JPH0329863B2 - - Google Patents
Info
- Publication number
- JPH0329863B2 JPH0329863B2 JP106088A JP106088A JPH0329863B2 JP H0329863 B2 JPH0329863 B2 JP H0329863B2 JP 106088 A JP106088 A JP 106088A JP 106088 A JP106088 A JP 106088A JP H0329863 B2 JPH0329863 B2 JP H0329863B2
- Authority
- JP
- Japan
- Prior art keywords
- cathode
- target
- anode
- sputtering
- vacuum container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004544 sputter deposition Methods 0.000 claims description 20
- 239000007789 gas Substances 0.000 claims description 16
- 239000000112 cooling gas Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 description 12
- 239000002184 metal Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 229910000679 solder Inorganic materials 0.000 description 6
- 239000007767 bonding agent Substances 0.000 description 3
- 238000011109 contamination Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000013077 target material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3407—Cathode assembly for sputtering apparatus, e.g. Target
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
Description
【発明の詳細な説明】
[発明の目的]
(産業上の利用分野)
本発明はスパツタリング装置に係り、特にター
ゲツトを陰極に容易、かつ着実に着脱できるとと
もに、ターゲツトを効率的に冷却し得るスパツタ
ガンを備えたスパツタリング装置に関する。[Detailed Description of the Invention] [Object of the Invention] (Industrial Application Field) The present invention relates to a sputtering device, and in particular to a sputtering gun that can easily and steadily attach and detach a target to a cathode and that can efficiently cool the target. The present invention relates to a sputtering device equipped with a sputtering device.
(従来の技術)
半導体その他の各種エレクトロニクス素子など
の製造に際しては、スパツタリング装置が多用さ
れている。(Prior Art) Sputtering equipment is often used in the manufacture of semiconductors and other various electronic devices.
このスパツタリング装置は、真空容器内の、上
下方向に対向して一対の電極を配置し、一方の電
極(陰極)にターゲツト(スパツタ源)を取付け
るとともに、他方の電極(陽極)に被処理物を取
付け、スパツタ電源により陰極にマイナス電位を
与えてプラズマを発生させ、このプラズマによつ
て生成したイオンスパツタまたは反応性イオンス
パツタを被処理物表面に導いて被着させるもので
ある。 This sputtering device has a pair of electrodes arranged vertically opposite each other in a vacuum container, a target (sputter source) is attached to one electrode (cathode), and a workpiece is attached to the other electrode (anode). During installation, a negative potential is applied to the cathode using a sputter power source to generate plasma, and ion spatter or reactive ion spatter generated by this plasma is guided to the surface of the object to be treated and deposited thereon.
このスパツタリング装置において、ターゲツト
を陰極に装着させる場合には、従来から、メタル
ボンデイング法あるいはボルト固定法が使用され
ていた。 In this sputtering apparatus, when attaching the target to the cathode, a metal bonding method or a bolt fixing method has conventionally been used.
メタルボンデイング法は第4図aに示すよう
に、ターゲツト1をボンデイング剤2によつて陰
極3に張付けるものであり、また、ボルト固定法
は第5図a,bに示すように、ターゲツト1に適
度の間隔をおいて複数個の孔1aを形成してお
き、これらの孔に通したボルト4を陰極3側にね
じこむことによりターゲツト4を陰極3に固定さ
せるものである。 In the metal bonding method, as shown in FIG. 4a, the target 1 is attached to the cathode 3 using a bonding agent 2, and in the bolt fixing method, as shown in FIGS. The target 4 is fixed to the cathode 3 by forming a plurality of holes 1a at appropriate intervals and screwing bolts 4 passed through these holes into the cathode 3 side.
(発明が解決しようとする課題)
上述したメタルボンデイング法においては、ボ
ンデイング剤としては主として「はんだ」が使用
されるが、このはんだは、第4図bに示すよう
に、はんだむら2aを生じやすい上、ターゲツト
へのはんだ拡散による汚染を発生させるおそれが
ある。はんだむら2aが発生すると、陰極との金
属接触面積が減少するため、スパツタリング中に
ターゲツトの温度が上昇し、ターゲツトの保持が
不確実になりやすい。(Problem to be Solved by the Invention) In the metal bonding method described above, "solder" is mainly used as the bonding agent, but this solder tends to cause solder unevenness 2a as shown in FIG. 4b. Moreover, contamination due to solder diffusion to the target may occur. When the solder unevenness 2a occurs, the metal contact area with the cathode decreases, so that the temperature of the target increases during sputtering, and the holding of the target tends to become uncertain.
なお、ターゲツトへのはんだ拡散は、ターゲツ
トのボンデイング面を前処理し、バリアメタルを
被着させておくことにより防止することができる
が、これにはかなりの時間と手数を要するという
欠点がある。 Incidentally, solder diffusion into the target can be prevented by pretreating the bonding surface of the target and depositing a barrier metal on it, but this has the drawback of requiring considerable time and effort.
一方、ボルト固定法は大形のターゲツトの取付
け方法としては確実で有用であるが、高価なター
ゲツト材料に孔明け加工を施すことになり、材料
費と加工費が無駄になる上、固定用のボルトがプ
ラズマにさらされて蒸発するため、被処理物が汚
染されるという不都合がある。 On the other hand, the bolt fixing method is reliable and useful as a method for attaching large targets, but it requires drilling holes in expensive target material, which wastes material and processing costs. Since the bolt is exposed to plasma and evaporates, there is a disadvantage that the object to be processed is contaminated.
そこで本発明の目的はターゲツトの着脱が容易
で、しかも効率よくターゲツトを冷却しうるスパ
ツタリング装置を提供することにある。 SUMMARY OF THE INVENTION It is therefore an object of the present invention to provide a sputtering apparatus which allows a target to be easily attached and detached and which can cool the target efficiently.
[発明の構成]
(課題を解決するための手段)
上記目的を達成するために本発明は、真空排気
管およびガス導入管を備えた真空容器と、この真
空容器内に配置されて被処理物を保持する陽極
と、前記真空容器内に前記陽極に対向して配置さ
れた陰極と、前記陽極と陰極の間に電圧を印加し
てそれらの間にプラズマを発生させるスパツタ電
源とからなるスパツタリング装置において、前記
陰極内には、静電チヤツク電極と、それに静電的
にチヤツキングされるターゲツトとの間に冷却用
のガスを導入するガス導入孔を形成したことを特
徴とするものである。[Structure of the Invention] (Means for Solving the Problems) In order to achieve the above object, the present invention provides a vacuum container equipped with a vacuum exhaust pipe and a gas introduction pipe, and a workpiece placed in the vacuum container. A sputtering device comprising: an anode that holds an anode; a cathode disposed in the vacuum container to face the anode; and a sputtering power source that applies a voltage between the anode and the cathode to generate plasma between them. The cathode is characterized in that a gas introduction hole is formed in the cathode to introduce a cooling gas between the electrostatic chuck electrode and the target electrostatically chucked thereon.
(作用)
上述のように構成した本発明のスパツタリング
装置においては、ターゲツトを静電方式により陰
極に固定しているので、ターゲツトに孔明け等の
加工を施す必要がなく、着脱が容易な上、被処理
物の汚染なども完全に防止される。(Function) In the sputtering apparatus of the present invention configured as described above, the target is fixed to the cathode by an electrostatic method, so there is no need to perform processing such as drilling holes on the target, and it is easy to attach and detach. Contamination of the objects to be processed is also completely prevented.
(実施例)
以下、図面を参照しながら本発明の実施例を説
明する。(Example) Hereinafter, an example of the present invention will be described with reference to the drawings.
第1図において、真空容器10には、その内を
真空排気する排気装置(図示せず)へ連なる真空
排気管11と、流量制御装置(図示せず)で制御
されたArガスまたは活性ガスを真空容器10内
へ導入するガス導入管12が連結されている。 In FIG. 1, a vacuum vessel 10 has a vacuum exhaust pipe 11 connected to an exhaust device (not shown) that evacuates the inside thereof, and an Ar gas or active gas controlled by a flow rate control device (not shown). A gas introduction pipe 12 that is introduced into the vacuum container 10 is connected.
真空容器10内の上方には被処理物を保持する
被処理物ホルダー13を取付けた陽極14が配置
されている。この陽極14は被処理物への被着が
均一に行われるよう回転駆動機構(図示せず)に
より回転自在に支承されており、また、接地電位
に保たれている。 An anode 14 to which a workpiece holder 13 for holding a workpiece is attached is disposed above the vacuum chamber 10 . This anode 14 is rotatably supported by a rotational drive mechanism (not shown) so that it can be evenly deposited on the object to be treated, and is maintained at a ground potential.
真空容器10内の下方には陽極14に対向して
陰極15が配置されている。この陰極15は静電
的にチヤツクされたターゲツト1を冷却すると共
に、その電位を所望のマイナス電位に保持するも
ので、その周囲は絶縁物16を介してアースリン
グ17で覆われている。 A cathode 15 is arranged at the lower part of the vacuum vessel 10, facing the anode 14. This cathode 15 cools the electrostatically chucked target 1 and maintains its potential at a desired negative potential, and its periphery is covered with an earth ring 17 via an insulator 16.
陰極15にはスパツタ電源18が接続されてお
り、また陰極15に内臓された冷却媒体通路(こ
の例では、第2図中に15aにて示す水路)には
冷却用の給水管19と排水管20が連結されてい
る。また、陰極15の中央に設けたガス導入孔
(第2図の15b)にはガス導入管21を介して
流量制御装置22が連結されている。 A sputter power supply 18 is connected to the cathode 15, and a cooling medium passage (in this example, the water channel indicated by 15a in FIG. 2) built into the cathode 15 is provided with a cooling water supply pipe 19 and a drain pipe. 20 are connected. Further, a flow rate control device 22 is connected to a gas introduction hole (15b in FIG. 2) provided at the center of the cathode 15 via a gas introduction pipe 21.
23は真空容器10内の圧力を測定する圧力計
を示す。 23 indicates a pressure gauge for measuring the pressure inside the vacuum container 10.
第2図は第1図における陰極15の近傍(スパ
ツタガン)を拡大して示すもので、スパツタガン
の導電性ベースプレート30内にはマグネツト3
1が配置されている。このマグネツト31は回転
軸32を介してマグネツト駆動機構33に連結さ
れている。 FIG. 2 shows an enlarged view of the vicinity of the cathode 15 (sputter gun) in FIG. 1. There is a magnet 3 in the conductive base plate 30 of the sputter gun.
1 is placed. This magnet 31 is connected to a magnet drive mechanism 33 via a rotating shaft 32.
陰極15の上面には静電チヤツク34が固着さ
れている。この静電チヤツク34は第3図a,b
に示すように銅フイルム等から成る電極34aの
全表面をポリイミドフイルム等から成る絶縁膜3
4bで被覆して構成されており、電極34aは絶
縁リード線35を介して直流の静電チヤツク電源
36に連結されている。 An electrostatic chuck 34 is fixed to the upper surface of the cathode 15. This electrostatic chuck 34 is shown in FIGS.
As shown in the figure, the entire surface of the electrode 34a made of copper film or the like is covered with an insulating film 3 made of polyimide film or the like.
The electrode 34a is connected to a DC electrostatic chuck power supply 36 via an insulated lead wire 35.
上述のように構成した本発明のスパツタリング
装置において、被処理物を陽極14側の被処理物
ホルダー13に取付け、マグネツト駆動機構33
によりマグネツト31を回転軸32を中心として
回転させ、静電チヤツク電源36から直流電圧を
静電チヤツク電極34aに印加する。 In the sputtering apparatus of the present invention configured as described above, the workpiece is attached to the workpiece holder 13 on the anode 14 side, and the magnet drive mechanism 33
The magnet 31 is rotated about the rotating shaft 32, and a DC voltage is applied from the electrostatic chuck power supply 36 to the electrostatic chuck electrode 34a.
この状態で、排気管11に連結した排気装置
(図示せず)により真空容器10内を真空排気し
た後、流量制御装置(図示せず)により制御され
た流量のArガスまたは活性ガスを導入管12を
通して真空容器10内に導入し、スパツタ電源1
8により陰極15に所定のマイナス直流電圧また
はマイナスバイアスの高周波電圧を印加する。 In this state, the inside of the vacuum container 10 is evacuated by an exhaust device (not shown) connected to the exhaust pipe 11, and then Ar gas or active gas is introduced into the tube at a flow rate controlled by a flow rate control device (not shown). 12 into the vacuum container 10, and the sputter power supply 1
8 applies a predetermined negative DC voltage or negative bias high frequency voltage to the cathode 15.
これによりターゲツト1の上面にはプラズマ4
0が形成され、ターゲツト1は静電チヤツク34
の電極34aにより静電的にチヤツクされ、スパ
ツタガンの陰極15表面に固定される。また、タ
ーゲツト1からはイオンスパツタまたは反応性イ
オンスパツタが発生し、被処理物ホルダー13側
に取付けた被処理物はターゲツト材料によつて被
覆される。 As a result, plasma 4 is placed on the upper surface of target 1.
0 is formed and target 1 is electrostatic chuck 34.
It is electrostatically chucked by the electrode 34a and fixed to the surface of the cathode 15 of the sputter gun. Further, ion spatter or reactive ion spatter is generated from the target 1, and the workpiece attached to the workpiece holder 13 is covered with the target material.
このスパツタリングに際し、ターゲツト1はプ
ラズマ40により加熱されるが、本実施例装置に
おいては、冷却水が給水管19を介して、陰極1
5内に設けた水路15a内に導入され、そこを冷
却した後、排水管20から排出されるので、陰極
15、静電チヤツクおよびこれに取付けられたタ
ーゲツト1は冷却される。 During this sputtering, the target 1 is heated by the plasma 40, but in this embodiment, cooling water is supplied to the cathode 1 through the water supply pipe 19.
The cathode 15, the electrostatic chuck, and the target 1 attached thereto are cooled.
なお、ターゲツト1は静電的な力によつて、静
電チヤツク34にしつかりとホールデイングされ
ているが、静電チヤツク34とターゲツト1の間
にはそれらの表面の不整によつて微少な空〓が形
成される。このような空〓は静電チヤツク34と
ターゲツト1の間の熱抵抗を著しく増大させ、ホ
ストスポツトを形成させることになるが、本実施
例においては、流量制御装置22からガス導入管
21およびガス導入孔15bを通して窒素ガスそ
の他のガスが、静電チヤツク34とターゲツト1
の間に供給されるので、上記ホツトスポツトの形
成は阻止される。 Note that although the target 1 is firmly held in the electrostatic chuck 34 by electrostatic force, there is a slight air gap between the electrostatic chuck 34 and the target 1 due to the irregularity of their surfaces. 〓 is formed. Such air significantly increases the thermal resistance between the electrostatic chuck 34 and the target 1 and forms a host spot, but in this embodiment, the gas inlet pipe 21 and the gas Nitrogen gas and other gases are introduced into the electrostatic chuck 34 and the target 1 through the introduction hole 15b.
The formation of the hot spots is prevented.
[発明の効果]
上述のように、本発明によれば静電チヤツクに
よりターゲツトを陰極に取付けるようにしたの
で、メタルボンデイング法やボルト固定法のよう
に取付けが不安定になつたり無駄な材料費や加工
費を必要とするという欠点を除去し、簡単かつ確
実にターゲツトを陰極に着脱自在に取付けること
ができる。[Effects of the Invention] As described above, according to the present invention, the target is attached to the cathode using an electrostatic chuck, which eliminates unstable attachment and wasteful material costs that would otherwise occur with the metal bonding method or bolt fixing method. This eliminates the drawbacks of high costs and processing costs, and allows the target to be easily and reliably attached to the cathode in a removable manner.
第1図は本発明のスパツタリング装置の実施例
を示す概略構成図、第2図は第1図におけるスパ
ツタガンの近傍の拡大説明図、第3図a,bは本
発明のスパツタリング装置において使用れる静電
チヤツクを例示する横断面図と概略図、第4図
a,bは従来のメタルボンデイング法を示す陰極
近傍の正面図と横断面図、第5図a,bは従来の
ボルト固定法を示す陰極近傍の正面図と横断面図
である。
1……ターゲツト、2……ボンデイング剤、3
……陰極、10……真空容器、11……排気管、
12……導入管、13……被処理物ホルダー、1
4……陽極、15……陰極、15a……冷却路、
15b……ガス導入孔、16……絶縁物、17…
…アースリング、18……スパツタ電源、19…
…給水管、20……排水管、21……ガス導入
管、22……流量制御装置、23……圧力計、3
0……ベースプレート、31……マグネツト、3
2……回転軸、33……マグネツト駆動機構、3
4……静電チヤツク、34a……電極、34b…
…絶縁膜、35……絶縁リード線、36……静電
チヤツク電源、40……プラズマ。
FIG. 1 is a schematic configuration diagram showing an embodiment of the sputtering apparatus of the present invention, FIG. 2 is an enlarged explanatory view of the vicinity of the sputtering gun in FIG. 1, and FIGS. A cross-sectional view and a schematic diagram illustrating an electric chuck; Figures 4a and 4b are a front view and a cross-sectional view near the cathode showing the conventional metal bonding method; Figures 5a and b are illustrating the conventional bolt fixing method. FIG. 4 is a front view and a cross-sectional view of the vicinity of the cathode. 1...Target, 2...Bonding agent, 3
... cathode, 10 ... vacuum container, 11 ... exhaust pipe,
12...Introduction pipe, 13...Workpiece holder, 1
4... Anode, 15... Cathode, 15a... Cooling path,
15b...Gas introduction hole, 16...Insulator, 17...
...Earth ring, 18...Spatsuta power supply, 19...
... Water supply pipe, 20 ... Drain pipe, 21 ... Gas introduction pipe, 22 ... Flow rate control device, 23 ... Pressure gauge, 3
0... Base plate, 31... Magnet, 3
2... Rotating shaft, 33... Magnetic drive mechanism, 3
4... Electrostatic chuck, 34a... Electrode, 34b...
...Insulating film, 35...Insulated lead wire, 36...Electrostatic chuck power supply, 40...Plasma.
Claims (1)
器と、この真空容器内に配置されて被処理物を保
持する陽極と、前記真空容器内に前記陽極に対向
して配置された陰極と、前記陽極と陰極の間に電
圧を印加してそれらの間にプラズマを発生させる
スパツタ電源とからなるスパツタリング装置にお
いて、前記陰極内には、静電チヤツク電極と、そ
れに静電的にチヤツキングされるターゲツトとの
間に冷却用のガスを導入するガス導入孔が形成さ
れていることを特徴とするスパツタリング装置。1. A vacuum container equipped with an evacuation tube and a gas introduction tube, an anode placed in the vacuum container to hold the object to be processed, a cathode placed in the vacuum container facing the anode, and the In a sputtering device comprising a sputtering power source that applies a voltage between an anode and a cathode to generate plasma between them, the cathode includes an electrostatic chuck electrode and a target to be electrostatically chucked therein. A sputtering apparatus characterized in that a gas introduction hole for introducing cooling gas is formed between the sputtering apparatus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP106088A JPH01177368A (en) | 1988-01-06 | 1988-01-06 | Sputtering device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP106088A JPH01177368A (en) | 1988-01-06 | 1988-01-06 | Sputtering device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01177368A JPH01177368A (en) | 1989-07-13 |
| JPH0329863B2 true JPH0329863B2 (en) | 1991-04-25 |
Family
ID=11490994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP106088A Granted JPH01177368A (en) | 1988-01-06 | 1988-01-06 | Sputtering device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01177368A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5221403A (en) * | 1990-07-20 | 1993-06-22 | Tokyo Electron Limited | Support table for plate-like body and processing apparatus using the table |
| GB2318590B (en) * | 1995-07-10 | 1999-04-14 | Cvc Products Inc | Magnetron cathode apparatus and method for sputtering |
| US6221217B1 (en) | 1995-07-10 | 2001-04-24 | Cvc, Inc. | Physical vapor deposition system having reduced thickness backing plate |
| US6039848A (en) * | 1995-07-10 | 2000-03-21 | Cvc Products, Inc. | Ultra-high vacuum apparatus and method for high productivity physical vapor deposition. |
| JPH11509273A (en) * | 1995-07-10 | 1999-08-17 | シーヴィシー、プラダクツ、インク | Permanent magnet arrangement apparatus and method |
| KR100291330B1 (en) * | 1998-07-02 | 2001-07-12 | 윤종용 | Sputtering equipment for semiconductor device manufacturing and sputtering method using the same |
-
1988
- 1988-01-06 JP JP106088A patent/JPH01177368A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01177368A (en) | 1989-07-13 |
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