JPH0345867B2 - - Google Patents
Info
- Publication number
- JPH0345867B2 JPH0345867B2 JP59016212A JP1621284A JPH0345867B2 JP H0345867 B2 JPH0345867 B2 JP H0345867B2 JP 59016212 A JP59016212 A JP 59016212A JP 1621284 A JP1621284 A JP 1621284A JP H0345867 B2 JPH0345867 B2 JP H0345867B2
- Authority
- JP
- Japan
- Prior art keywords
- fuel cell
- reformer
- air
- compressor
- warm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Description
【発明の詳細な説明】
〔発明の技術分野〕
この発明は燃料電池の空気極出口の余剰空気及
び上記改質器の排ガスによつて駆動され上記燃料
電池と改質器に必要な圧縮空気を供給するターボ
コンプレツサを備えた燃料電池発電システムに関
するものである。[Detailed Description of the Invention] [Technical Field of the Invention] This invention provides compressed air necessary for the fuel cell and the reformer, which is driven by excess air at the air electrode outlet of the fuel cell and exhaust gas from the reformer. This invention relates to a fuel cell power generation system equipped with a turbo compressor.
燃料電池発電システムは従来の汽力発電に比べ
高効率が期待できること、環境保全性が良い等の
利点があり、実用化を目指し近年盛んに開発が進
められている。燃料電池発電システムは基本的に
は電池本体、改質器、インバータにより構成され
るが、この他システムの効率向上に不可欠な構成
機器としてターボコンプレツサがある。
Fuel cell power generation systems have advantages over conventional steam power generation, such as higher efficiency and better environmental protection, and have been actively developed in recent years with the aim of putting them into practical use. A fuel cell power generation system basically consists of a battery, a reformer, and an inverter, but there is also a turbo compressor as an essential component for improving the efficiency of the system.
燃料電池本体は燃料ガスとして天然ガス等の炭
化水素系燃料を改質して得られる水素リツチな改
質ガスを使用し、酸化剤ガスとして空気を使用す
る。電池本体の性能は各反応ガスの圧力の増大に
よつて向上する傾向を示し、このため燃料、空気
各反応ガスの動作圧力は、例えば3〜6Kg/cm2g
程度に加圧維持される。このとき、空気の圧縮に
は多大の動力を必要とし、その値は電池の発生エ
ネルギーの約20%にも達する。一方、電池の燃料
ガスを生成するための改質反応は、約800℃の高
温で行われ、改質器からは高い温度の排ガスが排
出される。したがつて空気の圧縮動力源をシステ
ムの排ガスエネルギーに求めることができればシ
ステムの効率向上に大きな効果がある。ターボコ
ンプレツサはこのような目的で導入されるもの
で、システムの排ガスエネルギーをタービンで回
収し、同軸上のコンプレツサで必要な圧縮空気を
供給することによつて、システム内部で動力回収
をし、システム効率の向上を図るものである。 The fuel cell main body uses a hydrogen-rich reformed gas obtained by reforming a hydrocarbon fuel such as natural gas as the fuel gas, and air as the oxidant gas. The performance of the battery body tends to improve as the pressure of each reaction gas increases, so the operating pressure of each reaction gas, fuel and air, is, for example, 3 to 6 kg/cm 2 g.
The pressure is maintained at a certain level. At this time, compressing the air requires a large amount of power, amounting to about 20% of the energy generated by the battery. On the other hand, the reforming reaction to generate fuel gas for the battery is carried out at a high temperature of approximately 800°C, and high temperature exhaust gas is discharged from the reformer. Therefore, if the power source for compressing air can be found in the exhaust gas energy of the system, it will have a great effect on improving the efficiency of the system. A turbo compressor is introduced for this purpose; it recovers energy from the system's exhaust gas with a turbine, supplies the necessary compressed air with a coaxial compressor, and recovers power within the system. This aims to improve system efficiency.
第1図に一般的な燃料電池発電システムの空気
回路系統図を示す。図において、1は燃料電池本
体、2は改質器、3はターボコンプレツサ、3
a,3bはそれぞれターボコンプレツサ3のコン
プレツサ、タービンであり、コンプレツサ3aで
圧縮された空気の一部が流量調節弁5を経て燃料
電池1の反応に、残りの空気が流量調節弁6を経
て改質器2の燃焼用に使用されたあと、それぞれ
の排ガスがタービン3bに投入される。4はター
ビン3bの不足動力を補う助燃炉であり、ターボ
コンプレツサ3と組合わせて使用される。一般に
空気流量の少ない部分負荷運転条件時は定格負荷
時に比しターボコンプレツサ3の効率が低く、タ
ービン3bの動力が不足する傾向にある。このよ
うなとき、流量調節弁7を開いてコンプレツサ3
aの吐出空気の一部を助燃炉4に導き、その燃焼
ガスをシステムの排ガスに加えることにより、タ
ービン3bの動力不足をカバーする。又、低負荷
域でコンプレツサ3aのサージングを防止する必
要があるとき、調節弁8を開いて空気の一部をバ
イパスさせるが、これによつてタービン3bの動
力が不足する分は助燃炉4に空気を導いて補う。
この他、運転時の負荷調整用にタービンバイパス
調節弁9、及びタービンノズル(図示せず)があ
る。又、図示はしていないがシステム起動用圧縮
空気供給装置がコンプレツサ3aの入口側又は出
口側に設置される。 Figure 1 shows an air circuit diagram of a typical fuel cell power generation system. In the figure, 1 is the fuel cell main body, 2 is the reformer, 3 is the turbo compressor, 3
a and 3b are the compressor and turbine of the turbo compressor 3, respectively, where a part of the air compressed by the compressor 3a passes through the flow rate control valve 5 for reaction in the fuel cell 1, and the remaining air passes through the flow rate control valve 6. After being used for combustion in the reformer 2, each exhaust gas is input into the turbine 3b. Reference numeral 4 denotes an auxiliary combustion furnace that compensates for the insufficient power of the turbine 3b, and is used in combination with the turbo compressor 3. Generally, under partial load operating conditions with a small air flow rate, the efficiency of the turbo compressor 3 is lower than that under rated load, and the power of the turbine 3b tends to be insufficient. In such a case, open the flow control valve 7 and compressor 3.
A part of the discharged air of the turbine 3b is guided to the auxiliary combustion furnace 4, and its combustion gas is added to the exhaust gas of the system, thereby covering the lack of power of the turbine 3b. Also, when it is necessary to prevent surging of the compressor 3a in a low load range, the control valve 8 is opened to bypass a portion of the air. Guide and supplement air.
In addition, there is a turbine bypass control valve 9 and a turbine nozzle (not shown) for load adjustment during operation. Although not shown, a compressed air supply device for system startup is installed on the inlet or outlet side of the compressor 3a.
燃料電池発電システムは上記のように構成され
るが、燃料電池発電システムには種々の運転モー
ドが考えられているが、その一つに暖保持モード
がある。このモードは、システムが電力を発生し
ないいわゆる無負荷の状態で、電池本体1と改質
器2を負荷運転状態に近い温度に保持しておく運
転モードである。この運転モードは、短時間のう
ちにシステムを負荷運転に移行させることを意図
するもので、いわばシステムの待機状態を作り出
すものである。この状態では、電池本体1はヒー
タその他の手段で容易に保温できるが、改質器2
は燃焼による方法しか保温手段がない。暖保持モ
ードにおいて、改質器2の保温に必要な燃焼エネ
ルギーはごく僅かであり、したがつて燃焼に必要
とする空気量はごく僅かでその量は例えば定格の
燃焼空気量の1/10以下である。一方で、この空気
をターボコンプレツサ3に頼るとすれば、コンプ
レツサ3aのサージングを避けるために空気流量
のバイパスを多くとつてやる必要があり、不必要
に助燃エネルギーの消費をもたらすことになる。
一つの試算例で示せば、この場合電池の定格発生
電力の約6%にのぼる助燃エネルギーを消費す
る。又別の方法として、システムの起動用圧縮空
気供給装置を改質器2の保温燃焼に利用すること
も考えられるが、同装置の容量は比較的大きく、
例えば電池の定格発生電力の約5%程度の電気エ
ネルギーを消費する。したがつて、上記何れのケ
ースも暖保持運転を維持するのに必要以上のエネ
ルギーを消費するので望ましくない。暖保持運転
はその目的からいつて必要最小限のエネルギー消
費率にとどめるべきである。 The fuel cell power generation system is configured as described above, and various operation modes have been considered for the fuel cell power generation system, one of which is a warm-up mode. This mode is an operation mode in which the battery main body 1 and the reformer 2 are maintained at a temperature close to the loaded operating state in a so-called no-load state in which the system does not generate electric power. This operation mode is intended to shift the system to load operation within a short period of time, and creates a so-called standby state of the system. In this state, the battery body 1 can be easily kept warm with a heater or other means, but the reformer 2
The only way to keep warm is through combustion. In the warm maintenance mode, the combustion energy required to keep the reformer 2 warm is very small, and therefore the amount of air required for combustion is very small, for example, less than 1/10 of the rated combustion air amount. It is. On the other hand, if the turbo compressor 3 is used for this air, it is necessary to provide a large amount of air flow bypass to avoid surging of the compressor 3a, which results in unnecessary consumption of auxiliary combustion energy.
To give an example of a trial calculation, in this case, the auxiliary combustion energy amounting to about 6% of the rated power generated by the battery is consumed. Another method is to use the compressed air supply device for starting the system for warm combustion in the reformer 2, but the capacity of the device is relatively large,
For example, it consumes electrical energy of about 5% of the rated power generated by the battery. Therefore, both of the above cases are undesirable because more energy than necessary is consumed to maintain the warm-up operation. Due to its purpose, warm-up operation should be kept to the minimum necessary energy consumption rate.
この発明は上記のような従来のものの欠点に鑑
がみてなされたものであり、システムの停止時
に、システムの暖保持に必要最小限の空気を供給
する別置コンプレツサ又はブロワを設置すること
により、必要最小限のエネルギー消費率でシステ
ムの暖保持を行うことができる燃料電池発電シス
テムを提供するものである。
This invention was made in view of the above-mentioned drawbacks of the conventional system, and by installing a separate compressor or blower that supplies the minimum amount of air necessary to keep the system warm when the system is stopped, The present invention provides a fuel cell power generation system that can keep the system warm at the minimum necessary energy consumption rate.
以下、この発明の一実施例を第2図に基づいて
説明する。図において、1〜9は上述した従来の
構成と同様である。10はターボコンプレツサ3
とは別に設置され、燃料電池本体1と改質器2に
圧縮空気を供給するライン上に、システム停止時
に運転され改質器2の暖保持に必要最小限の空気
を供給する別置コンプレツサ又はブロワ、11は
逆止弁である。システム負荷運転状態から暖保持
運転に入るときの動作を次に述べる。まず、別置
コンプレツサ又はブロワ10を起動する。次いで
助燃炉4を停止し、調節弁7,8を閉じ、調節弁
9を開く。又電池本体1の保温は別の手段で行う
ので調節弁5を閉じる。この状態でターボコンプ
レツサ3は停止し、別置コンプレツサ又はブロウ
10からの空気が改質器2に供給される。この別
置コンプレツサ又はブロワ10は改質器2の暖保
持に必要最小限の容量であり、したがつて、改質
器2は暖保持を維持するだけの燃焼が行われる。
このようにしてシステムの暖保持運転が実現す
る。このような手段により暖保持運転を行うと
き、別置コンプレツサ又はブロワ10の消費電力
は僅かであり、その値は例えば燃料電池の定格出
力の1%以下のオーダーである。
Hereinafter, one embodiment of the present invention will be described based on FIG. 2. In the figure, numerals 1 to 9 are similar to the conventional structure described above. 10 is turbo compressor 3
On the line that supplies compressed air to the fuel cell main body 1 and the reformer 2, a separate compressor or Blower 11 is a check valve. The operation when entering warm-up operation from system load operation is described below. First, the separately installed compressor or blower 10 is started. Next, the auxiliary combustion furnace 4 is stopped, the control valves 7 and 8 are closed, and the control valve 9 is opened. Also, since the battery body 1 is kept warm by another means, the control valve 5 is closed. In this state, the turbo compressor 3 is stopped, and air from the separate compressor or blower 10 is supplied to the reformer 2. This separate compressor or blower 10 has the minimum capacity required to keep the reformer 2 warm, and therefore, combustion is performed to keep the reformer 2 warm.
In this way, warm-up operation of the system is achieved. When performing warm-up operation using such means, the power consumption of the separately installed compressor or blower 10 is small, and its value is, for example, on the order of 1% or less of the rated output of the fuel cell.
尚、上記実施例は大気圧状態での暖保持の場合
について述べたが、ターボコンプレツサ3のター
ビン入口ノズル(図示せず)を閉じ、調節弁9を
絞るか又は改質器2の出口に絞り弁(図示せず)
を挿入することにより、負荷運転時と同じ高圧状
態での暖保持が可能である。 Although the above embodiment describes the case of maintaining the temperature at atmospheric pressure, the turbine inlet nozzle (not shown) of the turbo compressor 3 is closed, the control valve 9 is throttled, or the outlet of the reformer 2 is Throttle valve (not shown)
By inserting it, it is possible to maintain heat in the same high pressure state as during load operation.
又、別置コンプレツサ又はブロワ10の位置
は、コンプレツサ3a出口側逆止弁11の下流側
で、調節弁5,6,7,8のそれぞれの弁に至ま
での間の回路上であれば何処に設置してもよく、
上記実施例と同様の効果を奏する。 Further, the separate compressor or blower 10 can be located anywhere on the circuit downstream of the outlet side check valve 11 of the compressor 3a and up to each of the control valves 5, 6, 7, and 8. It may be installed in
The same effects as in the above embodiment are achieved.
この発明は以上説明した通り、システムの停止
時に、システムの暖保持に必要最小限の空気を供
給する別置コンプレツサ又はブロワを設置したこ
とにより、必要最小限のエネルギー消費率でシス
テムの暖保持を行うことができる燃料電池発電シ
ステムを得ることができる。
As explained above, this invention keeps the system warm at the minimum energy consumption rate by installing a separate compressor or blower that supplies the minimum amount of air necessary to keep the system warm when the system is stopped. It is possible to obtain a fuel cell power generation system that can perform the following steps.
第1図は一般的な燃料電池発電システムを示す
系統図、第2図はこの発明の一実施例による燃料
電池発電システムを示す系統図である。
図において、1は燃料電池本体、2は改質器、
3はターボコンプレツサ、4は助燃炉、10は別
置コンプレツサ又はブロワである。尚、図中同一
符号は同一又は相当部分を示す。
FIG. 1 is a system diagram showing a general fuel cell power generation system, and FIG. 2 is a system diagram showing a fuel cell power generation system according to an embodiment of the present invention. In the figure, 1 is the fuel cell main body, 2 is a reformer,
3 is a turbo compressor, 4 is an auxiliary combustion furnace, and 10 is a separate compressor or blower. Note that the same reference numerals in the figures indicate the same or corresponding parts.
Claims (1)
燃料電池に水素ガスを供給する改質器と、この改
質器の排ガス又は上記燃料電池の空気極出口の余
剰空気及び上記改質器の排ガスの両方によつて駆
動され上記燃料電池と改質器に必要な圧縮空気を
供給するターボコンプレツサと、上記ターボコン
プレツサのタービンの不足動力を補う助燃炉を備
えた燃料電池発電システムにおいて、上記ターボ
コンプレツサとは別に設置され、上記燃料電池と
改質器に圧縮空気を供給するライン上に、システ
ム停止時に運転され上記改質器の暖保持に必要な
最小限の空気を供給するコンプレツサ又はブロワ
を備えたことを特徴とする燃料電池発電システ
ム。1. A fuel cell, a reformer that reforms hydrocarbon fuel and supplies hydrogen gas to the fuel cell, and exhaust gas from the reformer or surplus air at the air electrode outlet of the fuel cell and the reformer. In a fuel cell power generation system, the fuel cell power generation system is equipped with a turbo compressor that is driven by both the exhaust gas of , is installed separately from the turbo compressor, and is operated on a line that supplies compressed air to the fuel cell and reformer when the system is stopped, supplying the minimum amount of air necessary to keep the reformer warm. A fuel cell power generation system characterized by being equipped with a compressor or a blower.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59016212A JPS60158560A (en) | 1984-01-30 | 1984-01-30 | Fuel cell power generating system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59016212A JPS60158560A (en) | 1984-01-30 | 1984-01-30 | Fuel cell power generating system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60158560A JPS60158560A (en) | 1985-08-19 |
| JPH0345867B2 true JPH0345867B2 (en) | 1991-07-12 |
Family
ID=11910216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59016212A Granted JPS60158560A (en) | 1984-01-30 | 1984-01-30 | Fuel cell power generating system |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60158560A (en) |
-
1984
- 1984-01-30 JP JP59016212A patent/JPS60158560A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60158560A (en) | 1985-08-19 |
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