JPS6363189B2 - - Google Patents
Info
- Publication number
- JPS6363189B2 JPS6363189B2 JP55170287A JP17028780A JPS6363189B2 JP S6363189 B2 JPS6363189 B2 JP S6363189B2 JP 55170287 A JP55170287 A JP 55170287A JP 17028780 A JP17028780 A JP 17028780A JP S6363189 B2 JPS6363189 B2 JP S6363189B2
- Authority
- JP
- Japan
- Prior art keywords
- soymilk
- soybeans
- grinding
- okara
- soaking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000013322 soy milk Nutrition 0.000 claims description 32
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 235000010469 Glycine max Nutrition 0.000 claims description 23
- 244000068988 Glycine max Species 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 22
- 238000000227 grinding Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 238000002791 soaking Methods 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 6
- 239000012670 alkaline solution Substances 0.000 claims description 5
- 239000000796 flavoring agent Substances 0.000 description 9
- 238000000605 extraction Methods 0.000 description 7
- 235000019634 flavors Nutrition 0.000 description 7
- 235000011121 sodium hydroxide Nutrition 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- 238000004332 deodorization Methods 0.000 description 5
- 239000003925 fat Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 235000019640 taste Nutrition 0.000 description 4
- 238000007654 immersion Methods 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 102000003820 Lipoxygenases Human genes 0.000 description 2
- 108090000128 Lipoxygenases Proteins 0.000 description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 235000013527 bean curd Nutrition 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000019583 umami taste Nutrition 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 101710162629 Trypsin inhibitor Proteins 0.000 description 1
- 229940122618 Trypsin inhibitor Drugs 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000019606 astringent taste Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 235000019668 heartiness Nutrition 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000002753 trypsin inhibitor Substances 0.000 description 1
Landscapes
- Beans For Foods Or Fodder (AREA)
Description
本発明は、風味良好な豆乳の製造法に関するも
のである。さらに詳細には、大豆特有な嫌な臭気
は除去するが、大豆本来の旨味及びコク味を逃が
すことなく、しかも豆乳の抽出率を高めるように
した豆乳の製造法に関するものである。
従来、豆乳の製造は、1晩水に浸漬した大豆を
水挽きし、更に大量の水を加えて加熱、過して
製造するものであるが、これには我が国古来の方
法の外、コーネル方式、アメリカ濃務省方式、イ
リノイ大学方式等新式の方法が多数報告されてい
る。
豆乳の製造上最も問題となるのは脱臭で、これ
については溶媒抽出法、加熱処理法、蒸留法、発
酵法、酸素処理法、吸着剤処理法、特定物質添加
法(アミノ酸、褐変物質等)などがあるが、これ
らの方法は脱臭が不完全であつたり、脱臭処理に
より却て異味、異臭がついたりするなどの欠点が
ある。また上記の方法を組み合わせることも提案
されているが、操作が繁雑であつたり、脱臭はで
きても豆乳としての旨味、コク味まで失う結果に
なつたりして、豆乳の製造法としては実用化され
ていないのが現状である。つぎに問題となるのは
豆乳の抽出率である。大豆の浸漬条件あるいは磨
砕条件などは大豆成分(蛋白質、脂肪など)の抽
出率を大きく左右するので、これらの条件設定は
豆乳製造上重要な問題である。
本発明者らは、従来の豆乳の製造法の問題点を
解決し、風味の良好な豆乳を歩留まり良く製造せ
んと研究を進めた結果、脱皮大豆を70〜85℃のア
ルカリ溶液で1〜2分の短時間浸漬し、浸漬した
脱皮大豆を取り出し、一方0.009〜0.01%濃度の
NaOH溶液を95〜100℃に加熱し、これを脱皮大
豆の12〜15倍量もの大容量で大豆に加え、磨砕
し、磨砕物を95〜100℃で30分加熱しておからを
分離するか或は磨砕物からおからを分離したもの
を130〜140℃で1分間加熱し、加熱処理した豆乳
を約1/2量に真空濃縮することにより解決した。
以下本発明を工程順に説明すると、先づ脱皮大
豆をアルカリ溶液で高温、短時間浸漬処理し、所
謂あく抜きを行う。浸漬に使用するアルカリ溶液
としては苛性ソーダ、炭酸ソーダ、重炭酸ソーダ
等の希薄溶液が使用できるが好ましくは0.5%程
度の重炭酸ソーダである。浸漬液量は脱皮大豆の
2倍程度が常用され、浸漬温度は70〜85℃の高温
とし1〜2分の短時間浸漬とする。浸漬温度は低
温であると、アク抜きに長時間(1晩)を要し、
低分子である旨味やコク味が溶出してしまう。ま
た大豆自体も温度の低温になつてしまうので、次
工程での磨砕温度を高温に維持することが困難に
なるので本発明では採用できない。
又、浸漬温度が高温の場合は浸漬時間が長くな
るにつれ低分子である旨味やコク味成分が溶出す
るのは勿論であるが、一方豆自体が熱変性を受け
るため、次工程での磨砕による蛋白、脂肪、固形
分等の高分子成分の抽出率が図1のように低下す
る。したがつて本発明の浸漬は70〜85℃の高温で
しかも1〜2分の短時間で行うことが必要でこれ
によりあくは抜けるが必要成分の流出を防止し、
歩留まり向上に役立つのである。
上記浸漬物はこれを取り出し、これを磨砕する
が、磨砕時において高温(95〜100℃)の希薄ア
ルカリ溶液(0.009〜0.01%のNaOH)を大量に
(大豆の12〜15倍量)添加するものである。この
とき、使用する希薄アルカリ溶液としては苛性ソ
ーダ、炭酸ソーダ、重炭酸ソーダ等の溶液が使用
できるが、好ましくは苛性ソーダであり、できた
豆乳の風味が最も良好となる。又、濃度は苛性ソ
ーダとして0.009〜0.01%と少量で、この範囲で
は大豆の渋味を押え、まる味を出すが、これより
大量となりPHが7.4以上となると加熱により硫化
水素臭を生ずるので注意を要する。添加する液量
は脱皮大豆の12〜15倍量の大量とし、磨砕時に大
豆を添加する。これにより大豆成分の抽出率が著
しく向上し、次の脱臭工程において大量の蒸発を
可能とし脱臭を完全ならしむるものである。磨砕
は通常豆腐製造に使用するグラインダーによると
よいが、磨砕時には液温を95〜100℃とし、大豆
中のリポキシダーゼの作用を抑制し、青草臭の発
生を防止しなければならない。若し、95℃以下の
低温で磨砕すると、次の脱臭工程においても充分
脱臭することができず商品価値を損ずるので注意
を要する。尚磨砕は空気中で行つてもよいが、窒
素ガス、炭酸ガスの如き下活性気体の雰囲気下或
は蒸気シールを行つた雰囲気下で行うと更に良好
な風味の製品となる利点を有する。
上記磨砕物は次いで加熱し、リポキシダーゼを
完全に失活させるが、加熱条件は磨砕物そのまま
の時は95〜100℃で30分維持すれば良く、おから
を分離した豆乳にあつては130〜140℃で1分間加
熱するとよい。この処理により、青草臭の戻りを
防止できる外、同時にトリプシンインヒビターも
完全に失活し、保存に耐える製品となるのであ
る。若し加熱温度あるいは時間がこれを下廻ると
十分な効果が得られない。又、逆に加熱処理がこ
れを上廻ると煮豆臭、H2S臭が発生するのでさけ
ねばならない。
磨砕物よりデカンダー又はバスケツト型遠心
過機等の分離装置で粗豆乳とおからに分離すると
粗豆乳中には原料中の85〜90%の固形物がおから
中には10〜15%の固形物が移行し、従来法に比べ
て著しく回収率が向上する。今、本発明により得
た粗豆乳の分析例を示す。
The present invention relates to a method for producing soymilk with good flavor. More specifically, the present invention relates to a method for producing soymilk that removes the unpleasant odor characteristic of soybeans, does not lose the flavor and richness inherent in soybeans, and increases the extraction rate of soymilk. Conventionally, soy milk is produced by soaking soybeans overnight, grinding them in water, adding a large amount of water, heating, and straining. A number of new methods have been reported, such as the US Department of State's method and the University of Illinois method. The most important problem in the production of soymilk is deodorization, which includes solvent extraction methods, heat treatment methods, distillation methods, fermentation methods, oxygen treatment methods, adsorbent treatment methods, and specific substance addition methods (amino acids, browning substances, etc.). However, these methods have drawbacks such as incomplete deodorization and the fact that the deodorization process may even give off a strange taste or odor. It has also been proposed to combine the above methods, but the operations are complicated, and even if deodorization is possible, the flavor and richness of soy milk are lost, so it is not practical as a method for producing soy milk. The current situation is that this has not been done. The next issue is the extraction rate of soy milk. Since soybean soaking conditions or grinding conditions greatly affect the extraction rate of soybean components (protein, fat, etc.), setting these conditions is an important issue in soymilk production. The present inventors have conducted research to solve the problems of conventional soy milk production methods and produce soy milk with a good flavor at a high yield. Soak for a short time for 1 min, then take out the soaked dehulled soybeans, while at a concentration of 0.009-0.01%.
Heat the NaOH solution to 95-100℃, add this to soybeans in a large volume 12-15 times the amount of dehulled soybeans, grind them, and heat the ground product at 95-100℃ for 30 minutes to separate okara. Alternatively, the problem was solved by heating the okara separated from the ground product at 130 to 140°C for 1 minute, and vacuum concentrating the heat-treated soymilk to about 1/2 the volume. The present invention will be explained below in order of steps. First, dehulled soybeans are immersed in an alkaline solution at high temperature for a short period of time to perform so-called dulling. As the alkaline solution used for immersion, dilute solutions such as caustic soda, soda carbonate, and bicarbonate of soda can be used, but sodium bicarbonate of about 0.5% is preferred. The amount of soaking liquid used is usually about twice that of the dehulled soybeans, and the soaking temperature is set to a high temperature of 70 to 85°C for a short time of 1 to 2 minutes. If the soaking temperature is low, it will take a long time (overnight) to remove the scum.
Umami and richness, which are low molecules, are eluted. Furthermore, since the temperature of the soybeans themselves becomes low, it becomes difficult to maintain the grinding temperature at a high temperature in the next step, so this method cannot be used in the present invention. In addition, if the soaking temperature is high, it goes without saying that as the soaking time increases, the low-molecular umami and kokumi components will elute, but on the other hand, the beans themselves will undergo thermal denaturation, so it will be difficult to grind them in the next process. The extraction rate of macromolecular components such as protein, fat, and solid content decreases as shown in Figure 1. Therefore, the immersion of the present invention needs to be carried out at a high temperature of 70 to 85°C and for a short time of 1 to 2 minutes, which removes the scum but prevents the necessary components from flowing out.
This helps improve yield. The above-mentioned soaked food is taken out and ground. During grinding, a large amount of dilute alkaline solution (0.009-0.01% NaOH) at high temperature (95-100℃) is used (12-15 times the amount of soybeans). It is added. At this time, as the dilute alkaline solution used, solutions such as caustic soda, soda carbonate, and bicarbonate of soda can be used, but caustic soda is preferable, as the resulting soymilk will have the best flavor. Also, the concentration is as small as 0.009 to 0.01% as caustic soda, and in this range it suppresses the astringency of the soybeans and gives them a round taste, but if it is in a larger amount and the pH is over 7.4, it will produce a hydrogen sulfide odor when heated, so be careful. It takes. The amount of liquid to be added is 12 to 15 times the amount of dehulled soybeans, and the soybeans are added at the time of grinding. This significantly improves the extraction rate of soybean components and enables a large amount of evaporation in the next deodorizing step, thereby completing deodorization. Grinding can be carried out using a grinder normally used for tofu production, but during grinding, the liquid temperature must be 95 to 100°C to suppress the action of lipoxidase in the soybeans and prevent the generation of grassy odor. If grinding is carried out at a low temperature of 95°C or lower, the next deodorizing process will not be able to sufficiently deodorize the product, which will impair commercial value, so care must be taken. Although the grinding may be carried out in the air, it is advantageous to produce a product with a better flavor if it is carried out in an atmosphere of an active gas such as nitrogen gas or carbon dioxide, or in a steam-sealed atmosphere. The above-mentioned ground product is then heated to completely deactivate the lipoxidase, but the heating condition is that if the ground product is as it is, it should be maintained at 95 to 100°C for 30 minutes, and in the case of soymilk from which okara has been separated, the heating condition is 130°C. It is best to heat it at ~140℃ for 1 minute. This treatment not only prevents the return of the grassy odor, but also completely deactivates the trypsin inhibitor, resulting in a product that can withstand storage. If the heating temperature or time is lower than this, sufficient effects cannot be obtained. On the other hand, if the heat treatment exceeds this level, boiled bean odor and H 2 S odor will occur, which must be avoided. When the ground product is separated into coarse soy milk and okara using a separator such as a decander or basket centrifuge, the raw soy milk contains 85-90% solids and the okara contains 10-15% solids. transfer, and the recovery rate is significantly improved compared to the conventional method. An example of analysis of crude soymilk obtained according to the present invention will now be shown.
【表】
上記粗豆乳は濃縮し脱臭するが濃縮は真空度
620Hg〜650Hgの減圧とした濃縮缶で真空中の滞
留時間30分以上かけて行う。若し真空中でフラツ
シユさすように短時間で濃縮すると異臭の除去は
完全でない。又濃縮程度も約1/2程度とするよう
に大量濃縮を行わないと異臭が残り商品価値を損
ずる。この結果濃縮方法としてはバツチ式エバポ
レーターを使用した方が好ましく、濃縮により蛋
白濃度は4〜5%、全固形分9〜10%で旨味及び
コク味があり、異臭のない豆乳となる。次に、本
発明の方法により得た粗豆乳と、これを濃縮豆乳
とした時の豆乳中の揮発性成分の変化を示す。[Table] The above crude soy milk is concentrated and deodorized, but the concentration is done at a vacuum level.
It is carried out in a concentrator with a reduced pressure of 620Hg to 650Hg over a residence time of 30 minutes or more in vacuum. If it is concentrated in a short period of time, such as by flashing in a vacuum, the odor will not be completely removed. Also, unless a large amount of concentration is carried out, such as reducing the concentration level to about 1/2, an unpleasant odor will remain and the product value will be impaired. As a result, it is preferable to use a batch type evaporator as a concentration method, and the concentration produces soymilk with a protein concentration of 4 to 5%, a total solid content of 9 to 10%, a delicious and rich taste, and no off-flavor. Next, changes in volatile components in crude soymilk obtained by the method of the present invention and in soymilk when it is made into concentrated soymilk are shown.
【表】
第2表より判明する如く本発明の方法により得
た濃縮豆乳は揮発性物質が極めて少ないものであ
る。この濃縮豆乳は油脂、砂糖、食塩その他調味
料と混合し、均質機で均質化し、調合豆乳とする
と極めて味がよく異臭のない飲料となる。
以下実施例により説明する。
実施例 1
脱皮大豆100Kgを85℃の0.5%NaHCO3溶液200
Kg中に1分間浸漬した後、浸漬液を排除して85℃
の水で洗浄し、洗浄脱皮大豆123Kgを得た。つぎ
に95℃の0.0117%NaOH溶液1180Kgを加えながら
豆腐製造用グラインダーにより磨砕した。
得られた磨砕物1303Kgをコンベア型遠心分離機
に供給し、おからを分離除去して固形分7.18%の
粗豆乳1.091Kgを得た。つぎに粗豆乳をプレート
ヒーターを使用して間接加熱方式により130℃で
1分間加熱した後、バツチ式真空濃縮装置を使用
して55℃で90分間濃縮脱臭して固形分14.3%の豆
乳548Kgを得た。このときの抽出率は87%であつ
た。得られた豆乳は大豆特有の異臭を有せず、旨
味、コク味の点ですぐれていた。[Table] As is clear from Table 2, the concentrated soymilk obtained by the method of the present invention has extremely low volatile substances. This concentrated soymilk is mixed with fats and oils, sugar, salt, and other seasonings, and homogenized using a homogenizer. When the blended soymilk is prepared, it becomes a beverage with excellent taste and no off-flavors. This will be explained below using examples. Example 1 100 kg of dehulled soybeans were dissolved in 0.5% NaHCO 3 solution at 85°C.
After immersing in Kg for 1 minute, remove the immersion liquid and store at 85°C.
of water to obtain 123 kg of washed and dehulled soybeans. Next, 1180 kg of 0.0117% NaOH solution at 95°C was added while grinding using a tofu manufacturing grinder. 1303 kg of the obtained ground material was fed to a conveyor type centrifuge to separate and remove okara to obtain 1.091 kg of crude soy milk with a solid content of 7.18%. Next, the coarse soymilk was heated at 130℃ for 1 minute by indirect heating using a plate heater, and then concentrated and deodorized using a batch-type vacuum concentrator at 55℃ for 90 minutes to obtain 548kg of soymilk with a solid content of 14.3%. Obtained. The extraction rate at this time was 87%. The obtained soymilk did not have the unusual odor characteristic of soybeans and was excellent in flavor and richness.
図面は磨砕前の加熱処理が抽出率に及ぼす影響
を示すグラフである。
イ……蛋白質、ロ……脂肪、ハ……固形分。
The figure is a graph showing the effect of heat treatment before grinding on extraction rate. A...Protein, B...Fat, C...Solid content.
Claims (1)
2分間浸漬する工程と浸漬後の脱皮大豆を脱皮大
豆の12〜15倍量の95〜100℃に加熱した0.009〜
0.01%濃度のNaOH溶液と共に磨砕する工程と磨
砕物をそのまゝ或はおからを分離して加熱する工
程と、加熱後おからを分離した豆乳或はおからを
分離して加熱した豆乳を減圧下で約1/2に濃縮す
る工程よりなる脱臭された豆乳の製造法。1 Dehulled soybeans are placed in an alkaline solution at 70 to 85℃.
The process of soaking for 2 minutes and the dehulled soybeans after soaking are heated to 95 to 100℃, which is 12 to 15 times the amount of the dehulled soybeans.
A process of grinding with a 0.01% NaOH solution, a process of heating the ground product as it is or separating the okara, and depressurizing the soymilk from which the okara has been separated after heating, or the soymilk which has been heated after separating the okara. A method for producing deodorized soymilk that consists of a step of concentrating it to about 1/2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55170287A JPS5794264A (en) | 1980-12-04 | 1980-12-04 | Preparation of deodorized soybean milk |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55170287A JPS5794264A (en) | 1980-12-04 | 1980-12-04 | Preparation of deodorized soybean milk |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5794264A JPS5794264A (en) | 1982-06-11 |
| JPS6363189B2 true JPS6363189B2 (en) | 1988-12-06 |
Family
ID=15902146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55170287A Granted JPS5794264A (en) | 1980-12-04 | 1980-12-04 | Preparation of deodorized soybean milk |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5794264A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR0116679A (en) | 2000-12-19 | 2004-01-13 | Yakult Honsha Kk | Skin preparations for external application and process for manufacture |
| US7258889B2 (en) * | 2004-09-21 | 2007-08-21 | Alejandro Javier Delgado Araujo | Method for preparing a beanless-flavor soymilk and/or okara using carbon dioxide in a state of sublimation |
-
1980
- 1980-12-04 JP JP55170287A patent/JPS5794264A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5794264A (en) | 1982-06-11 |
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