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JPH0356179B2 - - Google Patents
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JPH0356179B2 - - Google Patents

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Publication number
JPH0356179B2
JPH0356179B2 JP58094358A JP9435883A JPH0356179B2 JP H0356179 B2 JPH0356179 B2 JP H0356179B2 JP 58094358 A JP58094358 A JP 58094358A JP 9435883 A JP9435883 A JP 9435883A JP H0356179 B2 JPH0356179 B2 JP H0356179B2
Authority
JP
Japan
Prior art keywords
thermite
agent
cylindrical
main tube
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP58094358A
Other languages
Japanese (ja)
Other versions
JPS59218840A (en
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to JP58094358A priority Critical patent/JPS59218840A/en
Publication of JPS59218840A publication Critical patent/JPS59218840A/en
Publication of JPH0356179B2 publication Critical patent/JPH0356179B2/ja
Granted legal-status Critical Current

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  • Ceramic Products (AREA)
  • Chemically Coating (AREA)

Description

【発明の詳細な説明】 この発明は、遠心力とテルミツト反応を利用し
て、母管の内面に金属−セラミツク層を被覆形成
する、所謂遠心テルミツト法による複合構造管の
製造方法の改良に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an improvement in a method for manufacturing composite structure pipes by the so-called centrifugal thermite method, which uses centrifugal force and thermite reaction to form a metal-ceramic layer on the inner surface of the main pipe. It is.

周知のように、遠心テルミツト法による複合構
造管の製造方法は、第1図に示す如く、母管1内
に金属還元剤と金属酸化物とが一定の比率の混合
物からなるテルミツト剤2を装填し、これを高速
回転による遠心力場内で着火し、下記式に例示す
る如きテルミツト反応を行なわせ、この反応熱に
より生成される溶融金属と溶融セラミツクとを比
重分離して、第2図に示す如く、母管1の内面に
金属層3を介して所望のセラミツク層4を被覆形
成する方法である。
As is well known, the method for manufacturing composite structural tubes using the centrifugal thermite method involves loading a thermite agent 2 made of a mixture of a metal reducing agent and a metal oxide in a certain ratio into a main tube 1, as shown in FIG. Then, this is ignited in a centrifugal force field due to high speed rotation to cause a thermite reaction as exemplified by the formula below, and the molten metal and molten ceramic produced by this reaction heat are separated by specific gravity, as shown in Figure 2. In this method, the inner surface of the main tube 1 is coated with a desired ceramic layer 4 via a metal layer 3.

Fe2O3+2Al→Al2O3+2Fe +199Kcal/Al2O31モル 3Fe3O4+8Al→4Al2O3+9Fe +194Kcal/Al2O31モル ここで、母管1には、テルミツト反応に耐える
もの、例えば鉄・銅・ニツケル等の金属材(好ま
しくは1000℃以上の融点をもつもの)、又は例え
ばコンクリート・石綿セメント等の無機質材が使
用できる。一方、テルミツト剤2もFe−Al2O3
を形成する上記反応系以外のものも種々利用する
ことができる。
Fe 2 O 3 +2Al→Al 2 O 3 +2Fe +199Kcal/ Al 2 O 3 1 mole3Fe 3 O 4 +8Al→4Al 2 O 3 +9Fe +194Kcal/Al 2 O 3 1 mole A durable material such as a metal material such as iron, copper, or nickel (preferably one having a melting point of 1000° C. or higher), or an inorganic material such as concrete or asbestos cement can be used. On the other hand, various thermite agents 2 other than the above-mentioned reaction system for forming the Fe--Al 2 O 3 layer can also be used.

このような遠心テルミツト法において、テルミ
ツト剤を母管1に散布する方法として、一般的に
は第3図に示す如く、左右に移動可能で、横断面
形状がU字形であり、その凹部に散布用テルミツ
ト剤2aを収容したテルミツト剤散布用樋6を、
遠心機金枠5に嵌装した母管1を固定するため前
記金枠5の両端に設けたバンド7,7の内の一方
のバンド7の中心孔7aを通して、挿入反転L、
樋6に収容された散布用テルミツト剤2aを、落
下散布することが行なわれている。
In such a centrifugal thermite method, the thermite agent is generally sprayed into the main tube 1, which is movable from side to side and has a U-shaped cross section, as shown in Figure 3. Thermite dispersion gutter 6 containing thermite agent 2a for use,
In order to fix the main tube 1 fitted into the centrifuge metal frame 5, the insertion inversion L,
The spraying thermite agent 2a contained in the gutter 6 is sprayed by falling.

しかし、上述のようなテルミツト剤散布方法で
は、特に長尺小径管を製造する場合、種々の点で
問題がある。先ず、樋6の横断面の大きさが、バ
ンド7の中心孔7aの大きさにより制限を受け、
樋6に十分な強度を持たせることができない場合
がある。樋6に十分な強度を与えないで、片持状
態に支持された樋6は、その自重と収容した散布
用テルミツト剤2aの重量とで、下方に容易に撓
むことになる。この撓みが大きいと、バンド7の
中心孔7aへの挿入が不可能になる場合も生じ
る。このような場合、従来においては第4図に示
す如く、母管1の両端より樋6を挿入しなければ
ならず、倍の設備を必要とし作業性も悪かつた。
また、樋6の散布用テルミツト剤2a収容量が少
ない場合、必要量のテルミツト剤を母管1内に供
給するには、散布作業を数回に分けて行なわなけ
ればならないこともあり、散布作業の効率が悪
く、延いては、複合構造管の生産性が低くなると
いう欠点もあつた。
However, the thermite spraying method described above has various problems, particularly when manufacturing long and small diameter pipes. First, the size of the cross section of the gutter 6 is limited by the size of the center hole 7a of the band 7,
There are cases where the gutter 6 cannot have sufficient strength. If the gutter 6 is supported in a cantilevered manner without providing sufficient strength to the gutter 6, the gutter 6 will easily bend downward due to its own weight and the weight of the thermite agent for dispersion 2a contained therein. If this deflection is large, it may become impossible to insert the band 7 into the center hole 7a. In such a case, conventionally, as shown in FIG. 4, the gutter 6 had to be inserted from both ends of the main pipe 1, requiring twice the amount of equipment and resulting in poor workability.
In addition, if the capacity of the thermite agent 2a for spraying in the gutter 6 is small, the spraying operation may have to be carried out in several parts in order to supply the required amount of thermite agent into the main pipe 1. This method also had the drawback of poor efficiency, which in turn led to low productivity of composite structure pipes.

この発明は、遠心テルミツト法において、母管
1が長尺小径管の場合であつても、前述の問題点
を解決し、生産性の向上を図る効率の良い複合構
造管の製造方法を提供するものである。そして、
この発明の要旨とするところは、母管内にテルミ
ツト剤を充填し、遠心力場内で該テルミツト剤を
着火反応せしめ、母管内面にテルミツト反応によ
り生成された金属−セラミツク層を被覆形成する
方法において、外筒と両端面とが金属製薄板、内
筒がテルミツト剤で目塗りされた網状金属材で作
成され、外筒と内筒の間に粉末テルミツト剤が充
填されてなる円筒状テルミツト単位体を、母管内
に装填して後、遠心力場内で該円筒状テルミツト
単位体に着火して、テルミツト反応を起こさせる
点にある。
The present invention solves the above-mentioned problems in the centrifugal thermite method even when the main tube 1 is a long and small diameter tube, and provides an efficient method for manufacturing a composite structure tube that improves productivity. It is something. and,
The gist of this invention is to provide a method for filling a thermite agent into a main tube, igniting the thermite agent in a centrifugal force field, and coating the inner surface of the main tube with a metal-ceramic layer produced by the thermite reaction. , a cylindrical thermite unit in which the outer cylinder and both end faces are made of thin metal plates, the inner cylinder is made of a net-like metal material coated with a thermite agent, and the outer cylinder and the inner cylinder are filled with powdered thermite agent. After being loaded into the main tube, the cylindrical thermite unit is ignited in a centrifugal force field to cause a thermite reaction.

以下この発明の一実施例について詳述する。 An embodiment of the present invention will be described in detail below.

先ず、この発明に使用する円筒状テルミツト単
位体8について、第5図に基づいて説明する。円
筒状テルミツト単位体8は、一端がその中心部に
円形孔9aを有し他端が開口している外筒9と、
その開口部に冠着可能で前記円形孔9aと同形状
の円形孔10aを中心部に有した蓋体10と、こ
れらの円形孔9a,10aに容易に挿入可能な円
筒11と、外筒9と内筒11との間に充填された
封入テルミツト剤12とから成る。前記外筒9と
蓋体10とは、金属製薄板で作成され、内筒11
は、テルミツト剤で目塗りされた網状金属材で作
成されている。その網状金属材にテルミツト剤を
目塗りする方法として、一例を挙げれば、約5wt
%の水ガラス水溶液で泥状にしたテルミツト剤
を、網状金属材の多孔に塗り込め乾燥する方法が
ある。この塗り込め乾燥の時期は、封入テルミツ
ト剤12の充填前であればいつでもよい。また、
この網状金属材の網目の大きさは、泥状テルミツ
ト剤の付着の容易さから2mm目くらいが好まし
い。そして、この内筒11の長さは、外筒9のそ
れより長いことが必要である。その理由は、外筒
9と蓋体10と内筒11と封入テルミツト剤12
とを用いて、円筒状テルミツト単位体8を組み立
てるとき必要となるからである。この組み立て方
法を詳しく述べると、先ず、外筒9の一端にある
円形孔9aに、内筒11の一部が折り曲げうる長
さを有するまで、外筒9の開口側から内筒11を
挿入し、その挿出した部分を、適度な放射状に切
断し、直角外方向へそれぞれ折り曲げる。(この
状態で、前述した内筒11の目塗り作業を行なつ
てもよい。)次に、封入テルミツト剤12を、こ
の外筒9と内筒11の間に充填して後、蓋体10
を内筒11に外嵌すると共に外筒9に冠着する。
このとき、内筒11が冠着した蓋体10より、折
り曲げる程度に挿出していなければならず、この
挿出した部分を前述のように折り曲げ、蓋体10
と外筒9と内筒11とを一体化させ、円筒状テル
ミツト単位体8を得る。
First, the cylindrical thermite unit 8 used in the present invention will be explained based on FIG. The cylindrical thermite unit 8 includes an outer cylinder 9 having a circular hole 9a in the center at one end and an open end at the other end;
A lid body 10 that can be attached to the opening thereof and has a circular hole 10a having the same shape as the circular hole 9a in the center, a cylinder 11 that can be easily inserted into these circular holes 9a and 10a, and an outer cylinder 9. and an encapsulated thermite agent 12 filled between the inner cylinder 11 and the inner cylinder 11. The outer cylinder 9 and the lid 10 are made of thin metal plates, and the inner cylinder 11
is made of reticulated metal material coated with a thermite agent. One example of a method for coating the net-like metal material with a thermite agent is approximately 5wt.
There is a method in which a thermite agent made into a slurry with an aqueous solution of 100% water glass is applied into the pores of a mesh metal material and allowed to dry. The application and drying may be performed at any time before the encapsulated thermite agent 12 is filled. Also,
The mesh size of this mesh metal material is preferably about 2 mm from the viewpoint of ease of adhesion of the muddy thermite agent. The length of this inner tube 11 needs to be longer than that of the outer tube 9. The reason is that the outer cylinder 9, the lid body 10, the inner cylinder 11, and the enclosed thermite agent 12
This is because it is necessary when assembling the cylindrical thermite unit body 8 using the. To describe this assembly method in detail, first, insert the inner cylinder 11 into the circular hole 9a at one end of the outer cylinder 9 from the opening side of the outer cylinder 9 until a part of the inner cylinder 11 has a length that can be bent. , cut the inserted part in an appropriate radial shape, and bend it outward at a right angle. (In this state, the aforementioned inner cylinder 11 may be painted.) Next, after filling the space between the outer cylinder 9 and the inner cylinder 11 with the encapsulated thermite agent 12, the lid 10
is fitted onto the inner cylinder 11 and attached to the outer cylinder 9.
At this time, the inner cylinder 11 must be inserted from the cap 10 to the extent that it can be bent.
The outer cylinder 9 and the inner cylinder 11 are integrated to obtain a cylindrical thermite unit body 8.

こうして得られた円筒状テルミツト単位体8は
第6図に示す如く、母管1の一端若しくは両端よ
り複数個を挿し込み挿入し、母管1全長に亘り装
填される。この場合、該円筒状テルミツト単位体
8同士は、なるべく密着した状態にすることが望
ましい。次に、この母管1をバンド7,7で固定
し、高速回転させ、該円筒状テルミツト単位体8
の内面に着火してテルミツト反応を起こさせ、母
管1内面に均一な厚みを有する金属−セラミツク
層を形成させる。
As shown in FIG. 6, a plurality of the thus obtained cylindrical thermite units 8 are inserted from one or both ends of the main pipe 1 and loaded over the entire length of the main pipe 1. In this case, it is desirable that the cylindrical thermite units 8 are brought into close contact with each other as much as possible. Next, this main tube 1 is fixed with bands 7, 7, and rotated at high speed, and the cylindrical thermite unit 8 is
The inner surface of the main tube 1 is ignited to cause a thermite reaction, and a metal-ceramic layer having a uniform thickness is formed on the inner surface of the main tube 1.

ところで、テルミツト反応を起こさせるための
着火方式として、従来は単なる花火を用いていた
が、第7図に示す如く、従来使用している花火1
3の一部に、約10gの粉末テルミツト剤14を、
包装材15、例えば、紙・セロフアン紙等で巻き
付けた粉末テルミツト剤付花火を使用すれば、着
火の容易さの点から好ましい。
By the way, in the past, simple fireworks were used as the ignition method to cause thermite reaction, but as shown in Figure 7, the conventional fireworks 1
About 10g of powdered thermite agent 14 is added to part of 3.
It is preferable to use fireworks with a powdered thermite agent wrapped in the packaging material 15, such as paper or cellophane paper, from the viewpoint of ease of ignition.

尚、母管1としては、予め製作されたものだけ
でなく、通常の遠心鋳造により、金枠5に形成し
たものであつてもよいことは勿論である。
It goes without saying that the main tube 1 may not only be made in advance, but may also be formed in the metal frame 5 by ordinary centrifugal casting.

以上述べたように、この発明では予め作成した
円筒状テルミツト単位体8を用いるので、母管1
の長短及び管径の大小を問わず、母管1内に一様
な厚みを有する金属−セラミツク層を得ることが
できる。このように、円筒状テルミツト単位体8
を用いれば、従来の樋6による散布方法の欠点は
解消される。その上、金枠5の回転の軸線方向
は、水平に限定されないという利点もある。
As described above, in this invention, since the cylindrical thermite unit body 8 prepared in advance is used, the main tube 1
A metal-ceramic layer having a uniform thickness can be obtained in the main tube 1 regardless of its length or the diameter of the tube. In this way, the cylindrical thermite unit 8
By using this, the drawbacks of the conventional spraying method using the gutter 6 are eliminated. Furthermore, there is an advantage that the axial direction of rotation of the metal frame 5 is not limited to the horizontal direction.

次に、本発明の実施例を挙げる。 Next, examples of the present invention will be given.

実施例 1 厚みが0.2mmの薄鋼板で作成された外径147mmの
外筒と、5wt%水ガラス水溶液で泥状にしたテル
ミツト剤により、約2mmの網目を目塗りされた金
網で作成された内径89mmの内筒との間に、約4Kg
のテルミツト剤を充填し、厚みが0.2mmの薄鋼板
で作成された外径149mmの蓋体を、内筒と外筒に
挿入冠着して一体とした全長300mmの円筒状テル
ミツト単位体5個を、母管として外径165.2mm、
内径151.0mm、全長1500mmの鋼管に順次押し込み
装填し、この鋼管をバンドで固定し、高速回転を
行ないながら、円筒状テルミツト単位体の内面に
着火し、テルミツト反応を起こさせ、金属−セラ
ミツク層を鋼管内面に形成させた。この方法で製
作したセラミツク複合鋼管は、従来の粉末テルミ
ツト剤を樋で散布して製作したものと比べて、品
質は同等であり、その製作効率は著しく向上した
ことが確認された。
Example 1 An outer cylinder with an outer diameter of 147 mm made of a thin steel plate with a thickness of 0.2 mm, and a wire mesh coated with a mesh of about 2 mm using a thermite agent made into a slurry with a 5 wt% water glass aqueous solution. Approximately 4 kg between the inner cylinder with an inner diameter of 89 mm
Five cylindrical thermite units with a total length of 300 mm are filled with a thermite agent and are made of a thin steel plate with a thickness of 0.2 mm and have an outer diameter of 149 mm and are inserted into the inner and outer cylinders and attached to the caps. , outer diameter 165.2mm as the main pipe,
Thermite is sequentially pushed and loaded into a steel tube with an inner diameter of 151.0 mm and a total length of 1500 mm, and the steel tube is fixed with a band.While rotating at high speed, the inner surface of the cylindrical thermite unit is ignited, causing a thermite reaction, and forming a metal-ceramic layer. Formed on the inner surface of a steel pipe. It was confirmed that the quality of ceramic composite steel pipes manufactured using this method was equivalent to that of conventional pipes manufactured by spraying powdered thermite with a gutter, and that the manufacturing efficiency was significantly improved.

実施例 2 母管として、外径165.2mm、内径151.0mm、全長
3000mmの鋼管を使用する場合、母管の一端より樋
を挿入する方法では、樋の撓みのため実施不可能
であるので、従来は母管の両端より樋を挿入し散
布しなければならなかつた。これに対し、本発明
によれば、実施例1で使用した円筒状テルミツト
単位体10個を、鋼管の一端より順次押し込み挿入
することにより、テルミツト剤を管内に均一且つ
効率良く装填でき、最終製品として、均一な厚み
の金属−セラミツク層を有するセラミツク複合鋼
管を得ることができた。
Example 2 As a main pipe, outer diameter 165.2 mm, inner diameter 151.0 mm, total length
When using a 3000mm steel pipe, it is impossible to insert a gutter from one end of the main pipe due to the flexure of the gutter, so conventionally it was necessary to insert a gutter from both ends of the main pipe for spraying. . In contrast, according to the present invention, by sequentially pushing and inserting the 10 cylindrical thermite units used in Example 1 from one end of the steel pipe, the thermite agent can be uniformly and efficiently loaded into the pipe, and the final product As a result, a ceramic composite steel pipe having a metal-ceramic layer of uniform thickness could be obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図及び第2図は、従来の遠心テルミツト法
による複合構造管の製造方法を示す横断面説明図
であり、第1図は、テルミツト反応前の装填状態
を、第2図は、金属−セラミツク層の被覆状態を
示している。第3図及び第4図は、従来のテルミ
ツト剤の散布方法の説明図で、散布用樋を挿入し
ている状態での縦断面図であり、第3図は、母管
の一端から、第4図は、母管の両端から樋を挿入
している状態を示している。第5図は、円筒状テ
ルミツト単位体の縦断面図、第6図は、複数の円
筒状テルミツト単位体を母管内に装填した状態を
示す縦断面説明図、第7図は、粉末テルミツト剤
付花火の縦断面図を示している。 1…母管、2…テルミツト剤、2a…散布用テ
ルミツト剤、3…金属層、4…セラミツク層、5
…金枠、6…樋、7…バンド、7a…中心孔、8
…円筒状テルミツト単位体、9…外筒、9a…円
形孔、10…蓋体、10a…円形孔、11…内
筒、12…封入テルミツト剤。
1 and 2 are explanatory cross-sectional views showing a method of manufacturing a composite structure tube by the conventional centrifugal thermite method. FIG. 1 shows the loaded state before the thermite reaction, and FIG. The state of the ceramic layer coating is shown. Figures 3 and 4 are explanatory diagrams of the conventional method of dispersing thermite agent, and are longitudinal cross-sectional views with the dispersion gutter inserted. Figure 4 shows the gutter being inserted from both ends of the main pipe. Fig. 5 is a longitudinal cross-sectional view of a cylindrical thermite unit, Fig. 6 is a longitudinal cross-sectional explanatory view showing a state in which a plurality of cylindrical thermite units are loaded into a main tube, and Fig. 7 is a longitudinal cross-sectional view of a cylindrical thermite unit. A vertical cross-sectional view of fireworks is shown. DESCRIPTION OF SYMBOLS 1... Main tube, 2... Thermite agent, 2a... Thermite agent for dispersion, 3... Metal layer, 4... Ceramic layer, 5
...Gold frame, 6...Gutter, 7...Band, 7a...Center hole, 8
... Cylindrical thermite unit, 9... Outer cylinder, 9a... Circular hole, 10... Lid, 10a... Circular hole, 11... Inner cylinder, 12... Enclosed thermite agent.

Claims (1)

【特許請求の範囲】[Claims] 1 母管内にテルミツト剤を装填し、遠心力場内
で該テルミツト剤を着火反応せしめ、母管内面に
テルミツト反応により生成された金属−セラミツ
ク層を被覆形成する方法において、外筒と両端面
とが金属製薄板、内筒がテルミツト剤で目塗りさ
れた網状金属材で作成され、外筒と内筒の間に粉
末テルミツト剤が充填されてなる円筒状テルミツ
ト単位体を、母管内に装填して後、遠心力場内で
該円筒状テルミツト単位体に着火して、テルミツ
ト反応を起こさせることを特徴とする複合構造管
の製造方法。
1 In a method in which a thermite agent is loaded into the main tube, the thermite agent is ignited in a centrifugal force field, and a metal-ceramic layer generated by the thermite reaction is coated on the inner surface of the main tube, the outer cylinder and both end surfaces are A cylindrical thermite unit made of a thin metal plate, an inner cylinder made of a net-like metal material coated with a thermite agent, and a powdered thermite agent filled between the outer cylinder and the inner cylinder is loaded into the main tube. A method for producing a composite structure tube, which comprises: then igniting the cylindrical thermite unit in a centrifugal force field to cause a thermite reaction.
JP58094358A 1983-05-27 1983-05-27 Manufacturing method of composite structure pipe Granted JPS59218840A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58094358A JPS59218840A (en) 1983-05-27 1983-05-27 Manufacturing method of composite structure pipe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58094358A JPS59218840A (en) 1983-05-27 1983-05-27 Manufacturing method of composite structure pipe

Publications (2)

Publication Number Publication Date
JPS59218840A JPS59218840A (en) 1984-12-10
JPH0356179B2 true JPH0356179B2 (en) 1991-08-27

Family

ID=14108068

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58094358A Granted JPS59218840A (en) 1983-05-27 1983-05-27 Manufacturing method of composite structure pipe

Country Status (1)

Country Link
JP (1) JPS59218840A (en)

Also Published As

Publication number Publication date
JPS59218840A (en) 1984-12-10

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