JPH0334346B2 - - Google Patents
Info
- Publication number
- JPH0334346B2 JPH0334346B2 JP58227955A JP22795583A JPH0334346B2 JP H0334346 B2 JPH0334346 B2 JP H0334346B2 JP 58227955 A JP58227955 A JP 58227955A JP 22795583 A JP22795583 A JP 22795583A JP H0334346 B2 JPH0334346 B2 JP H0334346B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- water
- aromatic
- parts
- deodorizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 125000003118 aryl group Chemical group 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000003205 fragrance Substances 0.000 claims description 9
- -1 polyoxyethylene Polymers 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 6
- 229920003169 water-soluble polymer Polymers 0.000 claims description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 5
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000002386 air freshener Substances 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 230000001877 deodorizing effect Effects 0.000 description 10
- 229920002125 Sokalan® Polymers 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000004584 polyacrylic acid Substances 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000002781 deodorant agent Substances 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- AEMOLEFTQBMNLQ-BKBMJHBISA-N alpha-D-galacturonic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-BKBMJHBISA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000010800 human waste Substances 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Description
【発明の詳細な説明】
本発明はトイレ用芳香消臭剤に関する。詳しく
はトイレ内に散布するか、又はトイレボール内壁
に塗布して使用される芳香消臭剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an aromatic deodorizer for toilets. More specifically, the present invention relates to an aromatic deodorizer that is used by being sprayed inside the toilet or applied to the inner wall of the toilet bowl.
従来、トイレ用芳香消臭剤としては、リム部
取付型又はタンク内に吊下げて消臭剤を溶解し、
洗浄水とともに極めて低濃度で排出するインタン
ク型製品、高分子ゲル、紙、無機質ビーズ或い
は合成樹脂等を担体とし、これに香料を含浸した
据置型又はインロール型製品、便器内直まき型
の低粘度製品、及びエアゾール型製品が市販さ
れている。 Conventionally, aromatic deodorizers for toilets have been either rim-mounted or suspended in a tank to dissolve the deodorizer.
In-tank type products that are discharged at extremely low concentrations along with the washing water; stationary or in-roll type products that use polymer gel, paper, inorganic beads, or synthetic resin as a carrier and impregnated with fragrance; Low viscosity products and aerosol type products are commercially available.
しかしながら、これらは末だ十分に満足される
ものではない。すなわち、については溶解量が
経時的に一定でない。使用当初は強い芳香を発散
し、これが他の部屋まで満延する欠点がある。 However, these are still not completely satisfactory. In other words, the amount dissolved is not constant over time. When first used, it emits a strong fragrance, which has the disadvantage of spreading to other rooms.
については最初低揮発性成分が揮散され、次
いで高揮発成分が濃縮されて増々揮散されにくく
なり、芳香消臭剤としての特性が認められない。 First, the low-volatile components are volatilized, and then the high-volatile components are concentrated and become increasingly difficult to volatilize, so that the characteristics as an aroma deodorizing agent are not recognized.
についてはその場限りで持続性がなく、水洗
により直ちに流される。また１回の水洗で全量が
洗い流されるため、使用頻度が増加するにつれし
尿浄化槽内の生態形を破壊する欠点がある。また
については即効性であるが、持続性が極めて悪
いと云う欠点がある。更にこれらの従来品は全て
防汚洗浄効果はほとんど期待できない。 It is temporary and non-persistent, and is immediately washed away with water. Furthermore, since the entire amount is washed away in one flush, there is a drawback that as the frequency of use increases, the ecology within the human waste septic tank is destroyed. Although it has an immediate effect, it has the disadvantage of being extremely short-lasting. Furthermore, all of these conventional products can hardly be expected to have antifouling and cleaning effects.
本発明者は上記の背景のもと、トイレに簡便に
使用できる持続性のある芳香消臭剤で、かつまた
防汚洗浄効果も達成できるものを目的として鋭意
検討を重ねたところ、或る特定の配合組成物が、
汚物と陶器面との間又は汚物の表面に均一な薄膜
を形成することにより、芳香消臭効果が持続し、
また汚物は陶器面から容易に除去されることを見
い出した。本発明はこの知見に基づくものであ
り、水溶性高分子増粘剤、界面活性剤、香料及び
水を含有し、かつ粘度を100〜10000cpsに調整し
てなるトイレ用芳香消臭剤を要旨とする。 With the above background in mind, the inventor of the present invention has conducted intensive studies with the aim of creating a long-lasting aromatic deodorizer that can be easily used in the toilet, and which also has an antifouling and cleaning effect. The blended composition of
By forming a uniform thin film between the filth and the ceramic surface or on the surface of the filth, the aromatic deodorizing effect lasts.
It has also been found that dirt can be easily removed from the ceramic surface. The present invention is based on this knowledge, and the gist of the present invention is to provide an air freshener deodorizer for toilets containing a water-soluble polymer thickener, a surfactant, a fragrance, and water, and having a viscosity adjusted to 100 to 10,000 cps. do.
以下、本発明を詳細に説明するに、本発明にお
いて水溶性高分子増粘剤としては、メチルセルロ
ーズ、カルボキシメチルセルローズナトリウム、
ヒドロキシエチルセルローズ、ヒドロキシプロピ
ルセルローズ、ヒドロキシメチルプロピルセルロ
ーズ、ポリビニールアルコール、ポリビニールピ
ロリドン、ポリアクリル酸ナトリウム、カルボキ
シビニールポリマー、ポリアクリル酸アマイド、
ザンタンガム、カラギーナン、ポリオキシエチレ
ン、ペクチン酸ナトリウム、アルギン酸ナトリウ
ム、ポリアクリル酸、α−オレフイン無水マレイ
ン酸共重合物、エチレン無水マレイン酸共重合物
等の従来公知のものの１種又は２種以上が挙げら
れ、とくにポリアクリル酸ナトリウム、ポリアク
リル酸アマイド、ポリオキシエチレンが好ましく
用いられる。 The present invention will be described in detail below. In the present invention, the water-soluble polymer thickeners include methyl cellulose, sodium carboxymethyl cellulose,
Hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxymethylpropyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone, sodium polyacrylate, carboxyvinyl polymer, polyacrylic acid amide,
One or more of the conventionally known ones such as xanthan gum, carrageenan, polyoxyethylene, sodium pectate, sodium alginate, polyacrylic acid, α-olefin maleic anhydride copolymer, ethylene maleic anhydride copolymer, etc. Among them, sodium polyacrylate, polyacrylamide, and polyoxyethylene are particularly preferably used.
界面活性剤としては、とくに限定されないが、
非イオン界面活性剤及び陰イオン界面活性剤が好
ましく用いられる。また非イオン界面活性剤は
HLBが９〜17のものが好ましく用いられる。香
料もとくに限定されないがトイレ防臭効果の優れ
たものが選択される。 Surfactants include, but are not particularly limited to,
Nonionic surfactants and anionic surfactants are preferably used. In addition, nonionic surfactants
Those having an HLB of 9 to 17 are preferably used. The fragrance is not particularly limited, but one with excellent toilet deodorizing effect is selected.
本発明の芳香消臭剤の組成は上記の３成分及び
水を次の割合で含有する。 The composition of the aromatic deodorant of the present invention contains the above three components and water in the following proportions.
水溶性高分子増粘剤…0.05〜10重量％、好ましく
は0.2〜５重量％
界面活性剤…0.1〜10重量％、好ましくは0.5〜7.5
重量％
香料…0.1〜５重量％、好ましくは0.2〜３重量％
水…バランス
また、本発明の芳香消臭剤は粘度を100〜
10000cps、好ましくは200〜5000cps、更に好まし
くは300〜4000cpsに調整する。かくすることによ
り、ぬめり性のあるスリツパリーな膜形成能を有
する。すなわち、トイレボール内壁の陶器面上或
いは非水洗トイレの汚物上面をシーテイングアク
シヨン（シートをかぶせたように覆う作用）によ
つて被覆し、芳香、消臭性成分を揮散させる。ま
た特異なすべり性のある湿潤性の層で汚物の陶器
面への直接付着を防止し、芳香、消臭成分の揮散
後の残留物は界面活性剤を含むので水洗、洗浄を
容易にする。とくに数回の水洗、洗浄によつても
この膜は粘着付着して残留し、芳香、消臭機能を
持続する。また本芳香消臭剤は、トイレボールの
リム部（垂直面）に塗布して使用することもでき
る。この場合は粘度を1000〜10000cpsとくに1500
〜3500cpsの範囲を選ぶのが好ましい。また、塗
布してたれどめ性を与えるため、水溶性高分子増
粘剤の中でとくに水溶性ポリアクリル酸（とくに
特公昭56−39838号に示される部分架橋型ポリア
クリル酸）、ヒドロキシエチルセルローズ、エチ
レン無水マレイン酸共重合物等のチクソトロピー
性（thioxotropy）を与えるものが好ましく用い
られる。本発明の芳香消臭剤は、必要に応じ鉱
酸、有機酸（とくに揮散性の酢酸、ギ酸等はアン
モニア臭を中和する。）木酢酸、金属封鎖剤、ハ
イドロトロープ、染料、色素、殺菌剤、防腐剤、
防黴剤等を適宜配合することもできる。Water-soluble polymer thickener...0.05-10% by weight, preferably 0.2-5% by weight Surfactant...0.1-10% by weight, preferably 0.5-7.5%
Weight% Fragrance...0.1 to 5% by weight, preferably 0.2 to 3% by weight Water...Balance In addition, the aromatic deodorant of the present invention has a viscosity of 100 to 5% by weight.
Adjust to 10,000 cps, preferably 200 to 5,000 cps, and more preferably 300 to 4,000 cps. By doing so, it has the ability to form a slimy and slippery film. That is, the ceramic surface of the inner wall of the toilet bowl or the upper surface of the filth in a non-flushing toilet is covered with a sheeting action (an action of covering it as if it were covered with a sheet), and the aromatic and deodorizing components are volatilized. In addition, the uniquely slippery wet layer prevents dirt from directly adhering to the ceramic surface, and the residue after the aromatic and deodorizing components are volatilized contains a surfactant, making it easy to wash with water and clean. In particular, even after several washings with water, this film sticks and remains, maintaining its aromatic and deodorizing functions. Furthermore, this aromatic deodorizer can also be used by applying it to the rim (vertical surface) of the toilet bowl. In this case, the viscosity is 1000 to 10000 cps, especially 1500
It is preferable to choose a range of ~3500cps. In addition, among water-soluble polymer thickeners, water-soluble polyacrylic acid (particularly the partially cross-linked polyacrylic acid shown in Japanese Patent Publication No. 56-39838), hydroxyethyl Those that provide thixotropy, such as cellulose and ethylene maleic anhydride copolymer, are preferably used. The aromatic deodorizer of the present invention may optionally contain mineral acids, organic acids (particularly volatile acetic acid, formic acid, etc. neutralize ammonia odor), wood acetic acid, sequestering agents, hydrotropes, dyes, pigments, and disinfectants. agents, preservatives,
Antifungal agents and the like can also be added as appropriate.
上記のように本発明の芳香消臭剤は、これをト
イレ内に散布するか、又はトイレボール内壁に塗
布するだけで、持続性のある膜を形成して芳香消
臭成分の揮散及び汚物の付着防止と洗浄除去とを
簡便に行うことができる。次に実施例により本発
明を更に具体的に説明するが、本発明はその要旨
を越えない限り、以下の実施例に限定されない。 As mentioned above, the aroma deodorizer of the present invention forms a long-lasting film by simply spraying it inside the toilet or applying it to the inner wall of the toilet bowl, thereby helping to volatilize the aroma deodorizing ingredients and remove waste. Adhesion prevention and cleaning removal can be easily performed. Next, the present invention will be explained in more detail with reference to examples, but the present invention is not limited to the following examples unless it exceeds the gist thereof.
実施例 １
水の適量にヒドロキシプロピルセルローズ0.65
重量部、安息香酸0.1重量部及びEDTA−2Na
0.1重量部を溶解する。これにポリアクリル酸ナ
トリウム0.1重量部を加えて溶解し、次いでポリ
オキシエチレンオクチルフエノール（10EO）5.0
重量部、エチレングリコール5.0重量部及びジヤ
スミン調合香料1.8重量部を加えて溶解し、水を
加えて全量を100重量部とする。かくして得られ
た芳香消臭剤（粘度2300cps）の20ｇを標準型洋
式水洗便器のリム部に塗布したところ、芳香消臭
性は２日間持続した。リム部に付着した汚物は極
めて容易に水洗により又はペーパー拭きとりによ
り除去することができた。Example 1 Hydroxypropyl cellulose 0.65 in an appropriate amount of water
Part by weight, 0.1 part by weight of benzoic acid and EDTA-2Na
Dissolve 0.1 part by weight. Add and dissolve 0.1 part by weight of sodium polyacrylate, then 5.0 parts of polyoxyethylene octylphenol (10EO).
parts by weight, 5.0 parts by weight of ethylene glycol, and 1.8 parts by weight of diasmine mixed fragrance are added and dissolved, and water is added to bring the total amount to 100 parts by weight. When 20 g of the thus obtained aromatic deodorizing agent (viscosity 2300 cps) was applied to the rim of a standard Western-style flush toilet, the aromatic deodorizing property lasted for two days. Dirt adhering to the rim could be removed very easily by washing with water or wiping with paper.
実施例 ２
水の適量にポリビニールアルコール1.0重量部、
安息香酸の0.1重量部、EDTA−2Na 0.1重量部
及び青色１号0.00005重量部を溶解する。これに
ポリアクリル酸ナトリウム0.3重量部を加えけ溶
解する。次いでポリオキシエチレンノニルフエノ
ール（16EO）2.5重量部、ポリオキシエチレンノ
ニルフエノール（10EO）2.5重量部、調合香料0.5
重量部及びエタノール（95％）3.0重量部を加え
て溶解し水を加えて全量を100重量部とする。か
くして得られた芳香消臭剤（粘度360cps）の15gr
を、洋式水洗トイレボウルのリム裏側にかかるよ
うに散布し、自然流下させ全面を均一に被覆させ
た。芳香消臭成分の揮散性が極めて良好で、使用
後汚物の水洗性がよく良好な防汚れが確認され
た。この効果は４回程度の水洗にも耐え持続性が
認められた。Example 2 1.0 parts by weight of polyvinyl alcohol in an appropriate amount of water,
Dissolve 0.1 part by weight of benzoic acid, 0.1 part by weight of EDTA-2Na, and 0.00005 part by weight of Blue No. 1. Add 0.3 parts by weight of sodium polyacrylate to this and dissolve. Next, 2.5 parts by weight of polyoxyethylene nonylphenol (16EO), 2.5 parts by weight of polyoxyethylene nonylphenol (10EO), and 0.5 parts by weight of blended fragrance.
Add parts by weight and 3.0 parts by weight of ethanol (95%) to dissolve, and add water to bring the total amount to 100 parts by weight. 15gr of the thus obtained fragrance deodorant (viscosity 360cps)
was sprinkled on the back side of the rim of a Western-style flush toilet bowl and allowed to flow down naturally to uniformly coat the entire surface. It was confirmed that the aromatic deodorizing component had very good volatility, and that the filth could be easily washed with water after use, and that it had good stain resistance. This effect was found to be durable even after washing about four times.
実施例 ３
実施例１のヒドロキシセルローズの代りに、部
分架橋ポリアクリル酸（米国グツドリツチ社製、
カーボポール、平均重合度10000）0.3重量部を含
み、その他は全く同じ成分を含む芳香消臭剤を実
施例１と同様に水洗便器のリム部に塗布したとこ
ろ、同様の効果が得られた。Example 3 In place of the hydroxycellulose in Example 1, partially crosslinked polyacrylic acid (manufactured by Gutdrich, USA) was used.
When an aromatic deodorizer containing 0.3 parts by weight of Carbopol (average degree of polymerization 10,000) and the same components as in Example 1 was applied to the rim of a flush toilet in the same manner as in Example 1, similar effects were obtained.
Claims (1)
水を含有し、かつ粘度を100〜10000cpsに調整し
てなるトイレ用芳香消臭剤。 ２ 特許請求の範囲第１項記載の水溶性高分子増
粘剤が、ポリアクリル酸ナトリウム、ポリアクリ
ル酸アマイド、又はポリオキシエチレンであるト
イレ用芳香消臭剤。 ３ 特許請求の範囲第１項記載の粘度が200〜
5000cpsであるトイレ用芳香消臭剤。[Scope of Claims] 1. An aromatic deodorizer for toilets containing a water-soluble polymer thickener, a surfactant, a fragrance, and water, and having a viscosity adjusted to 100 to 10,000 cps. 2. An aromatic deodorizer for toilets, wherein the water-soluble polymer thickener according to claim 1 is sodium polyacrylate, polyacrylamide, or polyoxyethylene. 3. The viscosity described in claim 1 is 200~
A 5000cps toilet air freshener.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58227955A JPS60119950A (en) | 1983-12-02 | 1983-12-02 | Aromatic deodorant for toilet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58227955A JPS60119950A (en) | 1983-12-02 | 1983-12-02 | Aromatic deodorant for toilet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60119950A JPS60119950A (en) | 1985-06-27 |
| JPH0334346B2 true JPH0334346B2 (en) | 1991-05-22 |
Family
ID=16868878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58227955A Granted JPS60119950A (en) | 1983-12-02 | 1983-12-02 | Aromatic deodorant for toilet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60119950A (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0657240B2 (en) * | 1985-10-31 | 1994-08-03 | アイコ−株式会社 | Deodorant |
| JPH0683720B2 (en) * | 1990-06-19 | 1994-10-26 | 日本曹達株式会社 | Circulating toilet treatment agent |
| GB2364710B (en) * | 2000-07-12 | 2003-01-15 | Johnson & Son Inc S C | Lavatory freshening and/or cleaning system and method |
| GB2364709B (en) * | 2000-07-12 | 2004-12-22 | Johnson & Son Inc S C | Lavatory freshening and/or cleaning system and method |
| US7048205B2 (en) | 2000-07-12 | 2006-05-23 | S.C. Johnson & Son, Inc. | Lavatory freshening and/or cleaning system and method |
| US7563755B2 (en) | 2000-07-12 | 2009-07-21 | S. C. Johnson & Son, Inc. | Lavatory freshening and/or cleaning system and method |
| JP4863583B2 (en) * | 2001-08-10 | 2012-01-25 | アース製薬株式会社 | On-tank toilet fragrance cleaning device |
| JP5191093B2 (en) * | 2005-09-30 | 2013-04-24 | 小林製薬株式会社 | Sol-like fragrance composition |
| JP5882881B2 (en) * | 2012-11-29 | 2016-03-09 | エステー株式会社 | Spray type deodorant composition and deodorant preparation |
-
1983
- 1983-12-02 JP JP58227955A patent/JPS60119950A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60119950A (en) | 1985-06-27 |
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