JPH0254311B2 - - Google Patents
Info
- Publication number
- JPH0254311B2 JPH0254311B2 JP9679483A JP9679483A JPH0254311B2 JP H0254311 B2 JPH0254311 B2 JP H0254311B2 JP 9679483 A JP9679483 A JP 9679483A JP 9679483 A JP9679483 A JP 9679483A JP H0254311 B2 JPH0254311 B2 JP H0254311B2
- Authority
- JP
- Japan
- Prior art keywords
- concrete
- parts
- weight
- water
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010410 layer Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000003822 epoxy resin Substances 0.000 claims description 14
- 229920000647 polyepoxide Polymers 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 9
- 239000004568 cement Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000002344 surface layer Substances 0.000 claims description 4
- 239000002861 polymer material Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- GNPWYHFXSMINJQ-UHFFFAOYSA-N 1,2-dimethyl-3-(1-phenylethyl)benzene Chemical compound C=1C=CC(C)=C(C)C=1C(C)C1=CC=CC=C1 GNPWYHFXSMINJQ-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
【発明の詳細な説明】
この発明は、コンクリート構造物を高分子材料
により舗装するに当り、特に、ブリスター現象を
有効に防止しうるプライマー層を形成する表面舗
装方法を提供するものである。
コンクリート構造物の内外装にエポキシ樹脂や
ウレタン樹脂などの合成樹脂塗料、ゴム材料や塩
化ビニルなどの長尺床材、プラスチツクタイルな
どが下地コンクリート面の舗装には従来から使わ
れている。
一般に、コンクリート構造物が低水位地域、湿
地帯、排水不良地域などに建築された場合、地中
の水分がセメントコンクリート中の微細空隙や亀
裂を通して浸透し、床面や壁面の下地コンクリー
ト内に多量の水分が含浸されることは良く知られ
ている。また、打設コンクリートの乾燥不足の場
合も同様な現象が起こりうる。
このような下地コンクリート面に、前記のよう
な高分子材料よりなる表面舗装層を形成すると、
下地コンクリート内に含浸された水分は大気中に
拡散できなくなる。そのため、水の蒸気圧が下地
コンクリートと表面舗装層との接着力を超える
と、表面舗装層にブリスターとよばれるふくれを
生じる。このブリスターは0.5mm程度の微小のも
のから5〜10cmのものまで様々であり、かつ、部
分的に集中して発生する傾向がある。ブリスター
は、その部分の外観をそこなうばかりでなく、舗
装層が剥離される為、その効果的対策が望まれて
いた。
従来、ブリスター現象の防止方法として、多孔
質の膜を介在させたり、溝を切つて含浸水分の蒸
気圧を逃がす方法などが提案されているが、いず
れも未だ充分ではなかつた。
この発明は、上記のような従来技術の欠点を解
消し、効果的にブリスターの発生を防止しうるコ
ンクリート構造物の表面舗装方法を提供すること
を目的とする。
すなわち、この発明はコンクリート構造物の下
地コンクリート面にプライマー層を介して高分子
材料を主体とする表面層を形成する舗装方法にお
いて、水およびセメントを分散させたエポキシ樹
脂を下地コンクリート面に塗布し硬化せしめてブ
リスター現象を有効に防止しうるプライマー層を
形成することを特徴とする。
以下、この発明の実施例により、その効果を詳
細に説明する。
まず、常温硬化型のエポキシ樹脂に硬化剤を添
加して充分混合し、水にセメントを溶解した物を
添加混合後、コンクリート床面に塗布硬化せしめ
プライマー層(プレコート下地層)を形成する。
プライマー層の厚さは0.1〜1mm程度が適当で
あるが、それ以上でも良い。エポキシ樹脂層の形
成は水およびセメントを分散させる以外は従来の
エポキシ樹脂による塗装と同様である。すなわ
ち、エポキシ樹脂としてはビスフエノールAのグ
リシジルエーテル、ビスフエノールFのグリシジ
ルエーテルなどいずれもが使用可能であり、硬化
剤もアミン系などのものを適宜使用すればよい。
また、主剤を硬化剤との配合比もエポキシ当量な
どを勘案して常法通り適宜決定すればよい。
エポキシ樹脂中への水の混合量はエポキシ樹脂
100重量部に対し2〜150重量部が適当であり、好
ましくは10〜70重量部である。混合量が2重量部
に満たないと必ずしも充分なブリスター防止効果
が得られず、一方、150重量部を越えると硬化物
中に水分を多量に含み水不足と同様の結果とな
る。セメントの添加量はエポキシ樹脂100重量部
に対して5〜200重量部程度が適当である。
また、エポキシ樹脂中には、充填材などを添加
してもよく、たとえば、珪砂を添加することによ
りさらに強度を向上させることもできる。
このプライマー層上に、高分子材料等を主体と
した表面層を形成する。
この発明は、親油性のエポキシ樹脂に対して親
和性も悪く、また、一般に接着には嫌われている
水を分散させたエポキシ樹脂のプライマー層を形
成し、ブリスター現象の発生を有効に防止するも
のである。
この発明は高分子材料等における、下地コンク
リート面の表面舗装方法、特に湿地帯等の湿潤地
域における建造物の床面舗装方法として好適であ
る。
実施例
30cm×30cm×5cmのコンクリート板を容器内に
設置し、コンクリート板が4cm浸漬するように容
器に水を入れ密閉する。水分を充分含んだ飽和状
態のコンクリート板上面に以下の処方で表面層を
形成し、ブリスター現象の発生状況を評価した。
A エポキシ樹脂
主剤〔1〕エピコート828 80重量部
[ビスフエノールA型、油化シエルエポキシ
(株)]
EXT−001 20重量部
[非反応性希釈剤、大都産業(株)]
主剤〔2〕エピコート828 80重量部
カージユラE−10 10重量部
[脂肪酸グリシジルエーテル、油化シエルエポ
キシ(株)]
ハイゾールSAS−296 10重量部
[日本石油化学(株)]
主剤〔3〕エピコート807 80重量部
[ビスフエノールF型、油化シエルエポキシ
(株)]
EXT−001 20重量部
B 硬化剤
硬化剤〔1〕フエノール、ホルマリン、キシリ
レンジアミン縮合物 60重量部
ポリアミドアミン 30重量部
ベンジルアルコール 10重量部
硬化剤〔2〕フエノール、ホルマリン、エチレ
ンジアミン縮合物 50重量部
ベンジルアルコール 20重量部
以上のエポキシ樹脂および硬化剤を用いてプラ
イマー層を形成した。
次の表はプライマー層の配合とその評価結果で
ある。
【表】DETAILED DESCRIPTION OF THE INVENTION The present invention provides a surface paving method for forming a primer layer that can effectively prevent blistering when concrete structures are paved with polymeric materials. Conventionally, synthetic resin paints such as epoxy resins and urethane resins, long flooring materials such as rubber materials and vinyl chloride, and plastic tiles have been used for paving the concrete surfaces of concrete structures on the interior and exterior surfaces. Generally, when a concrete structure is built in a low water level area, a wetland area, or an area with poor drainage, water in the ground permeates through microscopic pores and cracks in the cement concrete, and a large amount of water enters the underlying concrete of the floor and walls. It is well known that water can be impregnated with water. A similar phenomenon may also occur if poured concrete is insufficiently dried. When a surface paving layer made of the above-mentioned polymeric material is formed on such a base concrete surface,
Moisture impregnated into the base concrete cannot diffuse into the atmosphere. Therefore, when the vapor pressure of water exceeds the adhesive force between the base concrete and the surface pavement layer, blisters, called blisters, occur in the surface pavement layer. These blisters vary in size from about 0.5 mm to 5 to 10 cm, and tend to occur locally. Blisters not only spoil the appearance of the area, but also cause the pavement layer to peel off, so effective countermeasures have been desired. Conventionally, methods for preventing the blister phenomenon have been proposed, such as interposing a porous membrane or cutting grooves to release the vapor pressure of impregnated water, but none of these methods have been sufficient. An object of the present invention is to provide a method for surface paving a concrete structure that can overcome the drawbacks of the prior art as described above and effectively prevent the occurrence of blisters. That is, the present invention is a paving method for forming a surface layer mainly made of a polymeric material on a concrete base surface of a concrete structure via a primer layer, in which an epoxy resin in which water and cement are dispersed is applied to the base concrete surface. It is characterized by forming a primer layer that can be cured to effectively prevent the blister phenomenon. Hereinafter, the effects of this invention will be explained in detail using examples. First, a curing agent is added to a room-temperature curing epoxy resin and thoroughly mixed. After adding and mixing a mixture of cement dissolved in water, the mixture is applied and hardened to a concrete floor surface to form a primer layer (pre-coat base layer). The appropriate thickness of the primer layer is about 0.1 to 1 mm, but it may be thicker. Formation of the epoxy resin layer is similar to conventional epoxy resin painting except that water and cement are dispersed. That is, as the epoxy resin, any of glycidyl ether of bisphenol A, glycidyl ether of bisphenol F, etc. can be used, and as the curing agent, an amine type or the like may be used as appropriate.
Further, the blending ratio of the main agent to the curing agent may be appropriately determined in the usual manner, taking into account the epoxy equivalent and the like. The amount of water mixed into the epoxy resin is
A suitable amount is 2 to 150 parts by weight, preferably 10 to 70 parts by weight, per 100 parts by weight. If the mixing amount is less than 2 parts by weight, a sufficient anti-blister effect cannot necessarily be obtained, while if it exceeds 150 parts by weight, the cured product will contain a large amount of water, resulting in the same result as a lack of water. The appropriate amount of cement to be added is about 5 to 200 parts by weight per 100 parts by weight of the epoxy resin. Further, a filler or the like may be added to the epoxy resin, and the strength can be further improved by adding silica sand, for example. A surface layer mainly made of a polymeric material or the like is formed on this primer layer. This invention effectively prevents the occurrence of blistering by forming a primer layer of epoxy resin in which water is dispersed, which has poor affinity for lipophilic epoxy resins and is generally disliked for adhesion. It is something. The present invention is suitable as a method for paving the surface of a concrete base using a polymeric material, and is particularly suitable as a method for paving the floor of a building in a humid area such as a wetland. Example A concrete plate measuring 30 cm x 30 cm x 5 cm is placed in a container, water is poured into the container so that the concrete plate is submerged by 4 cm, and the container is sealed. A surface layer was formed using the following formulation on the top surface of a saturated concrete plate containing sufficient moisture, and the occurrence of blister phenomenon was evaluated. A Epoxy resin base [1] 80 parts by weight of Epicoat 828 [Bisphenol type A, oil-based shell epoxy
Co., Ltd.] EXT-001 20 parts by weight [non-reactive diluent, Daito Sangyo Co., Ltd.] Main agent [2] Epicote 828 80 parts by weight Cardiura E-10 10 parts by weight [fatty acid glycidyl ether, Yuka Ciel Epoxy Co., Ltd. )] Hysol SAS-296 10 parts by weight [Nippon Petrochemicals Co., Ltd.] Base agent [3] Epicote 807 80 parts by weight [Bisphenol F type, oil-based shell epoxy
Co., Ltd.] EXT-001 20 parts by weight B Curing agent Curing agent [1] Phenol, formalin, xylylenediamine condensate 60 parts by weight Polyamide amine 30 parts by weight Benzyl alcohol 10 parts by weight Curing agent [2] Phenol, formalin, ethylenediamine Condensate: 50 parts by weight Benzyl alcohol: 20 parts by weight A primer layer was formed using the above epoxy resin and curing agent. The following table shows the composition of the primer layer and its evaluation results. 【table】
Claims (1)
プライマー層を介して高分子材料を主体とする表
面層を形成する舗装方法において、水およびセメ
ントを分散させたエポキシ樹脂組成物を下地コン
クリート面に塗布し硬化せしめて、ブリスター現
象を有効に防止しうるプライマー層を形成するこ
とを特徴とするコンクリート構造物の表面舗装方
法。1 In a paving method that forms a surface layer mainly composed of a polymer material on the underlying concrete surface of a concrete structure via a primer layer, an epoxy resin composition in which water and cement are dispersed is applied to the underlying concrete surface and allowed to harden. A method for paving the surface of a concrete structure, characterized by forming a primer layer that can effectively prevent blistering.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9679483A JPS59223289A (en) | 1983-05-31 | 1983-05-31 | Concrete structure surface paving method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9679483A JPS59223289A (en) | 1983-05-31 | 1983-05-31 | Concrete structure surface paving method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59223289A JPS59223289A (en) | 1984-12-15 |
| JPH0254311B2 true JPH0254311B2 (en) | 1990-11-21 |
Family
ID=14174532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9679483A Granted JPS59223289A (en) | 1983-05-31 | 1983-05-31 | Concrete structure surface paving method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59223289A (en) |
-
1983
- 1983-05-31 JP JP9679483A patent/JPS59223289A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59223289A (en) | 1984-12-15 |
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