JPH0244048B2 - Chokusetsuhojiharogenkaginshashinkankozairyo - Google Patents
ChokusetsuhojiharogenkaginshashinkankozairyoInfo
- Publication number
- JPH0244048B2 JPH0244048B2 JP4483082A JP4483082A JPH0244048B2 JP H0244048 B2 JPH0244048 B2 JP H0244048B2 JP 4483082 A JP4483082 A JP 4483082A JP 4483082 A JP4483082 A JP 4483082A JP H0244048 B2 JPH0244048 B2 JP H0244048B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- tetrazolium
- silver halide
- present
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 silver halide Chemical class 0.000 claims description 97
- 229910052709 silver Inorganic materials 0.000 claims description 45
- 239000004332 silver Substances 0.000 claims description 45
- 239000000463 material Substances 0.000 claims description 27
- 150000001875 compounds Chemical group 0.000 claims description 15
- 150000001450 anions Chemical class 0.000 claims description 7
- 125000000623 heterocyclic group Chemical group 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000001624 naphthyl group Chemical group 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 125000000732 arylene group Chemical group 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000004181 carboxyalkyl group Chemical group 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 description 23
- 238000000576 coating method Methods 0.000 description 23
- 239000010410 layer Substances 0.000 description 21
- 108010010803 Gelatin Proteins 0.000 description 17
- 239000000839 emulsion Substances 0.000 description 17
- 239000008273 gelatin Substances 0.000 description 17
- 229920000159 gelatin Polymers 0.000 description 17
- 235000019322 gelatine Nutrition 0.000 description 17
- 235000011852 gelatine desserts Nutrition 0.000 description 17
- 239000000243 solution Substances 0.000 description 15
- 238000011161 development Methods 0.000 description 14
- 230000018109 developmental process Effects 0.000 description 14
- 239000007788 liquid Substances 0.000 description 14
- 239000000084 colloidal system Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 230000001681 protective effect Effects 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 125000003831 tetrazolyl group Chemical group 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- KVWRURXFRFEOAA-UHFFFAOYSA-N 3-[4-[2,3-bis[4-(2-carboxyethyl)phenyl]-1h-tetrazol-1-ium-5-yl]phenyl]propanoic acid;chloride Chemical compound [Cl-].C1=CC(CCC(=O)O)=CC=C1N1[NH+](C=2C=CC(CCC(O)=O)=CC=2)N=C(C=2C=CC(CCC(O)=O)=CC=2)N1 KVWRURXFRFEOAA-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 4
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 4
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- NNVNAJGCZFCILW-UHFFFAOYSA-N 1'-methylspiro[3,4-dihydrochromene-2,4'-piperidine]-4-amine;hydrochloride Chemical compound Cl.C1CN(C)CCC21OC1=CC=CC=C1C(N)C2 NNVNAJGCZFCILW-UHFFFAOYSA-N 0.000 description 3
- CDNHHFDCGUXITF-UHFFFAOYSA-N 2,3-diphenyl-5-[4-(2,4,4-trimethylpentan-2-yloxy)phenyl]-1h-tetrazol-1-ium;chloride Chemical compound [Cl-].C1=CC(OC(C)(C)CC(C)(C)C)=CC=C1C1=NN(C=2C=CC=CC=2)N(C=2C=CC=CC=2)[NH2+]1 CDNHHFDCGUXITF-UHFFFAOYSA-N 0.000 description 3
- QDVIEADSFRNGLY-UHFFFAOYSA-N 2-(5-dodecyl-3-phenyl-1h-tetrazol-1-ium-2-yl)-1,3-benzothiazole;bromide Chemical compound [Br-].N1C(CCCCCCCCCCCC)=N[NH+](C=2SC3=CC=CC=C3N=2)N1C1=CC=CC=C1 QDVIEADSFRNGLY-UHFFFAOYSA-N 0.000 description 3
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 3
- 229930182490 saponin Natural products 0.000 description 3
- 235000017709 saponins Nutrition 0.000 description 3
- 150000007949 saponins Chemical class 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 3
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 2
- LBUJPTNKIBCYBY-UHFFFAOYSA-N 1,2,3,4-tetrahydroquinoline Chemical compound C1=CC=C2CCCNC2=C1 LBUJPTNKIBCYBY-UHFFFAOYSA-N 0.000 description 2
- AUIKNBHTYGCEBL-UHFFFAOYSA-N 1-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)ethanone;bromide Chemical compound [Br-].N1C(C(=O)C)=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 AUIKNBHTYGCEBL-UHFFFAOYSA-N 0.000 description 2
- XIVWBKNPROLFNA-UHFFFAOYSA-N 1-[2,3-bis(4-ethoxyphenyl)-1,3-dihydrotetrazol-3-ium-5-yl]ethanone;bromide Chemical compound [Br-].C1=CC(OCC)=CC=C1N1[NH+](C=2C=CC(OCC)=CC=2)N=C(C(C)=O)N1 XIVWBKNPROLFNA-UHFFFAOYSA-N 0.000 description 2
- DCSVXNOJHXOKJQ-UHFFFAOYSA-N 2,3-diphenyl-1h-tetrazol-1-ium-5-carbonitrile;bromide Chemical compound [Br-].N1C(C#N)=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 DCSVXNOJHXOKJQ-UHFFFAOYSA-N 0.000 description 2
- VSXBOKHHCCGVKJ-UHFFFAOYSA-N 2,3-diphenyl-1h-tetrazol-1-ium;chloride Chemical compound [Cl-].[NH2+]1C=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 VSXBOKHHCCGVKJ-UHFFFAOYSA-N 0.000 description 2
- FDFBKUYVYSKJKX-UHFFFAOYSA-N 2-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)-1,3-benzoxazole;bromide Chemical compound [Br-].N1=C(C=2OC3=CC=CC=C3N=2)NN(C=2C=CC=CC=2)[NH+]1C1=CC=CC=C1 FDFBKUYVYSKJKX-UHFFFAOYSA-N 0.000 description 2
- WXECHSIKEZXOTL-UHFFFAOYSA-N 2-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)quinoline;bromide Chemical compound [Br-].N1=C(C=2N=C3C=CC=CC3=CC=2)NN(C=2C=CC=CC=2)[NH+]1C1=CC=CC=C1 WXECHSIKEZXOTL-UHFFFAOYSA-N 0.000 description 2
- YAZMEKFTTBGDCH-UHFFFAOYSA-N 2-(3,5-diphenyl-1h-tetrazol-1-ium-2-yl)-1h-triazine;chloride Chemical compound [Cl-].N1C=CC=NN1N1N(C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)[NH2+]1 YAZMEKFTTBGDCH-UHFFFAOYSA-N 0.000 description 2
- NBWRJAOOMGASJP-UHFFFAOYSA-N 2-(3,5-diphenyl-1h-tetrazol-1-ium-2-yl)-4,5-dimethyl-1,3-thiazole;bromide Chemical compound [Br-].S1C(C)=C(C)N=C1N1N(C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)[NH2+]1 NBWRJAOOMGASJP-UHFFFAOYSA-N 0.000 description 2
- MIPQDTFFRSHLQU-UHFFFAOYSA-N 2-(4-iodophenyl)-3,5-diphenyl-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].C1=CC(I)=CC=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 MIPQDTFFRSHLQU-UHFFFAOYSA-N 0.000 description 2
- GWLWKLATQDTEES-UHFFFAOYSA-N 2-(4-methylphenyl)-3,5-diphenyl-1h-tetrazol-1-ium;chloride Chemical compound [Cl-].C1=CC(C)=CC=C1N1N(C=2C=CC=CC=2)[NH2+]C(C=2C=CC=CC=2)=N1 GWLWKLATQDTEES-UHFFFAOYSA-N 0.000 description 2
- CWPXEQXAHVKIPE-UHFFFAOYSA-N 2-[2-(4-methoxyphenyl)-5-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;bromide Chemical compound [Br-].C1=CC(OC)=CC=C1N1[NH+](C=2SC3=CC=CC=C3N=2)N=C(C=2C=CC=CC=2)N1 CWPXEQXAHVKIPE-UHFFFAOYSA-N 0.000 description 2
- KRKQPRJQBTVZNQ-UHFFFAOYSA-N 2-[2-(4-methylphenyl)-5-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;bromide Chemical compound [Br-].C1=CC(C)=CC=C1N1[NH+](C=2SC3=CC=CC=C3N=2)N=C(C=2C=CC=CC=2)N1 KRKQPRJQBTVZNQ-UHFFFAOYSA-N 0.000 description 2
- KAOXCMHGMWDTBV-UHFFFAOYSA-N 2-[5-(2-chlorophenyl)-2-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;bromide Chemical compound [Br-].ClC1=CC=CC=C1C1=N[NH+](C=2SC3=CC=CC=C3N=2)N(C=2C=CC=CC=2)N1 KAOXCMHGMWDTBV-UHFFFAOYSA-N 0.000 description 2
- BLWMNAXCPBTEKO-UHFFFAOYSA-N 2-[5-(4-chlorophenyl)-2-(4-nitrophenyl)-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;chloride Chemical compound [Cl-].C1=CC([N+](=O)[O-])=CC=C1N1[NH+](C=2SC3=CC=CC=C3N=2)N=C(C=2C=CC(Cl)=CC=2)N1 BLWMNAXCPBTEKO-UHFFFAOYSA-N 0.000 description 2
- LPYUENQFPVNPHY-UHFFFAOYSA-N 3-methoxycatechol Chemical compound COC1=CC=CC(O)=C1O LPYUENQFPVNPHY-UHFFFAOYSA-N 0.000 description 2
- UAYRQYDAMDWXHD-UHFFFAOYSA-N 4-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)benzonitrile;chloride Chemical compound [Cl-].C1=CC(C#N)=CC=C1C1=N[NH+](C=2C=CC=CC=2)N(C=2C=CC=CC=2)N1 UAYRQYDAMDWXHD-UHFFFAOYSA-N 0.000 description 2
- IBPCVKATPZNICN-UHFFFAOYSA-N 4-(2,3-diphenyl-1h-tetrazol-1-ium-5-yl)pyridine;chloride Chemical compound [Cl-].N1N(C=2C=CC=CC=2)[NH+](C=2C=CC=CC=2)N=C1C1=CC=NC=C1 IBPCVKATPZNICN-UHFFFAOYSA-N 0.000 description 2
- PFYCIJQCNQPOTG-UHFFFAOYSA-N 4-(5-methyl-2-phenyl-1h-tetrazol-1-ium-3-yl)phenol;bromide Chemical compound [Br-].N1C(C)=N[NH+](C=2C=CC=CC=2)N1C1=CC=C(O)C=C1 PFYCIJQCNQPOTG-UHFFFAOYSA-N 0.000 description 2
- XCTSQILHZOXJKI-UHFFFAOYSA-N 4-[5-(4-nitrophenyl)-3-phenyl-1,3-dihydrotetrazol-3-ium-2-yl]phenol;chloride Chemical compound [Cl-].C1=CC(O)=CC=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC(=CC=2)[N+]([O-])=O)N1 XCTSQILHZOXJKI-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 2
- LTRYTFOYRKRJLU-UHFFFAOYSA-N 5-(3,4-dimethoxyphenyl)-2-(2-ethoxyphenyl)-3-(4-methoxyphenyl)-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].CCOC1=CC=CC=C1N1[NH+](C=2C=CC(OC)=CC=2)N=C(C=2C=C(OC)C(OC)=CC=2)N1 LTRYTFOYRKRJLU-UHFFFAOYSA-N 0.000 description 2
- YUUSISNBOVSHOI-UHFFFAOYSA-N 5-(4-bromophenyl)-3-phenyl-2-(2,4,6-trichlorophenyl)-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].ClC1=CC(Cl)=CC(Cl)=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC(Br)=CC=2)N1 YUUSISNBOVSHOI-UHFFFAOYSA-N 0.000 description 2
- QGOXSINMNRFRIG-UHFFFAOYSA-N 5-[2,3-diphenyl-4-(1h-tetrazol-1-ium-5-yl)butyl]-2,3-diphenyl-1h-tetrazol-1-ium;dibromide Chemical compound [Br-].[Br-].N=1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)[NH2+]C=1CC(C=1C=CC=CC=1)C(C=1C=CC=CC=1)CC=1N=NN[NH+]=1 QGOXSINMNRFRIG-UHFFFAOYSA-N 0.000 description 2
- CGVKBQYLTCVWCQ-UHFFFAOYSA-N 5-[2,3-diphenyl-4-(2h-tetrazol-1-ium-5-yl)phenyl]-2,3-diphenyl-1h-tetrazol-1-ium;dibromide Chemical compound [Br-].[Br-].[NH2+]1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C(C(=C1C=2C=CC=CC=2)C=2C=CC=CC=2)=CC=C1C=1N=NN[NH+]=1 CGVKBQYLTCVWCQ-UHFFFAOYSA-N 0.000 description 2
- DCWMUNBEDANGRF-UHFFFAOYSA-N 5-ethyl-2,3-diphenyl-1h-tetrazol-1-ium;bromide Chemical compound [Br-].N1C(CC)=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 DCWMUNBEDANGRF-UHFFFAOYSA-N 0.000 description 2
- HNFYQHZMFHWWGF-UHFFFAOYSA-N 5-hexyl-2,3-diphenyl-1h-tetrazol-1-ium;bromide Chemical compound [Br-].N1C(CCCCCC)=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 HNFYQHZMFHWWGF-UHFFFAOYSA-N 0.000 description 2
- BVWKGLFOHGTBOH-UHFFFAOYSA-N 5-nitro-2,3-diphenyl-1h-tetrazol-1-ium;bromide Chemical compound [Br-].N1C([N+](=O)[O-])=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 BVWKGLFOHGTBOH-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- DQQCYDBRDWWUBN-UHFFFAOYSA-N ethyl 2,3-bis(3-nitrophenyl)-1,3-dihydrotetrazol-3-ium-5-carboxylate;chloride Chemical compound [Cl-].N1C(C(=O)OCC)=N[NH+](C=2C=C(C=CC=2)[N+]([O-])=O)N1C1=CC=CC([N+]([O-])=O)=C1 DQQCYDBRDWWUBN-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 150000002344 gold compounds Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000006224 matting agent Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 2
- YWCNUPQVGSTATJ-UHFFFAOYSA-N n-[4-(3,5-diphenyl-1,3-dihydrotetrazol-3-ium-2-yl)phenyl]acetamide;bromide Chemical compound [Br-].C1=CC(NC(=O)C)=CC=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 YWCNUPQVGSTATJ-UHFFFAOYSA-N 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 2
- 235000019252 potassium sulphite Nutrition 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229940079877 pyrogallol Drugs 0.000 description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000005070 ripening Effects 0.000 description 2
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
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- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- QQPSGKLPTFKHCN-UHFFFAOYSA-N n-(4-benzamido-2,5-dihydroxyphenyl)benzamide Chemical compound OC=1C=C(NC(=O)C=2C=CC=CC=2)C(O)=CC=1NC(=O)C1=CC=CC=C1 QQPSGKLPTFKHCN-UHFFFAOYSA-N 0.000 description 1
- NPKFETRYYSUTEC-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide Chemical compound CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 NPKFETRYYSUTEC-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 125000002971 oxazolyl group Chemical group 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000714 pyrimidinyl group Chemical group 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003459 sulfonic acid esters Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- AKXUUJCMWZFYMV-UHFFFAOYSA-M tetrakis(hydroxymethyl)phosphanium;chloride Chemical compound [Cl-].OC[P+](CO)(CO)CO AKXUUJCMWZFYMV-UHFFFAOYSA-M 0.000 description 1
- 125000000335 thiazolyl group Chemical group 0.000 description 1
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/485—Direct positive emulsions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
Description
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Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžèšäžè¬åŒãããŸãã¯ããã§ç€ºãããã
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Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4483082A JPH0244048B2 (ja) | 1982-03-19 | 1982-03-19 | Chokusetsuhojiharogenkaginshashinkankozairyo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4483082A JPH0244048B2 (ja) | 1982-03-19 | 1982-03-19 | Chokusetsuhojiharogenkaginshashinkankozairyo |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58160949A JPS58160949A (ja) | 1983-09-24 |
| JPH0244048B2 true JPH0244048B2 (ja) | 1990-10-02 |
Family
ID=12702372
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4483082A Expired - Lifetime JPH0244048B2 (ja) | 1982-03-19 | 1982-03-19 | Chokusetsuhojiharogenkaginshashinkankozairyo |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0244048B2 (ja) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60126645A (ja) * | 1983-12-13 | 1985-07-06 | Konishiroku Photo Ind Co Ltd | æ宀çšçŽæ¥ããžããã²ã³åéåçæå ææã«ããç»å圢ææ¹æ³ |
| JPS6364040A (ja) * | 1986-09-04 | 1988-03-22 | Konica Corp | ä¿åæ§çãæ¹è¯ãããé«ã³ã³ãã©ã¹ãããã²ã³åéåçæå ææ |
| JPS63106645A (ja) * | 1986-10-22 | 1988-05-11 | Konica Corp | ä¿åå®å®æ§çãæ¹è¯ãããããã²ã³åéåçæå ææ |
| JP4929494B2 (ja) * | 2006-12-22 | 2012-05-09 | åœç«å€§åŠæ³äººçŠäºå€§åŠ | å°äžç±å©çšã®åŸªç°ååžæŸç±è£ 眮 |
-
1982
- 1982-03-19 JP JP4483082A patent/JPH0244048B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58160949A (ja) | 1983-09-24 |
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