth using an infrared lamp. Subsequently, a similar type of fabric was layered on top of the fabric, and the fabric was passed between two hot rolls heated to 160°C and pressed together to obtain an adhesive fabric. A part of the adhesive fabric was immediately cut into specimens with a width of 25 mm and a length of 100 mm, and a peel test was performed at 20°C at a drawdown speed of 100 mm/min, which showed an average peel strength of about 130 g/25 mm. . When the adhesive cloth was immediately ironed at 160°C and held for 1 minute, the adhesive seeped out onto the surface of the cloth and the texture became hard. The remaining adhesive fabric was left in a constant temperature and humidity test room at 25° C. and 65% humidity for 3 weeks, and then subjected to a similar heat resistance test by ironing. In this case, there was no seepage of the adhesive, and almost no change in texture was noticed. The average peel strength was about 160 g/25 mm. From these results, it was confirmed that thermoplasticity disappeared due to crosslinking of the adhesive due to moisture absorption, and heat resistance improved.

【図面の簡単な説明】[Brief explanation of drawings]

第1〜5図はそれぞれ本発明の布接着方法に用
いる装置の略示平面図である。 1……導電性ドラム、2……パターン、3……
接着剤ボツクス、4……ブラシ、5……ローラ
ー、6……ベルト、7……電極、8,8′……布
又はニツト製品、9……熱源、10……熱ロー
ル、11……ガイド、12……絶縁性ベルト、1
3,13′……転写ローラー、14,14′……熱
ロール、15……接着布、16……離型ベルト、
17……支持ベルト、18……熱ロール、19…
…加圧ロール。
1 to 5 are schematic plan views of apparatuses used in the cloth bonding method of the present invention. 1... Conductive drum, 2... Pattern, 3...
Adhesive box, 4... Brush, 5... Roller, 6... Belt, 7... Electrode, 8, 8'... Cloth or knit product, 9... Heat source, 10... Heat roll, 11... Guide , 12...Insulating belt, 1
3, 13'... Transfer roller, 14, 14'... Heat roll, 15... Adhesive cloth, 16... Release belt,
17... Support belt, 18... Heat roll, 19...
...Pressure roll.

Claims (1)

【特許請求の範囲】 1 導電性基体の上に設けられた導電性感光体層
をコロナ放電で一様に帯電せしめ、該感光体帯電
表面を任意のパターンで露光することにより、該
帯電表面上の露光部分の電荷を減少せしめて、該
感光体層表面上に表面電荷が多く残存した非露光
部分である当該パターンの静電潜像を形成せしめ
該静電潜像とは反対の極性に帯電せしめた粉体状
接着剤を用いるか、あるいは、表面電荷が減少し
た露光部分である当該パターンの静電潜像を形成
せしめ、該静電潜像と同じ極性に帯電せしめた粉
体状接着剤を用いて該静電潜像を顕像化すること
により感光体表面上に形成された粉体状接着剤に
よる像を、直接、布又はニツト製品に静電転写さ
せるか、もしくは他の媒体表面に静電転写させた
後、布又はニツト製品に再転写させることによ
り、接着剤が当該パターンで付着した接着布を調
製し、該接着剤を布又はニツト製品に加熱融着さ
せるか又はさせないで、該接着布の一部を折曲げ
て重ねるか又は別の布もしくはニツト製品を重ね
合わせて加熱し、接着剤を融着せしめることを特
徴とする布の接着方法。 2 布又はニツト製品が、30℃、相対湿度75%に
おいて表面比対抗が5×105Ωcm以上の繊維材料
から構成されるものである特許請求の範囲第1項
記載の接着方法。 3 他の媒体が絶縁性表面を有する媒体であり、
布又はニツト製品への再転写が静電転写である特
許請求の範囲第1項記載の接着方法。 4 絶縁性表面を有する媒体が、30℃、相対湿度
75%において表面を形成する材料の体積固有抵抗
が5×106Ωcm以上のフイルム、シート、ベルト、
もしくはロールである特許請求の範囲第3項記載
の接着方法。 5 他の媒体が離型性表面を有する媒体であり、
布又はニツト製品への再転写が熱転写あるいは圧
力転写である特許請求の範囲第1項記載の接着方
法。 6 離型性表面を有する媒体が、表面を形成する
材料の臨界表面張力32dyne/cm以下のフイルム、
シート、ベルトもしくはロールである特許請求の
範囲第5項記載の接着方法。 7 接着布が布又はニツト製品1m2あたり0.1g
〜400gの接着剤付着量もしくは融着量を有する
ものである特許請求の範囲第1〜6項のいずれか
一項に記載の接着方法。 8 粉体状接着剤が、加水分解性有機珪素官能基
を有する湿気架橋型の熱可塑性樹脂からなるもの
である特許請求の範囲第1〜7項のいずれか一項
に記載の接着方法。
[Scope of Claims] 1. A conductive photoreceptor layer provided on a conductive substrate is uniformly charged by corona discharge, and the charged surface of the photoreceptor is exposed to light in an arbitrary pattern, thereby forming a layer on the charged surface. The electrostatic latent image of the pattern, which is an unexposed area with a large amount of surface charge remaining, is formed on the surface of the photoreceptor layer by reducing the electric charge on the exposed area of the photoreceptor layer, and is charged to a polarity opposite to that of the electrostatic latent image. or a powdered adhesive that forms an electrostatic latent image of the pattern, which is the exposed portion with reduced surface charge, and is charged to the same polarity as the electrostatic latent image. The powdered adhesive image formed on the surface of the photoconductor is directly electrostatically transferred to cloth or knitted products, or transferred to the surface of other media. After electrostatically transferring the adhesive to the fabric or knitted product, the pattern is transferred to the fabric or knitted product to prepare an adhesive fabric with the adhesive adhered in the pattern, and the adhesive may or may not be heat-fused to the fabric or knitted product. . A method for bonding fabrics, which comprises folding a part of the adhesive fabric and stacking it, or stacking another fabric or knit product on top of each other and then heating to fuse the adhesive. 2. The bonding method according to claim 1, wherein the cloth or knit product is made of a fiber material having a surface resistance of 5×10 5 Ωcm or more at 30° C. and 75% relative humidity. 3. The other medium is a medium having an insulating surface,
2. The adhesion method according to claim 1, wherein the retransfer to cloth or knit products is electrostatic transfer. 4 The medium with an insulating surface is heated at 30°C and relative humidity.
Films, sheets, belts, whose surface material has a volume resistivity of 5×10 6 Ωcm or more in 75% of cases.
The bonding method according to claim 3, wherein the bonding method is a roll. 5. The other medium is a medium having a releasable surface,
2. The adhesion method according to claim 1, wherein the retransfer to cloth or knit products is thermal transfer or pressure transfer. 6 A film in which the medium having a releasable surface has a critical surface tension of the material forming the surface of 32 dyne/cm or less,
The bonding method according to claim 5, which is a sheet, a belt, or a roll. 7 Adhesive fabric: 0.1g per 1m2 of cloth or knitted products
The bonding method according to any one of claims 1 to 6, wherein the bonding method has an adhesive adhesion amount or fusion amount of ~400 g. 8. The bonding method according to any one of claims 1 to 7, wherein the powder adhesive is made of a moisture-crosslinkable thermoplastic resin having a hydrolyzable organosilicon functional group.
JP59168845A 1984-08-14 1984-08-14 Method of bonding cloth Granted JPS6147776A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59168845A JPS6147776A (en) 1984-08-14 1984-08-14 Method of bonding cloth

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59168845A JPS6147776A (en) 1984-08-14 1984-08-14 Method of bonding cloth

Publications (2)

Publication Number Publication Date
JPS6147776A JPS6147776A (en) 1986-03-08
JPS6357552B2 true JPS6357552B2 (en) 1988-11-11

Family

ID=15875598

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59168845A Granted JPS6147776A (en) 1984-08-14 1984-08-14 Method of bonding cloth

Country Status (1)

Country Link
JP (1) JPS6147776A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6377483A (en) * 1986-09-22 1988-04-07 工業技術院長 Stitch adhesive coating apparatus
WO1997034556A2 (en) * 1996-03-22 1997-09-25 The Procter & Gamble Company Method of folding and using static charge to align and retain folded material
JP4811278B2 (en) * 2007-01-17 2011-11-09 カシオ電子工業株式会社 Application method of powder adhesive
CN103324066B (en) * 2013-06-09 2015-09-23 珠海天威飞马打印耗材有限公司 Laser imaging method on special media

Also Published As

Publication number Publication date
JPS6147776A (en) 1986-03-08

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