JPH0467354B2 - - Google Patents
Info
- Publication number
- JPH0467354B2 JPH0467354B2 JP58170744A JP17074483A JPH0467354B2 JP H0467354 B2 JPH0467354 B2 JP H0467354B2 JP 58170744 A JP58170744 A JP 58170744A JP 17074483 A JP17074483 A JP 17074483A JP H0467354 B2 JPH0467354 B2 JP H0467354B2
- Authority
- JP
- Japan
- Prior art keywords
- quantum well
- layer
- well structure
- cladding layer
- semiconductor layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004065 semiconductor Substances 0.000 claims description 32
- 238000005253 cladding Methods 0.000 claims description 23
- 238000005036 potential barrier Methods 0.000 claims description 10
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 11
- 229910000980 Aluminium gallium arsenide Inorganic materials 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 238000013139 quantization Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000002109 crystal growth method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/34—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers
- H01S5/343—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
- H01S5/34313—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser with a well layer having only As as V-compound, e.g. AlGaAs, InGaAs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/34—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers
- H01S5/343—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
- H01S5/34313—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser with a well layer having only As as V-compound, e.g. AlGaAs, InGaAs
- H01S5/3432—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser with a well layer having only As as V-compound, e.g. AlGaAs, InGaAs the whole junction comprising only (AI)GaAs
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biophysics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Semiconductor Lasers (AREA)
Description
【発明の詳細な説明】
本発明は、多重量子井戸構造半導体レーザーの
改良に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to improvements in multi-quantum well structure semiconductor lasers.
従来の多重量子井戸構造半導体レーザとして
AlGaAs/GaAs変型多重量子井戸構造半導体レ
ーザがある。この主要部のエネルギーバンドダイ
ヤグラムを第1図に示す。図中、1はn型クラツ
ド層(n−Al0.4 Ga0.6 As)、2は多重量子井
戸構造、3はP型クラツド層(P−Al0.4 Ga0.6
As)、4はポテンシヤルバリヤー層(Al0.2
Ga0.8 As)、5は量子井戸層(GaAs)である。
図で示される様に、この例では多重量子井戸構造
2は5つの量子井戸層5と4つのポテンシヤルバ
リヤー層4からなつており、電子及び正孔は非常
に薄い量子井戸層5(〜100A)に閉じ込められ
ることにより、とびとびの量子化準位が発生す
る。この様な量子化効果によつて、多重量子井戸
構造半導体レーザーは1KA/cm2を大きく下回る
超低閾値に代表される高い性能を得ている。 As a conventional multi-quantum well structure semiconductor laser
There is an AlGaAs/GaAs modified multi-quantum well structure semiconductor laser. The energy band diagram of this main part is shown in FIG. In the figure, 1 is an n-type cladding layer (n-Al 0.4 Ga 0.6 As), 2 is a multiple quantum well structure, and 3 is a P-type cladding layer (P-Al 0.4 Ga 0.6
As), 4 is a potential barrier layer (Al 0.2
5 is a quantum well layer (GaAs).
As shown in the figure, in this example, the multi-quantum well structure 2 consists of five quantum well layers 5 and four potential barrier layers 4, and electrons and holes are formed in the very thin quantum well layer 5 (~100A). By being confined to , discrete quantization levels are generated. Due to such quantization effects, multi-quantum well structure semiconductor lasers achieve high performance, typified by ultra-low threshold values well below 1 KA/cm 2 .
しかしながら、この様な構造の多重量子井戸構
造半導体レーザーにおいては、閾値電流密度を低
減するには、多重量子井戸構造2の厚さを薄くし
た方が望ましい。しかしながら、あまり薄くする
と多重量子井戸構造への光の閉じ込めが悪くなり
逆に閾値電流密度が大きくなるという相反する事
実があつた。この様な事情によつて多重量子井戸
構造2はむやみに薄く出来ず、従つて閾値電流密
度を従来よりもさらに低減することは困難であつ
た。 However, in a multi-quantum well structure semiconductor laser having such a structure, it is desirable to reduce the thickness of the multi-quantum well structure 2 in order to reduce the threshold current density. However, there is a contradictory fact that if the thickness is made too thin, light confinement in the multi-quantum well structure deteriorates and the threshold current density increases. Due to these circumstances, the multi-quantum well structure 2 cannot be made unnecessarily thin, and therefore it has been difficult to further reduce the threshold current density than before.
また第2の問題点として、多重量子井戸層5の
量子準位がそれぞれ異なる点がある。すなわち、
n型クラツド層1及びp型クラツド層3に接する
外側の量子井戸層は、クラツド層の高いポテンシ
ヤルバリヤを見るために、内側の量子井戸層より
も量子準位のエネルギーが大きくなる。そのた
め、外側の量子井戸層の量子準位と、内側の量子
井戸層の量子準位の間にわずかな差が生ずること
になる。この差は、量子井戸レーザの利得スペク
トルを拡げることになり、しきい値電流の増大な
どの特性劣化を招いていた。 A second problem is that the quantum levels of the multiple quantum well layers 5 are different. That is,
The outer quantum well layer in contact with the n-type cladding layer 1 and the p-type cladding layer 3 has a quantum level energy larger than that of the inner quantum well layer because of the high potential barrier of the cladding layer. Therefore, a slight difference occurs between the quantum level of the outer quantum well layer and the quantum level of the inner quantum well layer. This difference broadens the gain spectrum of the quantum well laser, leading to characteristic deterioration such as an increase in threshold current.
本発明の目的は、多重量子井戸構造の厚みを低
減しても光の閉じ込めが悪くならず、そのため閾
値電流密度が従来よりもさらに小さな多重量子井
戸構造半導体レーザーを提供することにある。 An object of the present invention is to provide a multi-quantum well structure semiconductor laser in which optical confinement does not deteriorate even when the thickness of the multi-quantum well structure is reduced, and the threshold current density is therefore smaller than that of the conventional semiconductor laser.
本発明の多重量子井戸構造半導体レーザーは、
第1クラツド層と、該第1クラツド層の上に形成
され前記第1クラツド層よりも小さな禁制帯幅
Eg1を有する第1半導体層と、該第1半導体層の
上に形成された多重量子井戸構造と、該多重量子
井戸構造の上に形成され、Eg1の大きさの禁制帯
幅を有する第2半導体層と、該第2半導体層の上
に形成され前記Eg1よりも大きな禁制帯幅を有す
る第2クラツド層を具備し、前記多重量子井戸構
造内部に、前記Eg1よりも小さな禁制帯幅を有す
る少なくとも2つ以上の量子井戸層と該量子井戸
層の間にはさまれた前記Eg1とほぼ同じ大きさの
禁制帯幅を有するポテンジヤルバリヤー層とを有
する構成となつている。 The multi-quantum well structure semiconductor laser of the present invention includes:
a first cladding layer; a forbidden band formed on the first cladding layer and having a smaller forbidden band width than the first cladding layer;
a first semiconductor layer having E g1 ; a multiple quantum well structure formed on the first semiconductor layer; and a first semiconductor layer formed on the multiple quantum well structure and having a forbidden band width of E g1 . a second cladding layer formed on the second semiconductor layer and having a forbidden band width larger than the E g1 , and a forbidden band smaller than the E g1 inside the multiple quantum well structure. and a potential barrier layer sandwiched between the quantum well layers and having a forbidden band width approximately the same size as E g1 . .
本発明の第1の実施例としてAlGaAs/GaAs
多重量子井戸構造半導体レーザーについて説明す
る。第2図は本実施例の多重量子井戸構造半導体
レーザーの主要部のエネルギーバンドダイヤグラ
ムである。図中、21はn型クラツド層(第1ク
ラツド層、n−Alxn GA1−xnAs,xn≧0.25、
典型的にはxn〜0.4)22は第1半導体層(Alxg
Ga1−xg As,0.1≦xg<xn、典型的にはn−
Al0.2 Ga0.8 As、厚さ30〜1000A)、23は多重
量子井戸構造、24は第2半導体層(AlxgGa1
−xg As、典型的にはP−Al0.2 Ga0.8As 厚さ
30〜1000A)、25はP型クラツド層(第2クラ
ツド層、P−Alxp Ga1−xp As xp≧0.25、典
型的にはxp〜0.4)、26は量子井戸層(層数≧
2、Alxw Gal−xw As,0≦xw<xg、典型的
はノンドープGaAs、厚さ≦200A,27はポテン
シヤルバリヤー層(層数=nw−1,Alxg Ga−
xg As 典型的にはノンドープAl0.2 Ga0.8 As
厚さ≦200A)である。本実施例では、第1及
び第2半導体層とポテンシヤルバリヤー層の組成
が同じために禁制帯幅がこれらの層について全て
同じ大きさとなる。それ故、外側に位置する量子
井戸層26a及び内側に位置する量子井戸層26
bの両方とも全て同じポテンシヤルバリヤー高さ
で囲まれることとなり、これらの量子井戸層26
の間での量子化準位の違いは発生しない。従つ
て、量子化準位の拡がりは従来のものよりも小さ
くなることになり、発光スペクトルが充分狭く低
閾値が実現出来た。又、本構造では、第1及び第
2の半導体層があるため光導波層としての厚みを
多重量子井戸層23よりも大きくすることが出来
る。そのため多重量子井戸構造23の厚みを薄く
した場合にも、第1及び第2半導体層の厚みを最
適化することにより光の閉じ込めを良くすること
が出来る。この様に本実施例の多重量子井戸構造
半導体レーザーにおいては多重量子井戸層の間で
の量子化準位の拡がりが少なくかつ光の閉じ込め
が良いため、従来よりもさらに超低閾値電流密度
を達成することが出来る。 As the first embodiment of the present invention, AlGaAs/GaAs
A multi-quantum well structure semiconductor laser will be explained. FIG. 2 is an energy band diagram of the main parts of the multi-quantum well structure semiconductor laser of this example. In the figure, 21 is an n-type cladding layer (first cladding layer, n-Alxn GA1-xnAs, xn≧0.25,
Typically xn ~ 0.4) 22 is the first semiconductor layer (Alxg
Ga1−xg As, 0.1≦xg<xn, typically n−
Al 0.2 Ga 0.8 As, thickness 30-1000A), 23 is a multiple quantum well structure, 24 is a second semiconductor layer (AlxgGa1
-xg As, typically P-Al 0.2 Ga 0.8 As thickness
30~1000A), 25 is a P-type cladding layer (second cladding layer, P-Alxp Ga1-xp As xp≧0.25, typically xp~0.4), 26 is a quantum well layer (number of layers≧
2, Alxw Gal-xw As, 0≦xw<xg, typically non-doped GaAs, thickness≦200A, 27 is a potential barrier layer (number of layers = nw-1, Alxg Ga-
xg As typically undoped Al 0.2 Ga 0.8 As
Thickness ≦200A). In this embodiment, since the compositions of the first and second semiconductor layers and the potential barrier layer are the same, the forbidden band widths of these layers are all the same. Therefore, the quantum well layer 26a located on the outside and the quantum well layer 26 located on the inside
b are all surrounded by the same potential barrier height, and these quantum well layers 26
No difference in quantization level occurs between the two. Therefore, the spread of the quantization level is smaller than that of the conventional one, and the emission spectrum is narrow enough to realize a low threshold value. Further, in this structure, since there are the first and second semiconductor layers, the thickness of the optical waveguide layer can be made larger than that of the multiple quantum well layer 23. Therefore, even when the thickness of the multi-quantum well structure 23 is reduced, light confinement can be improved by optimizing the thicknesses of the first and second semiconductor layers. In this way, in the multi-quantum well structure semiconductor laser of this example, the spread of the quantization level between the multi-quantum well layers is small and the light confinement is good, so it achieves an even lower threshold current density than the conventional one. You can.
次に製造方法について簡単に述べる。第3図は
第1の実施例の多重量子井戸構造半導体レーザー
において電極構造を全面電極構造とした場合の断
面図である。図中、31はn−GaAs基板、32
はバツフアー層(n−GaAs)、33はキヤツプ
層(P−GaAs)、34はP電極、35はn電極
である。又、図中の21〜25は第2図の説明に
おいて述べた通りである。製造工程はまず最初に
n−GaAs基板31上に、バツフアー層32、n
型クラツド層21、n型ガイド層22、多重量子
井戸構造23、P型ガイド層24、P型クラツド
層25、キヤツプ層33をエピタキシヤル成長す
る。結晶成長法はMBE法、MO−CVD法、VPE
法、LPE法等いずれの成長方法を用いても良い。
次にP電極34及びn電極35を形成してウエハ
ープロセスが完了する。次に、ウエハーから壁開
等を用いてペレツトに切り出してスラム等に取付
け、最後にリード線を取付ける。 Next, the manufacturing method will be briefly described. FIG. 3 is a cross-sectional view of the multi-quantum well structure semiconductor laser of the first embodiment in which the electrode structure is an all-over electrode structure. In the figure, 31 is an n-GaAs substrate, 32
3 is a buffer layer (n-GaAs), 33 is a cap layer (P-GaAs), 34 is a P electrode, and 35 is an n electrode. Further, 21 to 25 in the figure are as described in the explanation of FIG. 2. In the manufacturing process, first, a buffer layer 32 and an n-GaAs substrate 31 are formed on an n-GaAs substrate 31.
A type cladding layer 21, an n-type guide layer 22, a multiple quantum well structure 23, a p-type guide layer 24, a p-type cladding layer 25, and a cap layer 33 are epitaxially grown. Crystal growth methods include MBE, MO-CVD, and VPE.
Any growth method may be used, such as the method or the LPE method.
Next, a P electrode 34 and an n electrode 35 are formed to complete the wafer process. Next, the wafer is cut into pellets using a wall cutter, etc., and attached to a slam or the like, and finally, lead wires are attached.
本実施例の製造方法においては全面電極構造の
電流注入構造において説明したが、これに限らず
プレーナストライプ構造、オキサイドストライプ
構造、プロトン照射ストライプ構造、リツジ導波
構造、埋め込み構造等の他の電流注入構造におい
てもその活性領域に本発明が適用出来ることは明
らかである。又、本実施例においては材料として
AlGaAs/GaAs系を用いたが、これに限らず
InGaAsP/InP,InGaAlAs/InP,InGaAlP/
GaAs、等の他の材料にも本発明が適用出来るこ
とは明らかである。 In the manufacturing method of this embodiment, the current injection structure with a full-surface electrode structure has been described, but the current injection structure is not limited to this, and other current injection structures such as a planar stripe structure, an oxide stripe structure, a proton irradiation stripe structure, a ridge waveguide structure, a buried structure, etc. It is clear that the present invention can be applied to the active region of the structure as well. In addition, in this example, as a material
Although AlGaAs/GaAs system was used, it is not limited to this.
InGaAsP/InP, InGaAlAs/InP, InGaAlP/
It is clear that the present invention is also applicable to other materials such as GaAs.
第1図は従来のAlGaAs/GaAs多重量子井戸
構造半導体レーザーのエネルギーバンドダイヤグ
ラムを示す図である。第2図は本発明の第1の実
施例のAlGaAs/GaAs多重量子井戸構造半導体
レーザーのエネルギーバンドダイヤグラムを示す
図である。第3図は本発明の第1の実施例の
AlGaAs/GaAs多重量子井戸構造半導体レーザ
ーの断面図である。
図中、1……n型クラツド層、2……多重量子
井戸構造、3……P型クラツド層、4……ポテン
シヤルバリヤー層、5……量子井戸層、21……
第1クラツド層(n型クラツド層)、22……第
1半導体層、23……多重量子井戸構造、24…
…第2半導体層、25……第2クラツド層(P型
クラツド層)、26……量子井戸層、27……ポ
テンシヤルバリヤー層、31……n−GaAs基
板、32……バツフアー層、33……キヤツプ
層、34……P電極、35……n電極である。
FIG. 1 is a diagram showing an energy band diagram of a conventional AlGaAs/GaAs multiple quantum well structure semiconductor laser. FIG. 2 is a diagram showing an energy band diagram of the AlGaAs/GaAs multiple quantum well structure semiconductor laser according to the first embodiment of the present invention. FIG. 3 shows the first embodiment of the present invention.
1 is a cross-sectional view of an AlGaAs/GaAs multiple quantum well structure semiconductor laser. In the figure, 1...n-type clad layer, 2...multi-quantum well structure, 3...p-type clad layer, 4...potential barrier layer, 5...quantum well layer, 21...
First cladding layer (n-type cladding layer), 22... first semiconductor layer, 23... multiple quantum well structure, 24...
...Second semiconductor layer, 25...Second cladding layer (P-type cladding layer), 26...Quantum well layer, 27...Potential barrier layer, 31...N-GaAs substrate, 32...Buffer layer, 33... . . . cap layer, 34 . . . P electrode, 35 . . . n electrode.
Claims (1)
形成され前記第1クラツド層よりも小さな禁制帯
幅Eg1を有する第1半導体層と、該第1半導体層
の上に形成された多重量子井戸構造と、該多重量
子井戸構造の上に形成され、Eg1の大きさの禁制
帯幅を有する第2半導体層と、該第2半導体層の
上に形成され前記Eg1よりも大きな禁制帯幅を有
する第2クラツド層を具備し、前記多重量子井戸
構造内部に、前記Eg1よりも小さな禁制帯幅を有
する少なくとも2つ以上の量子井戸層と該量子井
戸層の間にはさまれた前記Eg1とほぼ同じ大きさ
の禁制帯幅を有するポテンシヤルバリヤー層とを
有することを特徴とする多重量子井戸構造半導体
レーザ。1 a first cladding layer, a first semiconductor layer formed on the first cladding layer and having a smaller band gap E g1 than the first cladding layer, and a multilayer semiconductor layer formed on the first semiconductor layer. a quantum well structure, a second semiconductor layer formed on the multi-quantum well structure and having a forbidden band width of E g1 ; and a second semiconductor layer formed on the second semiconductor layer and having a forbidden band width larger than E g1 . a second cladding layer having a band width, sandwiched between the quantum well layer and at least two quantum well layers having a forbidden band width smaller than the E g1 inside the multi-quantum well structure; and a potential barrier layer having a forbidden band width approximately the same size as E g1 .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17074483A JPS6062176A (en) | 1983-09-16 | 1983-09-16 | Multiple quantum well structured semiconductor laser |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17074483A JPS6062176A (en) | 1983-09-16 | 1983-09-16 | Multiple quantum well structured semiconductor laser |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6062176A JPS6062176A (en) | 1985-04-10 |
| JPH0467354B2 true JPH0467354B2 (en) | 1992-10-28 |
Family
ID=15910579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17074483A Granted JPS6062176A (en) | 1983-09-16 | 1983-09-16 | Multiple quantum well structured semiconductor laser |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6062176A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60202980A (en) * | 1984-03-28 | 1985-10-14 | Nippon Telegr & Teleph Corp <Ntt> | Quantum well type semiconductor laser |
| JPS62188393A (en) * | 1986-02-14 | 1987-08-17 | Nec Corp | Semiconductor laser |
-
1983
- 1983-09-16 JP JP17074483A patent/JPS6062176A/en active Granted
Non-Patent Citations (1)
| Title |
|---|
| J.APPL.PHYS=1976 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6062176A (en) | 1985-04-10 |
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