JPH023269B2 - - Google Patents
Info
- Publication number
- JPH023269B2 JPH023269B2 JP56134271A JP13427181A JPH023269B2 JP H023269 B2 JPH023269 B2 JP H023269B2 JP 56134271 A JP56134271 A JP 56134271A JP 13427181 A JP13427181 A JP 13427181A JP H023269 B2 JPH023269 B2 JP H023269B2
- Authority
- JP
- Japan
- Prior art keywords
- cathode
- lead body
- anode
- welding
- spot welding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Connection Of Batteries Or Terminals (AREA)
Description
【発明の詳細な説明】
本発明は、少なくとも陰極缶側にリード体を接
続したリード体付きリチウム電池の製法に関す
る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing a lithium battery with a lead body in which a lead body is connected at least to the cathode can side.
リチウム電池は非常に長寿命であり、アルカリ
電池などに比べて優れた耐漏液性を有しているこ
となどから、ICメモリーバツクアツプ用電源な
どに賞用されている。これらの用途の場合、電池
の陰極缶ならびに陽極缶にそれぞれリード体を直
接スポツト溶接し、リード体の他端をそのままプ
リント基板に半田付けされる場合が多い。 Lithium batteries have an extremely long lifespan and have superior leakage resistance compared to alkaline batteries, so they are widely used as power supplies for IC memory backups. In these applications, lead bodies are often spot-welded directly to the cathode and anode cans of the battery, and the other ends of the lead bodies are soldered to a printed circuit board as they are.
第1図は、従来のリード体付きリチウム電池の
製法を説明するための図である。従来の方法で
は、予めリチウム電池を組立て、その後に陽極缶
1ならびに陰極缶2の所定個所にそれぞれリード
体8,8をスポツト溶接していた。 FIG. 1 is a diagram for explaining a conventional manufacturing method of a lithium battery with a lead body. In the conventional method, the lithium battery was assembled in advance, and then the lead bodies 8, 8 were spot-welded to predetermined positions of the anode can 1 and the cathode can 2, respectively.
すなわち、最初、陽極缶1の缶底に例えば二酸
化マンガンなどを主体とする陽極3ならびにセパ
レータ4を順次挿入する。これより別に、陰極缶
2の内面に金網7を予めスポツト溶接で固着し、
その金網7に金属リチウムからなる陰極5を圧
着・保持せしめ、陽極缶2の外周に環状のガスケ
ツト6を嵌合する。この陰極缶2と陰極5とガス
ケツト6の集合体を陽極缶1の開口部から挿入
し、陽極缶1の開口部を内方に折曲することによ
り締付けて電池の組立てを完了する。そののち、
陽極缶1ならびに陰極缶2にそれぞれリード体8
をスポツト溶接によつて固着していた。 That is, first, the anode 3 and the separator 4, which are mainly made of manganese dioxide, for example, are sequentially inserted into the bottom of the anode can 1. Apart from this, a wire mesh 7 is fixed to the inner surface of the cathode can 2 in advance by spot welding,
A cathode 5 made of metallic lithium is crimped and held on the wire mesh 7, and an annular gasket 6 is fitted around the outer periphery of the anode can 2. The assembly of the cathode can 2, cathode 5, and gasket 6 is inserted through the opening of the anode can 1, and the opening of the anode can 1 is bent inward and tightened to complete the assembly of the battery. after that,
A lead body 8 is attached to each of the anode can 1 and the cathode can 2.
were fixed by spot welding.
ところがこの方法では、陰極缶2にリード体8
をスポツト溶接する際に問題がある。すなわち、
通常、陰極缶2の最外層はニツケル層になつてお
り、またリード体8としてもニツケルの薄板が使
用されている。そのためリード体8を陰極缶2に
確実に溶接するには1500℃前後の温度が必要であ
るが、このような高温になる条件でスポツト溶接
すると、陰極5への熱的影響が大きい。金属リチ
ウムの融点は約186℃であるから、前述のような
高温にすると溶接部近傍の陰極5が一部溶融し、
それがセパレータ4を透過して陽極3と接触し内
部短絡を生じる。また、セパレータ4としては通
常、合成繊維の不織布や微孔性フイルムなどが使
用されており、溶接時の熱的影響で一部に孔が開
いたりしてセパレータ4の機能を喪失してしま
う。 However, in this method, the lead body 8 is attached to the cathode can 2.
There is a problem when spot welding. That is,
Usually, the outermost layer of the cathode can 2 is a nickel layer, and a thin nickel plate is also used as the lead body 8. Therefore, in order to reliably weld the lead body 8 to the cathode can 2, a temperature of around 1500° C. is required, but spot welding under such high temperature conditions has a large thermal effect on the cathode 5. The melting point of metallic lithium is approximately 186°C, so when the temperature is raised to the above-mentioned temperature, the cathode 5 near the weld part will partially melt.
It passes through the separator 4 and comes into contact with the anode 3, causing an internal short circuit. Further, as the separator 4, a non-woven fabric made of synthetic fibers, a microporous film, or the like is usually used, and the function of the separator 4 is lost due to the formation of holes in some parts due to the thermal effects during welding.
このようなことが起こらないようにするには、
陰極缶2とリード体8のスポツト溶接を小電流、
短時間で行なう必要があり、溶接条件を厳密に管
理しなければならない。前述のように小電流、短
時間でスポツト溶接すると、陰極缶2とリード体
8の溶接強度が必然的に弱くなり、両者間で接続
不良を生じることになる。 To prevent this from happening,
The cathode can 2 and the lead body 8 are spot welded using a small current.
Welding must be done in a short time, and welding conditions must be strictly controlled. When spot welding is performed using a small current and a short time as described above, the welding strength between the cathode can 2 and the lead body 8 inevitably becomes weak, resulting in a poor connection between the two.
本発明の目的は、このような従来技術の欠点を
解消し、陰極缶とリード体の溶接が確実に行なわ
れ、しかも内部短絡などの弊害を生じないリード
体付きリチウム電池の製法を提供するにある。 An object of the present invention is to eliminate the drawbacks of the prior art and to provide a method for manufacturing a lithium battery with a lead body in which the cathode can and the lead body can be reliably welded, and which does not cause problems such as internal short circuits. be.
この目的を達成するため、本発明は、陰極缶の
外表面に補助リード体の一部をスポツト溶接など
の溶接で固着し、その陰極缶を用いてリチウム電
池を組立て、その後に前記補助リード体に本リー
ド体をスポツト溶接などにより接続することを特
徴とする。 In order to achieve this object, the present invention fixes a part of the auxiliary lead body to the outer surface of the cathode can by welding such as spot welding, assembles a lithium battery using the cathode can, and then attaches the auxiliary lead body to the outer surface of the cathode can. The lead body is connected to the lead body by spot welding or the like.
次に本発明の実施例を第2図ないし第5図とと
もに説明する。 Next, embodiments of the present invention will be described with reference to FIGS. 2 to 5.
陰極缶2はニツケルとステンレスのクラツド板
から作られ、第2図に示すように外側にニツケル
薄層9が内側にステンレス薄層10がそれぞれ配
置されている。この陰極缶2の外表面には、ニツ
ケル薄板からなる長方形の補助リード体11の一
端が予めスポツト溶接12によつて固着される。
この陰極缶2を用いて電池を組立てる訳である
が、電池自動組立装置内での陰極缶2の供給に支
障が起こらないように、すなわち補助リード体1
1が陰極缶2の外周から突出して供給時に陰極缶
2が引掛つたりしないように、補助リード体11
の長さならびに固着位置が配慮されており、しか
も平板状のまま陰極缶2の外表面に密着してい
る。 The cathode can 2 is made of a clad plate of nickel and stainless steel, and as shown in FIG. 2, a thin nickel layer 9 is disposed on the outside and a thin stainless steel layer 10 is disposed on the inside. One end of a rectangular auxiliary lead body 11 made of a thin nickel plate is fixed in advance to the outer surface of the cathode can 2 by spot welding 12.
This cathode can 2 is used to assemble a battery, but the auxiliary lead body 1 is
1 protrudes from the outer periphery of the cathode can 2 and prevents the cathode can 2 from getting caught during supply.
The length and fixing position of the cathode can 2 are taken into consideration, and the cathode can 2 remains in close contact with the outer surface of the cathode can 2 while remaining flat.
この陰極缶2を用いて第4図に示すようなボタ
ン形電池が組立てられる。すなわち前記陰極缶2
の内面には金網7がスポツト溶接によつて固着さ
れ、それに金属リチウムからなる陰極5が圧着さ
れて前記金網7の一部が陰極5に埋設されること
により、陰極缶2と陰極5との電気的な接続なら
びに陰極5の保持がなされる。陰極缶2の外周部
には、合成樹脂の成形品からなるガスケツト6が
密嵌される。 Using this cathode can 2, a button type battery as shown in FIG. 4 is assembled. That is, the cathode can 2
A wire mesh 7 is fixed to the inner surface of the can by spot welding, and a cathode 5 made of metallic lithium is crimped onto the inner surface of the can, and a part of the wire mesh 7 is buried in the cathode 5, thereby creating a connection between the cathode can 2 and the cathode 5. Electrical connections and holding of the cathode 5 are made. A gasket 6 made of a synthetic resin molded product is tightly fitted onto the outer periphery of the cathode can 2 .
一方、二酸化マンガンと電導助剤の混合物から
なる陽極3が陽極缶1の缶底に挿入され、陽極3
の上にポリプロピレン繊維の不織布からなるセパ
レータ4が載置される。その後、前記陰極5なら
びにガスケツト6を保持した陰極缶2が陽極缶1
の開口部に嵌合され、ついで陽極缶1の開口部を
内方に折曲することにより締付けて電池の組立て
を完了する。 On the other hand, an anode 3 made of a mixture of manganese dioxide and a conductive additive is inserted into the bottom of the anode can 1.
A separator 4 made of a nonwoven fabric of polypropylene fibers is placed thereon. Thereafter, the cathode can 2 holding the cathode 5 and gasket 6 is transferred to the anode can 1.
Then, the opening of the anode can 1 is bent inward and tightened to complete the assembly of the battery.
次に第5図に示すように、補助リード体11の
スポツト溶接12がされていない他端の方を折り
曲げによつて起こし、それに陰極側の本リード体
13をスポツト溶接14で接続する。一方、陽極
缶1の下面には、直接陽極側の本リード体15が
スポツト溶接16によつて接続されてリード体付
きのリチウム電池が得られる。 Next, as shown in FIG. 5, the other end of the auxiliary lead body 11 that is not spot welded 12 is bent up and the main lead body 13 on the cathode side is connected to it by spot welding 14. On the other hand, the main lead body 15 on the anode side is directly connected to the lower surface of the anode can 1 by spot welding 16 to obtain a lithium battery with a lead body.
本発明は前述のような構成になつており、電池
を組立てる前に補助リード体が陰極缶に溶接され
るから、溶接時に発生する熱が陰極やセパレータ
に影響することがない。従つて内部短絡を生じる
ことがなく、補助リード体と陰極缶の溶接条件が
任意に選択でき、溶接が確実に行なわれる。な
お、補助リード体と本リード体をスポツト溶接な
どで接続する際には、その溶接個所は陰極から離
れているから、溶接時に発生する熱によつて陰極
が溶融するような懸念はない。 The present invention is constructed as described above, and since the auxiliary lead body is welded to the cathode can before assembling the battery, the heat generated during welding does not affect the cathode or separator. Therefore, internal short circuits do not occur, welding conditions for the auxiliary lead body and the cathode can can be arbitrarily selected, and welding can be performed reliably. Note that when the auxiliary lead body and the main lead body are connected by spot welding or the like, the welding point is separated from the cathode, so there is no concern that the cathode will melt due to the heat generated during welding.
第1図は従来のリード体付きリチウム電池の組
立工程を説明するための一部を切断した正面図、
第2図ないし第5図は本発明の実施例を説明する
ためのもので、第2図および第3図は補助リード
体を固着した陰極缶の断面図ならびに平面図、第
4図はその陰極缶を用いて組立てが完了したリチ
ウム電池の断面図、第5図はそのリチウム電池に
本リード体を接続した状態での一部を断面にした
正面図である。
2……陰極缶、5……陰極、11……補助リー
ド体、12……スポツト溶接、13……本リード
体、14……スポツト溶接。
Fig. 1 is a partially cutaway front view to explain the assembly process of a conventional lithium battery with a lead;
Figures 2 to 5 are for explaining embodiments of the present invention. Figures 2 and 3 are a sectional view and a plan view of a cathode can to which an auxiliary lead body is fixed, and Figure 4 is a cathode can. FIG. 5 is a cross-sectional view of a lithium battery that has been assembled using a can, and FIG. 5 is a partially cut-away front view of the lithium battery with the lead body connected thereto. 2... Cathode can, 5... Cathode, 11... Auxiliary lead body, 12... Spot welding, 13... Main lead body, 14... Spot welding.
Claims (1)
を溶接により固着し、その陰極缶2を用いてリチ
ウム電池を組立て、 その後に前記補助リード体11に本リード体1
3を接続することを特徴とするリード体付きリチ
ウム電池の製法。[Claims] 1. A part of the auxiliary lead body 11 is fixed to the outer surface of the cathode can 2 by welding, a lithium battery is assembled using the cathode can 2, and then the main lead body is attached to the auxiliary lead body 11. 1
A method for manufacturing a lithium battery with a lead body, characterized by connecting 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56134271A JPS5835863A (en) | 1981-08-28 | 1981-08-28 | Manufacture of lithium battery with lead body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56134271A JPS5835863A (en) | 1981-08-28 | 1981-08-28 | Manufacture of lithium battery with lead body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5835863A JPS5835863A (en) | 1983-03-02 |
| JPH023269B2 true JPH023269B2 (en) | 1990-01-23 |
Family
ID=15124381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56134271A Granted JPS5835863A (en) | 1981-08-28 | 1981-08-28 | Manufacture of lithium battery with lead body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5835863A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0644483B2 (en) * | 1983-03-16 | 1994-06-08 | 日立マクセル株式会社 | Flat type lithium battery with lead terminal |
| JP3066338B2 (en) * | 1996-03-27 | 2000-07-17 | 三洋電機株式会社 | Battery |
-
1981
- 1981-08-28 JP JP56134271A patent/JPS5835863A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5835863A (en) | 1983-03-02 |
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