JPH0250798B2 - - Google Patents
Info
- Publication number
- JPH0250798B2 JPH0250798B2 JP18727383A JP18727383A JPH0250798B2 JP H0250798 B2 JPH0250798 B2 JP H0250798B2 JP 18727383 A JP18727383 A JP 18727383A JP 18727383 A JP18727383 A JP 18727383A JP H0250798 B2 JPH0250798 B2 JP H0250798B2
- Authority
- JP
- Japan
- Prior art keywords
- jelly
- descaling
- water
- parts
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000015110 jellies Nutrition 0.000 claims description 21
- 239000008274 jelly Substances 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 229920001218 Pullulan Polymers 0.000 claims description 11
- 239000004373 Pullulan Substances 0.000 claims description 11
- 235000019423 pullulan Nutrition 0.000 claims description 11
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 6
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 claims description 3
- 235000010261 calcium sulphite Nutrition 0.000 claims description 3
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 2
- 235000010265 sodium sulphite Nutrition 0.000 claims description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 description 5
- 235000011194 food seasoning agent Nutrition 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 240000007087 Apium graveolens Species 0.000 description 1
- 235000015849 Apium graveolens Dulce Group Nutrition 0.000 description 1
- 235000010591 Appio Nutrition 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229940001482 sodium sulfite Drugs 0.000 description 1
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- -1 thiosulfate ions Chemical class 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Landscapes
- Removal Of Specific Substances (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Description
【発明の詳細な説明】
本発明は水のカルキを微量で効果的に除去する
ゼリー状水質改善剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a jelly-like water quality improving agent that effectively removes a trace amount of limescale from water.
本発明の目的は、(i)微量で大量の水の脱カルキ
処理が行え、(ii)無味無臭で人内に無害で、(iii)しか
も処理操作が容易に行えるという脱カルキ物質を
提供せんとするものである。 The purpose of the present invention is to provide a descaling substance that (i) can decalcify a small amount of water in a large amount, (ii) is tasteless and odorless and harmless to humans, and (iii) can be easily processed. That is.
この発明の要旨は、プルラン100重量部に対し
亜硫酸ナトリウム、チオ硫酸ナトリウム又は亜硫
酸カルシウムを含有する粉状又は結晶性脱カルキ
性薬品を70〜500重量部と、水を50〜200重量部と
を混合して流動状乃至半固状としたことを特徴と
する脱カルキ性ゼリーにある。本発明の脱カルキ
性ゼリーに更に種々の添加物、調味性薬品を混合
することも本発明に包含されるものである。添加
物としては繊維細片等のゼリーの流動性抑制剤、
強度保持剤、増量剤及びアラビヤゴム、メチルセ
ルロース、アルギン酸ナトリウム等の粘度接着性
調整剤、並びに殿粉、セルローズ、水ガラス、石
膏等のゼリーの溶解度を調整する難溶性物質等が
あり、適宜適量目的、用途に応じて混入される。
又調味性薬品は積極的に水に味を与えるための物
質であつて、クエン酸、コハク酸、甘味剤、調味
剤、水酸化カルシウム等がある。ここでプルラン
（化学一般名）とはマニトトリオースがα−１，
６結合で繰返した線状構造の天然多糖類で
（C6H10O5）o・H2Oの分子構造物である。又脱カ
ルキ性薬品としては無水亜硫酸ナトリウム結晶、
チオ硫酸ナトリウム５水塩または粉状無水チオ硫
酸ナトリウム、粉状無水亜硫酸カルシウム等があ
り、亜硫酸イオン、チオ硫酸イオンを得ることが
出来る薬品である。 The gist of this invention is that 70 to 500 parts by weight of a powdery or crystalline decalcifying agent containing sodium sulfite, sodium thiosulfate, or calcium sulfite and 50 to 200 parts by weight of water are added to 100 parts by weight of pullulan. A descaling jelly characterized by being mixed into a fluid or semi-solid state. The present invention also includes the addition of various additives and seasoning chemicals to the descaling jelly of the present invention. Additives include jelly fluidity inhibitors such as fiber strips,
There are strength maintaining agents, fillers, viscosity and adhesiveness modifiers such as gum arabic, methyl cellulose, and sodium alginate, and sparingly soluble substances that adjust the solubility of jelly such as starch, cellulose, water glass, and gypsum. It is mixed depending on the purpose.
Seasoning chemicals are substances that actively impart flavor to water, such as citric acid, succinic acid, sweeteners, seasonings, and calcium hydroxide. Here, pullulan (common chemical name) is manitotriose with α-1,
It is a natural polysaccharide with a linear structure consisting of six repeating bonds and a molecular structure of (C 6 H 10 O 5 ) o ·H 2 O. Also, as descaling chemicals, anhydrous sodium sulfite crystals,
There are sodium thiosulfate pentahydrate, powdered anhydrous sodium thiosulfate, powdered anhydrous calcium sulfite, etc., which are chemicals that can obtain sulfite ions and thiosulfate ions.
本発明の脱カルキ性ゼリーでは脱カルキ性薬品
１は大部分の結晶又は無定形の粒乃至粉体として
プルラン水溶液２内に混在分散している（第１図
参照）。そのため薬品のプルラン水溶液２で保護
された状態にあつて酸、アルカリに対して経時的
に安定である。しかもプルラン水溶液の外表面は
乾燥して酸素不透過性膜となつて外皮を形成して
いて、セリー内部の薬品の空気酸化を抑制してい
る。次にプルランゼリーはプルランが易水溶性の
ためゼリーを水中に入れるとゼリーの表皮が速や
かに溶けて内部の脱カルキ性薬品、添加物、調味
性薬品が溶け出す。又水中からゼリーを引上げれ
ばゼリーの表面は短時間に乾燥して元の外皮状態
に復する。 In the descaling jelly of the present invention, the descaling chemical 1 is mixed and dispersed in the pullulan aqueous solution 2 as most of crystals or amorphous particles or powder (see FIG. 1). Therefore, it is in a state protected by the chemical pullulan aqueous solution 2 and is stable against acids and alkalis over time. Moreover, the outer surface of the pullulan aqueous solution dries to form an oxygen-impermeable membrane, which suppresses air oxidation of the chemicals inside the celery. Next, since pullulan jelly is easily water-soluble, when the jelly is placed in water, the outer layer of the jelly will quickly dissolve and the descaling chemicals, additives, and seasoning chemicals inside will dissolve. Moreover, when the jelly is pulled out of water, the surface of the jelly dries in a short time and returns to its original shell state.
更に本ゼリーはプルラン水溶液２が接着力があ
るため各種の材質、形態の器物に塗着して使用で
きるので使用が容易である。尚その粘度（ゼリー
の固さ、流動性）はプルランの濃度、粘度調整剤
で適宜調整できる。 Furthermore, this jelly is easy to use because the pullulan aqueous solution 2 has adhesive strength and can be applied to various types of utensils and materials. The viscosity (jelly hardness and fluidity) can be adjusted as appropriate by adjusting the concentration of pullulan and a viscosity modifier.
実施例
プルラン100重量部に無水亜硫酸ナトリウム粉
抹を300重量部、水100重量部の割合で混合した脱
カルキ性ゼリー３をマドラー６に付着させて水道
水４を入れたコツプ５内で軽くひとまぜするだけ
で水道水４内のカルキが瞬時に消滅した（カルキ
の存在はヨード殿粉の呈色反応によつて現象を観
察した）。しかも本実施例脱カルキ性ゼリー0.3ｇ
でコツプ100杯の水を処理出来る程の効果があつ
た。Example: Descaling jelly 3, which is a mixture of 100 parts by weight of pullulan, 300 parts by weight of anhydrous sodium sulfite powder, and 100 parts by weight of water, is attached to a stirrer 6, and then gently stirred in a cup 5 containing 4 parts of tap water. Just by mixing, the limescale in the tap water 4 disappeared instantly (the presence of limescale was observed through the color reaction of iodine starch). Moreover, 0.3g of the descaling jelly of this example
It was so effective that it could treat 100 cups of water.
以上の様に本発明脱カルキ性ゼリーによれば、
(i)微量をもつて多量の水のカルキを除去でき、(ii)
無味無臭で体に無害であり、(iii)水中に軽くかきま
ぜるだけで水に瞬間的に浴解でき速効性があり、
(iv)ゼリーの表皮が酸素を通しにくいのでゼリー内
部の脱カルキ性薬品等薬品の経時的空気酸化が抑
制される。(v)また、ゼリーは接着力があるので各
種の材質、形態の器物に塗着して使用でき、(vi)そ
の粘度、溶解度の調整は容易且つ自在に出来ると
いう優れた効果がある。 As described above, according to the descaling jelly of the present invention,
(i) It is possible to remove scale from a large amount of water with a small amount; (ii)
It is tasteless and odorless and harmless to the body, and (iii) it is fast-acting as it can be instantly dissolved in water by just stirring it lightly in water.
(iv) Since the outer skin of the jelly is difficult for oxygen to pass through, air oxidation of chemicals such as descaling chemicals inside the jelly is suppressed over time. (v) Also, since jelly has adhesive strength, it can be used by applying it to objects of various materials and shapes, and (vi) its viscosity and solubility can be easily and freely adjusted, which is an excellent effect.
第１図は本発明脱カルキ性ゼリーの組織説明
図、第２図は実施例の溶解実験を示す説明図であ
る。
１：脱カルキ性薬品、２：プルラン水溶液、
３：ゼリー、４：水道水、５：コツプ、６：マド
ラー。
FIG. 1 is an explanatory diagram of the structure of the descaling jelly of the present invention, and FIG. 2 is an explanatory diagram showing the dissolution experiment of the example. 1: Descaling chemical, 2: Pullulan aqueous solution,
3: Jelly, 4: Tap water, 5: Cotup, 6: Muddler.
Claims (1)
チオ硫酸ナトリウム又は亜硫酸カルシウムを含有
する粉状又は結晶性脱カルキ性薬品を70〜500重
量部と、水を50〜200重量部とを混合して流動状
乃至半固状としたことを特徴とする脱カルキ性ゼ
リー。1 Sodium sulfite per 100 parts by weight of pullulan,
It is characterized by mixing 70 to 500 parts by weight of a powdered or crystalline descaling chemical containing sodium thiosulfate or calcium sulfite and 50 to 200 parts by weight of water to form a fluid or semi-solid state. Descaling jelly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18727383A JPS6078694A (en) | 1983-10-05 | 1983-10-05 | Bleaching powder removing jelly |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18727383A JPS6078694A (en) | 1983-10-05 | 1983-10-05 | Bleaching powder removing jelly |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6078694A JPS6078694A (en) | 1985-05-04 |
| JPH0250798B2 true JPH0250798B2 (en) | 1990-11-05 |
Family
ID=16203101
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18727383A Granted JPS6078694A (en) | 1983-10-05 | 1983-10-05 | Bleaching powder removing jelly |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6078694A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04128041U (en) * | 1991-05-02 | 1992-11-20 | 株式会社日幸電機製作所 | Phase loss protection circuit breaker |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006289208A (en) * | 2005-04-07 | 2006-10-26 | Jipangu Project Kk | Method for removing residual chlorine and removing material therefor |
| JP4584791B2 (en) * | 2005-08-03 | 2010-11-24 | 芳聰 前田 | Stirring bar for turbid water coagulation sedimentation |
-
1983
- 1983-10-05 JP JP18727383A patent/JPS6078694A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04128041U (en) * | 1991-05-02 | 1992-11-20 | 株式会社日幸電機製作所 | Phase loss protection circuit breaker |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6078694A (en) | 1985-05-04 |
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