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JPH0150482B2 - - Google Patents
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JPH0150482B2 - - Google Patents

Info

Publication number
JPH0150482B2
JPH0150482B2 JP6801383A JP6801383A JPH0150482B2 JP H0150482 B2 JPH0150482 B2 JP H0150482B2 JP 6801383 A JP6801383 A JP 6801383A JP 6801383 A JP6801383 A JP 6801383A JP H0150482 B2 JPH0150482 B2 JP H0150482B2
Authority
JP
Japan
Prior art keywords
rolling
web
rolling mill
steel
slit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP6801383A
Other languages
Japanese (ja)
Other versions
JPS59193702A (en
Inventor
Samon Yanagimoto
Takeshi Miki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP6801383A priority Critical patent/JPS59193702A/en
Publication of JPS59193702A publication Critical patent/JPS59193702A/en
Publication of JPH0150482B2 publication Critical patent/JPH0150482B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/08Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling structural sections, i.e. work of special cross-section, e.g. angle steel
    • B21B1/088H- or I-sections
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/08Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling structural sections, i.e. work of special cross-section, e.g. angle steel
    • B21B1/0815Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling structural sections, i.e. work of special cross-section, e.g. angle steel from flat-rolled products, e.g. by longitudinal shearing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/08Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling structural sections, i.e. work of special cross-section, e.g. angle steel
    • B21B2001/081Roughening or texturing surfaces of structural sections, bars, rounds, wire rods

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Metal Rolling (AREA)

Description

【発明の詳細な説明】 本発明はウエブに穴をもつ形鋼の圧延法に係
り、特にかかる形鋼の温間及び熱間での圧延法に
関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for rolling a section steel having holes in its web, and more particularly to a warm and hot rolling method for such a section steel.

従来ウエブに穴をもつ形鋼は、冷間成形により
板を曲げて成形した簡易なチヤンネル形鋼から製
造されていた。この形鋼は二段圧延機系を用いて
冷間チヤンネル成形後にスリツトを付し拡幅圧延
をおこなうものであり、冷間圧延によるために材
料の変形抵抗が著しく大きく、従つて大断面の造
形が困難であり、また曲げ成形によるひずみが隅
部に集中して加工硬化するため、形鋼としての負
荷特性が悪く、また破壊し易く、大型構造物用形
鋼として使用するのには限界があつた。
Conventionally, steel sections with holes in their webs have been manufactured from simple channel steel sections that are formed by bending plates by cold forming. This steel section is made by cold channel forming using a two-high rolling mill system, followed by slits and widening rolling.Due to cold rolling, the deformation resistance of the material is extremely high, making it difficult to form large cross-sections. Moreover, the strain caused by bending concentrates in the corners and causes work hardening, so the load characteristics as a section steel are poor and it is easy to break, so there are limits to its use as a section steel for large structures. Ta.

本発明はかかる実情に鑑みなされたものであ
り、その要旨は、鋼片素材を粗圧延、ならびに二
段圧延機系とユニバーサル圧延機系とからなる中
間仕上圧延、および仕上圧延により連続的に圧延
して形鋼を温間或いは熱間にて造形するに際し、
仕上圧延の前工程としてスリツト圧延工程を挿入
して造形材ウエブ部に適当な間隔及びパターンで
ウエブ板厚方向に線上に貫通したスリツトをあら
かじめ付与すると共に、次工程の仕上圧延におい
て該ウエブ部の拡幅を行なうことを特徴とするウ
エブに穴をもつ形鋼の圧延法である。
The present invention was made in view of the above circumstances, and its gist is to continuously roll a steel billet material through rough rolling, intermediate finishing rolling consisting of a two-high rolling mill system and a universal rolling mill system, and finishing rolling. When shaping steel sections in warm or hot conditions,
A slit rolling process is inserted as a pre-process of finish rolling to provide the web part of the shaped material with slits that penetrate linearly in the thickness direction of the web at appropriate intervals and patterns. This is a method of rolling steel sections with holes in the web, which is characterized by widening.

次に本発明法を図面により詳細に説明する。 Next, the method of the present invention will be explained in detail with reference to the drawings.

第1図は粗圧延に引続く二段圧延機系及びユニ
バーサル圧延機系により、温間或いは熱間にてウ
エブ部に穴をもつH形鋼を圧延する本発明方法の
工程を示したものである。加熱された鋼片素材1
は粗圧延機群A,Bにより所定の形状に造形さ
れ、ユニバーサル中間仕上圧延機Cにより中間仕
上されたH形鋼形状に造形され、次いで2段圧延
機Dによりフランジ高さが所定の形状に制御され
る。これらの圧延機C,Dを数パス通過すること
によりフランジとウエブを所定の形状に造形し、
ユニバーサル中間仕上圧延機Eにより更に正確な
寸法に仕上げられたのち、スリツト圧延機Fでウ
エブに適当な間隔及びパターンでスリツトが付与
され、最後に仕上ユニバーサル圧延機Gによりウ
エブの拡幅がおこなわれつつスリツトを拡大して
穴とすることによつて所定の穴あきウエブの形鋼
に造形される。
Figure 1 shows the steps of the present invention method of rolling an H-section steel with holes in the web portion in a warm or hot manner using a two-high rolling mill system and a universal rolling mill system following rough rolling. be. Heated billet material 1
is shaped into a predetermined shape by rough rolling mill groups A and B, then shaped into an intermediate finished H-beam shape by universal intermediate finishing mill C, and then shaped into a predetermined shape by two-high rolling mill D. controlled. By passing through these rolling mills C and D several times, the flange and web are shaped into a predetermined shape.
After being finished to more accurate dimensions by a universal intermediate finishing mill E, slits are given to the web at appropriate intervals and patterns in a slitting mill F, and finally the web is widened by a finishing universal mill G. By enlarging the slits to form holes, a predetermined perforated web section is formed.

第2図は第1図の工程をさらに具体的に例示し
た模式図である。第2図A,Bには粗圧延機群
A,Bに使用される上下ロール8a,8bにより
形成される孔型9,10の一例を示す。鋼片素材
1は孔型9,10を数パス通過し、さらに竪ロー
ル11a,11b、水平ロール12a,12bよ
りなるユニバーサル中間仕上圧延機Cにより孔型
13の形状に造形される。次に14a,14bの
上下ロールにより形成される孔型15を有する2
段圧延機Dによりウエブの減肉、拡幅と同時にフ
ランジの高さの制御がおこなわれ、更に竪ロール
17a,17b、水平ロール16a,16bを有
するユニバーサル圧延機Eで孔型18に示される
ように更に減肉されほぼ所定の仕上寸法に造形さ
れる。次に孔型20に示すように上下ロール19
a,19bに突起21をつけたスリツト圧延機F
により適当な間隔およびパターンでスリツトマー
クを付し、例えば後述の第3図bに示すようなパ
ターンのスリツトを得る。なお、スリツト圧延機
のロール突起21は上下ロールの両方についてお
り、ロールの回転によつて相対する突起がウエブ
両面に押し付けられてスリツトが形成される。こ
のスリツトの間隔およびパターンはスリツト圧延
機Fの上下ロール19a,19bの突起形状とそ
の位置を適当に選ぶことにより自由に変えること
ができる。スリツト加工された形鋼は最後に竪ロ
ール22a,22b及び水平ロール23a,23
bを有する仕上ユニバーサル圧延機Gの竪ロール
22a,22bによりフランジ部25に引張力を
加えられつつ拡幅されて圧延される。この結果と
してスリツトが拡大して穴26となり、ウエブに
穴をもつ形鋼を得ることができる。
FIG. 2 is a schematic diagram illustrating the process of FIG. 1 in more detail. FIGS. 2A and 2B show an example of the groove shapes 9 and 10 formed by the upper and lower rolls 8a and 8b used in the rough rolling mill groups A and B. The steel billet material 1 passes through the grooves 9 and 10 several times, and is further shaped into the shape of the groove 13 by a universal intermediate finishing mill C comprising vertical rolls 11a and 11b and horizontal rolls 12a and 12b. Next, 2 with a hole 15 formed by the upper and lower rolls 14a and 14b.
The height of the flange is controlled by the plate rolling mill D at the same time as the thinning and widening of the web, and furthermore, the universal rolling mill E having vertical rolls 17a, 17b and horizontal rolls 16a, 16b is used to roll the web as shown in the groove 18. The thickness is further reduced and the finished size is approximately the same. Next, as shown in the hole pattern 20, the upper and lower rolls 19
Slit rolling machine F with projections 21 on a and 19b
Then, slit marks are made at appropriate intervals and in a pattern to obtain a slit pattern as shown in FIG. 3b, which will be described later. The roll protrusions 21 of the slitting mill are attached to both the upper and lower rolls, and as the rolls rotate, the opposing protrusions are pressed against both surfaces of the web to form slits. The spacing and pattern of the slits can be freely changed by appropriately selecting the shapes and positions of the protrusions on the upper and lower rolls 19a, 19b of the slit rolling mill F. The slitted section steel is finally passed through vertical rolls 22a, 22b and horizontal rolls 23a, 23.
The flange portion 25 is widened and rolled while applying a tensile force to the flange portion 25 by the vertical rolls 22a and 22b of the finishing universal rolling mill G having the finishing universal rolling mill G. As a result of this, the slits are enlarged to form holes 26, and a section steel having holes in the web can be obtained.

この場合、本発明において温間とは200℃から
700℃、熱間とは700℃から1250℃の温度範囲を概
ね夫々指すものであり、これら温間及び熱間工程
を採用するのは、温間圧延では寸法精度と靭性の
向上を、熱間圧延では変形抵抗の低下による大断
面の造形をねらうことを目的とすることによるも
のである。
In this case, in the present invention, warm means from 200℃ to
700°C and hot generally refer to the temperature range from 700°C to 1250°C, respectively, and the reason for adopting these warm and hot processes is that warm rolling improves dimensional accuracy and toughness, while hot rolling This is because rolling aims to create a large cross-section by reducing deformation resistance.

なお、第2図のユニバーサル圧延機EとGのウ
エブ幅の間にはβ〓1.03αの関係が満たされ、且
つ造形工程Gではウエブを圧下して減肉率が3%
以上とすれば肉厚均一となつて望ましいが、製品
の性能上均一肉厚が必要なければウエブを圧下し
なくともよい。また第2図の造形工程はチヤンネ
ル、シートパイルおよびI形鋼の造形にも容易に
適用することができる。
Furthermore, the relationship β=1.03α is satisfied between the web widths of universal rolling mills E and G in Figure 2, and in the forming process G, the web is rolled down and the thinning rate is 3%.
If the thickness is above, the thickness will be uniform, which is desirable, but if a uniform thickness is not required for the performance of the product, it is not necessary to press down the web. Furthermore, the forming process shown in FIG. 2 can be easily applied to forming channels, sheet piles, and I-beams.

なお、第3図は第1図、第2図の工程によつて
加工されるH形鋼の造形途中段階での形状例を
夫々示すものであつて、第3図aは第1図及び第
2図におけるユニバーサル中間仕上圧延機の孔型
を通過した造形材2の形状例、第3図bは第1図
及び第2図のスリツト圧延機Fの孔型を通過した
スリツト4を有する造形材3の形状例、第3図c
は第1図及び第2図の仕上ユニバーサル圧延機G
の孔型を通過したウエブ部に穴26をもつH形鋼
5の例である。なお、25はフランジ部である。
Note that FIG. 3 shows an example of the shape of the H-section steel processed in the steps shown in FIGS. 1 and 2 at an intermediate stage of forming, and FIG. An example of the shape of the shaped material 2 that has passed through the groove of the universal intermediate finishing mill in FIG. 2, and FIG. Example of shape of 3, Fig. 3c
is the finishing universal rolling mill G in Figures 1 and 2.
This is an example of an H-section steel 5 having a hole 26 in the web portion that has passed through the hole shape. Note that 25 is a flange portion.

以上詳細に説明した通り、ユニバーサル圧延機
系および2段圧延機系にスリツト圧延機を加えた
工程を用いてウエブに穴をもつ形鋼を熱間又は温
間加工することにより、隅部の正確な造形をおこ
ない得ると共に、従来製造し得なかつた、穴を有
するウエブ幅が1000mmにも及ぶ大断面の形鋼を容
易にしかも経済的に製造することができる。
As explained in detail above, by hot-working or warm-working a section steel with holes in the web using a process that combines a universal rolling mill system, a two-high rolling mill system, and a slit rolling mill, it is possible to accurately form corners. In addition, it is possible to easily and economically manufacture large cross-sectional steel sections with holes and web widths of up to 1000 mm, which could not be manufactured conventionally.

以下に本発明の効果を実施例によりさらに具体
的に示す。
The effects of the present invention will be illustrated in more detail by way of examples below.

本発明を用いて第2図に示す孔型形式をもつ第
1図の圧延機系により形鋼の製造を行なつた。素
材として250mm×250mm、鋼種としてSM50のビレ
ツトを用い、11パスによりウエブ幅286mm、フラ
ンジ幅121mm、ウエブ厚さ4・4mmで、ウエブ部
に30mm×9mm高さの穴をもつ第3図cに示すよう
なH形鋼を造形した。すなわち、第2図において
250mm×250mm角のビレツト1は1200℃に加熱され
たのち2段圧延機A,Bの孔型を2回通され、C
のユニバーサル圧延機によりH形鋼に粗造形さ
れ、Dの2段圧延機で拡幅とフランジの高さを制
御され、更にユニバーサル圧延機Eにより整形さ
れる工程を2回通過したのち、ウエブ幅238mm、
フランジ幅120.8mmおよびウエブ肉厚4・8mmの
粗H形鋼に仕上げられた。しかるのち、Fなるス
リツト造形用の2段圧延機によりウエブの中心線
上とウエブの高さの1/2の線上に幅30mmのスリツ
トを付し、さらに仕上ユニバーサル圧延機Gによ
り仕上をおこなつた。この際拡幅はα=238mm、
β=286mmに選定され、ウエブの圧下率は8%と
した。仕上終了温度はウエブ部で600℃であつた。
Using the present invention, a section steel was manufactured using the rolling mill system shown in FIG. 1 having the groove type shown in FIG. A billet of 250 mm x 250 mm and SM50 steel was used as the material, and after 11 passes, the web width was 286 mm, the flange width was 121 mm, the web thickness was 4.4 mm, and the hole in the web part was 30 mm x 9 mm high. An H-section steel as shown was manufactured. That is, in Figure 2
Billet 1 of 250 mm x 250 mm square is heated to 1200°C and then passed through the grooves of two-high rolling mills A and B twice.
It is roughly formed into an H-beam by the universal rolling mill D, the width and flange height are controlled by the two-high rolling mill D, and it is shaped twice by the universal rolling mill E. After that, the web width is 238 mm. ,
Finished as a rough H-beam with a flange width of 120.8mm and a web thickness of 4.8mm. After that, a slit with a width of 30 mm was formed on the center line of the web and on a line half the height of the web using a two-high rolling mill F for slit forming, and finishing was performed using a finishing universal rolling mill G. . At this time, the width is increased by α=238mm.
β = 286 mm was selected, and the rolling reduction ratio of the web was 8%. The finishing temperature at the web portion was 600°C.

かして得られたH形鋼は、冷間圧延で得られた
同一断面係数の軽量形鋼に比してウエブ穴部に割
れの発生が著しく少ないために、破壊に対する抵
抗が極めて高く、フランジ先端部に発生するひず
み値を同一の0.05%を与えて繰返し曲げ試験をお
こなつた結果では、従来法による軽量形鋼が1万
回で破壊したのに比して、本発明になる製造法に
よつて得られた形鋼は5万回でも破壊は生じなか
つた。
The H-shaped steel obtained by this method has significantly less cracking in the web holes than the lightweight section steel with the same section modulus obtained by cold rolling, so it has extremely high resistance to fracture, and the flange The results of repeated bending tests with the same strain value of 0.05% generated at the tip showed that the manufacturing method of the present invention broke while the lightweight section steel produced by the conventional method broke after 10,000 cycles. The shaped steel obtained by this method did not break even after 50,000 cycles.

以上の実施例からも明らかな通り、本発明によ
りウエブに任意の穴をもつ形鋼について形状を正
確に保持しながら、しかも薄肉に圧延することが
可能となり、産業上の効果は極めて顕著なものが
ある。
As is clear from the above examples, the present invention makes it possible to accurately maintain the shape of a section steel with arbitrary holes in the web while rolling it into a thin wall, and the industrial effect is extremely significant. There is.

【図面の簡単な説明】[Brief explanation of drawings]

第1図及び第2図は本発明方法によりウエブに
穴をもつH形鋼を製造する工程を示す模式図、第
3図は第1図、第2図の工程により加工されるH
形鋼の造形途中段階での形状例を示す斜視図であ
る。 A,B……粗圧延機;C,E……ユニバーサル
中間仕上圧延機;D……2段圧延機;F……スリ
ツト圧延機;G……仕上ユニバーサル圧延機;1
……鋼片素材;2,3……造形材;4……スリツ
ト;5……穴をもつH形鋼;8a,8b……粗圧
延機の上下ロール;9,10……粗圧延機孔型;
11a,11b,17a,17b,22a,22
b……ユニバーサル圧延機の竪ロール;12a,
12b,16a,16b,23a,23b……ユ
ニバーサル圧延機の水平ロール;13,18……
ユニバーサル圧延機の孔型;14a,14b……
2段圧延機の上下ロール;15……2段圧延機の
孔型;19a,19b……スリツト圧延機の上下
ロール;20……スリツト圧延機の孔型;21…
…スリツト圧延機のロール突起;25……フラン
ジ部;26……穴。
Figures 1 and 2 are schematic diagrams showing the process of manufacturing an H-section steel with holes in the web by the method of the present invention, and Figure 3 is a schematic diagram showing the process of manufacturing an H-section steel with holes in the web by the method of the present invention.
FIG. 2 is a perspective view showing an example of the shape of a shaped steel in the middle of forming. A, B... Rough rolling mill; C, E... Universal intermediate finishing rolling mill; D... Two-high rolling mill; F... Slit rolling mill; G... Finishing universal rolling mill; 1
... Steel billet material; 2, 3 ... Shaping material; 4 ... Slit; 5 ... H-beam steel with holes; 8a, 8b ... Upper and lower rolls of rough rolling mill; 9, 10 ... Rough rolling mill hole Type;
11a, 11b, 17a, 17b, 22a, 22
b... Vertical roll of universal rolling mill; 12a,
12b, 16a, 16b, 23a, 23b...Horizontal rolls of the universal rolling mill; 13, 18...
Hole type of universal rolling mill; 14a, 14b...
Upper and lower rolls of the two-high rolling mill; 15... Hole shape of the two-high rolling mill; 19a, 19b... Upper and lower rolls of the slit rolling mill; 20... Hole shape of the slit rolling mill; 21...
... Roll protrusion of slit rolling mill; 25 ... Flange portion; 26 ... Hole.

Claims (1)

【特許請求の範囲】[Claims] 1 鋼片素材を粗圧延、ならびに二段圧延機系と
ユニバーサル圧延機系とからなる中間仕上圧延、
および仕上圧延により連続的に圧延して形鋼を温
間或いは熱間にて造形するに際し、仕上圧延の前
工程としてスリツト圧延工程を挿入して造形材ウ
エブ部に適当な間隔及びパターンでウエブ板厚方
向に線上に貫通したスリツトをあらかじめ付与す
ると共に、次工程の仕上圧延において該ウエブ部
の拡幅を行なうことを特徴とするウエブに穴をも
つ形鋼の圧延法。
1 Rough rolling of steel billet material, intermediate finishing rolling consisting of a two-high rolling mill system and a universal rolling mill system,
When forming a section steel in warm or hot conditions through continuous finishing rolling, a slit rolling process is inserted as a pre-process to finishing rolling to form web plates at appropriate intervals and patterns in the web part of the forming material. A method of rolling a section steel having holes in a web, characterized in that a slit that penetrates linearly in the thickness direction is provided in advance, and the width of the web portion is widened in the next step of finish rolling.
JP6801383A 1983-04-18 1983-04-18 Method for rolling steel shape having hole in its web Granted JPS59193702A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6801383A JPS59193702A (en) 1983-04-18 1983-04-18 Method for rolling steel shape having hole in its web

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6801383A JPS59193702A (en) 1983-04-18 1983-04-18 Method for rolling steel shape having hole in its web

Publications (2)

Publication Number Publication Date
JPS59193702A JPS59193702A (en) 1984-11-02
JPH0150482B2 true JPH0150482B2 (en) 1989-10-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP6801383A Granted JPS59193702A (en) 1983-04-18 1983-04-18 Method for rolling steel shape having hole in its web

Country Status (1)

Country Link
JP (1) JPS59193702A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE390297T1 (en) 2002-11-08 2008-04-15 Campagnolo Srl METHOD FOR PRODUCING A SPOKE WHEEL FOR BICYCLES
EP1506882B1 (en) 2003-08-11 2008-07-09 Campagnolo Srl Composite bicycle rim and method for producing it
EP1685979A1 (en) * 2005-01-28 2006-08-02 Campagnolo S.r.l. Bicycle wheel and spoke and hub body therefor
ITMI20072231A1 (en) 2007-11-26 2009-05-27 Campagnolo Srl RIM FOR BICYCLE WHEEL AND BICYCLE WHEEL INCLUDING SUCH RIM
CN115492306A (en) * 2022-08-26 2022-12-20 马鞍山钢铁股份有限公司 Hot-rolled H-shaped steel with web plate holes and production method thereof

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Publication number Publication date
JPS59193702A (en) 1984-11-02

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