JPH0460958B2 - - Google Patents
Info
- Publication number
- JPH0460958B2 JPH0460958B2 JP25979984A JP25979984A JPH0460958B2 JP H0460958 B2 JPH0460958 B2 JP H0460958B2 JP 25979984 A JP25979984 A JP 25979984A JP 25979984 A JP25979984 A JP 25979984A JP H0460958 B2 JPH0460958 B2 JP H0460958B2
- Authority
- JP
- Japan
- Prior art keywords
- mixed paste
- sulfuric acid
- phosphate
- mixed
- rags
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 26
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 12
- 239000003337 fertilizer Substances 0.000 claims description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 10
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 7
- 241001465754 Metazoa Species 0.000 claims description 7
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 7
- 239000004571 lime Substances 0.000 claims description 7
- 150000001413 amino acids Chemical class 0.000 claims description 6
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 claims description 6
- 229910000160 potassium phosphate Inorganic materials 0.000 claims description 6
- 235000011009 potassium phosphates Nutrition 0.000 claims description 6
- 102000004169 proteins and genes Human genes 0.000 claims description 6
- 108090000623 proteins and genes Proteins 0.000 claims description 6
- 239000002426 superphosphate Substances 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- 239000002367 phosphate rock Substances 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000001477 organic nitrogen group Chemical group 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 2
- 235000019700 dicalcium phosphate Nutrition 0.000 description 2
- 229940095079 dicalcium phosphate anhydrous Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000013379 molasses Nutrition 0.000 description 2
- 241000283153 Cetacea Species 0.000 description 1
- 206010062717 Increased upper airway secretion Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000007098 aminolysis reaction Methods 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 235000019691 monocalcium phosphate Nutrition 0.000 description 1
- 229910000150 monocalcium phosphate Inorganic materials 0.000 description 1
- 208000026435 phlegm Diseases 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Fertilizers (AREA)
Description
【発明の詳細な説明】
(イ) 産業上の利用分野
本発明は、動物性繊維のボロ布等から肥料を製
造する方法に関する。DETAILED DESCRIPTION OF THE INVENTION (a) Field of Industrial Application The present invention relates to a method for producing fertilizer from animal fiber rags and the like.
(ロ) 従来の技術
従来、ボロ布等は、何ら有効利用する方法がな
く、焼却するか、又は土中に埋込む他に処理方法
がなかつた。一方肥料は、化学肥料等を除き、そ
の多くが堆積、発酵等長時間の操作を必要とする
ものであつた。(b) Conventional technology Until now, there was no way to effectively utilize rags, etc., and there was no other way to dispose of them other than incinerating them or burying them in the ground. On the other hand, most fertilizers, with the exception of chemical fertilizers, require long-term operations such as deposition and fermentation.
(ハ) 発明が解決しようとする問題点
したがつて、ボロ布等を焼却し又は土中に埋込
む操作は、費用がかかるのみで、何ら有効利用と
はなり得ず、また一方従来の肥料では長時間の処
理工程の後でカルシウム塩等の肥料補助剤の添加
を必要と、コストが大となつていた。(c) Problems to be solved by the invention Therefore, the operation of incinerating rags or burying them in the soil is expensive and cannot be used effectively. However, it is necessary to add fertilizer supplements such as calcium salts after a long treatment process, resulting in high costs.
(ニ) 問題点を解決するための手段
本発明では、動物性繊維のボロ布等を硫酸でア
ミノ分解し、アミノ酸と未分解蛋白質と硫酸との
混合ペーストとした後、同混合ペーストに、同ペ
ースト中の硫酸を中和して過リン酸石灰を生成せ
しめるべくリン鉱石を混入し、次いで同混合ペー
ストに、過リン酸石灰中の遊離リン酸を中和して
リン酸カリウムを生成しせめるべくカリ分を混入
せしめてなる動物性繊維のボロ布等から肥料を製
造する方法を提供せんとするものである。(d) Means for solving the problem In the present invention, animal fiber rags, etc. are amino-decomposed with sulfuric acid to form a mixed paste of amino acids, undecomposed protein, and sulfuric acid, and then the same mixture is added to the mixed paste. Phosphate rock is mixed in to neutralize the sulfuric acid in the paste to generate lime superphosphate, and then to the mixed paste, free phosphoric acid in the lime superphosphate is neutralized to generate potassium phosphate. It is an object of the present invention to provide a method for producing fertilizer from animal fiber rags mixed with as much potassium as possible.
(ホ) 作用
本発明では、動物性繊維のボロ布などを硫酸で
アミノ分解すれば、アミノ酸と未分解蛋白質と硫
酸との混合ペーストが生成されるが、これにリン
鉱石を混入すれば、リン鉱石と硫酸とが反応して
第１リン酸カルシウム、セツコウ、遊離リン酸か
らなる過リン酸石灰が混合ペースト中に生成され
るものである。ついでかかる混合ペースト中にカ
リ分を混入せしめると、カリ分と過リン酸石灰中
の遊離リン酸が反応して、混合ペースト中にリン
酸カリウムが生成されるものであり、最終製品と
して、アミノ酸と未分解蛋白質から成る有機態窒
素並びに第１リン酸アルシウム、セツコウ、リン
酸カリウムからなる肥効性の高い肥料が生成され
るものである。(E) Effect In the present invention, if animal fiber rags or the like are aminolyzed with sulfuric acid, a mixed paste of amino acids, undegraded proteins, and sulfuric acid is produced, but if phosphate rock is mixed into this, phosphorus The ore and sulfuric acid react to produce superphosphate lime consisting of monocalcium phosphate, sulfuric acid, and free phosphoric acid in a mixed paste. When potassium is then mixed into the mixed paste, the potassium reacts with the free phosphoric acid in the superphosphate lime, producing potassium phosphate in the mixed paste, and the final product is amino acids. A highly effective fertilizer consisting of organic nitrogen consisting of undecomposed protein and dibasic aluminum phosphate, sludge, and potassium phosphate is produced.
(ヘ) 効果
本発明によれば、簡単な操作で、有機態窒素、
第１リン酸カルシウム、セツコウ、リン酸ウリウ
ムからなる肥効性の高い肥料が生成できるという
効果を奏する。(F) Effect According to the present invention, organic nitrogen,
The effect is that a highly effective fertilizer consisting of dibasic calcium phosphate, phlegm, and urium phosphate can be produced.
(ト) 実施例
本考案の実施例を詳説すれば次の通りである。
すなわち、クツカー内に硫酸の50％水溶液30〜80
Kgを投入し、同硫酸水溶液中に動物性繊維たる羊
毛又は絹織物のボロ布100Kgを投入して浸漬し、
100℃で約５〜10時間加熱して、ボロ布を一部ア
ミノ分解すれば、アミノ酸と未分解蛋白質と硫酸
との混合物より成る混合ペーストが生成される。
次にこの混合ペーストに第２リン酸カルシウムを
主成分とするリン鉱石を混入せしめることによ
り、混合のペーストの硫酸をリン鉱石で中和して
第１リン酸カルシウム、セツコウ、遊離リン酸を
主成分とする過リン酸石灰を混合ペースト中で生
成せしめる。(g) Examples Examples of the present invention will be explained in detail as follows.
i.e. 50% aqueous solution of sulfuric acid in the couture 30-80
100 kg of wool or silk rags, which are animal fibers, were added to the same sulfuric acid aqueous solution and immersed.
Partial aminolysis of the rag by heating at 100° C. for about 5 to 10 hours produces a mixed paste consisting of a mixture of amino acids, undegraded protein, and sulfuric acid.
Next, a phosphate rock containing dibasic calcium phosphate as a main component is mixed into this mixed paste, and the sulfuric acid in the mixed paste is neutralized with the phosphate rock. Lime phosphate is formed in a mixed paste.
次にこの混合ペースト中にアルコール発酵のは
い糖蜜を混入して混合ペースト中の遊離リン酸
と、はい糖蜜中に含まれるカリ分を反応せしめ
て、混合ペースト中でリン酸カリを生成せしめ
る。 Next, alcohol-fermented molasses is mixed into this mixed paste, and the free phosphoric acid in the mixed paste reacts with the potassium contained in the molasses to produce potassium phosphate in the mixed paste.
以上のように形成されたものを、天火又は乾燥
機等で乾燥した後、必要に応じて粉砕して肥料と
する。 After drying the product formed as described above using an open fire or dryer, it is crushed as necessary to make fertilizer.
かかる方法によつて製造された肥料は、アミノ
酸と未分解蛋白質から成る有機態窒素並びに第１
リン酸アルシウム、セツコウ、リン酸カリウムか
ら成る肥効性の高い肥料とすることができる。 Fertilizer produced by this method contains organic nitrogen consisting of amino acids and undegraded proteins, as well as primary
It can be made into a highly effective fertilizer consisting of aluminum phosphate, cetacean phosphate, and potassium phosphate.
Claims (1)
し、アミノ酸と未分解蛋白質との混合ペーストと
した後、同混合ペーストに、同ペースト中の硫酸
を中和して過リン酸石灰を生成せしめるべくリン
鉱石を混入し、次いで同混合ペーストに、過リン
酸石灰中の遊離リン酸を中和してリン酸カリウム
を生成せしめるべくカリウムを混入せしめてなる
動物性繊維のボロ布等から肥料を製造する方法。1 Aminolyze animal fiber rags, etc. with sulfuric acid to create a mixed paste of amino acids and undecomposed protein, and then neutralize the sulfuric acid in the mixed paste to generate superphosphate lime. Fertilizer is made from animal fiber rags, etc., which is made by mixing phosphate rock, and then adding potassium to the mixed paste to neutralize the free phosphoric acid in the superphosphate lime and generate potassium phosphate. How to manufacture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25979984A JPS61136980A (en) | 1984-12-08 | 1984-12-08 | Manufacture of compost from waste cloth or like of annimal fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25979984A JPS61136980A (en) | 1984-12-08 | 1984-12-08 | Manufacture of compost from waste cloth or like of annimal fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61136980A JPS61136980A (en) | 1986-06-24 |
| JPH0460958B2 true JPH0460958B2 (en) | 1992-09-29 |
Family
ID=17339156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25979984A Granted JPS61136980A (en) | 1984-12-08 | 1984-12-08 | Manufacture of compost from waste cloth or like of annimal fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61136980A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2804950B2 (en) * | 1992-07-22 | 1998-09-30 | 開成科学株式会社 | Method for producing amino acid-containing fertilizer |
| KR20020082309A (en) * | 2001-04-20 | 2002-10-31 | 이석원 | A Fertilizer Containing Amino Acids Derived from Animals |
| CN103951516B (en) * | 2014-05-05 | 2016-05-18 | 华南农业大学 | A kind of synergy calcium superphosphate and preparation method thereof and application |
-
1984
- 1984-12-08 JP JP25979984A patent/JPS61136980A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61136980A (en) | 1986-06-24 |
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