JPH0360866B2 - - Google Patents
Info
- Publication number
- JPH0360866B2 JPH0360866B2 JP25891484A JP25891484A JPH0360866B2 JP H0360866 B2 JPH0360866 B2 JP H0360866B2 JP 25891484 A JP25891484 A JP 25891484A JP 25891484 A JP25891484 A JP 25891484A JP H0360866 B2 JPH0360866 B2 JP H0360866B2
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- silver
- solid particles
- metal ions
- bactericidal effect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010457 zeolite Substances 0.000 claims description 143
- 229910021536 Zeolite Inorganic materials 0.000 claims description 126
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 101
- 238000000034 method Methods 0.000 claims description 49
- 230000000844 anti-bacterial effect Effects 0.000 claims description 42
- 229910021645 metal ion Inorganic materials 0.000 claims description 33
- 239000002245 particle Substances 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 29
- 239000007787 solid Substances 0.000 claims description 21
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 20
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 229910052680 mordenite Inorganic materials 0.000 claims description 13
- 239000010949 copper Substances 0.000 claims description 12
- 229910052709 silver Inorganic materials 0.000 claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 11
- 239000004332 silver Substances 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229920000620 organic polymer Polymers 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 8
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 239000011701 zinc Substances 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 230000000717 retained effect Effects 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- -1 silver ions Chemical class 0.000 description 14
- 238000005342 ion exchange Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 230000001954 sterilising effect Effects 0.000 description 8
- 239000012084 conversion product Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
- 239000007790 solid phase Substances 0.000 description 6
- 239000005708 Sodium hypochlorite Substances 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000004677 Nylon Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 241001367053 Autographa gamma Species 0.000 description 3
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 229920001059 synthetic polymer Polymers 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- 101710134784 Agnoprotein Proteins 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 2
- 229910001603 clinoptilolite Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052675 erionite Inorganic materials 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002074 melt spinning Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000005033 polyvinylidene chloride Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 229910001923 silver oxide Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- PMDHMYFSRFZGIO-UHFFFAOYSA-N 1,4,7-trioxacyclotridecane-8,13-dione Chemical compound O=C1CCCCC(=O)OCCOCCO1 PMDHMYFSRFZGIO-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- NEIHULKJZQTQKJ-UHFFFAOYSA-N [Cu].[Ag] Chemical compound [Cu].[Ag] NEIHULKJZQTQKJ-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229910052908 analcime Inorganic materials 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 229910052676 chabazite Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007806 chemical reaction intermediate Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229940106012 diethylene glycol adipate Drugs 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical class [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000002504 physiological saline solution Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Description
ïŒç£æ¥äžã®å©çšåéïŒ
æ¬çºæã¯æ®ºèäœçšãæãããŒãªã©ã€ãç³»åºäœç²
åã嫿ããææ©é«ååäœãããªãæåœ¢äœã®åŠç
æ¹æ³ã«é¢ãããæŽã«è©³ããã¯æ®ºèäœçšãæããé
å±ã€ãªã³ãä¿æãããããŒãªã©ã€ãç³»åºäœç²åã
嫿ããææ©é«ååæåœ¢äœã®ç±ã«ããäžéšå€±æŽ»ã
æããªã€ãéå±ã€ãªã³ãå®å®åãããçºã®åŠçæ¹
æ³ã«é¢ããã ïŒåŸæ¥ã®æè¡ïŒ éã€ãªã³ãé ã€ãªã³ãäºéã€ãªã³çãæèæ§ã
æããããšã¯å€ãããç¥ãããŠãããäŸãã°éã€
ãªã³ã¯ç¡é žéã®æº¶æ¶²ã®åœ¢æ ã§æ¶æ¯å€ã殺èå€ãšã
ãŠåºãå©çšãããŠæ¥ããããããªã溶液ç¶ã§ã¯å
ãæ±ãã®ç¹ã§äžäŸ¿ã§ãããåãçšéã®ç¹ã§ãéå®
ãããæ¬ ç¹ããããããã§éå±ã€ãªã³ãé«ååäœ
ã«ä¿æããããªãã°ãããæ¬ ç¹ãå°ãªããåºãå
éã§ã®å©çšãæåŸ ããããšãåºæ¥ãã åŸæ¥ãéå±ã€ãªã³ãé«ååäœã«ä¿æãããæ¹æ³
ãšããŠçš®ã ã®æ¹æ³ãææ¡ãããŠãããäŸãã°éå±
ååç©ãé«ååäœã«å«æãããæ¹æ³ãšããŠãç¹é
æ54â147220å·å ¬å ±çãææ¡ãããŠãããããã
ãã®æ¹æ³ã§ã¯è©²éå±ååç©ãé«ååãžåãŒã圱é¿
ã倧ãããŠå©çšã§ããç¯å²ãèããéå®ããã
ããããã§ãªãå Žåã§ãéå±ã€ãªã³ãé«ååã«å
ã«å«æãããŠããããåã¯ä»çãããŠããã«ãã
ãªãçºã䜿çšäžã®è±èœãå€ããæ®ºèå¹æã®æç¶æ§
ã«åé¡ãããããããæ¬ ç¹ã®å°ãªãæ³ãšããŠãã€
ãªã³äº€æèœåã¯é¯äœåœ¢æèœãæããææ©å®èœåºã
é«ååã«å«æãããè©²ææ©å®èœåºã«éå±ã€ãªã³ã
ä¿æãããæ¹æ³ããç¹éæ54â3895å·å ¬å ±ãç¹å ¬
æ57â17108å·å ¬å ±ãç¹éæ58â1769å·å ¬å ±ãç¹
éæ58â1770å·å ¬å ±ãç¹éæ58â156074å·å ¬å ±ã
ç¹éæ58â220877å·å ¬å ±çã ã«ææ¡ãããŠããã
ããããªããããããã®æ¹æ³ã«æŒãŠãè©²ææ©å®èœ
åºãšé«ååãšã®çžäºäœçšãç¡èŠåºæ¥ããææ©å®èœ
åºãé«ååéå ãžå°å ¥ããã«ããããããã¯ææ©
å®èœåºå«æååç©ãé«ååãžæ·»å ããã«ãããé«
ååã®èããç©æ§å€åãé¿ããçºã«ã¯é«ååã®çš®
é¡åã³ææ©å®èœåºã®çš®é¡ãšéãæ¥µããŠçãç¯å²ã®
ãã®ãšãªããããåŸãªãã ïŒçºæã解決ããããšããåé¡ç¹ïŒ æ¬çºæè ãã¯äžèšã®æ¬ ç¹ãæ¹è¯ããç¹é¡58â
7361å·å ¬å ±ã®åŠãããŒãªã©ã€ãç³»åºäœç²åãšææ©
é«ååäœãšãããªãã該ãŒãªã©ã€ãç³»åºäœç²åã®
å°ãªããšãäžéšã殺èäœçšãæããéå±ã€ãªã³ã
ä¿æããŠããäºãç¹åŸŽãšãããŒãªã©ã€ãç²å嫿
é«ååäœåã³ãã®è£œé æ¹æ³ãææ¡ããã 該ãŒãªã©ã€ãç²å嫿é«ååäœã¯æ¥µããŠæèæ§
ãé«ããç¹ã«å€§è žèãé»è²ãããŠç¶çèã«æ¥µããŠ
广ã®é«ãäºã確èªããããããããªããããã€
ãã³ïŒããã€ãã³66ããããã¯ããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒãçã®é«æž©ã§æº¶èåæåœ¢äœãšãªãããªã
ãŒã®å Žåãç±ã«ãã圱é¿ãåããçºããæåœ¢äœãš
ãªããçŽåã¯æ¥µããŠæèæ§ã¯è¯å¥œã§ããããé·æ
éæŸçœ®ããŠãããšãç°å¢æ¡ä»¶ã«ãã€ãŠã¯æèæ§ã®
äœäžãèŠãããå ŽåããããæãããŒãªã©ã€ãç²
åäžã®éå±ã€ãªã³ãäžéšå€åããŠãããã®ãšèã
ãããã æ¬çºæã¯é«ååæåœ¢äœã«ã嫿ãããããŒãªã©
ã€ãåºäœç²åå ã®éå±ã€ãªã³ãå®å®åããçºã®åŠ
çæ¹æ³ã«é¢ãããã®ã§ããã ïŒåé¡ç¹ã解決ããããã®ææ®µïŒ æ¬çºææ¹æ³ã¯æ®ºèäœçšãæãããŒãªã©ã€ãç³»åº
äœç²åã嫿ããææ©é«ååäœãããªãæåœ¢äœã
次äºå¡©çŽ é žå¡©åã³ïŒåã¯éé žåæ°ŽçŽ ã®æ°Žæº¶æ¶²ã§åŠ
çããããšãç¹åŸŽãšããã æ¬çºææ¹æ³ã«ãããŠæ®ºè广ãæãããŒãªã©ã€
ãç³»åºäœç²åãšã¯ãã¢ã«ããã·ãªã±ãŒããããªã
倩ç¶ãŸãã¯åæãŒãªã©ã€ãã®ã€ãªã³äº€æå¯èœãªéš
åã«æ®ºè广ãæã€éå±ã€ãªã³ã®ïŒçš®åã¯ïŒçš®ä»¥
äžãä¿æããŠãããã®ã§ãããæ®ºè广ã®ããé
å±ã€ãªã³ã®å¥œé©äŸãšããŠãAgãCuãZnãæãã
ãããåŸã€ãŠäžèšç®çã«å¯ŸããŠæ®ºèæ§ã®ããäžèš
éå±ã®åç¬ãŸãã¯æ··ååã®äœ¿çšãå¯èœã§ããã ãŒãªã©ã€ãã¯äžè¬ã«äžæ¬¡å çã«çºéããéªšæ Œæ§
é ãæããã¢ã«ããã·ãªã±ãŒãã§ãã€ãŠãäžè¬ã«
ã¯Al2O3ãåºæºã«ããŠXM2ïŒïœ ã»Al2O3ã»
ysio2ã»ZH2Oã§è¡šãããããïŒã¯ã€ãªã³äº€æå¯èœ
ãªéå±ã€ãªã³ã衚ãããéåžžã¯ïŒäŸ¡ãïŒäŸ¡ã®éå±
ã§ãããïœã¯ãã®åå䟡ã«å¯Ÿå¿ãããäžæ¹ïŒžãã
ã³ïœã¯ããããéå±é žåç©ãã·ãªã«ã®ä¿æ°ãã¯
çµæ¶æ°Žã®æ°ã衚ãããŠããããŒãªã©ã€ãã¯ããã®
çµææ¯åã³çްååŸãæ¯è¡šé¢ç©ãªã©ã®ç°ãå€ãã®çš®
é¡ã®ãã®ãç¥ãããŠããã ãããæ¬çºææ¹æ³ã§äœ¿çšãããŒãªã©ã€ãç³»åºäœ
ç²åã®æ¯è¡šé¢ç©ã¯150m2ïŒïœïŒç¡æ°ŽãŒãªã©ã€ãåº
æºïŒä»¥äžã§ãã€ãŠããŒãªã©ã€ãæ§ææåã®sio2ïŒ
Al2O3ã¢ã«æ¯ã¯14以äžå¥œãŸããã¯11以äžã§ãªãã
ã°ãªããªãã æ¬çºææ¹æ³ã§äœ¿çšããæ®ºèåãæããéå±ããš
ãã°éãé ããã³äºéã®æ°Žæº¶æ§å¡©é¡ã®æº¶æ¶²ã¯ãæ¬
çºæã§éå®ããŠãããŒãªã©ã€ããšã¯å®¹æã«ã€ãªã³
亀æããã®ã§ããããçŸè±¡ãå©çšããŠå¿ èŠãšãã
äžèšã®éå±ã€ãªã³ãåç¬ãŸãã¯æ··ååã§ãŒãªã©ã€
ãã®åºäœçžã«ä¿æãããããšãå¯èœã§ããããé
å±ã€ãªã³ãä¿æããŠãããŒãªã©ã€ãç³»ç²åã¯ãæ¯
衚é¢ç©ã150m2ïŒïœä»¥äžããã€sio2ïŒAl2O3ã¢ã«æ¯
ã14以äžã§ãããšããäºã€ã®æ¡ä»¶ãæºããªããã°
ãªããªããããããã§ãªããã°å¹æçãªæ®ºèäœçš
ãéæããç®çç©ãåŸãããªãããšãå€ã€ããã
ãã¯ã广ãçºæ®ã§ããç¶æ ã§ãŒãªã©ã€ãã«åºå®
ãããéå±ã€ãªã³ã®çµ¶å¯Ÿéãäžè¶³ããããã§ãã
ãšèããããã ã€ãŸãããŒãªã©ã€ãã®äº€æåºã®éã亀æé床ã
ã¢ã¯ã»ã·ããªãã€ãªã©ã®ç©çååŠçæ§è³ªã«åž°å ã
ããã®ãšèããããã åŸã€ãŠãã¢ã¬ããŠã©ãŒã·ãŒããšããŠç¥ãããŠã
ãsio2ïŒAl2O3ã¢ã«æ¯ã®å€§ããªãŒãªã©ã€ãã¯ãæ¬
é¡çºææ¹æ³ã«ãããŠå šãäžé©åœã§ããã ãŸãsio2ïŒAl2O3ã¢ã«æ¯ã14以äžã®ãŒãªã©ã€ã
ã«ãããŠã¯ã殺èäœçšãæããéå±ã€ãªã³ãåäž
ã«ä¿æãããããšãå¯èœã§ããããã®ããã«ãã
ããŒãªã©ã€ããçšããããšã«ããåããŠååãªæ®º
è广ãåŸããããå ããŠããŒãªã©ã€ãã®sio2ïŒ
Al2O3ã¢ã«æ¯ã14ãè¶ããã·ãªã«æ¯çã®é«ããŒãª
ã©ã€ãã®èé žãèã¢ã«ã«ãªæ§ã¯sio2ã®å¢å€§ãšãšã
ã«å¢å€§ããããäžæ¹ããã®åæã«ãé·æéãèŠ
ããçµæžçã«ã¿ãŠããããé«ã·ãªã«æ¯çã®ãŒãªã©
ã€ãã®äœ¿çšã¯åŸçã§ãªããåè¿°ããsio2ïŒAl2O3
âŠ14ã®å€©ç¶ãŸãã¯åæãŒãªã©ã€ãã¯æ¬æ§é ç©ã®é
åžžèããããå©çšåéã§ã¯ãèé žæ§ãèã¢ã«ã«ãª
æ§ã®ç¹ããã¿ãŠãå åã«äœ¿çšå¯èœã§ããããŸãçµ
æžçã«ã¿ãŠãå®äŸ¡ã§ããåŸçã§ããããã®æå³ã
ããsio2ïŒAl2O3ã¢ã«æ¯ã¯14以äžã§ãªããã°ãªã
ãªãã æ¬çºææ¹æ³ã§äœ¿çšããsio2ïŒAl2O3ã®ã¢ã«æ¯ã
14以äžã®ãŒãªã©ã€ãçŽ æãšããŠã¯å€©ç¶ãŸãã¯åæ
åã®äœãã®ãŒãªã©ã€ãã䜿çšå¯èœã§ãããäŸãã°
倩ç¶ã®ãŒãªã©ã€ããšããŠã¯ã¢ãã«ã·ã³
ïŒAnalcimeïŒsio2ïŒAl2O3ïŒ3.6ã5.6ïŒããã€ããµ
ã€ãïŒChabaziteïŒsio2ïŒAl2O3ïŒ3.2ã6.0ïŒãã
ã³6.4ã7.6ïŒãã¯ãªããããã©ã€ã
ïŒClinoptiloliteïŒsio2ïŒAl2O3ïŒ8.5ã10.5ïŒããšãª
ãªãã€ãïŒErioniteïŒsio2ïŒAl2O3ïŒ5.8ã7.4ïŒã
ããªãžã€ãµã€ãïŒFaujasiteïŒsio2ïŒAl2O3ïŒ4.2ã
4.6ïŒãã¢ã«ããã€ãïŒmordeniteïŒsio2ïŒAl2O3ïŒ
8.34ã10.0ïŒããã€ãªãããµã€ãïŒPhillipsiteïŒ
sio2ïŒAl2O3ïŒ2.6ã4.4ïŒçãæãããããããã
ã®å žåçãªå€©ç¶ãŒãªã©ã€ãã¯æ¬çºææ¹æ³ã«å¥œé©ã§
ãããäžæ¹åæãŒãªã©ã€ãã®å žåçã«ãã®ãšããŠ
ã¯ïŒ¡âåãŒãªã©ã€ãïŒsio2ïŒAl2O3ïŒ1.4ã2.4ïŒã
âåãŒãªã©ã€ãïŒsio2ïŒAl2O3ïŒïŒãïŒïŒãâ
åãŒãªã©ã€ãïŒsio2ïŒAl2O3ïŒïŒãïŒïŒãã¢ã«ãã
ã€ãïŒsio2ïŒAl2O3ïŒïŒã10ïŒçãæãããããã
ãããã®åæãŒãªã©ã€ãã¯æ¬çºææ¹æ³ã®ãŒãªã©ã€
ãçŽ æãšããŠå¥œé©ã§ãããç¹ã«å¥œãŸãããã®ã¯ã
åæã®ïŒ¡âåãŒãªã©ã€ããâåãŒãªã©ã€ãã
âåãŒãªã©ã€ãåã³åæåã¯å€©ç¶ã®ã¢ã«ããã€ã
ã§ããã ãŒãªã©ã€ãã®åœ¢ç¶ã¯ç²æ«ç²åç¶ã奜ãŸãããç²
ååŸã¯çšéã«å¿ããŠé©å®éžã¹ã°ãããåã¿ã®ãã
æåäœã¯ãäŸãã°å皮容åšããã€ããç²ç¶äœãã
ãã¯å€ªãããŒã«ã®ç¹ç¶çãžé©çšããå Žåã¯æ°ãã¯
ãã³ãæ°10ãã¯ãã³ãããã¯æ°100ãã¯ãã³ä»¥äž
ã§ãããäžæ¹çްãããŒã«ã®ç¹ç¶ããã€ã«ã ã«æå
ããå Žåã¯ç²ååŸãå°ããæ¹ã奜ãŸãããäŸãã°
è¡£æçšç¹ç¶ã®å Žåã¯ïŒãã¯ãã³ä»¥äžãç¹ã«ïŒãã¯
ãã³ä»¥äžã§ããããšãæãŸããã æ¬çºææ¹æ³ã«ãããŠçšããããææ©é«ååäœãš
ã¯å圢æã«ç±å±¥æŽãæããåæé«ååã§ãã€ãŠç¹
ã«éå®ããããã®ã§ã¯ãªããäŸãã°ããªãšãã¬
ã³ãããªãããã¬ã³ãããªã¹ãã¬ã³ãããªå¡©åã
ãã«ãããªå¡©åãããªãã³ãããªã¢ãããããªãš
ã¹ãã«ãããªããã«ã¢ã«ã³ãŒã«ããã€ã«ãŒãããŒ
ããããªã¢ã»ã¿ãŒã«ãABSæš¹èãã¢ã«ãªã«æš¹èã
ãµã€çŽ æš¹èãããªãŠã¬ã¿ã³ãšã©ã¹ãããŒãããªãš
ã¹ãã«ãšã©ã¹ãããŒãªã©ã®ç±å¯å¡æ§æ§æé«ååã
ããšããŒã«æš¹èããŠãªã¢æš¹èãã¡ã©ãã³æš¹èãäž
飜åããªãšã¹ãã«æš¹èããšããã·æš¹èããŠã¬ã¿ã³
æš¹èçã®ç±ç¡¬åæ§åæé«ååãªã©ãæããããã
é«ã殺è广ãå¿ èŠãšããå Žåã«ã¯æåäœã®è¡šé¢
ç©ã倧ããæ¹ã奜ãŸããããã®äžã€ã®æ¹æ³ãšããŠ
ç¹ç¶ç¶ã«æåããããšãèãããããããã芳ç¹
ãã奜ãŸããææ©é«ååäœã¯ç¹ç¶åœ¢ææ§é«ååã§
ãã€ãŠãäŸãã°ãã€ãã³ïŒããã€ãã³66ãããªã
ãã«ã¢ã«ã³ãŒããããªå¡©åããã«ãããªå¡©åãã
ãªãã³ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªãã
ã¬ã³ãã¬ãã¿ã¬ãŒããããªã¢ã¯ãªããããªã«ãã
ãªãšãã¬ã³ãããªãããã¬ã³ããã³ãããã®å ±é
åäœãªã©ã®åæé«ååãæããããã æ¬çºææ¹æ³ã®ãŒãªã©ã€ãç²å嫿é«ååäœã¯ã
ããããŒãªã©ã€ãç³»åºäœç²åãšææ©é«ååäœãšã
ããªããã®ã§ãã€ãŠã該ãŒãªã©ã€ãç³»åºäœç²åã®
å°ããšãïŒéšã殺èäœçšãæããéå±ã€ãªã³ãä¿
æããŠããããŒãªã©ã€ãç³»åºäœç²åãå šäœäžã«å
ããå²åã¯0.01ã50ééïŒ ïŒç¡æ°ŽãŒãªã©ã€ãåº
æºïŒã§ãããåèšã®äžéå€ä»¥äžã®å Žåã¯ã殺èå¹
æã®ç¹ã§äžæºè¶³ã§ãããäžæ¹åèšã®äžéå€ãè¶ã
ãŠã殺è广ã¯ã»ãŒäžå€ã§ããäžã«ãé«ååäœã®
ç©æ§å€åã倧ãããªããé«ååæååãšããŠã®çš
éãéå®ããããããã芳ç¹ãããã奜ãŸããå«
æéç¯å²ã¯0.05ã40ééïŒ ã§ãããããã«æ¬çºæ
ã®ç²å嫿é«ååäœãç¹ç¶åããŠçšããå Žåã«
ã¯ã0.05ã10ééïŒ ã®ç¯å²ã奜é©ã§ããã éå±ã€ãªã³ã¯ãŒãªã©ã€ãç³»åºäœç²åã«ã€ãªã³äº€
æåå¿ã«ããä¿æãããªããã°ãªããªããã€ãªã³
亀æã«ãããåã«åžçãããã¯ä»çãããã®ã§ã¯
殺è广ããã³ãã®æç¶æ§ãäžå åã§ãããéå±
ã€ãªã³ãä¿æãããæ¹æ³ãšããŠã¯ãåçš®ã®ãŒãªã©
ã€ããAgâãŒãªã©ã€ãã«è»¢æããå ŽåãäŸã«ãš
ããšãéåžžAgâãŒãªã©ã€ã転æã«éããŠã¯ç¡é ž
éã®ãããªæ°Žæº¶æ§éå¡©ã®æº¶æ¶²ã䜿çšãããããã
ãã®æ¿åºŠã¯é倧ã«ãªããªãããçæããå¿ èŠãã
ããäŸãã°ïŒ¡âåãŸãã¯ïŒžâåãŒãªã©ã€ãïŒãã
ãªãŠã âåïŒãã€ãªã³äº€æåå¿ãå©çšããŠAgâ
ãŒãªã©ã€ãã«è»¢æããéã«ãéã€ãªã³æ¿åºŠã倧ã§
ãããšïŒäŸãã°ïŒã2MAgHO3äœ¿çšæã¯ïŒã€ãªã³
亀æã«ããéã€ãªã³ã¯åºçžã®ãããªãŠã ã€ãªã³ãš
眮æãããšåæã«ãŒãªã©ã€ãåºçžäžã«éã®é žåç©
çãæ²æ®¿æåºããããã®ããã«ããŒãªã©ã€ãã®å€
åæ§ã¯æžå°ããæ¯è¡šé¢ç©ã¯èããæžå°ããæ¬ ç¹ã
ããããŸãæ¯è¡šé¢ç©ã¯ããã»ã©æžå°ããªããŠãã
éé žåç©ã®ååšèªäœã«ãã€ãŠæ®ºèåã¯äœäžããã
ãããéå°éã®ãŒãªã©ã€ãçžãžã®æåºã鲿¢ãã
ããã«ã¯éæº¶æ¶²ã®æ¿åºŠãããåžéç¶æ äŸãã°
0.3MAgNO3以äžã«ä¿ã€ããšãå¿ èŠã§ããããã€
ãšãå®å šãªAgNO3ã®æ¿åºŠã¯0.1M以äžã§ãããã
ããæ¿åºŠã®AgNO3溶液ã䜿çšããå Žåã«ã¯åŸã
ããAgâãŒãªã©ã€ãã®æ¯è¡šé¢ç©ã転æçŽ æã®ãŒ
ãªã©ã€ããšã»ãŒåçã§ãããæ®ºèåã®å¹æãæé©
æ¡ä»¶ã§çºæ®ã§ããã æ¬¡ã«ããŒãªã©ã€ãé¡ãCuâãŒãªã©ã€ãã«è»¢æ
ããå Žåã«ããã€ãªã³äº€æã«äœ¿çšããé å¡©ã®æ¿åºŠ
ã«ãã€ãŠã¯ãåè¿°ã®AgâãŒãªã©ã€ããšåæ§ãªçŸ
象ãèµ·ããäŸãã°ïŒ¡âåãŸãã¯ïŒžâåãŒãªã©ã€ã
ïŒãããªãŠã âåïŒãã€ãªã³äº€æåå¿ã«ããCuâ
ãŒãªã©ã€ãã«è»¢æããéã«ã1MCuSO4äœ¿çšæã¯ã
Cu2+ã¯åºçžã®Ma+ãšçœ®æãããããããšåæã«
ãŒãªã©ã€ãåºçžäžã«Cu3ïŒSO4ïŒïŒOHïŒ4ã®ãããªå¡©
åºæ§æ²æ®¿ãæåºããããã«ãŒãªã©ã€ãã®å€åæ§ã¯
æžå°ããæ¯è¡šé¢ç©ã¯èããæžå°ããæ¬ ç¹ãããã
ãããéå°ãªé ã®ãŒãªã©ã€ãçžãžã®æåºã鲿¢ã
ãããã«ã¯äœ¿çšããæ°Žæº¶æ§é æ¶²ã®æ¿åºŠãããåžé
ç¶æ ãäŸãã°0.05M以äžã«ä¿ã€ããšã奜ãŸããã
ãããæ¿åºŠã®CuSO4溶液ã®äœ¿çšæã«ã¯åŸããã
CuâãŒãªã©ã€ãã®æ¯è¡šé¢ç©ã転æçŽ æã®ãŒãªã©
ã€ããšã»ãŒåçã§ãããæ®ºè广ãæé©ãªç¶æ ã§
çºæ®ã§ããå©ç¹ãããã ZnâãŒãªã©ã€ããžã®è»¢æã«éããŠã¯ã䜿çšã
ãå¡©é¡ãïŒã3Mã®ä»è¿ã§ã¯ãŒãªã©ã€ãåºçžãžã®
åºåœ¢ç©ã®æåºã¯èŠãããªããZnâãŒãªã©ã€ãã¯
äžèšæ¿åºŠä»è¿ã®å¡©é¡ã䜿çšããããšã«ãã容æã«
åŸãããã äžè¿°ã®AgâãŒãªã©ã€ããCuâãŒãªã©ã€ããã
ã³ZnâãŒãªã©ã€ããžã®è»¢æã«éããŠã€ãªã³äº€æ
åå¿ããããæ³ã§å®æœããéã«ã¯äžè¿°ã®æ¿åºŠãæ
ãã塩顿º¶æ¶²ãçšããŠãŒãªã©ã€ãçŽ æã®æµžæŒ¬åŠç
ã宿œããã°ããããŒãªã©ã€ãçŽ æäžãžã®éå±å«
æéãé«ããããã«ã¯ãããåŠçã®åæ°ãå¢å€§ã
ãã°ãããäžæ¹ãäžè¿°ã®æ¿åºŠãæãã塩顿º¶æ¶²ã
çšããŠã«ã©ã æ³ã«ãããŒãªã©ã€ãçŽ æãåŠçãã
éã«ã¯åžçå¡ã«ãŒãªã©ã€ãçŽ æãå å¡«ããããã«
塩顿º¶æ¶²ãééãããã°å®¹æã«ç®çãšããéå±â
ãŒãªã©ã€ããåŸãããã äžèšã®éå±âãŒãªã©ã€ãïŒç¡æ°ŽãŒãªã©ã€ãåº
æºïŒäžã«å ããéå±ã®éã¯ãéã«ã€ããŠã¯30éé
ïŒ ä»¥äžã§ããã奜ãŸããç¯å²ã¯0.001ãïŒééïŒ
ã«ãããäžæ¹ãé ããã³äºéã«ã€ããŠã¯éå±âãŒ
ãªã©ã€ãïŒç¡æ°ŽãŒãªã©ã€ãåºæºïŒäžã«å ããé ãŸ
ãã¯äºéã®éã«35ééïŒ ä»¥äžã§ããã奜ãŸããç¯
å²ã¯0.01ã15ééïŒ ã«ãããéé ããã³äºéã€ãª
ã³ã䜵çšããŠå©çšããããšãå¯èœã§ããããã®å Ž
åã¯éå±ã€ãªã³ã®åèšéã¯éå±âãŒãªã©ã€ãïŒç¡
æ°ŽãŒãªã©ã€ãåºæºïŒã«å¯Ÿã35ééïŒ ä»¥äžã§ããã
奜ãŸããç¯å²ã¯éå±ã€ãªã³ã®æ§ææ¯ã«ããå·Šå³ã
ããããããã0.001ã15ééïŒ ã«ããã ãŸããéãé ãäºé以å€ã®éå±ã€ãªã³ãäŸãã°
ãããªãŠã ãã«ãªãŠã ãã«ã«ã·ãŠã ãããã¯ä»ã®
éå±ã€ãªã³ãå ±åããŠããŠã殺è广ãããŸãã
ãããšã¯ãªãã®ã§ããããã®ã€ãªã³ã®æ®ååã¯å ±
åã¯äœãããã€ãããªãã æ¬¡ãã§ããããéå±ãŒãªã©ã€ããææ©é«ååäœ
ãžåè¿°ã®å«æéãšãªãåŠãæ·»å æ··åããŠåŸãæåœ¢
äœãšãããéå±ãŒãªã©ã€ãã«å¯Ÿãããæ®ºèäœçšã
æããéå±ã®éïŒAwtïŒ ãšããïŒåã³æåœ¢äœã«
察ããéå±ãŒãªã©ã€ãã®éïŒBwtïŒ ãšããïŒã¯ã
ãããæ®ºè广ã«é¢ä¿ãããå€ããã°ïŒ¢ã¯å°ã
ãŠãããéã«ïŒ¡ãå°ãªããšïŒ¢ãå€ãããå¿ èŠãã
ããæ®ºè广ãæå¹ã«çºæ®ããããçºã«ã¯ïŒ¡Ã
ã®å€ãéâãŒãªã©ã€ãã®å Žåã¯0.01以äžãé ãŸã
ã¯äºéâãŒãªã©ã€ãã®å Žåã¯0.1以äžãšãªããã
ã«èª¿æŽããããšãæãŸãããæ·»å æ··åã®ææãã
ã³æ¹æ³ã¯ç¹ã«éå®ããããã®ã§ã¯ãªããäŸãã°å
æã¢ãããŒã«æ·»å æ··ååéåããæ¹æ³ãåå¿äžé
äœã«æ·»å æ··åããæ¹æ³ãéåçµäºæã®ããªããŒã«
æ·»å æ··åããæ¹æ³ãããªããŒãã¬ããã«æ·»å æ··å
ããŠæåããæ¹æ³ãæåçšããŒãäŸãã°çŽ¡ç³žåæ¶²
ãžæ·»å æ··åããæ¹æ³ãªã©ããããåããŒãªã©ã€ã
ç³»åºäœç²åãããã¯ã«ã«æ··åãã¹ã©ãªãŒãšãã
åŸãèäœããªããŒã«æ··åããŠãè¯ããèŠã¯çšãã
é«ååã®æ§è³ªãå·¥çšäžã®ç¹åŸŽãªã©ã«å¿ããŠæé©ã®
æ¹æ³ãæ¡çšããã°ãããéåžžãæåçŽåã«æ·»å æ··
åããæ¹æ³ã奜é©ã§ããããããè¯å¥œãªç²åã®å
æ£ã®ããã«ã¢ãããŒã«æ·»å æ··åããããšã奜ãŸã
ãå ŽåãããããŸã該éå±âãŒãªã©ã€ãã¯é«åå
äœã«æ·»å ããåã«èŠããã°ä¹Ÿç¥åŠçãè¡ãã也ç¥
æ¡ä»¶ã¯åžžå§åã¯æžå§äž100ã500âã®ç¯å²ã§é©å®éž
ã¹ã°ããã奜ãŸããä¹Ÿç¥æ¡ä»¶ã¯æžå§äž100ã350â
ã§ããã äžèšã®åŠããæ®ºèæ§ãæããéå±ã€ãªã³ãä¿æ
ãããããŒãªã©ã€ãç³»åºäœç²åãææ©é«ååãšæ··
åããæ··åèäœã玡糞çãæåœ¢äœãšããã該æåœ¢
äœã¯æåœ¢çŽåä¹è³æ°10æ¥éã¯ãã®æèæ§èœã¯æ¥µã
ãŠè¯å¥œã§ãããããããç°å¢æ¡ä»¶ã«ãã€ãŠã¯æ°ã±
æçµéããã«ã€ããŠæèæ§èœã®äœäžãèŠãããå Ž
åãããããã®åå ã¯äžæã§ãããããŒãªã©ã€ã
äžã®éå±ã€ãªã³ã®äžéšãç±ã«ããäžå®å®åãããŠ
ããçºã«å€§æ°äžã®çš®ã ã®ã¬ã¹ã玫å€ç·çã®åœ±é¿ã
åãæããªã€ãŠãããã®ãšèãããããæ¬çºææ¹
æ³ã«æŒãŠã¯ã該æåäœãæååŸã®æ©ãææã«æ¬¡äº
éçŽ é žå¡©åã³ïŒåã¯éé žåæ°ŽçŽ ã®æ°Žæº¶æ¶²ã§æµžæŒ¬åŠ
çããã®ã§ããã æ¬çºææ¹æ³ã§çšããæ¬¡äºå¡©çŽ é žå¡©ãšããŠã¯ã次
äºå¡©çŽ é žãããªãŠã ãæ¬¡äºå¡©çŽ é žã«ãªãŠã ãæ¬¡äº
å¡©çŽ é žã«ã«ã·ãŠã çãæãããããããããéåžž
0.05ïŒ ãïŒééïŒ ã®æ°Žæº¶æ¶²ãšããåžžæž©ä¹è³70âã§
該æåœ¢äœã浞挬ãã10ã30ååŠçãããåãéé ž
åæ°ŽçŽ ã®å Žåã¯éåžž30ïŒ æ°Žæº¶æ¶²ãïŒã50mlïŒãš
ããŠäœ¿çšãããäœããæ¿åºŠãæž©åºŠçã®æ¡ä»¶ã¯ç¹ã«
éå®ããããã®ã§ã¯ãªããç¹ç¶ç¶ã®è¡šé¢ç©ã®å€§ã
ããã®ã¯äœæ¿åºŠãäœæž©ã§ååã§ãããåãæ¬¡äºå¡©
çŽ é žå¡©ãšéé žåæ°ŽçŽ ãæ··åããŠäœ¿çšããŠãè¯ãã ïŒçºæã®å¹æïŒ æ¬çºææ¹æ³ã«ããåŠçããããåŸã®è©²æåœ¢äœã®
æèæ§èœã¯æ°ã±æãçµéããŠãã»ãšãã©äœäžãã
ããšããªããé·ææç¶æ§ã«åªãããã®ãšãªããæ®º
èåãæããéå±ã€ãªã³ã¯ãŒãªã©ã€ããæ äœãšã
ãŠé«ååäœå ã«åæ£ä¿æãããã®ã§ãéå±ãã®ã
ã®ãå©çšããæ¹æ³ã«æ¯ã¹ãéå±ã€ãªã³ãåºãååž
ããŠããæ®ºè广ãå ã 倧ããèš³ã§ããããåè¿°
ã®åŠãéå±ã€ãªã³ãå®å®åãããã®ã§ãå°ãªãé
å±ã€ãªã³éã§é·æéæ®ºèæ§ãæç¶ãããåããã®
çºã®åŠçæ¹æ³ã¯æ¥µããŠç°¡åã§å®äŸ¡ãªæ¹æ³ãšèšãã
ãšãã§ããã ïŒå®æœäŸïŒ 次ã®ãæ¬çºæã®å®æœäŸã«ã€ããŠè¿°ã¹ããã宿œ
äŸäžæ®ºè广ã®è©äŸ¡ã¯ä»¥äžã®è©Šé𿹿³ã«ãã€ãŠè¡
ãªã€ãã ïŒçްèã®æ»æ» çã®æž¬å®ïŒ Escherichia coliãåã¯Staphylococcus auâ
reusã®æžæ¿æ¶²ãçšãã詊éšèæ¶²ãïŒãïŒÃ105
ã±ïŒmlãšãªãæ§åžé調æŽããããã®è©Šéšèæ¶²0.2
mlãæåœ¢äœäžã«æ»Žäžããä¿æããããŸãŸ37âã§18
æéäœçšãããã18æéåŸãæåœ¢äœãççé£å¡©æ°Ž
ã§æŽãå šäœã100mlãšããåŸããã®äžïŒmlãå¯å€©
å¹å°ã«åæ£ããã37âã§24æéä¿æããçååæ°
ãæž¬å®ããŠæ»æ» çãç®åºããã åè宿œäŸ ïŒ æ¬çºæã®å®æœäŸã§äœ¿çšããæªè»¢æã®å€©ç¶åã³å
æãŒãªã©ã€ãç²åã第ïŒè¡šã«ç€ºãããåãŒãªã©ã€
ãã¯ç²åæãç²ç ã»åçŽããŠææã®ç²ååŸãåŸ
ãã第ïŒè¡šã®ïŒ¡âåãŒãªã©ã€ããZ1ãâåãŒãª
ã©ã€ããZ2ãâåãŒãªã©ã€ããZ3ã倩ç¶ã¢ã«ã
ãã€ãïŒãZ4ã倩ç¶ã¢ã«ããã€ãïŒãZ5ã倩ç¶ã
ã€ããµã€ããZ6ãšç¥èšãããããããŒãªã©ã€ãã®
ç²ååŸã嫿°Žçãæ¯è¡šé¢ç©ã¯ç¬¬ïŒè¡šã®éãã§ãã€
ãã æ¬¡ãã§ç¬¬ïŒè¡šã®åçš®ãŒãªã©ã€ãã®åŸ®ç²æ«ä¹Ÿç¥å
å250ïœãæ¡åããåã ã«1/10ïŒç¡é žé氎溶液500
mlãå ããŠåŸãããæ··åç©ã宀枩ã«ãŠïŒæéæ¹æ
äžã«ä¿æããŠã€ãªã³äº€æãè¡ãªã€ãããããã€ãª
ã³äº€ææ³ã«ããåŸãããéâãŒãªã©ã€ããéã
ãåŸãæ°ŽæŽããŠéå°ã®éã€ãªã³ãé€å»ãããæ¬¡ã«
æ°ŽæŽæžã¿ã®éâãŒãªã©ã€ãã100ã105âã§ä¹Ÿç¥ã
ãŠããç²ç ããŠéâãŒãªã©ã€ãã®åŸ®ç²æ«ãåŸãã
åŸãããéâãŒãªã©ã€ã也ç¥åã®é嫿éåã³æ¯
衚é¢ç©ã¯ç¬¬ïŒè¡šã®åŠãã§ãã€ãã
åã嫿ããææ©é«ååäœãããªãæåœ¢äœã®åŠç
æ¹æ³ã«é¢ãããæŽã«è©³ããã¯æ®ºèäœçšãæããé
å±ã€ãªã³ãä¿æãããããŒãªã©ã€ãç³»åºäœç²åã
嫿ããææ©é«ååæåœ¢äœã®ç±ã«ããäžéšå€±æŽ»ã
æããªã€ãéå±ã€ãªã³ãå®å®åãããçºã®åŠçæ¹
æ³ã«é¢ããã ïŒåŸæ¥ã®æè¡ïŒ éã€ãªã³ãé ã€ãªã³ãäºéã€ãªã³çãæèæ§ã
æããããšã¯å€ãããç¥ãããŠãããäŸãã°éã€
ãªã³ã¯ç¡é žéã®æº¶æ¶²ã®åœ¢æ ã§æ¶æ¯å€ã殺èå€ãšã
ãŠåºãå©çšãããŠæ¥ããããããªã溶液ç¶ã§ã¯å
ãæ±ãã®ç¹ã§äžäŸ¿ã§ãããåãçšéã®ç¹ã§ãéå®
ãããæ¬ ç¹ããããããã§éå±ã€ãªã³ãé«ååäœ
ã«ä¿æããããªãã°ãããæ¬ ç¹ãå°ãªããåºãå
éã§ã®å©çšãæåŸ ããããšãåºæ¥ãã åŸæ¥ãéå±ã€ãªã³ãé«ååäœã«ä¿æãããæ¹æ³
ãšããŠçš®ã ã®æ¹æ³ãææ¡ãããŠãããäŸãã°éå±
ååç©ãé«ååäœã«å«æãããæ¹æ³ãšããŠãç¹é
æ54â147220å·å ¬å ±çãææ¡ãããŠãããããã
ãã®æ¹æ³ã§ã¯è©²éå±ååç©ãé«ååãžåãŒã圱é¿
ã倧ãããŠå©çšã§ããç¯å²ãèããéå®ããã
ããããã§ãªãå Žåã§ãéå±ã€ãªã³ãé«ååã«å
ã«å«æãããŠããããåã¯ä»çãããŠããã«ãã
ãªãçºã䜿çšäžã®è±èœãå€ããæ®ºèå¹æã®æç¶æ§
ã«åé¡ãããããããæ¬ ç¹ã®å°ãªãæ³ãšããŠãã€
ãªã³äº€æèœåã¯é¯äœåœ¢æèœãæããææ©å®èœåºã
é«ååã«å«æãããè©²ææ©å®èœåºã«éå±ã€ãªã³ã
ä¿æãããæ¹æ³ããç¹éæ54â3895å·å ¬å ±ãç¹å ¬
æ57â17108å·å ¬å ±ãç¹éæ58â1769å·å ¬å ±ãç¹
éæ58â1770å·å ¬å ±ãç¹éæ58â156074å·å ¬å ±ã
ç¹éæ58â220877å·å ¬å ±çã ã«ææ¡ãããŠããã
ããããªããããããã®æ¹æ³ã«æŒãŠãè©²ææ©å®èœ
åºãšé«ååãšã®çžäºäœçšãç¡èŠåºæ¥ããææ©å®èœ
åºãé«ååéå ãžå°å ¥ããã«ããããããã¯ææ©
å®èœåºå«æååç©ãé«ååãžæ·»å ããã«ãããé«
ååã®èããç©æ§å€åãé¿ããçºã«ã¯é«ååã®çš®
é¡åã³ææ©å®èœåºã®çš®é¡ãšéãæ¥µããŠçãç¯å²ã®
ãã®ãšãªããããåŸãªãã ïŒçºæã解決ããããšããåé¡ç¹ïŒ æ¬çºæè ãã¯äžèšã®æ¬ ç¹ãæ¹è¯ããç¹é¡58â
7361å·å ¬å ±ã®åŠãããŒãªã©ã€ãç³»åºäœç²åãšææ©
é«ååäœãšãããªãã該ãŒãªã©ã€ãç³»åºäœç²åã®
å°ãªããšãäžéšã殺èäœçšãæããéå±ã€ãªã³ã
ä¿æããŠããäºãç¹åŸŽãšãããŒãªã©ã€ãç²å嫿
é«ååäœåã³ãã®è£œé æ¹æ³ãææ¡ããã 該ãŒãªã©ã€ãç²å嫿é«ååäœã¯æ¥µããŠæèæ§
ãé«ããç¹ã«å€§è žèãé»è²ãããŠç¶çèã«æ¥µããŠ
广ã®é«ãäºã確èªããããããããªããããã€
ãã³ïŒããã€ãã³66ããããã¯ããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒãçã®é«æž©ã§æº¶èåæåœ¢äœãšãªãããªã
ãŒã®å Žåãç±ã«ãã圱é¿ãåããçºããæåœ¢äœãš
ãªããçŽåã¯æ¥µããŠæèæ§ã¯è¯å¥œã§ããããé·æ
éæŸçœ®ããŠãããšãç°å¢æ¡ä»¶ã«ãã€ãŠã¯æèæ§ã®
äœäžãèŠãããå ŽåããããæãããŒãªã©ã€ãç²
åäžã®éå±ã€ãªã³ãäžéšå€åããŠãããã®ãšèã
ãããã æ¬çºæã¯é«ååæåœ¢äœã«ã嫿ãããããŒãªã©
ã€ãåºäœç²åå ã®éå±ã€ãªã³ãå®å®åããçºã®åŠ
çæ¹æ³ã«é¢ãããã®ã§ããã ïŒåé¡ç¹ã解決ããããã®ææ®µïŒ æ¬çºææ¹æ³ã¯æ®ºèäœçšãæãããŒãªã©ã€ãç³»åº
äœç²åã嫿ããææ©é«ååäœãããªãæåœ¢äœã
次äºå¡©çŽ é žå¡©åã³ïŒåã¯éé žåæ°ŽçŽ ã®æ°Žæº¶æ¶²ã§åŠ
çããããšãç¹åŸŽãšããã æ¬çºææ¹æ³ã«ãããŠæ®ºè广ãæãããŒãªã©ã€
ãç³»åºäœç²åãšã¯ãã¢ã«ããã·ãªã±ãŒããããªã
倩ç¶ãŸãã¯åæãŒãªã©ã€ãã®ã€ãªã³äº€æå¯èœãªéš
åã«æ®ºè广ãæã€éå±ã€ãªã³ã®ïŒçš®åã¯ïŒçš®ä»¥
äžãä¿æããŠãããã®ã§ãããæ®ºè广ã®ããé
å±ã€ãªã³ã®å¥œé©äŸãšããŠãAgãCuãZnãæãã
ãããåŸã€ãŠäžèšç®çã«å¯ŸããŠæ®ºèæ§ã®ããäžèš
éå±ã®åç¬ãŸãã¯æ··ååã®äœ¿çšãå¯èœã§ããã ãŒãªã©ã€ãã¯äžè¬ã«äžæ¬¡å çã«çºéããéªšæ Œæ§
é ãæããã¢ã«ããã·ãªã±ãŒãã§ãã€ãŠãäžè¬ã«
ã¯Al2O3ãåºæºã«ããŠXM2ïŒïœ ã»Al2O3ã»
ysio2ã»ZH2Oã§è¡šãããããïŒã¯ã€ãªã³äº€æå¯èœ
ãªéå±ã€ãªã³ã衚ãããéåžžã¯ïŒäŸ¡ãïŒäŸ¡ã®éå±
ã§ãããïœã¯ãã®åå䟡ã«å¯Ÿå¿ãããäžæ¹ïŒžãã
ã³ïœã¯ããããéå±é žåç©ãã·ãªã«ã®ä¿æ°ãã¯
çµæ¶æ°Žã®æ°ã衚ãããŠããããŒãªã©ã€ãã¯ããã®
çµææ¯åã³çްååŸãæ¯è¡šé¢ç©ãªã©ã®ç°ãå€ãã®çš®
é¡ã®ãã®ãç¥ãããŠããã ãããæ¬çºææ¹æ³ã§äœ¿çšãããŒãªã©ã€ãç³»åºäœ
ç²åã®æ¯è¡šé¢ç©ã¯150m2ïŒïœïŒç¡æ°ŽãŒãªã©ã€ãåº
æºïŒä»¥äžã§ãã€ãŠããŒãªã©ã€ãæ§ææåã®sio2ïŒ
Al2O3ã¢ã«æ¯ã¯14以äžå¥œãŸããã¯11以äžã§ãªãã
ã°ãªããªãã æ¬çºææ¹æ³ã§äœ¿çšããæ®ºèåãæããéå±ããš
ãã°éãé ããã³äºéã®æ°Žæº¶æ§å¡©é¡ã®æº¶æ¶²ã¯ãæ¬
çºæã§éå®ããŠãããŒãªã©ã€ããšã¯å®¹æã«ã€ãªã³
亀æããã®ã§ããããçŸè±¡ãå©çšããŠå¿ èŠãšãã
äžèšã®éå±ã€ãªã³ãåç¬ãŸãã¯æ··ååã§ãŒãªã©ã€
ãã®åºäœçžã«ä¿æãããããšãå¯èœã§ããããé
å±ã€ãªã³ãä¿æããŠãããŒãªã©ã€ãç³»ç²åã¯ãæ¯
衚é¢ç©ã150m2ïŒïœä»¥äžããã€sio2ïŒAl2O3ã¢ã«æ¯
ã14以äžã§ãããšããäºã€ã®æ¡ä»¶ãæºããªããã°
ãªããªããããããã§ãªããã°å¹æçãªæ®ºèäœçš
ãéæããç®çç©ãåŸãããªãããšãå€ã€ããã
ãã¯ã广ãçºæ®ã§ããç¶æ ã§ãŒãªã©ã€ãã«åºå®
ãããéå±ã€ãªã³ã®çµ¶å¯Ÿéãäžè¶³ããããã§ãã
ãšèããããã ã€ãŸãããŒãªã©ã€ãã®äº€æåºã®éã亀æé床ã
ã¢ã¯ã»ã·ããªãã€ãªã©ã®ç©çååŠçæ§è³ªã«åž°å ã
ããã®ãšèããããã åŸã€ãŠãã¢ã¬ããŠã©ãŒã·ãŒããšããŠç¥ãããŠã
ãsio2ïŒAl2O3ã¢ã«æ¯ã®å€§ããªãŒãªã©ã€ãã¯ãæ¬
é¡çºææ¹æ³ã«ãããŠå šãäžé©åœã§ããã ãŸãsio2ïŒAl2O3ã¢ã«æ¯ã14以äžã®ãŒãªã©ã€ã
ã«ãããŠã¯ã殺èäœçšãæããéå±ã€ãªã³ãåäž
ã«ä¿æãããããšãå¯èœã§ããããã®ããã«ãã
ããŒãªã©ã€ããçšããããšã«ããåããŠååãªæ®º
è广ãåŸããããå ããŠããŒãªã©ã€ãã®sio2ïŒ
Al2O3ã¢ã«æ¯ã14ãè¶ããã·ãªã«æ¯çã®é«ããŒãª
ã©ã€ãã®èé žãèã¢ã«ã«ãªæ§ã¯sio2ã®å¢å€§ãšãšã
ã«å¢å€§ããããäžæ¹ããã®åæã«ãé·æéãèŠ
ããçµæžçã«ã¿ãŠããããé«ã·ãªã«æ¯çã®ãŒãªã©
ã€ãã®äœ¿çšã¯åŸçã§ãªããåè¿°ããsio2ïŒAl2O3
âŠ14ã®å€©ç¶ãŸãã¯åæãŒãªã©ã€ãã¯æ¬æ§é ç©ã®é
åžžèããããå©çšåéã§ã¯ãèé žæ§ãèã¢ã«ã«ãª
æ§ã®ç¹ããã¿ãŠãå åã«äœ¿çšå¯èœã§ããããŸãçµ
æžçã«ã¿ãŠãå®äŸ¡ã§ããåŸçã§ããããã®æå³ã
ããsio2ïŒAl2O3ã¢ã«æ¯ã¯14以äžã§ãªããã°ãªã
ãªãã æ¬çºææ¹æ³ã§äœ¿çšããsio2ïŒAl2O3ã®ã¢ã«æ¯ã
14以äžã®ãŒãªã©ã€ãçŽ æãšããŠã¯å€©ç¶ãŸãã¯åæ
åã®äœãã®ãŒãªã©ã€ãã䜿çšå¯èœã§ãããäŸãã°
倩ç¶ã®ãŒãªã©ã€ããšããŠã¯ã¢ãã«ã·ã³
ïŒAnalcimeïŒsio2ïŒAl2O3ïŒ3.6ã5.6ïŒããã€ããµ
ã€ãïŒChabaziteïŒsio2ïŒAl2O3ïŒ3.2ã6.0ïŒãã
ã³6.4ã7.6ïŒãã¯ãªããããã©ã€ã
ïŒClinoptiloliteïŒsio2ïŒAl2O3ïŒ8.5ã10.5ïŒããšãª
ãªãã€ãïŒErioniteïŒsio2ïŒAl2O3ïŒ5.8ã7.4ïŒã
ããªãžã€ãµã€ãïŒFaujasiteïŒsio2ïŒAl2O3ïŒ4.2ã
4.6ïŒãã¢ã«ããã€ãïŒmordeniteïŒsio2ïŒAl2O3ïŒ
8.34ã10.0ïŒããã€ãªãããµã€ãïŒPhillipsiteïŒ
sio2ïŒAl2O3ïŒ2.6ã4.4ïŒçãæãããããããã
ã®å žåçãªå€©ç¶ãŒãªã©ã€ãã¯æ¬çºææ¹æ³ã«å¥œé©ã§
ãããäžæ¹åæãŒãªã©ã€ãã®å žåçã«ãã®ãšããŠ
ã¯ïŒ¡âåãŒãªã©ã€ãïŒsio2ïŒAl2O3ïŒ1.4ã2.4ïŒã
âåãŒãªã©ã€ãïŒsio2ïŒAl2O3ïŒïŒãïŒïŒãâ
åãŒãªã©ã€ãïŒsio2ïŒAl2O3ïŒïŒãïŒïŒãã¢ã«ãã
ã€ãïŒsio2ïŒAl2O3ïŒïŒã10ïŒçãæãããããã
ãããã®åæãŒãªã©ã€ãã¯æ¬çºææ¹æ³ã®ãŒãªã©ã€
ãçŽ æãšããŠå¥œé©ã§ãããç¹ã«å¥œãŸãããã®ã¯ã
åæã®ïŒ¡âåãŒãªã©ã€ããâåãŒãªã©ã€ãã
âåãŒãªã©ã€ãåã³åæåã¯å€©ç¶ã®ã¢ã«ããã€ã
ã§ããã ãŒãªã©ã€ãã®åœ¢ç¶ã¯ç²æ«ç²åç¶ã奜ãŸãããç²
ååŸã¯çšéã«å¿ããŠé©å®éžã¹ã°ãããåã¿ã®ãã
æåäœã¯ãäŸãã°å皮容åšããã€ããç²ç¶äœãã
ãã¯å€ªãããŒã«ã®ç¹ç¶çãžé©çšããå Žåã¯æ°ãã¯
ãã³ãæ°10ãã¯ãã³ãããã¯æ°100ãã¯ãã³ä»¥äž
ã§ãããäžæ¹çްãããŒã«ã®ç¹ç¶ããã€ã«ã ã«æå
ããå Žåã¯ç²ååŸãå°ããæ¹ã奜ãŸãããäŸãã°
è¡£æçšç¹ç¶ã®å Žåã¯ïŒãã¯ãã³ä»¥äžãç¹ã«ïŒãã¯
ãã³ä»¥äžã§ããããšãæãŸããã æ¬çºææ¹æ³ã«ãããŠçšããããææ©é«ååäœãš
ã¯å圢æã«ç±å±¥æŽãæããåæé«ååã§ãã€ãŠç¹
ã«éå®ããããã®ã§ã¯ãªããäŸãã°ããªãšãã¬
ã³ãããªãããã¬ã³ãããªã¹ãã¬ã³ãããªå¡©åã
ãã«ãããªå¡©åãããªãã³ãããªã¢ãããããªãš
ã¹ãã«ãããªããã«ã¢ã«ã³ãŒã«ããã€ã«ãŒãããŒ
ããããªã¢ã»ã¿ãŒã«ãABSæš¹èãã¢ã«ãªã«æš¹èã
ãµã€çŽ æš¹èãããªãŠã¬ã¿ã³ãšã©ã¹ãããŒãããªãš
ã¹ãã«ãšã©ã¹ãããŒãªã©ã®ç±å¯å¡æ§æ§æé«ååã
ããšããŒã«æš¹èããŠãªã¢æš¹èãã¡ã©ãã³æš¹èãäž
飜åããªãšã¹ãã«æš¹èããšããã·æš¹èããŠã¬ã¿ã³
æš¹èçã®ç±ç¡¬åæ§åæé«ååãªã©ãæããããã
é«ã殺è广ãå¿ èŠãšããå Žåã«ã¯æåäœã®è¡šé¢
ç©ã倧ããæ¹ã奜ãŸããããã®äžã€ã®æ¹æ³ãšããŠ
ç¹ç¶ç¶ã«æåããããšãèãããããããã芳ç¹
ãã奜ãŸããææ©é«ååäœã¯ç¹ç¶åœ¢ææ§é«ååã§
ãã€ãŠãäŸãã°ãã€ãã³ïŒããã€ãã³66ãããªã
ãã«ã¢ã«ã³ãŒããããªå¡©åããã«ãããªå¡©åãã
ãªãã³ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªãã
ã¬ã³ãã¬ãã¿ã¬ãŒããããªã¢ã¯ãªããããªã«ãã
ãªãšãã¬ã³ãããªãããã¬ã³ããã³ãããã®å ±é
åäœãªã©ã®åæé«ååãæããããã æ¬çºææ¹æ³ã®ãŒãªã©ã€ãç²å嫿é«ååäœã¯ã
ããããŒãªã©ã€ãç³»åºäœç²åãšææ©é«ååäœãšã
ããªããã®ã§ãã€ãŠã該ãŒãªã©ã€ãç³»åºäœç²åã®
å°ããšãïŒéšã殺èäœçšãæããéå±ã€ãªã³ãä¿
æããŠããããŒãªã©ã€ãç³»åºäœç²åãå šäœäžã«å
ããå²åã¯0.01ã50ééïŒ ïŒç¡æ°ŽãŒãªã©ã€ãåº
æºïŒã§ãããåèšã®äžéå€ä»¥äžã®å Žåã¯ã殺èå¹
æã®ç¹ã§äžæºè¶³ã§ãããäžæ¹åèšã®äžéå€ãè¶ã
ãŠã殺è广ã¯ã»ãŒäžå€ã§ããäžã«ãé«ååäœã®
ç©æ§å€åã倧ãããªããé«ååæååãšããŠã®çš
éãéå®ããããããã芳ç¹ãããã奜ãŸããå«
æéç¯å²ã¯0.05ã40ééïŒ ã§ãããããã«æ¬çºæ
ã®ç²å嫿é«ååäœãç¹ç¶åããŠçšããå Žåã«
ã¯ã0.05ã10ééïŒ ã®ç¯å²ã奜é©ã§ããã éå±ã€ãªã³ã¯ãŒãªã©ã€ãç³»åºäœç²åã«ã€ãªã³äº€
æåå¿ã«ããä¿æãããªããã°ãªããªããã€ãªã³
亀æã«ãããåã«åžçãããã¯ä»çãããã®ã§ã¯
殺è广ããã³ãã®æç¶æ§ãäžå åã§ãããéå±
ã€ãªã³ãä¿æãããæ¹æ³ãšããŠã¯ãåçš®ã®ãŒãªã©
ã€ããAgâãŒãªã©ã€ãã«è»¢æããå ŽåãäŸã«ãš
ããšãéåžžAgâãŒãªã©ã€ã転æã«éããŠã¯ç¡é ž
éã®ãããªæ°Žæº¶æ§éå¡©ã®æº¶æ¶²ã䜿çšãããããã
ãã®æ¿åºŠã¯é倧ã«ãªããªãããçæããå¿ èŠãã
ããäŸãã°ïŒ¡âåãŸãã¯ïŒžâåãŒãªã©ã€ãïŒãã
ãªãŠã âåïŒãã€ãªã³äº€æåå¿ãå©çšããŠAgâ
ãŒãªã©ã€ãã«è»¢æããéã«ãéã€ãªã³æ¿åºŠã倧ã§
ãããšïŒäŸãã°ïŒã2MAgHO3äœ¿çšæã¯ïŒã€ãªã³
亀æã«ããéã€ãªã³ã¯åºçžã®ãããªãŠã ã€ãªã³ãš
眮æãããšåæã«ãŒãªã©ã€ãåºçžäžã«éã®é žåç©
çãæ²æ®¿æåºããããã®ããã«ããŒãªã©ã€ãã®å€
åæ§ã¯æžå°ããæ¯è¡šé¢ç©ã¯èããæžå°ããæ¬ ç¹ã
ããããŸãæ¯è¡šé¢ç©ã¯ããã»ã©æžå°ããªããŠãã
éé žåç©ã®ååšèªäœã«ãã€ãŠæ®ºèåã¯äœäžããã
ãããéå°éã®ãŒãªã©ã€ãçžãžã®æåºã鲿¢ãã
ããã«ã¯éæº¶æ¶²ã®æ¿åºŠãããåžéç¶æ äŸãã°
0.3MAgNO3以äžã«ä¿ã€ããšãå¿ èŠã§ããããã€
ãšãå®å šãªAgNO3ã®æ¿åºŠã¯0.1M以äžã§ãããã
ããæ¿åºŠã®AgNO3溶液ã䜿çšããå Žåã«ã¯åŸã
ããAgâãŒãªã©ã€ãã®æ¯è¡šé¢ç©ã転æçŽ æã®ãŒ
ãªã©ã€ããšã»ãŒåçã§ãããæ®ºèåã®å¹æãæé©
æ¡ä»¶ã§çºæ®ã§ããã æ¬¡ã«ããŒãªã©ã€ãé¡ãCuâãŒãªã©ã€ãã«è»¢æ
ããå Žåã«ããã€ãªã³äº€æã«äœ¿çšããé å¡©ã®æ¿åºŠ
ã«ãã€ãŠã¯ãåè¿°ã®AgâãŒãªã©ã€ããšåæ§ãªçŸ
象ãèµ·ããäŸãã°ïŒ¡âåãŸãã¯ïŒžâåãŒãªã©ã€ã
ïŒãããªãŠã âåïŒãã€ãªã³äº€æåå¿ã«ããCuâ
ãŒãªã©ã€ãã«è»¢æããéã«ã1MCuSO4äœ¿çšæã¯ã
Cu2+ã¯åºçžã®Ma+ãšçœ®æãããããããšåæã«
ãŒãªã©ã€ãåºçžäžã«Cu3ïŒSO4ïŒïŒOHïŒ4ã®ãããªå¡©
åºæ§æ²æ®¿ãæåºããããã«ãŒãªã©ã€ãã®å€åæ§ã¯
æžå°ããæ¯è¡šé¢ç©ã¯èããæžå°ããæ¬ ç¹ãããã
ãããéå°ãªé ã®ãŒãªã©ã€ãçžãžã®æåºã鲿¢ã
ãããã«ã¯äœ¿çšããæ°Žæº¶æ§é æ¶²ã®æ¿åºŠãããåžé
ç¶æ ãäŸãã°0.05M以äžã«ä¿ã€ããšã奜ãŸããã
ãããæ¿åºŠã®CuSO4溶液ã®äœ¿çšæã«ã¯åŸããã
CuâãŒãªã©ã€ãã®æ¯è¡šé¢ç©ã転æçŽ æã®ãŒãªã©
ã€ããšã»ãŒåçã§ãããæ®ºè广ãæé©ãªç¶æ ã§
çºæ®ã§ããå©ç¹ãããã ZnâãŒãªã©ã€ããžã®è»¢æã«éããŠã¯ã䜿çšã
ãå¡©é¡ãïŒã3Mã®ä»è¿ã§ã¯ãŒãªã©ã€ãåºçžãžã®
åºåœ¢ç©ã®æåºã¯èŠãããªããZnâãŒãªã©ã€ãã¯
äžèšæ¿åºŠä»è¿ã®å¡©é¡ã䜿çšããããšã«ãã容æã«
åŸãããã äžè¿°ã®AgâãŒãªã©ã€ããCuâãŒãªã©ã€ããã
ã³ZnâãŒãªã©ã€ããžã®è»¢æã«éããŠã€ãªã³äº€æ
åå¿ããããæ³ã§å®æœããéã«ã¯äžè¿°ã®æ¿åºŠãæ
ãã塩顿º¶æ¶²ãçšããŠãŒãªã©ã€ãçŽ æã®æµžæŒ¬åŠç
ã宿œããã°ããããŒãªã©ã€ãçŽ æäžãžã®éå±å«
æéãé«ããããã«ã¯ãããåŠçã®åæ°ãå¢å€§ã
ãã°ãããäžæ¹ãäžè¿°ã®æ¿åºŠãæãã塩顿º¶æ¶²ã
çšããŠã«ã©ã æ³ã«ãããŒãªã©ã€ãçŽ æãåŠçãã
éã«ã¯åžçå¡ã«ãŒãªã©ã€ãçŽ æãå å¡«ããããã«
塩顿º¶æ¶²ãééãããã°å®¹æã«ç®çãšããéå±â
ãŒãªã©ã€ããåŸãããã äžèšã®éå±âãŒãªã©ã€ãïŒç¡æ°ŽãŒãªã©ã€ãåº
æºïŒäžã«å ããéå±ã®éã¯ãéã«ã€ããŠã¯30éé
ïŒ ä»¥äžã§ããã奜ãŸããç¯å²ã¯0.001ãïŒééïŒ
ã«ãããäžæ¹ãé ããã³äºéã«ã€ããŠã¯éå±âãŒ
ãªã©ã€ãïŒç¡æ°ŽãŒãªã©ã€ãåºæºïŒäžã«å ããé ãŸ
ãã¯äºéã®éã«35ééïŒ ä»¥äžã§ããã奜ãŸããç¯
å²ã¯0.01ã15ééïŒ ã«ãããéé ããã³äºéã€ãª
ã³ã䜵çšããŠå©çšããããšãå¯èœã§ããããã®å Ž
åã¯éå±ã€ãªã³ã®åèšéã¯éå±âãŒãªã©ã€ãïŒç¡
æ°ŽãŒãªã©ã€ãåºæºïŒã«å¯Ÿã35ééïŒ ä»¥äžã§ããã
奜ãŸããç¯å²ã¯éå±ã€ãªã³ã®æ§ææ¯ã«ããå·Šå³ã
ããããããã0.001ã15ééïŒ ã«ããã ãŸããéãé ãäºé以å€ã®éå±ã€ãªã³ãäŸãã°
ãããªãŠã ãã«ãªãŠã ãã«ã«ã·ãŠã ãããã¯ä»ã®
éå±ã€ãªã³ãå ±åããŠããŠã殺è广ãããŸãã
ãããšã¯ãªãã®ã§ããããã®ã€ãªã³ã®æ®ååã¯å ±
åã¯äœãããã€ãããªãã æ¬¡ãã§ããããéå±ãŒãªã©ã€ããææ©é«ååäœ
ãžåè¿°ã®å«æéãšãªãåŠãæ·»å æ··åããŠåŸãæåœ¢
äœãšãããéå±ãŒãªã©ã€ãã«å¯Ÿãããæ®ºèäœçšã
æããéå±ã®éïŒAwtïŒ ãšããïŒåã³æåœ¢äœã«
察ããéå±ãŒãªã©ã€ãã®éïŒBwtïŒ ãšããïŒã¯ã
ãããæ®ºè广ã«é¢ä¿ãããå€ããã°ïŒ¢ã¯å°ã
ãŠãããéã«ïŒ¡ãå°ãªããšïŒ¢ãå€ãããå¿ èŠãã
ããæ®ºè广ãæå¹ã«çºæ®ããããçºã«ã¯ïŒ¡Ã
ã®å€ãéâãŒãªã©ã€ãã®å Žåã¯0.01以äžãé ãŸã
ã¯äºéâãŒãªã©ã€ãã®å Žåã¯0.1以äžãšãªããã
ã«èª¿æŽããããšãæãŸãããæ·»å æ··åã®ææãã
ã³æ¹æ³ã¯ç¹ã«éå®ããããã®ã§ã¯ãªããäŸãã°å
æã¢ãããŒã«æ·»å æ··ååéåããæ¹æ³ãåå¿äžé
äœã«æ·»å æ··åããæ¹æ³ãéåçµäºæã®ããªããŒã«
æ·»å æ··åããæ¹æ³ãããªããŒãã¬ããã«æ·»å æ··å
ããŠæåããæ¹æ³ãæåçšããŒãäŸãã°çŽ¡ç³žåæ¶²
ãžæ·»å æ··åããæ¹æ³ãªã©ããããåããŒãªã©ã€ã
ç³»åºäœç²åãããã¯ã«ã«æ··åãã¹ã©ãªãŒãšãã
åŸãèäœããªããŒã«æ··åããŠãè¯ããèŠã¯çšãã
é«ååã®æ§è³ªãå·¥çšäžã®ç¹åŸŽãªã©ã«å¿ããŠæé©ã®
æ¹æ³ãæ¡çšããã°ãããéåžžãæåçŽåã«æ·»å æ··
åããæ¹æ³ã奜é©ã§ããããããè¯å¥œãªç²åã®å
æ£ã®ããã«ã¢ãããŒã«æ·»å æ··åããããšã奜ãŸã
ãå ŽåãããããŸã該éå±âãŒãªã©ã€ãã¯é«åå
äœã«æ·»å ããåã«èŠããã°ä¹Ÿç¥åŠçãè¡ãã也ç¥
æ¡ä»¶ã¯åžžå§åã¯æžå§äž100ã500âã®ç¯å²ã§é©å®éž
ã¹ã°ããã奜ãŸããä¹Ÿç¥æ¡ä»¶ã¯æžå§äž100ã350â
ã§ããã äžèšã®åŠããæ®ºèæ§ãæããéå±ã€ãªã³ãä¿æ
ãããããŒãªã©ã€ãç³»åºäœç²åãææ©é«ååãšæ··
åããæ··åèäœã玡糞çãæåœ¢äœãšããã該æåœ¢
äœã¯æåœ¢çŽåä¹è³æ°10æ¥éã¯ãã®æèæ§èœã¯æ¥µã
ãŠè¯å¥œã§ãããããããç°å¢æ¡ä»¶ã«ãã€ãŠã¯æ°ã±
æçµéããã«ã€ããŠæèæ§èœã®äœäžãèŠãããå Ž
åãããããã®åå ã¯äžæã§ãããããŒãªã©ã€ã
äžã®éå±ã€ãªã³ã®äžéšãç±ã«ããäžå®å®åãããŠ
ããçºã«å€§æ°äžã®çš®ã ã®ã¬ã¹ã玫å€ç·çã®åœ±é¿ã
åãæããªã€ãŠãããã®ãšèãããããæ¬çºææ¹
æ³ã«æŒãŠã¯ã該æåäœãæååŸã®æ©ãææã«æ¬¡äº
éçŽ é žå¡©åã³ïŒåã¯éé žåæ°ŽçŽ ã®æ°Žæº¶æ¶²ã§æµžæŒ¬åŠ
çããã®ã§ããã æ¬çºææ¹æ³ã§çšããæ¬¡äºå¡©çŽ é žå¡©ãšããŠã¯ã次
äºå¡©çŽ é žãããªãŠã ãæ¬¡äºå¡©çŽ é žã«ãªãŠã ãæ¬¡äº
å¡©çŽ é žã«ã«ã·ãŠã çãæãããããããããéåžž
0.05ïŒ ãïŒééïŒ ã®æ°Žæº¶æ¶²ãšããåžžæž©ä¹è³70âã§
該æåœ¢äœã浞挬ãã10ã30ååŠçãããåãéé ž
åæ°ŽçŽ ã®å Žåã¯éåžž30ïŒ æ°Žæº¶æ¶²ãïŒã50mlïŒãš
ããŠäœ¿çšãããäœããæ¿åºŠãæž©åºŠçã®æ¡ä»¶ã¯ç¹ã«
éå®ããããã®ã§ã¯ãªããç¹ç¶ç¶ã®è¡šé¢ç©ã®å€§ã
ããã®ã¯äœæ¿åºŠãäœæž©ã§ååã§ãããåãæ¬¡äºå¡©
çŽ é žå¡©ãšéé žåæ°ŽçŽ ãæ··åããŠäœ¿çšããŠãè¯ãã ïŒçºæã®å¹æïŒ æ¬çºææ¹æ³ã«ããåŠçããããåŸã®è©²æåœ¢äœã®
æèæ§èœã¯æ°ã±æãçµéããŠãã»ãšãã©äœäžãã
ããšããªããé·ææç¶æ§ã«åªãããã®ãšãªããæ®º
èåãæããéå±ã€ãªã³ã¯ãŒãªã©ã€ããæ äœãšã
ãŠé«ååäœå ã«åæ£ä¿æãããã®ã§ãéå±ãã®ã
ã®ãå©çšããæ¹æ³ã«æ¯ã¹ãéå±ã€ãªã³ãåºãååž
ããŠããæ®ºè广ãå ã 倧ããèš³ã§ããããåè¿°
ã®åŠãéå±ã€ãªã³ãå®å®åãããã®ã§ãå°ãªãé
å±ã€ãªã³éã§é·æéæ®ºèæ§ãæç¶ãããåããã®
çºã®åŠçæ¹æ³ã¯æ¥µããŠç°¡åã§å®äŸ¡ãªæ¹æ³ãšèšãã
ãšãã§ããã ïŒå®æœäŸïŒ 次ã®ãæ¬çºæã®å®æœäŸã«ã€ããŠè¿°ã¹ããã宿œ
äŸäžæ®ºè广ã®è©äŸ¡ã¯ä»¥äžã®è©Šé𿹿³ã«ãã€ãŠè¡
ãªã€ãã ïŒçްèã®æ»æ» çã®æž¬å®ïŒ Escherichia coliãåã¯Staphylococcus auâ
reusã®æžæ¿æ¶²ãçšãã詊éšèæ¶²ãïŒãïŒÃ105
ã±ïŒmlãšãªãæ§åžé調æŽããããã®è©Šéšèæ¶²0.2
mlãæåœ¢äœäžã«æ»Žäžããä¿æããããŸãŸ37âã§18
æéäœçšãããã18æéåŸãæåœ¢äœãççé£å¡©æ°Ž
ã§æŽãå šäœã100mlãšããåŸããã®äžïŒmlãå¯å€©
å¹å°ã«åæ£ããã37âã§24æéä¿æããçååæ°
ãæž¬å®ããŠæ»æ» çãç®åºããã åè宿œäŸ ïŒ æ¬çºæã®å®æœäŸã§äœ¿çšããæªè»¢æã®å€©ç¶åã³å
æãŒãªã©ã€ãç²åã第ïŒè¡šã«ç€ºãããåãŒãªã©ã€
ãã¯ç²åæãç²ç ã»åçŽããŠææã®ç²ååŸãåŸ
ãã第ïŒè¡šã®ïŒ¡âåãŒãªã©ã€ããZ1ãâåãŒãª
ã©ã€ããZ2ãâåãŒãªã©ã€ããZ3ã倩ç¶ã¢ã«ã
ãã€ãïŒãZ4ã倩ç¶ã¢ã«ããã€ãïŒãZ5ã倩ç¶ã
ã€ããµã€ããZ6ãšç¥èšãããããããŒãªã©ã€ãã®
ç²ååŸã嫿°Žçãæ¯è¡šé¢ç©ã¯ç¬¬ïŒè¡šã®éãã§ãã€
ãã æ¬¡ãã§ç¬¬ïŒè¡šã®åçš®ãŒãªã©ã€ãã®åŸ®ç²æ«ä¹Ÿç¥å
å250ïœãæ¡åããåã ã«1/10ïŒç¡é žé氎溶液500
mlãå ããŠåŸãããæ··åç©ã宀枩ã«ãŠïŒæéæ¹æ
äžã«ä¿æããŠã€ãªã³äº€æãè¡ãªã€ãããããã€ãª
ã³äº€ææ³ã«ããåŸãããéâãŒãªã©ã€ããéã
ãåŸãæ°ŽæŽããŠéå°ã®éã€ãªã³ãé€å»ãããæ¬¡ã«
æ°ŽæŽæžã¿ã®éâãŒãªã©ã€ãã100ã105âã§ä¹Ÿç¥ã
ãŠããç²ç ããŠéâãŒãªã©ã€ãã®åŸ®ç²æ«ãåŸãã
åŸãããéâãŒãªã©ã€ã也ç¥åã®é嫿éåã³æ¯
衚é¢ç©ã¯ç¬¬ïŒè¡šã®åŠãã§ãã€ãã
ã衚ã
éâãŒãªã©ã€ã転æåã®ãã¡ãéâåãŒãªã©ã€
ããZ7ãéâåãŒãªã©ã€ããZ8ãéâåãŒãª
ã©ã€ããZ9ãéâ倩ç¶ã¢ã«ããã€ãïŒãZ10ãé
â倩ç¶ã¢ã«ããã€ãïŒãZ11ãéâ倩ç¶ãã€ããµ
ã€ããZ12ãšç¥èšããã åè宿œäŸ ïŒ ç¬¬ïŒè¡šã®åçš®ãŒãªã©ã€ãã®äžããïŒçš®é¡ã®åæ
ãŸãã¯å€©ç¶ãŒãªã©ã€ãã®åŸ®ç²æ«ä¹Ÿç¥åå250ïœã
æ¡åããåã ã«1/20ïŒç¡«é žé 氎溶液ïŒãå ã
ããåŸãããæ··åç©ãå®€æž©ã§æ¹æäžã«ïŒæéä¿æ
ããããããã€ãªã³äº€ææ³ã«ããåŸãããé âãŒ
ãªã©ã€ãã¯åžåŒéåŸç¡«é žã€ãªã³ããªããªããŸã§
æ°ŽæŽããããæ¬¡ã«æ°ŽæŽæžã¿ã®é âãŒãªã©ã€ãã
100ã105âã§ä¹Ÿç¥ããåŸç²ç ããŠåŸ®ç²æ«ã®é âãŒ
ãªã©ã€ã転æåãåŸãã äžè¿°ã®æ¹æ³ã§åŸãããé âãŒãªã©ã€ã転æåã®
é 嫿éåã³æ¯è¡šé¢ç©ã第ïŒè¡šã«ç€ºãããé âãŒ
ãªã©ã€ã転æåã®ãã¡ãé âåãŒãªã©ã€ãã
Z13ãé âåãŒãªã©ã€ããZ14ãé â倩ç¶ã¢ã«ã
ãã€ãïŒãZ15ãé â倩ç¶ãã€ããµã€ããZ16ãšç¥
èšããã åè宿œäŸ ïŒ ç¬¬ïŒè¡šã®ïŒ¡âåãŒãªã©ã€ãïŒZ1ïŒã®ä¹Ÿç¥ç²æ«
250ïœãæ¡åããããã«2Må¡©åäºé溶液ïŒãå
ããŠåŸãããæ··åç©ã60âä»è¿ã«ãŠæ¹æäžã«ïŒæ
é20åä¿æããããããã€ãªã³äº€æã«ããåŸãã
ãäºéâãŒãªã©ã€ããé å¿åé¢ã«ããåé¢ããã
次ã«åèšåæ§ã®åŠçãç¹°è¿ãããæ¬èª¿è£œæ¹æ³ã§ã¯
ããããããæ³ã«ããåŠçãïŒå宿œãããæçµ
çã«åŸããã転æåãæ°ŽæŽããŠéå°ã®äºéã€ãªã³
ãé€å»ããã æ¬¡ã«äºé転æç©ã100âä»è¿ã«ãŠä¹Ÿç¥åŸãç²ç
ããŠäºéâåãŒãªã©ã€ãã®åŸ®ç²æ«ãåŸãã ãŸãã第ïŒè¡šã®ïŒžâåãŒãªã©ã€ãïŒZ2ïŒããã³
倩ç¶ã¢ã«ããã€ãïŒïŒZ5ïŒã®åŸ®ç²æ«ä¹Ÿç¥å250ïœã
æ¡åããåã ã«1/20ïŒç¡«é žäºé溶液ïŒãå ããŠ
åŸããŠãæ··åç©ã宀枩ã«ãŠïŒæéæ¹æäžã«ä¿æã
ãŠã€ãªã³äº€æãè¡ãªã€ããåŸãããäºéâãŒãªã©
ã€ãã¯åžåŒéåŸç¡«é žã€ãªã³ããªããªããŸã§æ°ŽæŽ
ããããæ¬¡ã«æ°ŽæŽæžã¿äºéâãŒãªã©ã€ãã100ã
105âã§ä¹Ÿç¥ããŠããç²ç ããŠäºéâãŒãªã©ã€ã
ã®åŸ®ç²æ«ãåŸãã äžè¿°ã®æ¹æ³ã§åŸãããïŒçš®é¡ã®äºéâãŒãªã©ã€
ã転æåã®äºé嫿éåã³æ¯è¡šé¢ç©ã第ïŒè¡šã«ç€º
ããã äºéâãŒãªã©ã€ã転æåã®ãã¡ãäºéâåãŒ
ãªã©ã€ããZ17ãäºéâåãŒãªã©ã€ããZ18ãäº
éâ倩ç¶ã¢ã«ããã€ãïŒãZ10ãšç¥èšããã
ããZ7ãéâåãŒãªã©ã€ããZ8ãéâåãŒãª
ã©ã€ããZ9ãéâ倩ç¶ã¢ã«ããã€ãïŒãZ10ãé
â倩ç¶ã¢ã«ããã€ãïŒãZ11ãéâ倩ç¶ãã€ããµ
ã€ããZ12ãšç¥èšããã åè宿œäŸ ïŒ ç¬¬ïŒè¡šã®åçš®ãŒãªã©ã€ãã®äžããïŒçš®é¡ã®åæ
ãŸãã¯å€©ç¶ãŒãªã©ã€ãã®åŸ®ç²æ«ä¹Ÿç¥åå250ïœã
æ¡åããåã ã«1/20ïŒç¡«é žé 氎溶液ïŒãå ã
ããåŸãããæ··åç©ãå®€æž©ã§æ¹æäžã«ïŒæéä¿æ
ããããããã€ãªã³äº€ææ³ã«ããåŸãããé âãŒ
ãªã©ã€ãã¯åžåŒéåŸç¡«é žã€ãªã³ããªããªããŸã§
æ°ŽæŽããããæ¬¡ã«æ°ŽæŽæžã¿ã®é âãŒãªã©ã€ãã
100ã105âã§ä¹Ÿç¥ããåŸç²ç ããŠåŸ®ç²æ«ã®é âãŒ
ãªã©ã€ã転æåãåŸãã äžè¿°ã®æ¹æ³ã§åŸãããé âãŒãªã©ã€ã転æåã®
é 嫿éåã³æ¯è¡šé¢ç©ã第ïŒè¡šã«ç€ºãããé âãŒ
ãªã©ã€ã転æåã®ãã¡ãé âåãŒãªã©ã€ãã
Z13ãé âåãŒãªã©ã€ããZ14ãé â倩ç¶ã¢ã«ã
ãã€ãïŒãZ15ãé â倩ç¶ãã€ããµã€ããZ16ãšç¥
èšããã åè宿œäŸ ïŒ ç¬¬ïŒè¡šã®ïŒ¡âåãŒãªã©ã€ãïŒZ1ïŒã®ä¹Ÿç¥ç²æ«
250ïœãæ¡åããããã«2Må¡©åäºé溶液ïŒãå
ããŠåŸãããæ··åç©ã60âä»è¿ã«ãŠæ¹æäžã«ïŒæ
é20åä¿æããããããã€ãªã³äº€æã«ããåŸãã
ãäºéâãŒãªã©ã€ããé å¿åé¢ã«ããåé¢ããã
次ã«åèšåæ§ã®åŠçãç¹°è¿ãããæ¬èª¿è£œæ¹æ³ã§ã¯
ããããããæ³ã«ããåŠçãïŒå宿œãããæçµ
çã«åŸããã転æåãæ°ŽæŽããŠéå°ã®äºéã€ãªã³
ãé€å»ããã æ¬¡ã«äºé転æç©ã100âä»è¿ã«ãŠä¹Ÿç¥åŸãç²ç
ããŠäºéâåãŒãªã©ã€ãã®åŸ®ç²æ«ãåŸãã ãŸãã第ïŒè¡šã®ïŒžâåãŒãªã©ã€ãïŒZ2ïŒããã³
倩ç¶ã¢ã«ããã€ãïŒïŒZ5ïŒã®åŸ®ç²æ«ä¹Ÿç¥å250ïœã
æ¡åããåã ã«1/20ïŒç¡«é žäºé溶液ïŒãå ããŠ
åŸããŠãæ··åç©ã宀枩ã«ãŠïŒæéæ¹æäžã«ä¿æã
ãŠã€ãªã³äº€æãè¡ãªã€ããåŸãããäºéâãŒãªã©
ã€ãã¯åžåŒéåŸç¡«é žã€ãªã³ããªããªããŸã§æ°ŽæŽ
ããããæ¬¡ã«æ°ŽæŽæžã¿äºéâãŒãªã©ã€ãã100ã
105âã§ä¹Ÿç¥ããŠããç²ç ããŠäºéâãŒãªã©ã€ã
ã®åŸ®ç²æ«ãåŸãã äžè¿°ã®æ¹æ³ã§åŸãããïŒçš®é¡ã®äºéâãŒãªã©ã€
ã転æåã®äºé嫿éåã³æ¯è¡šé¢ç©ã第ïŒè¡šã«ç€º
ããã äºéâãŒãªã©ã€ã転æåã®ãã¡ãäºéâåãŒ
ãªã©ã€ããZ17ãäºéâåãŒãªã©ã€ããZ18ãäº
éâ倩ç¶ã¢ã«ããã€ãïŒãZ10ãšç¥èšããã
ã衚ã
宿œäŸ ïŒ
第ïŒè¡šã«ç€ºããéâåãŒãªã©ã€ãïŒZ7ïŒãé
âåãŒãªã©ã€ãïŒZ8ïŒãéâåãŒãªã©ã€ã
ïŒZ9ïŒãéâ倩ç¶ã¢ã«ããã€ãïŒïŒïŒïŒZ10ãZ11ïŒ
åã¯éâ倩ç¶ãã€ããµã€ããZ12ãæžå§äž200âã§
ïŒæé也ç¥ãããæ¬¡ãã§ããã95ïŒ ç¡«é žã§æž¬å®ã
ãçžå¯Ÿå¹ŽåºŠïŒÎ·relïŒ2.3ã®ïŒãã€ãã³ä¹Ÿç¥ããã
ã«åã 2wtïŒ ã®æ¿åºŠãšãªããããªæ·»å æ··åããåžž
æ³ã«åŸã溶è玡糞å延䌞ããŠ120dïŒïŒãã€ã©ã¡
ã³ãïŒçš®é¡ã®å»¶äŒžç³žãåŸããæ¬¡ã«è©²å»¶äŒžç³žãçç·š
ã粟緎ããåŸãåã ã®æ®ºè广ã®è©äŸ¡ãè¡ã€ãã
åã該çç·šåžã次äºéçŽ é žãããªãŠã ã®0.3wtïŒ
氎溶液äžã«40âã«ãŠ30åéæµžæŒ¬åŸãå åã«æ°ŽæŽ
ãããã®æ®ºè广ã®è©äŸ¡ãè¡ã€ããæŽã«ãããã®
次äºå¡©çŽ é žãããªãŠã 氎溶液ã§ã®åŠçåžåã³æªåŠ
çåžãåã æ¥åœãã®è¯ã倧æ°äžã«ïŒã±æéé£ç¶æŸ
眮ããåãæ®ºè广ã詊éšèãšããŠ
Staphylococcus aureusãçšããŠè¡ã€ãã第ïŒè¡š
ã«æ®ºèã®æ»æ» çã®æž¬å®çµæã瀺ãã
âåãŒãªã©ã€ãïŒZ8ïŒãéâåãŒãªã©ã€ã
ïŒZ9ïŒãéâ倩ç¶ã¢ã«ããã€ãïŒïŒïŒïŒZ10ãZ11ïŒ
åã¯éâ倩ç¶ãã€ããµã€ããZ12ãæžå§äž200âã§
ïŒæé也ç¥ãããæ¬¡ãã§ããã95ïŒ ç¡«é žã§æž¬å®ã
ãçžå¯Ÿå¹ŽåºŠïŒÎ·relïŒ2.3ã®ïŒãã€ãã³ä¹Ÿç¥ããã
ã«åã 2wtïŒ ã®æ¿åºŠãšãªããããªæ·»å æ··åããåžž
æ³ã«åŸã溶è玡糞å延䌞ããŠ120dïŒïŒãã€ã©ã¡
ã³ãïŒçš®é¡ã®å»¶äŒžç³žãåŸããæ¬¡ã«è©²å»¶äŒžç³žãçç·š
ã粟緎ããåŸãåã ã®æ®ºè广ã®è©äŸ¡ãè¡ã€ãã
åã該çç·šåžã次äºéçŽ é žãããªãŠã ã®0.3wtïŒ
氎溶液äžã«40âã«ãŠ30åéæµžæŒ¬åŸãå åã«æ°ŽæŽ
ãããã®æ®ºè广ã®è©äŸ¡ãè¡ã€ããæŽã«ãããã®
次äºå¡©çŽ é žãããªãŠã 氎溶液ã§ã®åŠçåžåã³æªåŠ
çåžãåã æ¥åœãã®è¯ã倧æ°äžã«ïŒã±æéé£ç¶æŸ
眮ããåãæ®ºè广ã詊éšèãšããŠ
Staphylococcus aureusãçšããŠè¡ã€ãã第ïŒè¡š
ã«æ®ºèã®æ»æ» çã®æž¬å®çµæã瀺ãã
ã衚ã
第ïŒè¡šã§æãããªæ§ã«ã次äºå¡©çŽ é
žãããªãŠã
ã®æ°Žæº¶æ¶²ã§åŠçãããã®ã«ã€ããŠã¯ïŒã±æéã®é²
å ãŠãšã¶ãªã³ã°ã®åŸãæ®ºèæ§èœãä¿æããŠããã æ¯èŒäŸ ïŒ ç¬¬ïŒè¡šã«ç€ºããéæ«è»¢æã®ãŒãªã©ã€ãZ1ãZ2ã
Z3ã¯Z4ã®åŸ®ç²æ«ä¹Ÿç¥åã宿œäŸïŒãšåæ§ã«ãã€ã
ã³ã«åã æ·»å æ··å玡糞ããŠ120dïŒïŒãã€ã©ã¡ã³
ãã®å»¶äŒžç³žïŒçš®é¡ãåŸãã該延䌞糞ãçç·šãã
åŸã宿œäŸïŒãšåæ§ã«æ¬¡äºå¡©çŽ é žãããªãŠã ã®æ°Ž
溶液ã§åŠçãè¡ãããã®æ®ºèæ§èœã枬å®ãããã
æ»æ» çã¯ïŒïŒ ã§ãããåã«æ¬¡äºå¡©çŽ é žãããªãŠã
ã®ã¿ã®æ®ºè广ã§ã¯ãªãããšã倿ããã 宿œäŸ ïŒ ç¬¬ïŒè¡šã«ç€ºããé âåãŒãªã©ã€ãïŒZ13ïŒãé
âåãŒãªã©ã€ãïŒZ14ïŒãé â倩ç¶ã¢ã«ããã€ã
ïŒïŒZ15ïŒãé â倩ç¶ãã€ããµã€ãïŒZ16ïŒãäºéâ
åãŒãªã©ã€ãïŒZ17ïŒãäºéâåãŒãªã©ã€ã
ïŒZ18ïŒãäºéâ倩ç¶ã¢ã«ããã€ãïŒïŒZ10ïŒãæžå§
äž200âã§ïŒæé也ç¥ãããæ¬¡ãã§ãããããšã
ãŒã«ïŒåå¡©åãšã¿ã³ïŒïŒïŒïŒïŒæ··å溶å€äžã§æž¬å®
ããæ¥µéç²åºŠãηã0.640ã®ããªãšãã¬ã³ãã¬ã
ã¿ã¬ãŒã也ç¥ãããã«0.5wtïŒ ãšãªãæ§æ·»å ãã
290âã§åžžæ³ã«åŸããæº¶è玡糞ãã延䌞ããŠã50
ãããŒã«ïŒïŒãã€ã©ã¡ã³ãã®å»¶äŒžç³žïŒçš®ãåŸãã
ããããçç·šãã粟緎ãè¡ã€ãåŸã30ïŒ éé žåæ°Ž
çŽ æ°Žã®ïŒïœïŒæ°Žæº¶æ¶²70âã®äžã«æµžæŒ¬ãã30åé
åŠçããããããã®æ®ºèæ§èœåã³å€§æ°äžæŸçœ®ïŒã±
æåŸã®æ®ºèæ§èœãæ¯é žåæ°ŽçŽ æ°Žã§æªåŠçã®çç·šåž
ãšæ¯èŒããŠã枬å®è©äŸ¡ããçµæã第ïŒè¡šã«ç€ºãã
詊éšèãšããŠEscherichia coliãçšããã
ã®æ°Žæº¶æ¶²ã§åŠçãããã®ã«ã€ããŠã¯ïŒã±æéã®é²
å ãŠãšã¶ãªã³ã°ã®åŸãæ®ºèæ§èœãä¿æããŠããã æ¯èŒäŸ ïŒ ç¬¬ïŒè¡šã«ç€ºããéæ«è»¢æã®ãŒãªã©ã€ãZ1ãZ2ã
Z3ã¯Z4ã®åŸ®ç²æ«ä¹Ÿç¥åã宿œäŸïŒãšåæ§ã«ãã€ã
ã³ã«åã æ·»å æ··å玡糞ããŠ120dïŒïŒãã€ã©ã¡ã³
ãã®å»¶äŒžç³žïŒçš®é¡ãåŸãã該延䌞糞ãçç·šãã
åŸã宿œäŸïŒãšåæ§ã«æ¬¡äºå¡©çŽ é žãããªãŠã ã®æ°Ž
溶液ã§åŠçãè¡ãããã®æ®ºèæ§èœã枬å®ãããã
æ»æ» çã¯ïŒïŒ ã§ãããåã«æ¬¡äºå¡©çŽ é žãããªãŠã
ã®ã¿ã®æ®ºè广ã§ã¯ãªãããšã倿ããã 宿œäŸ ïŒ ç¬¬ïŒè¡šã«ç€ºããé âåãŒãªã©ã€ãïŒZ13ïŒãé
âåãŒãªã©ã€ãïŒZ14ïŒãé â倩ç¶ã¢ã«ããã€ã
ïŒïŒZ15ïŒãé â倩ç¶ãã€ããµã€ãïŒZ16ïŒãäºéâ
åãŒãªã©ã€ãïŒZ17ïŒãäºéâåãŒãªã©ã€ã
ïŒZ18ïŒãäºéâ倩ç¶ã¢ã«ããã€ãïŒïŒZ10ïŒãæžå§
äž200âã§ïŒæé也ç¥ãããæ¬¡ãã§ãããããšã
ãŒã«ïŒåå¡©åãšã¿ã³ïŒïŒïŒïŒïŒæ··å溶å€äžã§æž¬å®
ããæ¥µéç²åºŠãηã0.640ã®ããªãšãã¬ã³ãã¬ã
ã¿ã¬ãŒã也ç¥ãããã«0.5wtïŒ ãšãªãæ§æ·»å ãã
290âã§åžžæ³ã«åŸããæº¶è玡糞ãã延䌞ããŠã50
ãããŒã«ïŒïŒãã€ã©ã¡ã³ãã®å»¶äŒžç³žïŒçš®ãåŸãã
ããããçç·šãã粟緎ãè¡ã€ãåŸã30ïŒ éé žåæ°Ž
çŽ æ°Žã®ïŒïœïŒæ°Žæº¶æ¶²70âã®äžã«æµžæŒ¬ãã30åé
åŠçããããããã®æ®ºèæ§èœåã³å€§æ°äžæŸçœ®ïŒã±
æåŸã®æ®ºèæ§èœãæ¯é žåæ°ŽçŽ æ°Žã§æªåŠçã®çç·šåž
ãšæ¯èŒããŠã枬å®è©äŸ¡ããçµæã第ïŒè¡šã«ç€ºãã
詊éšèãšããŠEscherichia coliãçšããã
ã衚ã
ãšã瀺ãã
宿œäŸ ïŒ ç¬¬ïŒè¡šã«ç€ºããéâåãŒãªã©ã€ãïŒZ9ïŒãæž
å§äž200âã§ïŒæé也ç¥ãããæ¬¡ãã§ããã50ïœ
æ¡ãã75âã§ã®ç²åºŠã800cpsã®ãžãšãã¬ã³ã°ãªã³
ãŒã«ã¢ãžããŒã100ïœãæ··åããèªåä¹³é¢ã§24æ
éæ··ç·Žãã¹ã©ãªãŒãšããã éåžžã®æº¶è玡糞æ©ãçšããŠã95ïŒ ç¡«é žã§æž¬å®ã
ãçžå¯Ÿç²åºŠ2.3ã®ïŒãã€ãã³ä¹Ÿç¥ããããã¹ã¯ãª
ãŠãŒã§æº¶èãã玡糞ãããã«éã蟌ãŸããæº¶èïŒ
ãã€ãã³ããªããŒäžã«ãäžèšã®éâãŒãªã©ã€ãå«
æã¹ã©ãªãŒãã®ã€ãã³ãã§å§å ¥ããããã®ææ··å
ããªããŒå šå¯Ÿã«å¯ŸããŠã¹ã©ãªãŒã0.03ã10wtïŒ ã®
ç¯å²ã§å€åãããã 玡糞ãããå ã®éåæ··ç·ŽçŽ å20ã±ã«éããåŸã
å£éããæŒãåºãæ²ãåãã延䌞ããŠ50ãããŒ
ã«ïŒ12ãã€ã©ã¡ã³ãã®ïŒçš®é¡ã®å»¶äŒžç³žãåŸããã
ãããçç·šãã0.1wtïŒ ã®æ¬¡äºå¡©çŽ é žã«ã«ã·ãŠã
æ°Žæº¶æ¶²ã«æµžæŒ¬ãã70âã§30ååŠçããããããã
倧æ°äžã«ïŒã±ææŸçœ®ãããåãæ¬¡äºå¡©çŽ é žã«ã«ã·
ãŠã ã§æªåŠçã®ãã®ã«ã€ããŠãåæ§ã«å€§æ°äžæŸçœ®
ãããæ®ºèæ§èœè©äŸ¡ã«ã€ããŠã¯ã詊éšèãšããŠ
Staphylococcus aureusãçšããã
宿œäŸ ïŒ ç¬¬ïŒè¡šã«ç€ºããéâåãŒãªã©ã€ãïŒZ9ïŒãæž
å§äž200âã§ïŒæé也ç¥ãããæ¬¡ãã§ããã50ïœ
æ¡ãã75âã§ã®ç²åºŠã800cpsã®ãžãšãã¬ã³ã°ãªã³
ãŒã«ã¢ãžããŒã100ïœãæ··åããèªåä¹³é¢ã§24æ
éæ··ç·Žãã¹ã©ãªãŒãšããã éåžžã®æº¶è玡糞æ©ãçšããŠã95ïŒ ç¡«é žã§æž¬å®ã
ãçžå¯Ÿç²åºŠ2.3ã®ïŒãã€ãã³ä¹Ÿç¥ããããã¹ã¯ãª
ãŠãŒã§æº¶èãã玡糞ãããã«éã蟌ãŸããæº¶èïŒ
ãã€ãã³ããªããŒäžã«ãäžèšã®éâãŒãªã©ã€ãå«
æã¹ã©ãªãŒãã®ã€ãã³ãã§å§å ¥ããããã®ææ··å
ããªããŒå šå¯Ÿã«å¯ŸããŠã¹ã©ãªãŒã0.03ã10wtïŒ ã®
ç¯å²ã§å€åãããã 玡糞ãããå ã®éåæ··ç·ŽçŽ å20ã±ã«éããåŸã
å£éããæŒãåºãæ²ãåãã延䌞ããŠ50ãããŒ
ã«ïŒ12ãã€ã©ã¡ã³ãã®ïŒçš®é¡ã®å»¶äŒžç³žãåŸããã
ãããçç·šãã0.1wtïŒ ã®æ¬¡äºå¡©çŽ é žã«ã«ã·ãŠã
æ°Žæº¶æ¶²ã«æµžæŒ¬ãã70âã§30ååŠçããããããã
倧æ°äžã«ïŒã±ææŸçœ®ãããåãæ¬¡äºå¡©çŽ é žã«ã«ã·
ãŠã ã§æªåŠçã®ãã®ã«ã€ããŠãåæ§ã«å€§æ°äžæŸçœ®
ãããæ®ºèæ§èœè©äŸ¡ã«ã€ããŠã¯ã詊éšèãšããŠ
Staphylococcus aureusãçšããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ®ºèäœçšãæããéå±ã€ãªã³ãä¿æãããã
ãŒãªã©ã€ãç³»åºäœç²åã嫿ããææ©é«ååäœã
ããªãæåœ¢äœã次äºå¡©çŽ é žå¡©åã³ïŒåã¯éé žåæ°Ž
çŽ ã®æ°Žæº¶æ¶²ã§åŠçããããšãç¹åŸŽãšãããŒãªã©ã€
ãç³»åºäœç²å嫿é«ååæåœ¢äœã®åŠçæ¹æ³ã ïŒ ãŒãªã©ã€ãç³»åºäœç²åã150m2ïŒïœä»¥äžã®æ¯
衚é¢ç©åã³14以äžã®SiO2ïŒAl2O3ã¢ã«æ¯ãæãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ ãŒãªã©ã€ãç³»åºäœç²åãâåãŒãªã©ã€ãã
âåãŒãªã©ã€ããâåãŒãªã©ã€ãåã¯ã¢ã«ã
ãã€ãããæ§æãããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé
èšèŒã®æ¹æ³ã ïŒ ãŒãªã©ã€ãç³»åºäœç²åã®ã€ãªã³äº€æå¯èœãªéš
åã«æ®ºèäœçšãæããéå±ã€ãªã³ãä¿æãããŠã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ æ®ºèäœçšãæããéå±ã€ãªã³ãéãé ãäºé
ããæã矀ããéžã°ããïŒçš®ãŸãã¯ïŒçš®ä»¥äžã®é
å±ã€ãªã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹
æ³ã ïŒ ãŒãªã©ã€ãç³»åºäœç²åã®å«æéã0.01ã50é
éïŒ ïŒç¡æ°ŽãŒãªã©ã€ãåºæºïŒã§ããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé èšèŒã®æ¹æ³ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25891484A JPS61136530A (ja) | 1984-12-06 | 1984-12-06 | ãŒãªã©ã€ãç³»åºäœç²å嫿é«ååæåœ¢äœã®åŠçæ¹æ³ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25891484A JPS61136530A (ja) | 1984-12-06 | 1984-12-06 | ãŒãªã©ã€ãç³»åºäœç²å嫿é«ååæåœ¢äœã®åŠçæ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61136530A JPS61136530A (ja) | 1986-06-24 |
| JPH0360866B2 true JPH0360866B2 (ja) | 1991-09-18 |
Family
ID=17326782
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25891484A Granted JPS61136530A (ja) | 1984-12-06 | 1984-12-06 | ãŒãªã©ã€ãç³»åºäœç²å嫿é«ååæåœ¢äœã®åŠçæ¹æ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61136530A (ja) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0826166B2 (ja) * | 1987-08-17 | 1996-03-13 | æ±èã±ãã«ã«æ ªåŒäŒç€Ÿ | èèæ§ãæããé 匵ç©å±€æ¿ |
| JPH01311008A (ja) * | 1988-06-06 | 1989-12-15 | Dainippon Ink & Chem Inc | å å·¥çšçµæç© |
| JP2901255B2 (ja) * | 1988-10-04 | 1999-06-07 | åžçå°å·æ ªåŒäŒç€Ÿ | ææã容åšã®æ®ºèæ¹æ³ |
| JPH0684561B2 (ja) * | 1988-12-23 | 1994-10-26 | æ ªåŒäŒç€Ÿã¯ã©ã¬ | æèæ§éŽäž |
| JPH0680201B2 (ja) * | 1989-01-09 | 1994-10-12 | æ ªåŒäŒç€Ÿã¯ã©ã¬ | æ°Žæ³³çšæèã€ã³ã㌠|
| TW200709239A (en) * | 2005-06-30 | 2007-03-01 | Showa Denko Kk | Capacitor, capacitor element and method for manufacturing such capacitor element |
| SA07280540B1 (ar) * | 2006-10-19 | 2012-05-06 | Ø³ÙØšØ§ Ø³ØšØŽÙØ§Ùت٠ÙÙÙ ÙÙØ§Ùز ÙÙÙØ¯ÙÙØ¬ اÙÙ | Ø¹ÙØ§ØµØ± تغÙÙ٠خاصة ØšØ£Ø¬ÙØ²Ø© ØªØšØ±ÙØ¯ ØšØ®Ø§Ø±ÙØ© ÙÙØ§ Ù ÙØ§ÙÙ Ø© ضد تÙÙÙ Ø·ØšÙØ© رÙÙÙØ© ØÙÙÙØ© |
-
1984
- 1984-12-06 JP JP25891484A patent/JPS61136530A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61136530A (ja) | 1986-06-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0116865B1 (en) | Polymer article having an antibacterial property containing zeolite particles therein and the processes for producing same | |
| US5064599A (en) | Process for producing an antibacterial fiber article | |
| CA2037314C (en) | Antimicrobial composition | |
| EP0722660B1 (en) | An antimicrobial polymer composition | |
| AU604724B2 (en) | Polymer containing amorphous aluminosilicate particles and process for producing the same | |
| JPH0360866B2 (ja) | ||
| JPS62195037A (ja) | æèæ§ãæããããªãšã¹ãã«ç³»æåœ¢äœ | |
| JPH0384066A (ja) | æèäœçšãæããæš¹èçµæç©ããã³ãã®è£œé æ¹æ³ | |
| JPH03124810A (ja) | æèæ©èœãæããç¹ç¶ | |
| JPH11246212A (ja) | æèæ§ãŒãªã©ã€ã | |
| JPH0372102B2 (ja) | ||
| KR20060036972A (ko) | íê· ë°©ì·šì±ìŽ ì°ìí íŽëЬì°ë íì°ë ì íì±ì¬ì ì ì¡°ë°©ë² | |
| KR950012816B1 (ko) | íê· ë°©ì·šì±ìŽ ì°ìí íŽëЬíë¡íë ì¥ì¬ì ë¶ì§í¬ì ì ì¡°ë°©ë² | |
| JPS63260810A (ja) | æ®ºèæ§ãŒãªã©ã€ãçµæç©åã³ãã®è£œé æ³ | |
| JP4313592B2 (ja) | æåŸ®çç©æ§ãæãããã©ã·ç𿝿åã³ãã®è£œé æ¹æ³ | |
| JP3185697B2 (ja) | èä¹ æ§ã«åªããæèå€ | |
| JPH0251940B2 (ja) | ||
| JPH11189919A (ja) | æèæ§ããªãããã¬ã³ãã¬ãã¿ã¬ãŒãç¹ç¶ | |
| JPH0132254B2 (ja) | ||
| JP2648282B2 (ja) | ïŒïœïœïœçšæ®ºèå€ | |
| KR970010711B1 (ko) | íê· ë°©ì·šì±ìŽ ì°ìí í©ì±ì¬ì ì ì ì¡°ë°©ë² | |
| JPH02160914A (ja) | æèæ§ã¢ã¯ãªã«ç³»ç¹ç¶åã³ãã®è£œé æ¹æ³ | |
| JPH0339335A (ja) | æèæ§æš¹èçµæç© | |
| JPH03145411A (ja) | èåæ§åã³èç±æ§ãæããæ®ºèæ§ããªããŒçµæç© | |
| JPH1025215A (ja) | æèæ§çµæç© |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |