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JPH0135106B2 - - Google Patents
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JPH0135106B2 - - Google Patents

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Publication number
JPH0135106B2
JPH0135106B2 JP56008839A JP883981A JPH0135106B2 JP H0135106 B2 JPH0135106 B2 JP H0135106B2 JP 56008839 A JP56008839 A JP 56008839A JP 883981 A JP883981 A JP 883981A JP H0135106 B2 JPH0135106 B2 JP H0135106B2
Authority
JP
Japan
Prior art keywords
strength
fibers
nonwoven fabric
water permeability
sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP56008839A
Other languages
Japanese (ja)
Other versions
JPS57128249A (en
Inventor
Setsuo Sanoma
Hirobumi Sugita
Mitsuo Nakamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toa Boshoku Co Ltd
Original Assignee
Toa Boshoku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toa Boshoku Co Ltd filed Critical Toa Boshoku Co Ltd
Priority to JP56008839A priority Critical patent/JPS57128249A/en
Publication of JPS57128249A publication Critical patent/JPS57128249A/en
Publication of JPH0135106B2 publication Critical patent/JPH0135106B2/ja
Granted legal-status Critical Current

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Landscapes

  • Investigation Of Foundation Soil And Reinforcement Of Foundation Soil By Compacting Or Drainage (AREA)
  • Revetment (AREA)
  • Nonwoven Fabrics (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は土木資材の一つである多数のコンクリ
ートブロツクをシートに取付けた所謂ブロツクマ
ツトのシートとして使用する土木資材不織布に関
するものである。 上記ブロツクマツトは近時合成繊維等よりなる
フイルター性を持たせたシートに多数のコンクリ
ートブロツクを取付けたものがその施工性や土壌
の表面浸食に対する耐抗性が優れているとして新
しい治水、治山、道路等の土木資材に多用される
ようになつてきた。しかしながらかかる治水、治
山等の土木資材として要求される諸性能は極めて
厳しく特殊のものであるから前記ブロツクマツト
が施工性、耐浸食性に優れているとしても他の性
能から見て必ずしも満足すべきものではなかつ
た。即ち、ブロツクマツトは1枚のシートにコン
クリートブロツクをできるだけ多数取付ける程施
工上有利であるから、その目方は極めて大となつ
ていた。即ち、例えばシートは通常長さ7m×幅
2.1m面積14.7m2の長尺物にしてこれに縦横夫々
0.2m、高さ0.1mの立方体ブロツクを240個取付
けている。コンクリートブロツクは1個約5.6Kg
であるからブロツクの総重量は1344Kgと極めて大
きい。そのためにシートはこの重いブロツク重量
に十分に耐えるものでなければならず、更にブロ
ツクマツトは施工時粗雑な取扱い及び過酷な作業
を受けるものであるからこれらの点からシートが
要求される強力は極めて大であるがこの点従来の
ブロツクマツトは未だ十分ではなかつた。 即ち、この点について例えばシートが織物の場
合、強力を増大するためには経糸本数を増やす必
要があるがそのために経糸整理が困難となつて製
織作業を低下し、コスト高となつて到底資材製品
として実用化するのが困難であるという結果にな
つていた。また、この強力については不織布のシ
ートについても問題があつた。その他シートに要
求される性能として透水性があるが織物シートの
場合は強力を持たせようとすると織物密度が大と
なつて良好な透水性は得られず、不織布にしても
ニードルパンチングの針刺通密度を細かくすると
或る程度強力は増大するが透水性は低下してい
た。いずれにしても従来のシートに土木資材とし
て要求される強力と透水性を両立させることは困
難であつた。 本発明は以上の点に鑑み、これを改良、除去し
たものであつて、特にブロツクマツトのシートと
して前記織物シートよりも問題点を有利に解決す
ることができる不織布を使用し、これにより経方
向に強大な強力を持ち、而も良好な透水性を具有
した土木資材不織布を提供することを目的とする
ものである。 即ち、本発明はブロツクマツト用不織布の構成
繊維としてポリプロピレン短繊維1とポリエステ
ル長繊維2とを重量比1/2=0.5〜4.0の割合と
し、かつ、上記ポリエステル長繊維2を3000d以
上の太糸状として経方向に配列して経方向の強力
を300Kg/5cm以上とし、かつ、透水係数を1×
10-1cm/sec以上に保持するようニードルパンチン
グを施したものであつて、これにより強力、透水
性を所望範囲に具有させるのみならずこの短繊維
による表面の毛羽立ちによつてコンクリートブロ
ツクの接着を容易で而も強固になし得るようにし
たものである。 以下本発明の構成を一部図面を参照して詳述す
る。 本発明は主としてポリプロピレン短繊維を使用
するがその理由はポリプロピレン系繊維は強伸度
において巾広い値を有し、不織布用繊維としては
最適である上に、虫やかびに対する抵抗力、土壌
の酸性度、アルカリ度に対する抵抗力に優れ、製
品の性能を長期に亘り失わない所謂耐久性、耐用
性に富んだ繊維でかつ経済的にも有利な繊維であ
るからである。而もこれが短繊維であるから不織
布表面に形成される毛羽はコンクリートブロツク
の半固形状態に於いてブロツク内部に侵入してア
ンカーとしての作用を容易に強固にすることが他
の合成繊維よりも有効であることによる。また、
長繊維のポリエステル系繊維を使用するのはこの
繊維は単繊維当りの強力が強く、資材用として強
力を増大させたものがつくり易い。そしてまた骨
材として耐候性、セメントに対する対アルカリ性
が強いことによる。 かかるポリプロピレン短繊維1を主とし、これ
にポリエステル長繊維2を経方向に配列して重量
比0.5〜4.0の割合に混合し、透水係数が1×10-
cm/sec以上に保持するニードルパンチングを施
し、第1図に示すような不織布aとするのであ
る。不織布aは従来のシートと同等の大きさにつ
くる。なお、ポリエステル長繊維2は図示の如く
太糸として使用する。この不織布aをシートとし
てこれに第2図及び第3図に示すように多数のコ
ンクリートブロツク3を短繊維1の毛羽1′のア
ンカー作用によつて固着し、ブロツクマツトbを
得る。 上記ポリプロピレン短繊維とポリエステル長繊
維との重量比を0.5乃至4.0とするのは糸状で経方
向に配列するポリエステル長繊維の本数や強力等
から判断して工業的に容易に加工することができ
る最適な範囲であることによる。この0.5乃至4.0
の範囲外になると強力が著しく弱くなり実用的価
値が全然無くなつたり、逆に長繊維の本数が多く
て実際の加工に問題が発生したり、また透水性を
著しく減少させてしまう。 また、経方向の強力を300Kg/5cm以上に限定
した理由は、コンクリートブロツクを不織布上に
固着して移動、運搬、敷設するときに、その重量
に耐えるには300Kg/5cm以上の強力があること
が施工上是非とも必要であることが判明したこと
による。この強力以下になると不織布シートは破
れたりしてコンクリートブロツクの落下等の事故
につながる危険を伴う。この300Kg/5cm以上の
強力はポリエステル長繊維を経方向に太糸条とし
て配列し、ポリプロピレン短繊維1とポリエステ
ル長繊維2との重量比1/2を0.5〜4.0とするこ
とにより確実に達せられる。 更に、本発明において透水性を1×10-1cm/sec
以上にしたことは透水性を良くして吸出防止効果
を向上し、被覆土壌中での水圧の上昇を防ぐため
であり、前記1×10-1cm/sec以上の透水性は内圧
上昇による被覆面の押出し破壊等のトラブル発生
の惧れをなくすことができる。 また、シートはコンクリートブロツク構成のセ
メントに対して接着性の優れていることが望まれ
るが、この接着性を満足させるためには、ニード
ルパンチングの条件、特にニードルの刺通密度を
透水性等との関連を見て決めることが重要であ
る。即ち、過度に刺通密度を密にすることは繊維
の絡みを増して透水性能を低下し、逆に刺通密度
が少なすぎると短繊維と長繊維との一体化が無く
なり、製品として好ましくないという問題が発生
する。従つて良好な透水性能を具有させるために
は必然的に刺通条件を或る範囲内に限定する必要
がある。本発明は良好な透水性を発揮するために
必要な前記1×10-1cm/sec以上の透水性能を持た
せるようなニードルパンチングを施すのである。 上記透水性を与えるための刺通密度は、またコ
ンクリートブロツクにポリプロピレン短繊維の毛
羽を刺入して毛羽をアンカー作用させてブロツク
を不織布に固着させるのに有効なものであつて、
ブロツクの固着を強固にする。なお、刺通密度が
大で毛羽が多いということは必ずしも接着力を大
きくするとは限らないという実験結果がでてお
り、むしろ少ない毛羽にしてこれをセメント中に
深く刺入する方がより好ましいという事実にもと
づき、透水性を1×10-1cm/sec以上にすることを
考慮して刺通密度を決定する。なお適切な毛羽密
度、長さを得るために場合によつては起毛を施す
こともある。 以下実施例にて本発明をさらに説明する。ポリ
プロピレン短繊維を4d×94mm、強度4.1g/d、伸度
75%とし、ポリエステル長繊維を、1000d(4d×
250本)、強度8g/dのものを3本撚糸した1000d
×3本=3000dの糸とし、両者を構成繊維として
不織布を得た。この場合、長繊維の供給は張力が
均一になるようによく調整されたクリールスタン
ドを設置してラチスコンベア上に振込み、その上
に短繊維ウエブを積層し、長繊維糸を経方向に比
較的多く配列し、ニードルパンチングを施した。
ニードルパングングの条件としては、 第1ロツカーでは刺通密度100本/cm2、刺通深
さ18mm、刺通方向ウエブの上から、 第2ロツカーでは刺通密度70本/cm2、刺通深さ
13mm、刺通方向ウエブの下からとした。 以下上記条件を基本とした複数の実施例の性能
を次表に示す。
The present invention relates to a civil engineering material nonwoven fabric used as a sheet for a so-called block mat, in which a large number of concrete blocks, which are one type of civil engineering material, are attached to the sheet. The above-mentioned block mats are made by attaching a large number of concrete blocks to a sheet made of synthetic fibers, etc. that has a filtering property, and are considered to have excellent workability and resistance to soil surface erosion. It has come to be widely used in civil engineering materials such as However, the various performances required for civil engineering materials such as flood control and mountain control are extremely strict and special, so even if the block mat has excellent workability and erosion resistance, it is not necessarily satisfactory in terms of other performances. Nakatsuta. That is, since block mats are more advantageous in terms of construction, the more concrete blocks can be attached to one sheet, the more concrete blocks can be attached to one sheet. That is, for example, a sheet is usually 7m long x wide.
Make it a long object with an area of 2.1m and 14.7m2
240 cubic blocks measuring 0.2m and 0.1m in height are installed. Each concrete block weighs approximately 5.6Kg.
Therefore, the total weight of the block is extremely large at 1344Kg. Therefore, the sheet must be able to withstand the weight of this heavy block, and since block mats are subject to rough handling and harsh work during construction, the strength required of the sheet is extremely high. However, in this respect, conventional block mats were still not sufficient. In this regard, for example, if the sheet is a woven fabric, it is necessary to increase the number of warp threads in order to increase the strength, but this makes it difficult to organize the warp threads, slowing down the weaving process, and increasing costs, making it impossible to make a material product. The result was that it was difficult to put it into practical use. In addition, there was also a problem with nonwoven fabric sheets regarding this strength. Another performance required of sheets is water permeability, but in the case of woven sheets, if you try to make them strong, the density of the fabric increases and good water permeability cannot be obtained, and even if you use non-woven sheets, needle punching When the throughput density was made finer, the strength increased to some extent, but the water permeability decreased. In any case, it has been difficult for conventional sheets to have both the strength and water permeability required for civil engineering materials. In view of the above-mentioned points, the present invention improves and eliminates the above problems, and uses a non-woven fabric that can solve the problems more advantageously than the above-mentioned woven sheet as a block mat sheet. The object of the present invention is to provide a nonwoven fabric for civil engineering materials that is extremely strong and has good water permeability. That is, the present invention uses polypropylene short fibers 1 and polyester long fibers 2 as constituent fibers of the nonwoven fabric for block mats in a weight ratio of 1/2 = 0.5 to 4.0, and the polyester long fibers 2 are in the form of thick threads of 3000 d or more. Arranged in the longitudinal direction, the strength in the longitudinal direction is 300Kg/5cm or more, and the permeability coefficient is 1×
Needle-punched to maintain a strength of 10 -1 cm/sec or more, this not only provides strength and water permeability within the desired range, but also allows for the adhesion of concrete blocks by the fluff on the surface of these short fibers. This makes it possible to do this easily and firmly. The configuration of the present invention will be explained in detail below with reference to some drawings. The present invention mainly uses polypropylene staple fibers because polypropylene fibers have a wide range of strength and elongation values, making them optimal as fibers for nonwoven fabrics, as well as being resistant to insects and mold, and resistant to soil acidity. This is because it is a highly durable and long-lasting fiber that has excellent resistance to alkalinity and alkalinity, and does not lose product performance over a long period of time, and is also economically advantageous. However, since these are short fibers, the fluff that forms on the surface of the nonwoven fabric can penetrate into the inside of the concrete block in its semi-solid state, making it easier to strengthen its function as an anchor than other synthetic fibers. By being. Also,
The reason why long-fiber polyester fibers are used is that this fiber has high strength per single fiber, and it is easy to make products with increased strength for use as materials. Furthermore, it is weather resistant as an aggregate and has strong alkali resistance against cement. The polypropylene short fibers 1 are mainly used, and the polyester long fibers 2 are arranged in the warp direction and mixed at a weight ratio of 0.5 to 4.0, and the water permeability coefficient is 1×10
Needle punching is performed to maintain a pressure of cm/sec or more to form a nonwoven fabric a as shown in FIG. The nonwoven fabric a is made to have the same size as a conventional sheet. Note that the polyester long fibers 2 are used as thick yarns as shown in the figure. This nonwoven fabric a is used as a sheet, and a large number of concrete blocks 3 are fixed thereto by the anchoring action of the fluff 1' of the short fibers 1, as shown in FIGS. 2 and 3, to obtain a block mat b. Setting the weight ratio of polypropylene short fibers and polyester long fibers to 0.5 to 4.0 is the optimum method for easy industrial processing, judging from the number and strength of the polyester long fibers arranged in the warp direction. This is due to the fact that it is within a certain range. This 0.5 to 4.0
If it is outside the range, the strength will be significantly weakened and there will be no practical value at all, or on the contrary, the number of long fibers will be too large, causing problems in actual processing, or the water permeability will be significantly reduced. In addition, the reason why we limited the strength in the longitudinal direction to 300 kg/5 cm or more is that we need a strength of 300 kg/5 cm or more to withstand the weight of concrete blocks fixed on nonwoven fabric and moved, transported, and laid. This is because it was found to be absolutely necessary for construction purposes. If the strength is lower than this, the nonwoven fabric sheet may tear and there is a risk of accidents such as concrete blocks falling. This strength of 300 kg/5 cm or more can be achieved reliably by arranging polyester long fibers as thick threads in the warp direction and setting the weight ratio of polypropylene short fibers 1 to polyester long fibers 2 to 1/2 from 0.5 to 4.0. . Furthermore, in the present invention, the water permeability is set to 1×10 -1 cm/sec.
This is done to improve water permeability, improve the suction prevention effect, and prevent an increase in water pressure in the covered soil. It is possible to eliminate the possibility of troubles such as extrusion breakage of the surface. In addition, it is desired that the sheet has excellent adhesion to the cement of the concrete block structure, but in order to satisfy this adhesion, the needle punching conditions, especially the needle penetration density, must be adjusted according to water permeability, etc. It is important to decide based on the relationship between In other words, if the piercing density is too high, the fibers will become entangled and the water permeability will be reduced. Conversely, if the piercing density is too low, the short fibers and long fibers will not be integrated, which is not desirable as a product. This problem arises. Therefore, in order to have good water permeability, it is necessary to limit the piercing conditions within a certain range. In the present invention, needle punching is performed to provide a water permeability of 1×10 -1 cm/sec or more, which is necessary for exhibiting good water permeability. The above-mentioned piercing density for imparting water permeability is also effective for piercing the fluff of short polypropylene fibers into the concrete block and making the fluff act as an anchor to fix the block to the nonwoven fabric.
Strengthen the block's adhesion. Experiments have shown that having a high penetration density and a lot of fluff does not necessarily increase adhesive strength; rather, it is preferable to have less fluff and penetrate deeper into the cement. Based on the facts, the penetration density is determined taking into consideration the water permeability of 1 x 10 -1 cm/sec or more. In some cases, napping may be applied to obtain appropriate fluff density and length. The present invention will be further explained below with reference to Examples. Polypropylene short fibers 4d x 94mm, strength 4.1g/d, elongation
75% polyester long fiber, 1000d (4d×
250 strands), 1000 d made of 3 twisted yarns with a strength of 8 g/d
x3 = 3000 d of thread, and a nonwoven fabric was obtained using both as constituent fibers. In this case, the long fibers are supplied by installing a well-adjusted creel stand so that the tension is uniform, transferring them onto the lattice conveyor, stacking the short fiber web on top of the creel stand, and then stacking the short fiber web on top of it. Many were arranged and needle punched.
The conditions for needle punching are as follows: For the first needle, the needle penetration density is 100 needles/cm 2 , the penetration depth is 18 mm, and the penetration direction is from above the web, and for the second needle, the penetration density is 70 needles/cm 2 , and the penetration depth is 18 mm. depth
13mm, the piercing direction was from the bottom of the web. The following table shows the performance of a plurality of examples based on the above conditions.

【表】【table】

【表】 上記表にて示すように本発明のものは従来のも
のより強力において格段に優れ、而も適切な透水
性を有していた。そして各実施例の不織布をシー
トとしたブロツクマツトはコンクリートブロツク
の毛羽による固着が極めて強固であつた。 以上説明したように本発明は、長方形単位シー
トの一方の面に多数のコンクリートブロツクを碁
盤目状に固着させ、治山治水等の分野で土壌表面
の雨水等による流出及び浸食防止用として土壌表
面に所要枚数敷設固定される土木資材不織布であ
つて、ポリプロピレン短繊維1とポリエステル長
繊維2とを重量比1/2=0.5〜4.0の割合とし、
かつ、上記ポリエステル長繊維2を3000d以上の
太糸状として経方向に配列して経方向の強力を
300Kg/5cm以上とし、かつ、透水係数を1×
10-1cm/sec以上に保持するようにニードルパンチ
ングを施したから、次の如き作用効果がある。 (a) 目的地例えば、宅地法面、河川海浜護岸、川
床等への敷設時のレツカーやクレーン等による
取扱いにおいて、ポリエステル長繊維を太糸条
として経方向に配列してあることにより、シー
トの長辺を上記経方向とし、この長辺の両端を
持つて運搬される際、該シートの片方の面に固
着された多数のコンクリートブロツクの自重に
よる張力に十分耐えて裂断することを防止でき
る。 (b) 強伸度、耐虫害、耐菌、耐酸、耐アルカリ性
等のシート構成繊維の固有特性を活用して長期
間土壌表面を被覆保護させることができる。 (c) 透水性により敷設面への雨水の浸透を可能と
し、植物の生育を可能ならしめ、かつ、敷設面
から水のみ濾過透水させて外部へ排出させるこ
とができ、排水パイプの埋設を不要化できる。
[Table] As shown in the table above, the product of the present invention was significantly superior in strength to the conventional product, and also had appropriate water permeability. The block mats made of the nonwoven fabric sheets of each example were extremely firmly fixed by the fluff of the concrete blocks. As explained above, the present invention has a large number of concrete blocks fixed to one side of a rectangular unit sheet in a grid pattern, and is applied to the soil surface to prevent runoff and erosion caused by rainwater on the soil surface in fields such as mountain and flood control. A civil engineering material nonwoven fabric that is laid and fixed in the required number of sheets, with a weight ratio of 1 polypropylene short fiber and 2 polyester long fibers at a weight ratio of 1/2 = 0.5 to 4.0,
In addition, the polyester long fibers 2 are arranged in the warp direction in the form of thick threads of 3000 d or more to increase the strength in the warp direction.
300Kg/5cm or more, and the permeability coefficient is 1×
Since needle punching is performed to maintain the velocity at 10 -1 cm/sec or higher, the following effects are achieved. (a) Destination For example, when handling with a truck or crane when laying on residential slopes, river seashore seawalls, riverbeds, etc., the sheets are The long side is in the warp direction, and when the sheet is transported by holding both ends of the long side, it can sufficiently withstand the tension due to the weight of many concrete blocks fixed to one side of the sheet and prevent it from tearing. . (b) It is possible to cover and protect the soil surface for a long period of time by utilizing the inherent properties of the fibers that make up the sheet, such as strength and elongation, insect resistance, bacterial resistance, acid resistance, and alkali resistance. (c) Water permeability allows rainwater to penetrate into the installation surface, allowing plants to grow, and only water can be filtered through the installation surface and discharged to the outside, eliminating the need to bury drainage pipes. can be converted into

【図面の簡単な説明】[Brief explanation of drawings]

図面は本発明の実施例であつて、第1図はその
不織布断片の斜視図、第2図は本不織布をシート
としたブロツクマツトの一部の平面図、第3図は
そのブロツク固着状態を示す断面図である。 1…ポリプロピレン短繊維、2…ポリエステル
長繊維、3…コンクリートブロツク。
The drawings show examples of the present invention, in which Fig. 1 is a perspective view of a fragment of the nonwoven fabric, Fig. 2 is a plan view of a part of a block mat using the nonwoven fabric as a sheet, and Fig. 3 shows the state in which the block is fixed. FIG. 1...Polypropylene short fiber, 2...Polyester long fiber, 3...Concrete block.

Claims (1)

【特許請求の範囲】[Claims] 1 長方形単位シートの一方の面に多数のコンク
リートブロツクを碁盤目状に固着させ、治山治水
等の分野で土壌表面の雨水等による流出及び浸食
防止用として土壌表面に所要枚数敷設固定される
土木資材不織布であつて、ポリプロピレン短繊維
1とポリエステル長繊維2とを重量比1/2=
0.5〜4.0の割合とし、かつ、上記ポリエステル長
繊維2を3000d以上の太糸状として経方向に配列
して経方向の強力を300Kg×5cm以上とし、かつ、
透水係数を1×10-1cm/sec以上に保持するように
ニードルパンチングを施したことを特徴とする土
木資材不織布。
1. A civil engineering material in which a large number of concrete blocks are fixed in a grid pattern to one side of a rectangular unit sheet, and the required number of concrete blocks are laid and fixed on the soil surface to prevent runoff and erosion caused by rainwater, etc. on the soil surface in fields such as mountain and flood control. It is a nonwoven fabric, and the weight ratio of polypropylene short fiber 1 and polyester long fiber 2 is 1/2 =
The ratio is 0.5 to 4.0, and the polyester long fibers 2 are arranged in the warp direction as thick threads of 3000 d or more, so that the strength in the warp direction is 300 Kg × 5 cm or more, and
A civil engineering material nonwoven fabric characterized by being needle-punched so as to maintain a water permeability coefficient of 1×10 -1 cm/sec or more.
JP56008839A 1981-01-22 1981-01-22 Nonwoven fabric of engineering material Granted JPS57128249A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56008839A JPS57128249A (en) 1981-01-22 1981-01-22 Nonwoven fabric of engineering material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56008839A JPS57128249A (en) 1981-01-22 1981-01-22 Nonwoven fabric of engineering material

Publications (2)

Publication Number Publication Date
JPS57128249A JPS57128249A (en) 1982-08-09
JPH0135106B2 true JPH0135106B2 (en) 1989-07-24

Family

ID=11703942

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56008839A Granted JPS57128249A (en) 1981-01-22 1981-01-22 Nonwoven fabric of engineering material

Country Status (1)

Country Link
JP (1) JPS57128249A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4916625B2 (en) * 2001-06-25 2012-04-18 三菱樹脂株式会社 Nonwoven fabric for civil engineering materials

Also Published As

Publication number Publication date
JPS57128249A (en) 1982-08-09

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