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JPH0359985B2 - - Google Patents
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JPH0359985B2 - - Google Patents

Info

Publication number
JPH0359985B2
JPH0359985B2 JP59096923A JP9692384A JPH0359985B2 JP H0359985 B2 JPH0359985 B2 JP H0359985B2 JP 59096923 A JP59096923 A JP 59096923A JP 9692384 A JP9692384 A JP 9692384A JP H0359985 B2 JPH0359985 B2 JP H0359985B2
Authority
JP
Japan
Prior art keywords
metal substrate
metal
titanium
titanium nitride
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP59096923A
Other languages
Japanese (ja)
Other versions
JPS60243267A (en
Inventor
Yoshio Morita
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Epson Corp
Original Assignee
Seiko Epson Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seiko Epson Corp filed Critical Seiko Epson Corp
Priority to JP9692384A priority Critical patent/JPS60243267A/en
Publication of JPS60243267A publication Critical patent/JPS60243267A/en
Publication of JPH0359985B2 publication Critical patent/JPH0359985B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02Pretreatment of the material to be coated
    • C23C14/024Deposition of sublayers, e.g. to promote adhesion of the coating
    • C23C14/025Metallic sublayers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Dry Shavers And Clippers (AREA)
  • Physical Vapour Deposition (AREA)

Description

【発明の詳細な説明】 〔技術分野〕 本発明は、電気カミソリ用外刃に関する。[Detailed description of the invention] 〔Technical field〕 The present invention relates to an outer blade for an electric razor.

〔従来技術〕[Prior art]

従来、電気カミソリの切れ味を向上させ、かつ
その切れ味の寿命を長くするために、外刃の刃先
部に硬質被膜を形成することが知られている。こ
の硬質被膜としては、硬質クロム、硬質ニツケ
ル・リン等の硬質湿式メツキが代表的なものとし
てあげられる。しかしこれらの膜も、ビツカーズ
硬度1000(Kg/mm)以下であるため、外刃の寿命
としては、通常に使用して1〜2年というのが現
状であつた。
Conventionally, in order to improve the sharpness of electric razors and extend the life of the sharpness, it has been known to form a hard coating on the cutting edge of the outer blade. Typical examples of this hard coating include hard wet plating such as hard chromium and hard nickel phosphorus. However, since these films also have a Bitkers hardness of 1000 (Kg/mm) or less, the lifespan of the outer cutter is currently 1 to 2 years after normal use.

この対策のために、イオンプレーテイング法に
おいて窒化チタンの被膜を形成することが検討さ
れてきたが、金属基板と被膜との密着が悪く剥離
してしまうという問題、金属素材上に直接超硬質
被膜を形成して強い曲げ応力を加えた場合に超硬
質被膜にクラツクが入りやすく、そのクラツクが
金属基板にまで到達してしまうという問題、又イ
オンプレーテイングの際に処理熱により脆化する
ものがあるという問題があつた。
As a countermeasure to this problem, forming a titanium nitride film using the ion plating method has been considered, but there have been problems with poor adhesion between the metal substrate and the film, resulting in peeling, and the possibility of forming an ultra-hard film directly on the metal material. The problem is that when a strong bending stress is applied to an ultra-hard coating, cracks tend to form in the ultra-hard coating, and the cracks can reach the metal substrate.Also, there is the problem that the coating becomes brittle due to the processing heat during ion plating. There was a problem.

〔目 的) 本発明は、この問題点を解決するもので、その
目的とするところは、金属素材と密着の良い皮膜
構成でかつ曲げによるクラツクが入りにくい硬質
被膜を形成し、又イオンプレーテイング処理によ
る脆化を防止し硬質被膜により切れ味を向上させ
るとともに外刃の寿命を大幅に向上させようと言
うものである。
[Purpose] The present invention is intended to solve this problem, and its purpose is to form a hard coating that has a coating structure that has good adhesion to metal materials and is resistant to cracks due to bending, and also to form a hard coating that is difficult to crack due to bending. The aim is to prevent embrittlement due to processing, improve sharpness with a hard coating, and significantly extend the life of the outer blade.

〔概 要〕〔overview〕

本発明の電気カミソリ用外刃は、 金属基板に多数の透孔を穿設し、該金属基板の
表面に順に金属チタニウム層とチタニウムの窒化
物層とを、その金属チタニウム層とチタニウムの
窒化物層との厚みの割合が5:5〜9:1となる
ようにイオンプレーテイング法により合計で0.2
〜2.0μの厚さで形成したことを特徴とする電気カ
ミソリ用外刃である。
The outer cutter for an electric razor of the present invention has a metal substrate with a large number of through holes, a metal titanium layer and a titanium nitride layer on the surface of the metal substrate, and a metal titanium layer and a titanium nitride layer formed on the surface of the metal substrate. The ion plating method is used so that the thickness ratio between the layers is 5:5 to 9:1.
This outer blade for an electric razor is characterized by being formed with a thickness of ~2.0μ.

〔実施例〕〔Example〕

以下、本発明について、実施例に基づき詳細に
説明する。
Hereinafter, the present invention will be described in detail based on examples.

第1図は、従来の電気カミソリ用外刃と内刃の
断面配置図であり、第2図は、本発明による外刃
の骨格部の断面拡大図である。
FIG. 1 is a cross-sectional layout diagram of a conventional outer cutter and inner cutter for an electric razor, and FIG. 2 is an enlarged cross-sectional view of the skeleton of the outer cutter according to the present invention.

第1図において、1は外刃の骨格部の断面図で
あり、2は内刃の断面図であり矢印の方向に高速
に移動させることにより、透孔から導入された髪
を切断する。第2図において3はイオンプレーテ
イングを施したチタニウム層であり、4は窒化チ
タニウム層である。
In FIG. 1, reference numeral 1 is a cross-sectional view of the skeleton of the outer cutter, and reference numeral 2 is a cross-sectional view of the inner cutter, which cuts hair introduced through the through hole by moving the cutter at high speed in the direction of the arrow. In FIG. 2, 3 is a titanium layer subjected to ion plating, and 4 is a titanium nitride layer.

第2図において、金属基板1の材質は、13Cr
ステンレス鋼、Ni,Ni−Co材等が用いられる。
この上に4の窒化チタニウムを直接形成すると、
非常に剥離しやすく、又曲げ応力が加わつた時に
窒化チタニウム層に入つたクラツクが1の金属基
板に到達し、基板自体にクラツクが入つてしま
う。そのために中間層として3のチタニウム層を
入れることにより上記課題を解決するものであ
る。チタニウム層と窒化チタニウム層との総厚み
は外刃としての最低限の耐摩耗性を確保するため
に、0.2μ以上必要であり、かつ剥離とクラツクを
防止するためには、2μ以下であることが必要で
ある。ここにおける最適値は、1μである。又チ
タニウム層と窒化チタニウム層との厚みの割合は
5:5〜9:1の範囲が実用上特性がすぐれてお
り、特に8:2が最適である。5:5よりもチタ
ニウム層が薄いと、剥離、クラツクが生じやす
く、又9:1よりもチタニウム層が厚いと、外力
によりくぼみ等が表面につきやすくなつてしま
う。
In Fig. 2, the material of the metal substrate 1 is 13Cr.
Stainless steel, Ni, Ni-Co materials, etc. are used.
When titanium nitride 4 is directly formed on this,
It is very easy to peel off, and when bending stress is applied, cracks in the titanium nitride layer reach the metal substrate 1, causing cracks in the substrate itself. Therefore, the above-mentioned problem is solved by inserting a titanium layer 3 as an intermediate layer. The total thickness of the titanium layer and titanium nitride layer must be 0.2μ or more to ensure the minimum wear resistance of the outer cutter, and 2μ or less to prevent peeling and cracking. is necessary. The optimum value here is 1μ. Further, the ratio of the thickness of the titanium layer to the titanium nitride layer in the range of 5:5 to 9:1 has excellent practical characteristics, and in particular, 8:2 is optimal. If the titanium layer is thinner than 5:5, peeling and cracking will easily occur, and if the titanium layer is thicker than 9:1, dents and the like will easily form on the surface due to external forces.

上記のイオンプレーテイング法は公知の種々の
方法を用いることが可能であるが、いずれの方法
を用いても金属基板の温度が300℃以上に上昇し
てしまう。この金属基板として電鋳法による通常
のNi基板を用いた場合、Ni中には光沢剤として
0.08%以上のSが添加してあるため素材が脆化し
てしまうという問題がある。この問題を解決する
ためにはSの添加量を限定して、Sが低下により
硬度が低下した分だけCoの添加により補つてや
る必要がある。最低限の強度を有するためには、
20wt%のCo,0.01wt%のS及び残部Niの成分で
CoとSでHv=400以上を確保し、Sの量も少な
くして耐熱性の劣化を防止する。
Although various known methods can be used for the above-mentioned ion plating method, the temperature of the metal substrate increases to 300° C. or higher no matter which method is used. When a normal Ni substrate made by electroforming is used as the metal substrate, the Ni contains a brightening agent.
Since 0.08% or more of S is added, there is a problem that the material becomes brittle. In order to solve this problem, it is necessary to limit the amount of S added and compensate for the decrease in hardness due to the decrease in S by adding Co. In order to have the minimum strength,
With a composition of 20wt% Co, 0.01wt% S, and the balance Ni.
Ensure Hv=400 or higher with Co and S, and reduce the amount of S to prevent deterioration of heat resistance.

一方、40wt%のCo,0.001wt%のS及び残部の
Niの成分において、主にCoのみにより基本強度
を確保し、Hv=450以上としてゆく。0.001wt%
のSは自然に共析してしまう下限量である。この
20〜40wt%のCo,0.01〜0.001wt%のS及び残部
Niからなる外刃を製造するには、スルフアミン
酸ニツケル、スルフアミン酸コバルト、ホウ酸、
塩化ニツケルを主成分とするスルフアミン酸浴が
最適である。この組成の金属基板上に二層の上記
被膜を形成することにより熱による脆化もなく、
この場合イオンプレーテイングにより形成するの
で上記被膜の基板に対する密着性も著しく高く、
表面硬度も著しく高く切れ味の良い、しかも耐久
性の高い外刃を提供することができる。
On the other hand, 40wt% Co, 0.001wt% S and the balance
Regarding the Ni component, the basic strength is secured mainly by Co alone, and Hv=450 or higher. 0.001wt%
S is the lower limit amount that naturally eutectoids. this
20~40wt% Co, 0.01~0.001wt% S and balance
To manufacture the outer cutter made of Ni, nickel sulfamate, cobalt sulfamate, boric acid,
A sulfamic acid bath containing nickel chloride as the main component is most suitable. By forming two layers of the above film on a metal substrate with this composition, there is no embrittlement caused by heat.
In this case, since it is formed by ion plating, the adhesion of the film to the substrate is extremely high.
It is possible to provide an outer cutter with extremely high surface hardness, good cutting ability, and high durability.

〔効 果〕〔effect〕

以上述べたように、本発明によれば、通常の金
属基板、あるいは組成を限定した金属基板上に、
チタニウムと窒化チタニウムを一定の厚みと割合
で形成することにより、剥離がしにくく、かつ表
面からのクラツクが入りにくく、又加熱による脆
化のない切れ味が良く長寿命の外刃をつくること
ができた。
As described above, according to the present invention, on a normal metal substrate or a metal substrate with a limited composition,
By forming titanium and titanium nitride in a certain thickness and proportion, it is possible to create an outer cutter that is hard to peel off, hard to crack from the surface, and has good sharpness and long life without becoming brittle due to heating. Ta.

特に、電気カミソリ用外刃としては、肌への当
たり具合を良くするためには外刃全体が剛体では
なく変形が可能な柔軟性の高いことが要求され、
加えてヒゲを短く切断する(深ゾリ性)ために
は、外刃が薄いことが望ましいが、本発明の様
に、外刃の金属基材の表面に順に金属チタニウム
層とチタニウム窒化物層とを、合計で0.2〜2.0μ
の厚さで形成するので前述の柔軟性や深ゾリ性を
何ら損なわず、且つ表面硬度を著しく高め切れ味
を向上させ、且つ長寿命化をもたらすことができ
た。この場合、金属チタニウム層とチタニウム窒
化物層との厚みの割合が5:5〜9:1となつて
いるので、前述の様に外刃が肌に対し変形しても
金属基材に対し金属チタニウム層がバインダーの
役目となつてチタニウム窒化物層が剥離すること
がなく、且つチタニウム窒化物層が程良く厚いの
で、外刃が肌に当たつたり、他の硬いものに当た
つてもへこんだりすることがなく、総じて実用的
に極めて優れた電気カミソリの外刃を提供でき
る。
In particular, for the outer blade for electric razors, in order to improve the contact with the skin, the entire outer blade is required to be highly flexible and capable of deformation, rather than being a rigid body.
In addition, in order to cut hairs short (deep shaving properties), it is desirable that the outer blade be thin, but as in the present invention, a metal titanium layer and a titanium nitride layer are sequentially formed on the surface of the metal base material of the outer blade. , 0.2 to 2.0μ in total
Since it is formed to a thickness of 1,000 yen, the above-mentioned flexibility and deep shaving properties are not impaired in any way, and the surface hardness is significantly increased, sharpness is improved, and the tool life is extended. In this case, since the thickness ratio of the metal titanium layer and the titanium nitride layer is 5:5 to 9:1, even if the outer blade deforms against the skin as described above, the metal base material The titanium layer acts as a binder and the titanium nitride layer does not peel off, and since the titanium nitride layer is moderately thick, it will not dent even if the outer blade hits your skin or hits other hard objects. Therefore, it is possible to provide an electric razor outer blade that is completely excellent in practical use without causing any damage.

ことに、前述の金属チタニウム層と窒化チタニ
ウム層との厚みの割合が5:5〜9:1となつて
いるが、金属チタニウム層が5:5よりも薄い場
合の様に、外刃が肌に当たる時に前述の如く外刃
が変形する際、窒化チタニウム層が金属基板に対
して剥離しクラツクが生じることがなく、又金属
チタニウム層が9:1よりも厚く硬質の窒化物層
が薄い場合の様に、外刃表面に硬い物が当たつた
時外刃表面にくぼみ等がつくこともなく、電気カ
ミソリ外刃特有の秀れた作用効果を有するもので
ある。
In particular, although the thickness ratio of the metal titanium layer and the titanium nitride layer is 5:5 to 9:1, as in the case where the metal titanium layer is thinner than 5:5, the outer cutter may When the outer cutter is deformed as mentioned above, the titanium nitride layer will not peel off from the metal substrate and cracks will not occur, and when the metal titanium layer is thicker than 9:1 and the hard nitride layer is thin. Similarly, when a hard object hits the outer cutter surface, no dents are formed on the outer cutter surface, and the outer cutter has excellent functions and effects unique to the outer cutter of an electric razor.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の電気カミソリ用外刃と内刃の断
面配置図である。第2図は、本発明による外刃の
骨格部の断面拡大図である。 1…外刃体の骨格断面図、2…内刃体の断面
図、3…チタニウム層、4…窒化チタニウム層。
FIG. 1 is a cross-sectional layout diagram of an outer cutter and an inner cutter for a conventional electric razor. FIG. 2 is an enlarged cross-sectional view of the skeleton of the outer cutter according to the present invention. DESCRIPTION OF SYMBOLS 1... A cross-sectional view of the skeleton of the outer blade body, 2... A cross-sectional view of the inner blade body, 3... Titanium layer, 4... Titanium nitride layer.

Claims (1)

【特許請求の範囲】 1 金属基板に多数の透孔を穿設し、該金属基板
の表面に順に金属チタニウム層とチタニウムの窒
化物層とを、その金属チタニウム層とチタニウム
の窒化物層との厚みの割合が5:5〜9:1とな
るようにイオンプレーテイング法により合計で
0.2〜2.0μの厚さで形成したことを特徴とする電
気カミソリ用外刃。 2 特許請求の範囲第1項記載の電気カミソリ用
外刃において、多数の透孔を穿設した金属基板と
して、電鋳法による20〜40wt%のCo,0.01〜
0.001wt%のS及び残部NiからなるNi基合金の基
板を使用することを特徴とする電気カミソリ用外
刃。
[Claims] 1. A large number of through holes are formed in a metal substrate, and a metal titanium layer and a titanium nitride layer are sequentially formed on the surface of the metal substrate. In total, the ion plating method is used so that the thickness ratio is 5:5 to 9:1.
An outer blade for an electric razor characterized by being formed with a thickness of 0.2 to 2.0μ. 2. In the outer blade for an electric razor according to claim 1, the metal substrate with a large number of through holes is made of 20 to 40 wt% of Co, 0.01 to 0.01 by electroforming.
An outer blade for an electric razor characterized by using a substrate of a Ni-based alloy consisting of 0.001wt% S and the balance Ni.
JP9692384A 1984-05-15 1984-05-15 Manufacturing method for outer blades for electric razors Granted JPS60243267A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9692384A JPS60243267A (en) 1984-05-15 1984-05-15 Manufacturing method for outer blades for electric razors

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9692384A JPS60243267A (en) 1984-05-15 1984-05-15 Manufacturing method for outer blades for electric razors

Publications (2)

Publication Number Publication Date
JPS60243267A JPS60243267A (en) 1985-12-03
JPH0359985B2 true JPH0359985B2 (en) 1991-09-12

Family

ID=14177871

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9692384A Granted JPS60243267A (en) 1984-05-15 1984-05-15 Manufacturing method for outer blades for electric razors

Country Status (1)

Country Link
JP (1) JPS60243267A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6340591A (en) * 1986-08-07 1988-02-20 九州日立マクセル株式会社 Blade
JPH01104289A (en) * 1987-10-17 1989-04-21 Matsushita Electric Works Ltd Blade

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5438755B2 (en) * 1972-05-02 1979-11-22
JPS52149279A (en) * 1976-06-07 1977-12-12 Tsuneo Nishida Golden colored decorative casing parts

Also Published As

Publication number Publication date
JPS60243267A (en) 1985-12-03

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