JPH0250981B2 - - Google Patents
Info
- Publication number
- JPH0250981B2 JPH0250981B2 JP59191930A JP19193084A JPH0250981B2 JP H0250981 B2 JPH0250981 B2 JP H0250981B2 JP 59191930 A JP59191930 A JP 59191930A JP 19193084 A JP19193084 A JP 19193084A JP H0250981 B2 JPH0250981 B2 JP H0250981B2
- Authority
- JP
- Japan
- Prior art keywords
- wire
- symbol
- less
- toughness
- wear resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Impact Printers (AREA)
- Heat Treatment Of Steel (AREA)
Description
本発明は、ドツト・プリンター用ワイヤーに係
り、極細線とするための伸線加工が非常に容易で
あり、また熱処理も簡単であり、しかも強靭性並
びに耐摩耗性の優れたドツト・プリンター用ワイ
ヤーに関するものである。
ドツト・プリンターは、複数本のワイヤーを作
動して、所定の文字或いは数字を印字するもの
で、その印字速度が非常に速いという特長を有し
ている。プリントワイヤーとしては、耐摩耗性が
大きく、しかも強靭であり、疲労強度が大きいこ
と、伸線加工並びに熱処理の簡単なこと、及び耐
食性の良好なことが要求される。
現在、プリントワイヤーには、高速度鋼線の焼
入極細線が主として使用されている。高速度鋼線
は、引抜伸線を繰返して極細線としたワイヤー
を、焼入れ、焼もどしたのち切断して製造される
が、高速度鋼を極細線とするために長い伸線工程
を必要とするため価格が高くなる欠点がある。ま
た、耐摩耗性には優れているが靭性が不足気味
で、使用中、折損を生ずることがある。
本発明は、これらの問題に鑑みてなされたもの
であり、極細線とするための伸線加工が非常に容
易であり、また硬化熱処理が簡単で、しかも強性
並びに耐摩耗性の優れたドツト・プリンター用ワ
イヤーを提供することを目的とする。
即ち、本発明は、C0.04〜0.20%、Si0.10%以
下、Mn0.10%以下、Ni16.0〜19.0%、Mo3.0〜
6.0%、Co7.0〜13.0%、Al0.05〜0.20%、Ti0.50
〜1.90%残部鉄及び不純物よりなる鋼によつて構
成されており、その伸線コイルを約820℃に加熱
して水冷する溶体化処理を行なつた後、減面率約
90%まで伸線し、次いで、溶体化処理を行ない、
引続き約90%減面率の伸線を行なうという工程を
繰返して直径を細くし、最後に減面率約90%の伸
線加工を施して、直径0.3mm前後の所定の寸法の
ワイヤーとし更にその後、480℃前後で3h(時間)
前後の時効処理を行なつて、Hv700以上に析出硬
化させることにより、強靭性並びに耐摩耗性とも
に優れた性能を有する。
次に、本発明ドツト・プリンター用ワイヤーの
組成限定理由を述べる。CはTiと結合して硬い
特殊炭化物TiCを形成し、耐摩耗性の向上に有効
であるが0.04%未満ではその効果小さく、またC
が0.20%をこえると靭性を害するので0.04〜0.20
%とした。SiおよびMnは脱酸効果を有するが、
0.10%をこえると靭性が低下するので、それぞれ
0.1%以下とした。Niはマルテンサイト組織とす
るために必要であり、またマルテンサイトを時効
温度まで安定させるのに必要であるが、16%未満
ではその効果少なく、また19%をこえると残留オ
ーステナイトがあらわれるので16.0〜19.0%とし
た。Moは金属間化合物をつくり、時効処理によ
つて析出硬化を生ずるのに必要であるが、3%未
満ではその効果少なく、また6%をこえると靭性
を低下するので3.0〜6.0%とした。CoはMoによ
る析出硬化を促進させる効果を有するが、7%未
満ではその効果少なく、また13%をこえても効果
の向上が小さいので7.0〜13.0%とした。Alは脱
酸剤として添加し、また時効硬化特性を改善する
ので0.05〜0.20%とした。Tiは金属間化合物
Ni3Tiを形成し、析出硬化を生ずるのに必要であ
り、またCと結合して特殊炭化物を形成し、耐摩
耗性を向上するが、0.50%未満ではその効果少な
く、また1.9%をこえると靭性が低下するので0.5
〜1.9%とした。
本組成の鋼は、約820℃水冷の溶体化処理によ
つて、特殊炭化物TiCの分散した低炭素マルテン
サイトとなり、硬さはHRC30〜35と比較的軟らか
いので引抜伸線加工が容易であり、中間の溶体化
処理なしで減面率約95%までの冷間引抜伸線が可
能である。このように、減面率70%以上の強度の
冷間伸線を行なつた後、480℃×3h(時間)時効
処理を行なうと、HV700〜750の高い硬さに析出
硬化する。
即ち、本組成の鋼は析出硬化によつてHV700〜
750となつた低炭素マルテンサイト基質に、硬い
特殊炭化物TiC粒子の分散した組織となるため、
強靭性と耐摩耗性を兼ね備えることができる。
次に本発明の効果を実施例によつて説明する。
第1表は本発明ワイヤーとSKH9製ワイヤーの化
学組成を示す。
The present invention relates to a wire for dot printers, which is extremely easy to draw into ultra-fine wires, can be easily heat treated, and has excellent toughness and wear resistance. It is related to. Dot printers operate multiple wires to print predetermined characters or numbers, and are characterized by extremely fast printing speeds. Printed wires are required to have high abrasion resistance, high toughness, high fatigue strength, easy wire drawing and heat treatment, and good corrosion resistance. Currently, hardened ultrafine high-speed steel wires are mainly used for print wires. High-speed steel wire is manufactured by repeatedly drawing and drawing wire into ultra-fine wire, quenching and tempering it, and then cutting it. However, a long wire-drawing process is required to make high-speed steel wire into ultra-fine wire. This has the disadvantage of increasing the price. Also, although it has excellent wear resistance, it lacks toughness and may break during use. The present invention was made in view of these problems, and it provides a dot that is extremely easy to draw into ultra-fine wire, easy to heat cure, and has excellent strength and wear resistance.・The purpose is to provide wire for printers. That is, the present invention provides C0.04~0.20%, Si0.10% or less, Mn0.10% or less, Ni16.0~19.0%, Mo3.0~
6.0%, Co7.0~13.0%, Al0.05~0.20%, Ti0.50
It is composed of steel with ~1.90% balance iron and impurities, and after the wire drawing coil is subjected to solution treatment by heating it to approximately 820℃ and cooling it with water, the area reduction rate is approximately
Wire drawing to 90%, then solution treatment,
Next, the process of drawing the wire with an area reduction rate of about 90% is repeated to make the diameter thinner, and finally the wire is drawn with an area reduction rate of about 90% to make the wire into a predetermined size of around 0.3 mm in diameter. After that, 3 hours (hours) at around 480℃
By performing pre- and post-aging treatments and precipitation hardening to Hv700 or higher, it has excellent performance in both toughness and wear resistance. Next, the reasons for limiting the composition of the wire for dot printers of the present invention will be described. C combines with Ti to form a hard special carbide, TiC, and is effective in improving wear resistance, but if it is less than 0.04%, the effect is small;
If it exceeds 0.20%, it will damage the toughness, so 0.04 to 0.20
%. Si and Mn have a deoxidizing effect, but
If it exceeds 0.10%, the toughness decreases, so each
It was set to 0.1% or less. Ni is necessary to form a martensitic structure and to stabilize martensite up to the aging temperature, but if it is less than 16%, the effect will be small, and if it exceeds 19%, retained austenite will appear, so 16.0~ It was set at 19.0%. Mo is necessary to form an intermetallic compound and cause precipitation hardening by aging treatment, but if it is less than 3%, the effect will be small, and if it exceeds 6%, the toughness will decrease, so it is set at 3.0 to 6.0%. Co has the effect of accelerating precipitation hardening due to Mo, but if it is less than 7%, the effect is small, and if it exceeds 13%, the improvement in the effect is small, so it is set at 7.0 to 13.0%. Al was added as a deoxidizing agent and also improved the age hardening properties, so it was set at 0.05 to 0.20%. Ti is an intermetallic compound
It is necessary to form Ni 3 Ti and cause precipitation hardening, and also combines with C to form a special carbide to improve wear resistance, but if it is less than 0.50%, the effect is small, and if it exceeds 1.9%. 0.5 because the toughness decreases.
~1.9%. Steel with this composition undergoes water-cooling solution treatment at approximately 820°C to become low-carbon martensite with dispersed special carbide TiC, and has a relatively soft hardness of H R C30 to 35, making it easy to draw and draw. Cold drawing with an area reduction of up to 95% is possible without intermediate solution treatment. In this manner, after performing cold wire drawing with a strength of 70% or more in area reduction, aging treatment at 480° C. for 3 hours results in precipitation hardening to a high hardness of HV 700 to 750. In other words, steel with this composition has a H V of 700~ due to precipitation hardening.
750, which has a structure in which hard special carbide TiC particles are dispersed in the low carbon martensite matrix.
It can have both toughness and wear resistance. Next, the effects of the present invention will be explained using examples.
Table 1 shows the chemical composition of the wire of the present invention and the wire made of SKH9.
【表】
記号Aは本発明に係る組成を有するワイヤーを
示し、記号BはSKH9ワイヤーを示す。記号Bの
SKH9は中間焼鈍なしに冷間引抜伸線できるのは
減面率30〜40%であるので、SKH9の5.5mmφか
ら0.3mmφワイヤーまで伸線するのに必要な中間
焼鈍は12〜6回である。これに対し、記号Aの鋼
は減面率約90%まで中間溶体化なしに伸線可能で
あるので、5.5mmφコイルから、0.3mmφワイヤー
まで引抜伸線するのに必要な中間溶体化は、僅か
3回である。このように記号Aは、ワイヤーとす
るための伸線加工が非常に容易である。[Table] Symbol A indicates a wire having a composition according to the present invention, and symbol B indicates a SKH9 wire. symbol B
SKH9 can be cold drawn without intermediate annealing with an area reduction rate of 30 to 40%, so intermediate annealing is required 12 to 6 times to draw SKH9 from 5.5 mmφ to 0.3 mmφ wire. . On the other hand, steel with symbol A can be drawn without intermediate solution treatment up to an area reduction of approximately 90%, so the intermediate solution treatment required to draw from a 5.5 mmφ coil to a 0.3 mmφ wire is as follows: Only 3 times. In this way, symbol A is very easy to draw into a wire.
【表】
第2表は0.3mmφワイヤーの熱処理硬さ及びプ
リントワイヤーとして106回槌打試験を行なつた
後の折損率を示す。即ち、記号Aは、伸線コイル
を820℃溶体化処理後90%減面率の冷間伸線を行
なつて0.3mmφとしたのち、480℃×3h(時間)の
時効処理をして、HV730に析出硬化させたもので
ある。この記号Aと記号Bのプリンターワイヤー
を106回槌打試験した結果、記号Bの折損率が15
%であつたのに対し、記号Aは折損率0%であ
り、本発明ワイヤーが強靭性に優れていることが
わかる。また耐摩耗性も記号Aは記号Bとほぼ同
等に良好である。
以上説明したように、本発明はC0.04〜0.20%、
Si0.10%以下、Mn0.10%以下、Ni16.0〜19.0%、
Mo3.0〜6.0%、Co7.0〜13.0%、Al0.05〜0.20%、
Ti0.50〜1.90%残部鉄及び不純物よりなる鋼の伸
線コイルによつて形成されたことを特徴とするド
ツト・プリンター用ワイヤーであり、強靭性並び
に耐摩耗性に優れた性能を有するものである。[Table] Table 2 shows the heat treatment hardness of the 0.3 mmφ wire and the breakage rate after performing the hammering test 10 6 times as a printed wire. In other words, symbol A is a wire drawn coil that is solution-treated at 820°C, then cold-drawn with a 90% reduction in area to a diameter of 0.3 mm, and then subjected to aging treatment at 480°C for 3 hours (hours). Precipitation hardened to H V 730. As a result of the hammering test of these printer wires with symbol A and symbol B 106 times, the breakage rate of symbol B was 15
%, whereas symbol A has a breakage rate of 0%, indicating that the wire of the present invention has excellent toughness. In addition, the wear resistance of symbol A is almost as good as symbol B. As explained above, the present invention has C0.04 to 0.20%,
Si0.10% or less, Mn0.10% or less, Ni16.0~19.0%,
Mo3.0~6.0%, Co7.0~13.0%, Al0.05~0.20%,
This wire for dot printers is characterized by being formed from a drawn coil of steel with Ti0.50 to 1.90% balance iron and impurities, and has excellent performance in toughness and wear resistance. be.
Claims (1)
Mn0.10%以下、Ni16.0〜19.0%、Mo3.0〜6.0%、
Co7.0〜13.0%、Al0.05〜0.20%、Ti0.50〜1.90
%、残部鉄および不純物よりなる鋼の伸線コイル
によつて形成されたことを特徴とする強靭性並び
に耐摩耗性の優れたドツト・プリンター用ワイヤ
ー。1% by weight, C0.04-0.20%, Si0.10% or less,
Mn0.10% or less, Ni16.0~19.0%, Mo3.0~6.0%,
Co7.0~13.0%, Al0.05~0.20%, Ti0.50~1.90
A wire for dot printers having excellent toughness and wear resistance, characterized in that it is formed from a drawn coil of steel, the balance being iron and impurities.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59191930A JPS6169919A (en) | 1984-09-13 | 1984-09-13 | Wire for dot printer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59191930A JPS6169919A (en) | 1984-09-13 | 1984-09-13 | Wire for dot printer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6169919A JPS6169919A (en) | 1986-04-10 |
| JPH0250981B2 true JPH0250981B2 (en) | 1990-11-06 |
Family
ID=16282809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59191930A Granted JPS6169919A (en) | 1984-09-13 | 1984-09-13 | Wire for dot printer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6169919A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2750139B2 (en) * | 1989-01-10 | 1998-05-13 | プレパイ工業株式会社 | Miscellaneous wastewater purification equipment |
| CN109207853B (en) * | 2018-09-30 | 2019-11-22 | 东北大学 | A kind of high wear resistance martensitic wear-resistant steel plate and its manufacturing method |
-
1984
- 1984-09-13 JP JP59191930A patent/JPS6169919A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6169919A (en) | 1986-04-10 |
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