JPS636593B2 - - Google Patents
Info
- Publication number
- JPS636593B2 JPS636593B2 JP57200369A JP20036982A JPS636593B2 JP S636593 B2 JPS636593 B2 JP S636593B2 JP 57200369 A JP57200369 A JP 57200369A JP 20036982 A JP20036982 A JP 20036982A JP S636593 B2 JPS636593 B2 JP S636593B2
- Authority
- JP
- Japan
- Prior art keywords
- portland cement
- soil
- blast furnace
- furnace slag
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Description
本発明は、深層混合処理に用いる地盤改良材に
関する。
一般に深層混合処理は、地盤改良用特殊船から
改良すべき海底土壌に対して地盤改良材を注入
し、同時に撹拌する工法によつて行なわれ、海底
表面下数十メートルに及ぶ施工となる。
この処理における地盤改良材と被改良土との撹
拌、混合は、地盤改良材あるいは改良材スラリー
吐出口を備えた回転翼を回転させながらおこな
う。この場合連続した改良土層を得るために、す
でに改良した部分と未改良部分の境界部分につい
て回転翼を回転させながら移動している。
しかるに従来は、この深層混合処理に用いる地
盤改良材として初期強度の大きい普通ポルトラン
ドセメントや高炉セメントを使用している。従つ
てこの地盤改良材を撹拌、混合した個所が短時間
で硬化し、硬化した土壌の一部を回転翼が移動す
ることとなる。このため回転翼の撹拌はもとよ
り、回転翼がシヤフトごと回収不能となる事態も
起こり得る。また回転翼そのものの貫入が困難あ
るいは不可能になる。
このようなことから従来の深層混合処理は、既
改良部分の強度が増加しないうちに次々と改良を
行ない、昼夜兼行の工事を余儀なくされるケース
が多い。
更に従来の地盤改良材を用いると、改良部分が
早期に高い硬化強度をもつため、改良土に銅管ぐ
い等のパイルを打ち込む工法をとることができな
い。このため、例えば改良土の上にケーソンを取
付けるというような工法しかとり得ず、改良後の
工法が著しく制限される問題がある。
本発明はこの問題を解決すべくなされたもの
で、その目的とするところは、初期強度を低く保
ち、しかも長期的には強度増加の保障できる深層
混合処理用地盤改良材を得んとするものである。
すなわち本発明は、ガラス質高炉スラグ粉末40
〜80重量%と、中庸熱ポルトランドセメント20〜
60重量%とからなる深層混合処理用地盤改良材で
ある。
以下本発明を詳細に説明する。
本発明は、ガラス質高炉スラグ粉末を主成分と
し、これに中庸熱ポルトランドセメントを配合し
たものである。ガラス質高炉スラグ粉末は、従来
の地盤改良材に使用するもので、石灰等によるア
ルカリ性刺激により水和硬化するものである。こ
のガラス質高炉スラグ粉末として水砕スラグ等が
あり、水砕スラグの組成の一例を挙げれば下記第
1表の如くである。
The present invention relates to a ground improvement material used in deep mixing treatment. In general, deep mixing treatment is carried out by injecting a soil improvement material into the seabed soil to be improved from a special ground improvement vessel and stirring it at the same time, and the work is carried out several tens of meters below the seabed surface. In this process, the soil improvement material and soil to be improved are stirred and mixed while rotating a rotary blade equipped with a soil improvement material or improvement material slurry discharge port. In this case, in order to obtain a continuous layer of improved soil, the rotary blade is rotated while moving along the boundary between the improved and unimproved areas. However, conventionally, ordinary Portland cement or blast furnace cement, which has a high initial strength, has been used as a ground improvement material for this deep mixing treatment. Therefore, the area where the ground improvement material is stirred and mixed will harden in a short time, and the rotor will move a portion of the hardened soil. For this reason, not only the rotor blades are agitated, but also a situation may occur in which the rotor blades cannot be recovered together with the shaft. It also becomes difficult or impossible for the rotor itself to penetrate. For this reason, in conventional deep mixing treatment, improvements are often made one after another before the strength of the already improved parts increases, forcing construction to be carried out day and night. Furthermore, when conventional ground improvement materials are used, the improved portion quickly hardens and hardens, making it impossible to use a method of driving piles such as copper pipe piles into the improved soil. For this reason, the only possible construction method is, for example, installing a caisson on top of the improved soil, and there is a problem in that the construction methods after the improvement are severely limited. The present invention was made to solve this problem, and its purpose is to provide a ground improvement material for deep mixing treatment that can maintain a low initial strength and also guarantee an increase in strength over the long term. It is. That is, the present invention provides vitreous blast furnace slag powder 40
~80% by weight and moderate heat Portland cement ~20~
This is a ground improvement material for deep mixing treatment consisting of 60% by weight. The present invention will be explained in detail below. The present invention has vitreous blast furnace slag powder as its main component, and moderate heat Portland cement is blended therein. Glassy blast furnace slag powder is used as a conventional ground improvement material, and is hydrated and hardened by alkaline stimulation from lime or the like. Examples of the glassy blast furnace slag powder include granulated slag, and an example of the composition of granulated slag is shown in Table 1 below.
【表】
ガラス質高炉スラグの配合量は、被改良土の土
質、旋工方法等により適宜選定されるが、その範
囲は40〜80重量%である。これは40重量%より少
ないと初期強度が大きすぎ、又80重量%を越える
と長期材令における必要強度を得ることができな
いためである。ガラス質高炉スラグは、粉末度
(プレーン比表面積)1500〜6000cm2/gの範囲で、
土質又は旋工方法により選択する。例えば粗いス
ラグを用いれば、改良土の強度が高くなるのに期
間がかかり、細いスラグを用いればこの逆とな
る。またガラス質高炉スラグは、これと混合する
中庸熱ポルトランドセメントが水分との接触を忌
避するので、通常乾式粉砕した乾燥粉末を用い
る。ただし地盤改良材をスラリー状で使用する場
合、ガラス質高炉スラグは必ずしも乾燥粉末であ
る必要はなく、湿式粉砕されたものでもよい。こ
の場合乾燥工程が不要となる。例えば高炉水砕ス
ラグ粒は、高炉スラグを水で破砕急冷することに
よつて生成され、強制脱水したものでも10〜15重
量%程度の水を含有しており、これを乾燥するた
め、たとえば水砕スラグ1トン当り約17の重油
が必要である。また湿式粉砕のコストは、乾式粉
砕コストより著しく小さいうえに乾式粉砕のよう
に防塵対策をとる必要がなくなる。
本発明は、上述したガラス質高炉スラグ粉末に
中庸熱ポルトランドセメントを配合する。これを
配合するのは、改良土の初期強度を低くし、かつ
長期強度を高くするためである。中庸熱ポルトラ
ンドセメントがこのような作用を有することは、
本発明者らの実験により明らかとなつたもので、
その作用機構は明らかではない。本発明者らの推
定によれば、中庸熱ポルトランドセメント自身の
水和硬化組織の形成、その硬化組織と土壌粒子
(シルト、粘土など)との相互作用、中庸熱ポル
トランドセメントの水和により生成した石灰によ
る土壌粒子の凝集・団粒化組織の形成、同石灰の
アルカリ性刺激作用によるスラグ粒子の水和硬化
組織の形成、同石灰の作用による土壌粒子(特に
粘土)のポゾラン反応による硬化組織の形成など
により改良土の硬化作用が起こるが、本発明によ
れば、これらの硬化作用の総合的効果により改良
土の初期強度発現を抑えることができると考えら
れる。
すなわち中庸熱ポルトランドセメントは、普通
ポルトランドセメントと比較して、3CaO・SiO2
と3CaO・Al2O3とが顕著に少なく、2CaO・SiO2
が多い。化合物量の一例を下記第2表に示す。[Table] The blending amount of vitreous blast furnace slag is appropriately selected depending on the quality of the soil to be improved, the turning method, etc., and the range is 40 to 80% by weight. This is because if it is less than 40% by weight, the initial strength will be too high, and if it exceeds 80% by weight, it will not be possible to obtain the required strength in the long term. Glassy blast furnace slag has a fineness (plain specific surface area) in the range of 1500 to 6000 cm 2 /g,
Select depending on soil quality or turning method. For example, if a coarse slag is used, it will take a long time for the strength of the improved soil to increase; if a thin slag is used, the opposite will occur. Further, as the vitreous blast furnace slag, the medium-heat Portland cement mixed therewith avoids contact with moisture, so dry powder obtained by dry grinding is usually used. However, when the ground improvement material is used in the form of a slurry, the vitreous blast furnace slag does not necessarily need to be a dry powder, and may be wet-pulverized. In this case, a drying step is not necessary. For example, granulated blast furnace slag grains are produced by crushing and rapidly cooling blast furnace slag with water, and even those that have been forcibly dehydrated contain about 10 to 15% water by weight. Approximately 17 parts of heavy oil is required per ton of crushed slag. Furthermore, the cost of wet pulverization is significantly lower than that of dry pulverization, and unlike dry pulverization, there is no need to take dust-proof measures. In the present invention, moderate heat Portland cement is blended with the above-mentioned vitreous blast furnace slag powder. The purpose of blending this is to lower the initial strength and increase the long-term strength of the improved soil. The fact that moderate heat Portland cement has such an effect is that
This was revealed through experiments by the inventors,
Its mechanism of action is not clear. According to the inventors' estimation, the formation of a hydration-hardened structure of moderate-heat Portland cement itself, the interaction of that hardened structure with soil particles (silt, clay, etc.), and the hydration of moderate-heat Portland cement produced Formation of agglomerated and agglomerated structures in soil particles due to lime; Formation of hydrated and hardened structures in slag particles due to the alkaline stimulating action of lime; Formation of hardened structures due to pozzolanic reaction of soil particles (especially clay) due to the action of lime. Although the hardening effect of the improved soil occurs due to such factors, it is thought that according to the present invention, the initial strength development of the improved soil can be suppressed due to the comprehensive effect of these hardening effects. In other words, moderate heat Portland cement has a higher concentration of 3CaO・SiO 2 than ordinary Portland cement.
and 3CaO・Al 2 O 3 are significantly less, and 2CaO・SiO 2
There are many. An example of the amount of the compound is shown in Table 2 below.
【表】
この中庸熱ポルトランドセメントの特徴は、次
のとおりである。水和熱が普通ポルトランドセメ
ントより低いのでマスコンクリート用に適してい
る。早期強さは普通ポルトランドセメントより低
いが、長期強さは普通ポルトランドセメントと同
じくらいか、ややまさる。乾燥収縮が小さい。化
学抵抗性が大きいなどである。
中庸熱ポルトランドセメントの水和熱を、普通
ポルトランドセメントと比較して示すと下記第3
表のようになる。[Table] The characteristics of this moderate heat Portland cement are as follows. It is suitable for mass concrete because its heat of hydration is lower than ordinary Portland cement. Its early strength is lower than ordinary Portland cement, but its long-term strength is equal to or slightly better than ordinary Portland cement. Low drying shrinkage. It has high chemical resistance. The heat of hydration of medium-heat Portland cement compared with ordinary Portland cement is shown in the third table below.
It will look like a table.
【表】
これらの発熱による熱量は、改良土内部に蓄積
される。
また両セメントの主要構成鉱物であるC3Sと
C2Sの水和反応により生成する石灰量を比較する
と
2C3S+6H2O→C3S2H3+3Ca(OH)2
2C2S+4H2O→C3S2H3+Ca(OH)2
ここでC3S2H3は3CaO・2SiO2・3H2Oを表わ
す。この反応式から、1モルのC3Sは1モルの
C2Sの3倍量のCa(OH)2を生成することがわか
る。
すなわちC3Sを少なく含み、C2Sを多く含む中
庸熱ポルトランドセメントの水和により生成する
石灰量は、普通ポルトランドセメントのそれより
少ない。従つてガラス質高炉スラグの共存下で深
層混合処理用地盤改良材として用いる場合、水和
熱が低く、又水和により生成する石灰量が少ない
ことから、改良土の初期強度発現を抑えることが
できると考えられる。
このような性質を有する中庸熱ポルトランドセ
メントは、20〜60重量%の配合量とする。これ
は、20重量%未満では改良土の硬化強度が十分で
はなく、又60重量%を越えると初期強度が高くな
りすぎるためである。
このようにガラス質高炉スラグ粉末と中庸熱ポ
ルトランドセメントとを配合した地盤改良材は、
被改良土の土質、旋工方法により、被改良土に添
加する量が異なるが、例えば以下の基準にもとづ
いて添加する。材令1日で5Kgf/cm2以下、望ま
しくは材令3日で5Kgf/cm2以下であり、材令91
日で20Kgf/cm2以上、望ましくは50Kgf/cm2以上
となるように添加量を定める。具体例を挙げれ
ば、被改良土1m3に対し例えば160Kg〜200Kg添加
する。
次に本発明の実施例につき説明する。
ガラス質高炉スラグとして、ボールミルで粉末
度ブレーン比面積3600cm2/gに粉砕した高炉水砕
スラグを用い、中庸熱ポルトランドセメントは市
販品を用いた。
これらを第4表に示す割合に配合して、本発明
に係る地盤改良材(No.1〜No.3)及び配合割合
が本発明と異なる地盤改良材(No.記4、No.5)
を試作した。この場合改良材スラリーの水/改良
材重量比は、市販の普通ポルトランドセメントの
W/C(水/セメント)比が0.6であるときのスラ
リー粘度と同一になるように決定した。[Table] The amount of heat generated by this heat is accumulated inside the improved soil. In addition, C 3 S, which is the main constituent mineral of both cements,
Comparing the amount of lime produced by the hydration reaction of C 2 S, 2C 3 S + 6H 2 O → C 3 S 2 H 3 + 3Ca (OH) 2 2C 2 S + 4H 2 O → C 3 S 2 H 3 + Ca (OH) 2Here C 3 S 2 H 3 represents 3CaO.2SiO 2.3H 2 O. From this reaction equation, 1 mol of C 3 S is 1 mol of C 3 S.
It can be seen that three times as much Ca(OH) 2 as C 2 S is produced. That is, the amount of lime produced by hydration of moderate heat Portland cement containing less C 3 S and more C 2 S is less than that of ordinary Portland cement. Therefore, when used as a ground improvement material for deep mixing treatment in the coexistence of glassy blast furnace slag, the initial strength development of the improved soil can be suppressed because the heat of hydration is low and the amount of lime produced by hydration is small. It seems possible. Moderate heat Portland cement having such properties is blended in an amount of 20 to 60% by weight. This is because if it is less than 20% by weight, the cured strength of the improved soil will not be sufficient, and if it exceeds 60% by weight, the initial strength will be too high. In this way, a ground improvement material containing vitreous blast furnace slag powder and moderate heat Portland cement is
The amount added to the improved soil varies depending on the soil quality of the improved soil and the turning method, but it is added based on the following criteria, for example. 5Kgf/ cm2 or less in 1 day of wood age, preferably 5Kgf/ cm2 or less in 3 days of wood age, and 91
The amount added is determined so that the amount is 20 Kgf/cm 2 or more, preferably 50 Kgf/cm 2 or more per day. To give a specific example, for example, 160 kg to 200 kg is added to 1 m 3 of soil to be improved. Next, examples of the present invention will be described. As the vitreous blast furnace slag, granulated blast furnace slag pulverized in a ball mill to a particle size Blaine specific area of 3600 cm 2 /g was used, and as the moderate heat Portland cement, a commercially available product was used. These are mixed in the proportions shown in Table 4 to form soil improvement materials according to the present invention (No. 1 to No. 3) and soil improvement materials (No. 4, No. 5) with different mixing proportions from the present invention.
We made a prototype. In this case, the water/improver weight ratio of the improver slurry was determined to be the same as the slurry viscosity when the W/C (water/cement) ratio of commercially available ordinary Portland cement is 0.6.
【表】
これら改良材(No.1〜No.5)を第5表に示す
物性値の被改良用試料土(東京湾内横浜港粘性
土)1m3に対して乾燥重量(スラグ粉末と中庸熱
ポルトランドセメントの重量の和)で160Kg加え
て混合撹拌し、直径5cm、高さ10cmの円柱型モー
ルドに3層に分けて充填し、供試体を成形した。[Table] Dry weight (slag powder and moderate heat 160 kg of Portland cement (total weight of Portland cement) was added, mixed and stirred, and filled in three layers into a cylindrical mold with a diameter of 5 cm and a height of 10 cm to form a specimen.
【表】
このようにして得られた供試体をポリエチレン
シートで封緘し、所定の強度試験材令まで20℃、
相対湿度85%以上の恒温恒湿器内にて養生したの
ち、一軸圧縮強度を測定した。その結果を第6表
に示す。[Table] The specimen thus obtained was sealed with a polyethylene sheet and kept at 20°C until the specified strength test material rating.
After curing in a constant temperature and humidity chamber with a relative humidity of 85% or higher, the unconfined compressive strength was measured. The results are shown in Table 6.
【表】
上表から本発明に係る地盤改良材によれば、改
良土の強度発現特性を材令1日で5Kgf/cm2以
下、材令91日で20Kgf/cm2以上とし得る。また材
令3日で5Kgf/cm2以下、材令91日で、50Kgf/
cm2以上という非常に満足すべき結果も得られるこ
とがわかつた。
以上の如く本発明によれば、初期強度を低く保
つので、接合不良や、旋工機械の損耗、更には昼
夜兼行作業等の問題を解決することができる。ま
た改良土層へ鋼管パイル等を打ち込むことがで
き、種々の工法を展開できるなど顕著な効果を奏
する。[Table] According to the above table, according to the soil improvement material according to the present invention, the strength development characteristics of the improved soil can be 5 Kgf/cm 2 or less at 1 day of age and 20 Kgf/cm 2 or more at 91 days. Also, less than 5Kgf/cm2 at 3 days old, 50Kgf/cm2 at 91 days old.
It was found that very satisfactory results of more than cm 2 were also obtained. As described above, according to the present invention, since the initial strength is kept low, it is possible to solve problems such as poor joining, wear and tear of the turning machine, and furthermore, work performed day and night. In addition, steel pipe piles and the like can be driven into the improved soil layer, making it possible to develop various construction methods and other remarkable effects.
Claims (1)
庸熱ポルトランドセメント20〜60重量%とからな
る深層混合処理用地盤改良材。1. A ground improvement material for deep mixing treatment consisting of 40-80% by weight of vitreous blast furnace slag powder and 20-60% by weight of moderate heat Portland cement.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57200369A JPS5991190A (en) | 1982-11-17 | 1982-11-17 | Ground conditioner to be mixed in depths |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57200369A JPS5991190A (en) | 1982-11-17 | 1982-11-17 | Ground conditioner to be mixed in depths |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5991190A JPS5991190A (en) | 1984-05-25 |
| JPS636593B2 true JPS636593B2 (en) | 1988-02-10 |
Family
ID=16423156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57200369A Granted JPS5991190A (en) | 1982-11-17 | 1982-11-17 | Ground conditioner to be mixed in depths |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5991190A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61211394A (en) * | 1985-03-18 | 1986-09-19 | Mitsubishi Mining & Cement Co Ltd | Delayed curing material |
| JPS61247782A (en) * | 1985-04-26 | 1986-11-05 | Ube Ind Ltd | Solidifying material for deep seat mixing treatment |
| JPS6262886A (en) * | 1985-09-13 | 1987-03-19 | Nippon Kokan Kk <Nkk> | Ground improvement material |
| JPS6399289A (en) * | 1986-05-22 | 1988-04-30 | Mitsubishi Mining & Cement Co Ltd | Delayed hardening soil stabilizer |
| FR2615183B1 (en) * | 1987-05-14 | 1992-07-17 | Gagneraud Pere Fils Entreprise | COMPOUND CEMENT, USABLE IN PARTICULAR IN WELLS |
| IT1397187B1 (en) * | 2009-11-30 | 2013-01-04 | Italcementi Spa | HYDRAULIC BINDER INCLUDING A LARGE FORCID PASTA. |
| JP6747034B2 (en) * | 2016-04-22 | 2020-08-26 | 宇部興産株式会社 | Cement composition and method for producing the same |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56125257A (en) * | 1980-03-06 | 1981-10-01 | Denki Kagaku Kogyo Kk | Cement for grout |
| JPS57158420A (en) * | 1981-03-26 | 1982-09-30 | Nippon Cement Co Ltd | Mixing and treating method for soft ground at deep stratum |
-
1982
- 1982-11-17 JP JP57200369A patent/JPS5991190A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5991190A (en) | 1984-05-25 |
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