JPH0454753B2 - - Google Patents
Info
- Publication number
- JPH0454753B2 JPH0454753B2 JP61108578A JP10857886A JPH0454753B2 JP H0454753 B2 JPH0454753 B2 JP H0454753B2 JP 61108578 A JP61108578 A JP 61108578A JP 10857886 A JP10857886 A JP 10857886A JP H0454753 B2 JPH0454753 B2 JP H0454753B2
- Authority
- JP
- Japan
- Prior art keywords
- concrete
- current
- atmosphere
- electrolyte
- cathodic protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004567 concrete Substances 0.000 claims description 27
- 238000004210 cathodic protection Methods 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 19
- 229910001294 Reinforcing steel Inorganic materials 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 238000005260 corrosion Methods 0.000 claims description 13
- 239000003792 electrolyte Substances 0.000 claims description 13
- 230000007797 corrosion Effects 0.000 claims description 10
- 239000011358 absorbing material Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004745 nonwoven fabric Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 230000003014 reinforcing effect Effects 0.000 description 8
- 239000003973 paint Substances 0.000 description 5
- 239000013535 sea water Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910001297 Zn alloy Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- -1 etc.) Inorganic materials 0.000 description 2
- 238000005246 galvanizing Methods 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011150 reinforced concrete Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Prevention Of Electric Corrosion (AREA)
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、鉄筋またはPC鋼材を補強鋼材と
する大気中と電解質中にまたがるコンクリート構
造物、たとえば、長大橋や湾岸道路の橋梁、沖合
プラツトホーム、岸壁、桟橋、消波施設などの電
気防食法に関する。[Detailed Description of the Invention] [Field of Industrial Application] This invention is applicable to concrete structures that use reinforcing bars or prestressed steel as reinforcing steel materials and span both the atmosphere and electrolyte, such as long bridges, bridges on coastal roads, and offshore platforms. , concerning cathodic protection methods for quays, piers, wave-dissipating facilities, etc.
鉄筋コンクリート構造物(以下、RC構造物と
いう。)は、コンクリートと鋼という材料的に優
れた素材の組合せより構造上の頑丈さに加えて維
持や保守のいらない半永久構造物とみなされてき
た。ところが、海洋環境におけるRC構造物にお
いては海水飛沫や潮風に含まれる大量の塩分が飛
来し、付着するとコンクリート内部へ浸透して内
部の鉄筋を腐食させることがわかつてきた。ま
た、大気環境におけるRC構造物においても、自
動車や工場からの排出ガスの影響を受けてコンク
リートの中性化が進み、さらに海砂の利用による
コンクリート中の塩分の増加によつて鉄筋が腐食
膨潤してかぶりコンクリートが剥落する事故が生
じマスコミでも大きくとりあげられるにいたつ
た。
Reinforced concrete structures (hereinafter referred to as RC structures) have been regarded as semi-permanent structures that do not require upkeep or maintenance, in addition to being structurally robust due to the superior material combination of concrete and steel. However, it has been found that in RC structures in the marine environment, large amounts of salt contained in seawater spray and sea breeze are blown into the air, and when it adheres, it permeates into the concrete and corrodes the internal reinforcing steel. In addition, even in RC structures in atmospheric environments, the neutralization of concrete progresses due to the influence of exhaust gases from automobiles and factories, and the reinforcing bars corrode and swell due to the increase in salt content in concrete due to the use of sea sand. As a result, an accident occurred in which the concrete cover fell off, and it was widely covered by the media.
従来、このようなRC構造物に対する防食対策
としては、鉄筋に溶融亜鉛めつきを施す方法、あ
るいは防錆材をコンクリートの練り混ぜ時に混和
剤として添加し、鉄筋に強い酸化被膜を作る方法
などが実施され、また電気防食による方法、たと
えば、海水中のRC構造物にあつては、流電陽極
方式または外部電源方式による電気防食法が、ま
た大気中のRC構造物にあつては構造物表面を導
電性塗料で覆い、この面に直流電源に接続した白
金線電極を埋め込むことによつて防食電流を供給
する電気防食が有効であることが海外の文献に紹
介されている。 Conventional anti-corrosion measures for such RC structures include applying hot-dip galvanizing to the reinforcing bars, or adding anti-rust materials as an admixture when mixing concrete to create a strong oxide film on the reinforcing bars. For example, for RC structures in seawater, cathodic protection methods using a galvanic anode method or an external power source method are used, and for RC structures in the atmosphere, cathodic protection methods are used. It has been introduced in foreign literature that cathodic protection is effective in supplying a corrosion protection current by covering the surface with conductive paint and embedding a platinum wire electrode connected to a DC power source on this surface.
しかしながら、上述した亜鉛メツキによる方法
は、低濃度塩分存在下では十分な耐食性を有する
が、より高い濃度の塩分存在下やひび割れ到達箇
所で鉄筋が腐食する危険が大きい。また、防錆剤
による方法は、防錆剤のコンクリート中への添加
量が防食に要する量より少ないと鉄筋に孔食が発
生するなど使用規準を十分に守らないとかえつて
危険なことになる。さらに、従来の電気防食によ
る方法は、大気中のRC構造物では電源の取れる
ところでしか実施できないという制約があり、ま
た、同一構造物でありながら、大気中と海水中と
にそれぞれ電極を設置して別々に防食設計・施工
することは極めて不経済といわねばならない。
However, although the above-mentioned galvanizing method has sufficient corrosion resistance in the presence of a low concentration of salt, there is a great risk that the reinforcing steel will corrode in the presence of a higher concentration of salt or at a location where cracks are reached. In addition, the method using rust preventive agents can be dangerous if the usage standards are not fully observed, such as pitting corrosion occurring in reinforcing bars if the amount of rust preventive agent added to the concrete is less than the amount required for corrosion prevention. . Furthermore, conventional cathodic protection methods have the limitation that they can only be applied to RC structures in the atmosphere where power is available, and electrodes are installed separately in the atmosphere and in seawater, even though the same structure is used. It must be said that it is extremely uneconomical to design and construct corrosion protection separately.
この発明は、従来のものがもつ、以上のような
問題点を解消させ、大気中と電解質中とにまたが
るコンクリート構造物に対し、一貫して低防食電
流密度による経済的な電気防食を可能にしたコン
クリート構造物の電気防食方法を提供することを
目的とする。 This invention solves the above-mentioned problems of conventional methods, and enables economical cathodic protection by consistently low corrosion protection current density for concrete structures that span both the atmosphere and electrolyte. The purpose of this invention is to provide a method for cathodic protection of concrete structures.
この目的を達成するために、この発明は次のよ
うな構成としている。
In order to achieve this object, the present invention has the following configuration.
すなわち、その発明に係るコンクリート構造物
の電気防食法は、大気中の前記構造物表面を導電
性被覆物で被覆し、この外側を電解質中にまたが
つて吸水保水性の電流吸上げ材で保持すると共
に、電解質中の前記構造物の補強鋼材を電気防食
することによつて電解質中の前記補強鋼材に流入
する防所電流一部を電流吸上げ材、導電性被覆物
を経由して大気中の前記補強鋼材に流入するよう
にする。 That is, the cathodic protection method for concrete structures according to the invention covers the surface of the structure exposed to the atmosphere with a conductive coating, and the outside of this is held in an electrolyte with a water-absorbing and water-retaining current absorbing material. At the same time, by electrolytically protecting the reinforcing steel of the structure in the electrolyte, a part of the current flowing into the reinforcing steel in the electrolyte is transferred to the atmosphere through the current absorption material and the conductive coating. so that it flows into the reinforcing steel material.
このように構成された電気防食法においては、
電気防食による防食電気iは電解質中のコンクリ
ート層を直接通過して補強鋼材に流入し、該表面
を良好な防食状態に保持する。この場合、コンク
リート層を介して電流を流入させるため、防食に
必要な電流密度は海水中における裸鋼材の場合の
ほぼ10分の1以下とかなり小さくて良いことが知
られている。一方、一部の防食電流iは、一旦電
解質中の電流吸上げ材に流入し、大気中の導電性
被覆物及びコンクリート層を通過して補強鋼材に
流入し、該表面に対し均一な電位分布を与える。
In the cathodic protection method configured in this way,
The corrosion-protecting electricity i by cathodic protection directly passes through the concrete layer in the electrolyte and flows into the reinforcing steel material, keeping the surface in a good corrosion-protected state. In this case, it is known that because the current flows through the concrete layer, the current density required for corrosion protection can be quite small, approximately one-tenth or less of that for bare steel in seawater. On the other hand, a part of the anticorrosion current i flows into the current absorbing material in the electrolyte, passes through the conductive coating in the atmosphere and the concrete layer, and flows into the reinforcing steel material, creating a uniform potential distribution on the surface. give.
導電性被覆物は、広範囲にわたる電流の分布電
極として働くから、陽極電流密度は低くなり、導
電性被覆物の消耗の度合は極度に少ないものにな
る。 Since the conductive coating acts as a wide current distribution electrode, the anodic current density is low and the degree of consumption of the conductive coating is extremely low.
以下、この発明の一実施例を図面に基づいて説
明する。
Hereinafter, one embodiment of the present invention will be described based on the drawings.
第1図は、桟橋におけるコンクリート杭の縦断
面概略図である。第1図において、コンクリート
杭1の被覆が施される部分、すなわち、大気中
(満潮位から上)のコンクリート表面に導電性被
覆物2、たとえば導電性塗料を300〜500μの厚さ
で塗装する。この導電性塗料は、導電性フイラー
としてグラフアイト粉、カーボン粉、ニツケル
粉、過酸化鉛粉あるいは亜鉛末等を混入したウレ
タン、エポキシ、アクリル系樹脂バインダーから
なる耐侯性に優れた塗料を使用する。 FIG. 1 is a schematic vertical cross-sectional view of concrete piles on a pier. In Figure 1, the part of the concrete pile 1 to be coated, that is, the concrete surface in the atmosphere (above the high tide level), is coated with a conductive coating 2, for example, a conductive paint to a thickness of 300 to 500μ. . This conductive paint uses a highly weather-resistant paint made of urethane, epoxy, or acrylic resin binder mixed with graphite powder, carbon powder, nickel powder, lead peroxide powder, or zinc powder as a conductive filler. .
前記導電性被覆物2は、導電性塗料の他の、
Zn溶射、Al溶射、導電性コンクリート、シート
状の導電性樹脂、耐食性金属、(Ti,Ta,Nb,
Cu,Cu合金、Cr−Ni鋼等)、Zn合金、及びAl合
金等が使用できる。 The conductive coating 2 is made of a conductive coating material other than conductive paint.
Zn spraying, Al spraying, conductive concrete, sheet-shaped conductive resin, corrosion-resistant metals, (Ti, Ta, Nb,
Cu, Cu alloy, Cr-Ni steel, etc.), Zn alloy, Al alloy, etc. can be used.
つぎに、導電性被覆物2の外側に、電流吸上げ
材3としてアクリル酸系吸水ポリマーを含有した
不織布シートを、その下部が海水中に浸漬される
ように保持する。この電流吸上げ材3は、吸水保
水性を有するもの、たとえば、前記不織布シート
の他、ポリエチレンオキサイド系吸水ポリマーを
低密度ポリエチレン、ポリプロピレンとブレンド
してフイルム状やシート状としたものなどを用い
る。 Next, a nonwoven fabric sheet containing an acrylic acid-based water-absorbing polymer as a current absorbing material 3 is held outside the conductive coating 2 so that its lower part is immersed in seawater. The current absorbing material 3 uses a material having water absorbing and water retaining properties, for example, in addition to the above-mentioned nonwoven fabric sheet, a polyethylene oxide water absorbing polymer blended with low density polyethylene or polypropylene is used in the form of a film or sheet.
また、本実施例のような海洋環境中では、電流
吸上げ材3の外側に、下部に防食電流の流入孔4
を設けた繊維強化プラスチツクシートなどの外装
材5を被覆して強化することは、電流吸上げ材3
が劣化したり、浮遊物の衝突によつて剥離したり
することが防止できるのできわめて有効である。 In addition, in a marine environment as in this embodiment, an inflow hole 4 for anti-corrosion current is provided on the outside of the current absorption material 3 at the bottom.
Covering and reinforcing the exterior material 5 such as a fiber-reinforced plastic sheet provided with the current absorption material 3
This is extremely effective because it prevents deterioration or peeling off due to collision with floating objects.
この外装材5は、端部に設けたアングル状の締
付部を用いてコンクリート杭1にボルトナツトで
固定する。また、この外装材5と前記電流吸上げ
材3とは、予め接着材などで接合して施工すると
良い。 This exterior material 5 is fixed to the concrete pile 1 with bolts and nuts using an angled tightening portion provided at the end. Further, it is preferable that the exterior material 5 and the current absorbing material 3 are bonded together in advance using an adhesive or the like.
一方、海中部におけるコンクリート杭1の表面
に、Al合金、Zn合金、Mg合金等の流電陽極6
を、予め鉄筋7と電気的に接触させたアンカーボ
ルト8によつて取り付ける。この流電陽極方式の
電気防食の他、外部電源方式の電気防食でも同等
の効果を有することは言うまでもない。 On the other hand, a galvanic anode 6 made of Al alloy, Zn alloy, Mg alloy, etc. is placed on the surface of a concrete pile 1 in the sea.
are attached by anchor bolts 8 that have been brought into electrical contact with reinforcing bars 7 in advance. It goes without saying that in addition to this electrolytic anode type cathodic protection, an external power source type cathodic protection has the same effect.
なお、導電性被覆物2とコンクリート表面との
間にバツクフイル材を介在させても良い。 Note that a backfill material may be interposed between the conductive covering 2 and the concrete surface.
以上説明したように、この発明の電気防食法に
よれば、導電性被覆物が電気防食の分布電極及び
大気との遮蔽物として作用するので大気中の補強
鋼材を広範囲にわたつて均一に防食することがで
きる。
As explained above, according to the cathodic protection method of the present invention, the conductive coating acts as a distributed electrode for cathodic protection and as a shield from the atmosphere, so that reinforcement steel materials in the atmosphere can be uniformly protected from corrosion over a wide range. be able to.
したがつて、大気中と電解質中にまたがるコン
クリート構造物に対し、電解質中の補強鋼材を電
気防食するだけで大気中の補強鋼材まで一貫して
電気防食効果が得られるので、繁雑な電極の設置
が電解質中だけですむと共に、電源のないところ
の大気中の電気防食が可能となる。 Therefore, for concrete structures that span both the atmosphere and the electrolyte, by simply applying cathodic protection to the reinforcing steel in the electrolyte, the effect of cathodic protection can be achieved on the reinforcing steel in the atmosphere, which eliminates the need for complicated electrode installation. This requires only in the electrolyte, and cathodic protection can be carried out in the atmosphere in areas where there is no power source.
また、コンクリート層や導電性被覆物によつて
酸素等が遮断されるので、補強鋼材の防食電流密
が大幅に低減される。 Furthermore, since oxygen and the like are blocked by the concrete layer and the conductive coating, the corrosion protection current density of the reinforcing steel material is significantly reduced.
第1図は、この発明の一実施例を示す断面概略
図である。
1……コンクリート杭、2……導電性被覆物、
3……電流吸上げ材、6……流電陽極、7……鉄
筋。
FIG. 1 is a schematic cross-sectional view showing one embodiment of the present invention. 1... Concrete pile, 2... Conductive coating,
3... Current absorption material, 6... Galvanic anode, 7... Reinforcing bar.
Claims (1)
造物の防食方法であつて、大気中の前記構造物表
面を導電性被覆物で被覆し、この外側を電解質中
にまたがつて吸水保水性の電流吸上げ材で保持す
ると共に、電解質中の前記構造物の補強鋼材を電
気防食することによつて電解質中の前記補強鋼材
に流入する防食電流の一部を電流吸上げ材、導電
性被覆物を経由して大気中の前記補強鋼材に流入
するようにしたことを特徴とするコンクリート構
造物の電気防食法。 2 電流吸上げ材が、吸水性ポリマーを含有した
不織布である特許請求の範囲第1項記載のコンク
リート構造物の電気防食法。[Claims] 1. A method for preventing corrosion of a concrete structure that spans both the atmosphere and an electrolyte, in which the surface of the structure that is exposed to the atmosphere is coated with a conductive coating, and the outside of the structure is covered with a conductive coating that absorbs water. In addition to retaining the current with a water-retaining current absorbing material, by electrolytically protecting the reinforcing steel of the structure in the electrolyte, a part of the anti-corrosion current flowing into the reinforcing steel in the electrolyte is absorbed by the current absorbing material and conductive. 1. A method for cathodic protection of concrete structures, characterized in that the atmosphere flows into the reinforcing steel material through a conductive coating. 2. The cathodic protection method for concrete structures according to claim 1, wherein the current absorbing material is a nonwoven fabric containing a water-absorbing polymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61108578A JPS62267485A (en) | 1986-05-14 | 1986-05-14 | Method for electrically protecting concrete structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61108578A JPS62267485A (en) | 1986-05-14 | 1986-05-14 | Method for electrically protecting concrete structure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62267485A JPS62267485A (en) | 1987-11-20 |
| JPH0454753B2 true JPH0454753B2 (en) | 1992-09-01 |
Family
ID=14488365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61108578A Granted JPS62267485A (en) | 1986-05-14 | 1986-05-14 | Method for electrically protecting concrete structure |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62267485A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2729694B1 (en) * | 1995-01-24 | 1997-04-04 | Guerin Richard | CONCRETE REGENERATION AND PROTECTION PROCESS |
| ATA40398A (en) * | 1998-03-09 | 1999-09-15 | Wolfgang Dr Schwarz | ELECTRICALLY CONDUCTING MICROCAPILLAR COMPOSITE MATRIX AND METHOD FOR THE PRODUCTION THEREOF |
| KR101321939B1 (en) * | 2011-10-28 | 2013-10-28 | 주식회사 화승알앤에이 | Cathode protecting system for above water portion in marine structure |
| WO2013140645A1 (en) | 2012-03-22 | 2013-09-26 | 積水化成品工業株式会社 | Adhesive hydrogel and method for electrolytic protection of concrete structure |
-
1986
- 1986-05-14 JP JP61108578A patent/JPS62267485A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62267485A (en) | 1987-11-20 |
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Legal Events
| Date | Code | Title | Description |
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| EXPY | Cancellation because of completion of term |