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JPH0219781B2 - - Google Patents
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JPH0219781B2 - - Google Patents

Info

Publication number
JPH0219781B2
JPH0219781B2 JP21735482A JP21735482A JPH0219781B2 JP H0219781 B2 JPH0219781 B2 JP H0219781B2 JP 21735482 A JP21735482 A JP 21735482A JP 21735482 A JP21735482 A JP 21735482A JP H0219781 B2 JPH0219781 B2 JP H0219781B2
Authority
JP
Japan
Prior art keywords
foam
glaze
intermediate layer
building material
filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP21735482A
Other languages
Japanese (ja)
Other versions
JPS59111948A (en
Inventor
Tetsuya Koide
Takayuki Shirai
Masao Kachi
Shozo Harada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inax Corp
Original Assignee
Inax Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inax Corp filed Critical Inax Corp
Priority to JP21735482A priority Critical patent/JPS59111948A/en
Publication of JPS59111948A publication Critical patent/JPS59111948A/en
Publication of JPH0219781B2 publication Critical patent/JPH0219781B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Panels For Use In Building Construction (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Glass (AREA)

Description

【発明の詳細な説明】 本発明は泡ガラス等よりなる発泡体表面と該発
泡体の表面側に塗布された釉薬層との間に目止め
材よりなる中間層を設けた発泡建築材及びその製
造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a foam building material in which an intermediate layer made of a filler is provided between the surface of a foam made of foam glass or the like and a glaze layer applied to the surface of the foam, and a foam construction material thereof. This relates to a manufacturing method.

一般に、泡ガラス等の発泡体は軽量であり、し
かも断熱性及び防音性がよいので建築材として多
用されている。ところが第1図に示すように発泡
体1の表面には、成形時に発泡した小さな気孔2
が多数露出して表面形状が凹凸になつており、該
部分に塵埃が附着して汚れる等して外観上の見栄
えが悪くなる欠点があり、また微細な貫入を通し
て水を吸収するので、水まわりに使用するには耐
久性が劣るという欠点があつた。このため、発泡
体1の表面に表面処理材としての釉薬を塗布し、
釉薬層3を設けて建築材4としている。しかしな
がら、上記釉薬は、焼成前の塗布時には気孔2を
閉塞していても、その焼成時の熔融軟化に伴い、
釉薬中に含まれる気泡が脱気し、とりわけ気孔2
内は釉薬量も多いことから脱気量が多く、したが
つて気孔2を閉塞していた部分の減量が激しく、
第1図に示すように、釉薬層3の表面にピンホー
ル5やへこみ6を発生させ、やはり表面形状が凹
凸になる欠点があつた。
In general, foamed materials such as foamed glass are often used as construction materials because they are lightweight and have good heat insulation and soundproofing properties. However, as shown in Figure 1, there are small pores 2 on the surface of the foam 1 that were formed during molding.
This has the disadvantage that many parts are exposed and the surface shape is uneven, and the appearance becomes poor due to dust adhering to these parts and making them dirty.In addition, water is absorbed through minute penetrations, so The drawback was that it was not durable enough to be used for. For this reason, a glaze as a surface treatment material is applied to the surface of the foam 1,
A building material 4 is provided with a glaze layer 3. However, even though the above glaze closes the pores 2 when applied before firing, as it melts and softens during firing,
Air bubbles contained in the glaze are degassed, especially pores 2
Since there is a large amount of glaze inside, there is a large amount of deaeration, and therefore the area that was blocking pores 2 loses a lot of weight.
As shown in FIG. 1, pinholes 5 and dents 6 were generated on the surface of the glaze layer 3, resulting in an uneven surface shape.

本発明は従来の発泡建築材の上記欠点に鑑みて
これを改良除去したものであつて、泡ガラス等よ
りなる発泡体表面と該発泡体の表面側に塗布され
た釉薬層との間に目止め材よりなる中間層を設け
た発泡建築材及びその製造方法を提供することに
より、上記発泡建築材をしてその表面からの吸水
性及び透湿性が全くなく、しかも平滑な釉面を有
するようにしたものである。
In view of the above-mentioned drawbacks of conventional foam building materials, the present invention has been developed to improve and eliminate these drawbacks. By providing a foamed building material provided with an intermediate layer made of a stopper material and a method for producing the same, it is possible to make the foamed building material have no water absorption or moisture permeability from its surface and a smooth glazed surface. This is what I did.

以下に本発明の発泡建築材の構成並びにその製
造方法を図面に示す実施例に基づいて説明すると
次の通りである。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The structure of the foamed building material of the present invention and its manufacturing method will be explained below based on examples shown in the drawings.

第2図は本発明に係る建築材7を示すものであ
る。この建築材7は、泡ガラス等よりなる発泡体
8の表面と該表面側に塗布して設けられた釉薬層
9との間に、目止め材としての中間層10を設け
ている。而してこの中間層10の目止め材は、本
発明の初期の目的から釉薬の焼成時にガラス質の
物質を含む釉薬が、従来のように気孔11内にお
いて大幅に減量するのを防止し、釉薬層9の表面
を平滑にすることと、ガラス質の物質を含む上記
釉薬及び発泡体8の両者を馴染ませ、釉薬層9の
剥離防止へ寄与すること、更には釉薬塗布時に該
釉薬が均一に塗布されるように作用することが大
事である。したがつて、この目止め材は、発泡体
8及び釉薬の成分や調合割合によつてその成分及
び調合割合が決定されなければならない。このよ
うに、中間層10の目止め材はその成分及び調合
割合に重要な意義があり、本発明では水硬性物質
及び骨材若しくは水硬性物質及び骨材に更にガラ
ス質の物質を添加した混合物又は該混合物に水及
び必要に応じてCMCの適量を添加したスラリー
状のものを目止め材としている。上記水硬性物質
としては、普通ポルトランドセメント、白色ポル
トランドセメント、アルミナセメント、フライア
ツシユセメント、高炉スラグセメント等のセメン
ト或いは二水石膏、半水石膏、無水石膏等の石膏
類があげられ、また骨材としては熱的変化(特に
体積変化)の小さい福島珪石と俗称されるものを
粉体にしたもの等があげられ、更にガラス質の物
質としてはフリツト、ガラス粉及びシラス等があ
げられる。
FIG. 2 shows a construction material 7 according to the present invention. This building material 7 has an intermediate layer 10 as a sealing material between the surface of a foam 8 made of foam glass or the like and a glaze layer 9 coated on the surface. Therefore, the filling material of the intermediate layer 10 is used to prevent the glaze containing a glassy substance from being significantly reduced in weight within the pores 11 during firing of the glaze, as in the case of the conventional method. The purpose is to make the surface of the glaze layer 9 smooth, to make both the glaze containing a glassy substance and the foam 8 blend together, to contribute to preventing the glaze layer 9 from peeling, and to ensure that the glaze is uniform during application. It is important that the product acts in such a way that it is applied to the skin. Therefore, the components and blending ratio of this filler must be determined by the components and blending ratio of the foam 8 and the glaze. As described above, the filling material of the intermediate layer 10 has important significance in its components and mixing ratio, and in the present invention, a hydraulic substance and aggregate or a mixture of a hydraulic substance and aggregate with a vitreous substance added thereto. Alternatively, a slurry prepared by adding water and, if necessary, an appropriate amount of CMC to the mixture is used as a filler. Examples of the above-mentioned hydraulic substances include cements such as ordinary Portland cement, white Portland cement, alumina cement, fly ash cement, and blast furnace slag cement, and gypsums such as dihydrate gypsum, hemihydrate gypsum, anhydrite gypsum, etc. Examples of such materials include powders of what is commonly called Fukushima silica, which exhibits small thermal changes (particularly volume changes), and examples of glassy materials include frit, glass powder, and shirasu.

次に具体的な目止め材の成分及び調合割合を示
す実施例に基づいて、発泡建築材7の製造方法を
説明する。
Next, a method for manufacturing the foamed building material 7 will be described based on an example showing specific components and mixing ratios of the sealing material.

先づ第1の実施例であるが、この実施例は白色
ポルトランドセメントの水硬性物質と福島珪石の
骨材を、水硬性物質:骨材=1:2の重量割合で
混ぜ合わせた混合物に、更に水硬性物質に対する
重量割合が0.6の量の水を添加して混合したスラ
リー状のものを目止め材とする。またこれらの混
合物に必要に応じていわゆる粘結材CMCを適量
添加する。このような成分及び調合割合の目止め
材は、第2図に示すような発泡体8の表面に塗り
込まれ、該表面に露出するオープン状気孔11を
目止めし、かつ極めて肉厚の薄い中間層10を形
成する。なお中間層10は平滑に塗布されるもの
である。しかる後は発泡体8を室内気中に1昼夜
放置して、中間層10の目止め材を硬化させ、硬
化後の中間層10上に、フリツト100重量部、顔
料5重量部、CMC1%溶液60重量部よりなる釉薬
をスプレー塗布し、釉薬層9を設ける。この釉薬
の塗布は中間層10上に塗布されるものであり、
適度な吸水性があり、釉薬とのヌレもよく、発泡
体8表面に直接塗布する場合よりも、均一に塗布
することが可能である。そして後は、釉薬層9の
乾燥後に、焼成の前後に徐熱徐冷期を設けて発泡
体8が大きく変形しない温度と時間の下で焼成を
行なう。焼成温度及び焼成時間は通常750℃、30
分間とされるが、発泡体8及び釉薬層9の成分や
その調合割合によつて、多少の変化があることは
いうまでもない。この焼成にあつて、釉薬層9の
釉薬、中間層10の目止め材、発泡体8の表面側
がそれぞれ熔融軟化し、中間層10の目止め材は
釉薬層9と発泡体8の馴染みをよくする。このよ
うな発泡建築材7であれば、釉薬層9、中間層1
0、発泡体8の表面側がそれぞれ溶融軟化後、固
化するので表面からの吸水性及び透湿性が全くな
く、しかも釉薬層9の剥離の虞れもなく、更には
発泡体8自身の有する軽量で断熱性及び防音性に
優れているという効果を併せ持つものである。
First, the first example is a mixture of white Portland cement hydraulic material and Fukushima silica aggregate in a weight ratio of hydraulic material: aggregate = 1:2, Furthermore, a slurry-like material obtained by adding and mixing water at a weight ratio of 0.6 to the hydraulic material is used as a sealing material. Further, an appropriate amount of a so-called caking agent CMC is added to these mixtures as necessary. The filler having such ingredients and proportions is applied to the surface of the foam 8 as shown in FIG. An intermediate layer 10 is formed. Note that the intermediate layer 10 is applied smoothly. After that, the foam 8 is left in indoor air for one day and night to harden the filler of the intermediate layer 10, and 100 parts by weight of frit, 5 parts by weight of pigment, and 1% CMC solution are applied on the hardened intermediate layer 10. A glaze layer 9 is provided by spraying a glaze containing 60 parts by weight. This glaze is applied on the intermediate layer 10,
It has appropriate water absorption and wets well with the glaze, making it possible to apply it more uniformly than when directly applying it to the surface of the foam 8. Then, after drying the glaze layer 9, slow heating and slow cooling periods are provided before and after firing, and firing is performed at a temperature and time that does not significantly deform the foamed body 8. Firing temperature and firing time are usually 750℃ and 30℃.
However, it goes without saying that there may be some changes depending on the components of the foam 8 and glaze layer 9 and their mixing ratios. During this firing, the glaze of the glaze layer 9, the filler of the intermediate layer 10, and the surface side of the foam 8 are melted and softened, and the filler of the intermediate layer 10 improves the compatibility between the glaze layer 9 and the foam 8. do. In such a foamed building material 7, the glaze layer 9, the intermediate layer 1
0. The surface side of the foam 8 is melted and softened and then solidified, so there is no water absorption or moisture permeability from the surface, and there is no risk of peeling of the glaze layer 9, and furthermore, the foam 8 itself is lightweight. It has the effect of being excellent in heat insulation and soundproofing properties.

第2の実施例にあつては、白色ポルトランドセ
メントの水硬性物質と、ガラス粉と、福島珪石の
骨材の量の比が1:1:1になる混合物に、水硬
性物質に対する重量割合が0.6の量の水を添加し
て混合したスラリー状のものを目止め材としてい
る。この目止め材の場合も、上記混合物に更に必
要に応じて粘結材としてのCMCを適量添加して
使用される。この第2の実施例は、前記第1の実
施例と同要領で発泡建築材7を得るものである。
この場合、施釉後の焼成時に、釉薬層9の釉薬、
中間層10の上記目止め材及び発泡体8の表面側
の3者が共にガラス質の物質を含有し、ガラス熔
融軟化するので、前記第1の実施例の場合よりも
これら3者の結合状態がよい。その他の作用効果
は同じである。
In the second example, a mixture in which the ratio of the amounts of white Portland cement hydraulic substance, glass powder, and Fukushima silica aggregate is 1:1:1, and the weight ratio to the hydraulic substance is The sealing material is a slurry made by adding 0.6 parts of water to the mixture. In the case of this sealing material as well, an appropriate amount of CMC as a caking agent is added to the above mixture as necessary. In this second example, the foamed building material 7 is obtained in the same manner as in the first example.
In this case, during firing after glazing, the glaze of the glaze layer 9,
Since both the filling material of the intermediate layer 10 and the surface side of the foam 8 contain a glassy substance and are melted and softened, the bonding state of these three is better than in the case of the first embodiment. Good. Other effects are the same.

第3図は発泡建築材7の表面にタイル模様を得
る場合の製造方法を説明するための図面である。
この場合に使用する目止め材の成分及び調合割合
は、前記第1及び第2の実施例のいずれによつて
もよい。製造方法は、前記第1又は第2の実施例
の目止め材を、発泡体8の表面に塗布して目止め
を行ない、中間層10(第2図参照)を形成した
後、これを硬化させてタイル間の目地部に相当す
る位置にパラフイン、撥水剤等12を塗布する。
そして前記第1及び第2の実施例の釉薬を塗布
し、乾燥後に前記各実施例と同じ条件で焼成すれ
ばタイル模様を有する発泡建築材7が得られる。
またこれによりパラフイン、撥水剤等12の部分
が釉薬層9(第2図参照)を小さく分割するの
で、発泡体8と釉薬層9との熱膨張差が緩和さ
れ、前記各実施例にも増して釉薬層9の剥離の問
題が発生しにくい利点がある。その他の構成並び
に作用効果は前記各実施例と同じである。
FIG. 3 is a drawing for explaining a manufacturing method for obtaining a tile pattern on the surface of the foam building material 7.
The ingredients and blending ratio of the filler used in this case may be the same as those in the first and second embodiments. The manufacturing method includes applying the filling material of the first or second embodiment to the surface of the foam 8 to form the intermediate layer 10 (see FIG. 2), and then curing it. Then, paraffin, water repellent, etc. 12 is applied to positions corresponding to the joints between the tiles.
Then, by applying the glazes of the first and second embodiments, drying, and firing under the same conditions as in each of the embodiments, a foamed building material 7 having a tile pattern can be obtained.
Also, as the paraffin, water repellent, etc. 12 divides the glaze layer 9 (see FIG. 2) into small pieces, the difference in thermal expansion between the foam 8 and the glaze layer 9 is alleviated, which also applies to each of the above embodiments. Furthermore, there is an advantage that the problem of peeling of the glaze layer 9 is less likely to occur. The other configurations and effects are the same as in each of the above embodiments.

なお本発明に使用する目止め材の成分及び調合
割合は上述した各実施例のものに限定されるもの
ではなく、発泡体8及び釉薬の成分、調合割合等
によつて適宜変更することが必要である。また発
泡体8の形状も、上述の各実施例に限定されるも
のではなく、例えば発泡体8の表面に大きな凹凸
が形成されているものであつても、該凹凸の表面
にオープン状の気孔が露出しているので、これに
本発明の方法を適用すれば、前記各実施例と同様
の効果が得られるものである。
Note that the components and blending ratio of the sealing material used in the present invention are not limited to those in each of the examples described above, and may need to be changed as appropriate depending on the components of the foam 8 and glaze, blending ratio, etc. It is. Further, the shape of the foam 8 is not limited to the above-mentioned embodiments. For example, even if the foam 8 has large irregularities formed on its surface, open pores may be formed on the surface of the irregularities. is exposed, so if the method of the present invention is applied to this, the same effects as in each of the above embodiments can be obtained.

以上説明したように本発明によれば、目止め材
によつて釉薬が発泡体のオープン状気孔で減量す
ることがないので釉薬層の表面にピンホールやへ
こみが形成されることがなく、美観的にも耐久性
にも優れた発泡建築材を得ることが可能である。
また施釉時にあつては、発泡体表面に塗布された
上記目止め材が硬化して介在しており、釉薬の拡
散を防止してこれが均一に塗布されるのを助長す
る。更に釉薬の焼成時にあつては、目止め材が釉
薬層と発泡体表面との馴染みを良くし、焼成後の
釉薬層の剥離防止へと寄与することができる。し
かもこの焼成時に目止め材、釉薬層及び発泡体表
面が熔融軟化後、気孔を完全に閉塞した状態で固
着するので、表面からの吸水性及び透湿性の全く
ない発泡建築材を得ることが可能である。
As explained above, according to the present invention, the glaze does not lose weight in the open pores of the foam due to the filler, so pinholes and dents are not formed on the surface of the glaze layer, resulting in an aesthetic appearance. It is possible to obtain a foamed building material that is excellent in both physical and durable properties.
Further, during glazing, the filler applied to the surface of the foam hardens and intervenes, preventing the glaze from spreading and promoting uniform application of the glaze. Furthermore, when firing the glaze, the filler improves the compatibility between the glaze layer and the surface of the foam, and can contribute to preventing the glaze layer from peeling off after firing. Moreover, during firing, the filler, glaze layer, and foam surface melt and soften and then solidify with the pores completely closed, making it possible to obtain a foamed building material with no water absorption or moisture permeability from the surface. It is.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の発泡建築材の施釉面側の一部を
示す縦断面図、第2図は本発明に係る発泡建築材
の施釉面側の一部を示す縦断面図、第3図は本発
明に係る発泡建築材の表面にタイル模様を得る場
合の製造方法を説明する発泡建築材の斜視図であ
る。 8……発泡体、9……釉薬層、10……中間
層、11……オープン状気孔。
FIG. 1 is a longitudinal sectional view showing a part of the glazed surface side of a conventional foam building material, FIG. 2 is a longitudinal sectional view showing a part of the glazed surface side of a foam building material according to the present invention, and FIG. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a perspective view of a foamed building material illustrating a manufacturing method for obtaining a tile pattern on the surface of the foamed building material according to the present invention. 8... Foam, 9... Glaze layer, 10... Intermediate layer, 11... Open pores.

Claims (1)

【特許請求の範囲】 1 泡ガラス等よりなる発泡体の表面と該発泡体
の表面側に塗布された釉薬層との間に目止め材よ
りなる中間層を設けてなる発泡建築材。 2 泡ガラス等よりなる発泡体の表面に水硬性物
質及び骨材若しくは水硬性物質及び骨材に更にガ
ラス質の物質を添加した混合物又は該混合物に水
及び必要に応じてCMCの適量を添加したスラリ
ー状の目止め材を塗布して上記発泡体表面のオー
プン状気孔を目止めし、該目止め材を中間層とし
てその上に釉薬を塗布し、しかる後上記発泡体が
実用に供し得る形体を崩すに至らない温度及び時
間の範囲で焼成することを特徴とする発泡建築材
の製造方法。
[Scope of Claims] 1. A foam building material comprising an intermediate layer made of a filler between the surface of a foam made of foam glass or the like and a glaze layer applied to the surface of the foam. 2 A hydraulic substance and aggregate, a mixture of a hydraulic substance and aggregate with a glassy substance added to the surface of a foam made of foam glass, etc., or water and an appropriate amount of CMC added as necessary to the mixture. A slurry-like sealing material is applied to seal the open pores on the surface of the foam, and a glaze is applied on top of the sealing material as an intermediate layer. After that, the foam is formed into a shape that can be put to practical use. A method for producing a foamed building material, which comprises firing at a temperature and time range that does not cause the foam to collapse.
JP21735482A 1982-12-10 1982-12-10 Foamed building material and application of glaze to it Granted JPS59111948A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21735482A JPS59111948A (en) 1982-12-10 1982-12-10 Foamed building material and application of glaze to it

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21735482A JPS59111948A (en) 1982-12-10 1982-12-10 Foamed building material and application of glaze to it

Publications (2)

Publication Number Publication Date
JPS59111948A JPS59111948A (en) 1984-06-28
JPH0219781B2 true JPH0219781B2 (en) 1990-05-07

Family

ID=16702853

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21735482A Granted JPS59111948A (en) 1982-12-10 1982-12-10 Foamed building material and application of glaze to it

Country Status (1)

Country Link
JP (1) JPS59111948A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62176310U (en) * 1986-04-25 1987-11-09
GB2203143B (en) * 1987-03-20 1991-06-05 Central Glass Co Ltd Multilayer foam glass with dense glass surface layer and method of producing same
RU2467963C1 (en) * 2011-03-25 2012-11-27 Государственное образовательное учреждение высшего профессионального образования "Белгородский государственный технологический университет им. В.Г. Шухова" Method of making coating on block foam glass

Also Published As

Publication number Publication date
JPS59111948A (en) 1984-06-28

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